CN107502053A - Pearl ink for glass and preparation method thereof - Google Patents
Pearl ink for glass and preparation method thereof Download PDFInfo
- Publication number
- CN107502053A CN107502053A CN201710774507.6A CN201710774507A CN107502053A CN 107502053 A CN107502053 A CN 107502053A CN 201710774507 A CN201710774507 A CN 201710774507A CN 107502053 A CN107502053 A CN 107502053A
- Authority
- CN
- China
- Prior art keywords
- parts
- pearl ink
- glass
- pearl
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to glass ink technical field, pearl ink of glass and preparation method thereof is particularly used for, wherein pearl ink is made up of 25~40 parts of rosin modified phenolic resins, 5~15 parts of water soluble acrylic resins, 15~25 parts of hydroxyl fluorine silicon resins, 20~30 parts of pearlescent pigments, 15~35 parts of binders, 30~40 parts of solvents, 0.5~2.5 part of defoamer.Compared with prior art, the present invention improves the dispersiveness and dissolubility of resin system by binder and solvent, with good flowability properties and dispersive property, the viscosity of mixed material is controlled simultaneously, make binder not stratified in pearl ink, pearlescent pigment is soaked, pearly-lustre and glossiness are all improved, so that the pearl ink prepared has good printability and full abundant pearl effect concurrently.
Description
Technical field
The present invention relates to glass printing technical field of ink, and in particular to for the pearl ink of glass and its preparation side
Method.
Background technology
Pearl ink is formed by allotments such as pearlescent pigment and link stuffs, pearlescent pigment therein, has unique pearl
Gloss can improve the bright-coloured degree of product color, can also change color colouring effect, be for packages printing, colored printing
New material.
In the prior art, pearl ink is mainly used on the stocks such as wrapping paper, magazine, advertisement poster, textile, due to
Ink is to the poor adhesive force of glass baseplate, so as to be difficult to that pearl ink is applied on glass printing.In addition, current pearly-lustre oil
In printability and its pearl effect there is certain contradiction in ink, can not have superior printability and full abundant simultaneously
Pearl effect.
The content of the invention
Above-mentioned technical problem be present for prior art, it is an object of the invention to provide the pearl ink for glass and
Its preparation method, prepared pearl ink adhesive force is good, can be applied to glass printing, and have good printability concurrently
With full abundant pearl effect.
To achieve the above object, the present invention provides following technical scheme：
Pearl ink for glass is provided, is made up of the raw material of following parts by weight：
Wherein, the glass base glaze is made up of the raw material of following parts by weight：
Preferably, the pearl ink is made up of the raw material of following parts by weight：
Wherein, the glass base glaze is made up of the raw material of following parts by weight：
Preferably, the colouring agent includes at least one of cupric and chromic oxide, zinc oxide and high temperature resistant pearl essence.
It is furthermore preferred that the colouring agent is with weight ratio 3~5 by cupric and chromic oxide, zinc oxide and high temperature resistant pearl essence:
1~2.5:The mixture of 2~4 compositions.
Preferably, the varnish is made up of the raw material of following parts by weight：10~20 parts of turpentine oil, terpinol 10~20
Part, 10~20 parts of rosin resin, 10~20 parts of hydroxyethyl cellulose and 5~15 parts of high boiling organic solvent.
Preferably, the additive is dimethyl silicone polymer and polyoxypropylene ethylene oxide glycerin ether with weight ratio 0.5
~1.5:The mixture of 1~1.5 composition.
The present invention also provides the preparation method of above-mentioned pearl ink, comprises the following steps：
Step b, glass base glaze is prepared：
By formula ratio, the raw material for weighing glass base glaze is put into crucible, melts under 1000~1200 DEG C of high temperature, then make
Its melt liquid is flowed into water, after drying, then is broken into glass dust with gravity and is produced glass base glaze；
Step a, varnish is prepared：
By formula ratio, the raw material of varnish is weighed, container for stirring is invested in and is well mixed, be then heated to 70~80
DEG C, the cold filtration after raw material all dissolving, barreled is stand-by；
Step c, pearl ink is prepared：
By formula ratios, colouring agent and varnish are sequentially added into glass base glaze, stirs, then adds additive,
Continue that mixed material is made after stirring, use ball mill grinding to fineness for 500~800 mesh mixed material, obtain pearl
Ink.
Beneficial effects of the present invention：
The pearl ink for glass of the present invention, is by 25~40 parts of rosin modified phenolic resins, 5~15 parts of water solubilitys
Acrylic resin, 15~25 parts of hydroxyl fluorine silicon resins, 20~30 parts of pearlescent pigments, 15~35 parts of binders, 30~40 parts of solvents,
0.5~2.5 part of defoamer is made.Compared with prior art, had using pearl ink made of the raw material and technique of the present invention
Good adhesive force, the printing available for glass.Employed in raw material rosin modified phenolic resin, water soluble acrylic resin and
Hydroxyl fluorine silicon resin forms resin system, and the dispersiveness and dissolubility of resin system are improved by binder and solvent, is had very
Good flowability properties and dispersive property, while the viscosity of mixed material is controlled, make binder not stratified in pearl ink, it is right
Pearlescent pigment is soaked, and pearly-lustre and glossiness are all improved, so that the pearl ink prepared has good printing concurrently and fitted
Property and full abundant pearl effect.In addition, the preparation technology of the present invention is simple, easily operated, suitable for large-scale production.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1：
For the pearl ink of glass, it is prepared using following steps：
(1) will be mixed in 5 parts of 10 parts of phenolic resin, 15 parts of rosin resin, 15 parts of vegetable oil and mineral oil input agitating devices
Close uniformly, obtain binder, save backup；
(2) by 25 parts of rosin modified phenolic resins, 5 parts of water soluble acrylic resins, 15 parts of hydroxyl fluorine silicon resins and 30 parts
Uniformly mixed in solvent input agitating device, speed of agitator 1200rpm, stir 30min, obtain the first mixed liquor；
(3) 20 parts of pearlescent pigments, the binder of step (1) and 0.5 part of defoamer is sequentially added into the first mixed liquor to throw
Enter in agitating device, speed of agitator 700rpm, stir 40min, adjust to required viscosity, obtain mixed material；
(4) mixed material is ground to scattered, acquisition pearl ink using ball mill.
In step (2), solvent is ethanol and ethyl ester according to weight ratio 1:Mixture made of 1.
Embodiment 2：
For the pearl ink of glass, it is prepared using following steps：
(1) will be mixed in 10 parts of 15 parts of phenolic resin, 10 parts of rosin resin, 10 parts of vegetable oil and mineral oil input agitating devices
Close uniformly, obtain binder, save backup；
(2) by 30 parts of rosin modified phenolic resins, 10 parts of water soluble acrylic resins, 20 parts of hydroxyl fluorine silicon resins and 35 parts
Uniformly mixed in solvent input agitating device, speed of agitator 1250rpm, stir 25min, obtain the first mixed liquor；
(3) 25 parts of pearlescent pigments, the binder of step (1) and 1 part of defoamer input are sequentially added into the first mixed liquor
In agitating device, speed of agitator 750rpm, 35min is stirred, is adjusted to required viscosity, obtain mixed material；
(4) mixed material is ground to scattered, acquisition pearl ink using ball mill.
In step (2), solvent is isopropanol, monoethanolamine and ethyl ester according to weight ratio 1:1:Mixture made of 2.
Embodiment 3：
For the pearl ink of glass, it is prepared using following steps：
(1) will be mixed in 15 parts of 20 parts of phenolic resin, 12 parts of rosin resin, 20 parts of vegetable oil and mineral oil input agitating devices
Close uniformly, obtain binder, save backup；
(2) by 40 parts of rosin modified phenolic resins, 15 parts of water soluble acrylic resins, 25 parts of hydroxyl fluorine silicon resins and 40 parts
Uniformly mixed in solvent input agitating device, speed of agitator 1300rpm, stir 20min, obtain the first mixed liquor；
(3) 30 parts of pearlescent pigments, the binder of step (1) and 2.5 parts of defoamers are sequentially added into the first mixed liquor to throw
Enter in agitating device, speed of agitator 800rpm, stir 30min, adjust to required viscosity, obtain mixed material；
(4) mixed material is ground to scattered, acquisition pearl ink using ball mill.
In step (2), solvent is isopropanol.
Embodiment 4：
For the pearl ink of glass, it is prepared using following steps：
(1) will be mixed in 8 parts of 12 parts of phenolic resin, 20 parts of rosin resin, 12 parts of vegetable oil and mineral oil input agitating devices
Close uniformly, obtain binder, save backup；
(2) by 35 parts of rosin modified phenolic resins, 12 parts of water soluble acrylic resins, 23 parts of hydroxyl fluorine silicon resins and 35 parts
Uniformly mixed in solvent input agitating device, speed of agitator 1300rpm, stir 25min, obtain the first mixed liquor；
(3) 28 parts of pearlescent pigments, the binder of step (1) and 2 parts of defoamer inputs are sequentially added into the first mixed liquor
In agitating device, speed of agitator is 700~800rpm, stirs 30~40min, adjusts to required viscosity, obtains mixed material；
(4) mixed material is ground to scattered, acquisition pearl ink using ball mill.
In step (2), solvent is ethanol, isopropanol, monoethanolamine and ethyl ester according to weight ratio 1:1:1:Mixed made of 1
Thing.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of scope is protected, although being explained with reference to preferred embodiment to the present invention, one of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent substitution, without departing from the reality of technical solution of the present invention
Matter and scope.
Claims (5)
1. the pearl ink for glass, it is characterised in that：It is made up of the raw material of following parts by weight：
2. the pearl ink according to claim 1 for glass, it is characterised in that：The pearl ink is by following weight
The raw material of part is made：
3. the pearl ink according to claim 1 or 2 for glass, it is characterised in that：The binder is by following
The raw material composition of parts by weight：
10~20 parts of phenolic resin
10~20 parts of rosin resin
10~20 parts of vegetable oil
5~15 parts of mineral oil.
4. the pearl ink according to claim 1 or 2 for glass, it is characterised in that：The solvent is ethanol, isopropyl
At least one of alcohol, monoethanolamine and ethyl ester.
5. the preparation method of the pearl ink for glass as described in Claims 1-4 any one, it is characterised in that：Bag
Include following steps：
(1) formula ratio is pressed, rosin modified phenolic resin, water soluble acrylic resin, hydroxyl fluorine silicon resin and solvent input are stirred
Mix in device and uniformly mix, speed of agitator is 1200~1300rpm, stirs 20~30min；
(2) press formula ratio, sequentially add pearlescent pigment, binder and defoamer input agitating device in, speed of agitator be 700~
800rpm, 30~40min is stirred, is adjusted to required viscosity, obtain mixed material；
(3) mixed material is ground to scattered, acquisition pearl ink using ball mill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710774507.6A CN107502053A (en) | 2017-08-31 | 2017-08-31 | Pearl ink for glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710774507.6A CN107502053A (en) | 2017-08-31 | 2017-08-31 | Pearl ink for glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502053A true CN107502053A (en) | 2017-12-22 |
Family
ID=60693362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710774507.6A Pending CN107502053A (en) | 2017-08-31 | 2017-08-31 | Pearl ink for glass and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502053A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753165A (en) * | 2018-06-22 | 2018-11-06 | 东莞市尚艺玻璃制品有限公司 | The preparation method of glass manufacture cover gloss oil and marble grain glass |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011153208A (en) * | 2010-01-27 | 2011-08-11 | Toppan Printing Co Ltd | Ink produced by using pearlescent pigment |
| CN104893409A (en) * | 2015-07-03 | 2015-09-09 | 陈养生 | Light-resistant glass printing ink and preparation method thereof |
| CN105820653A (en) * | 2016-05-12 | 2016-08-03 | 东莞泰升玻璃有限公司 | High-adhesive-force pearlescent silver oil ink for glass and preparing technology |
| CN106118230A (en) * | 2016-07-18 | 2016-11-16 | 佛山市高明绿色德化工有限公司 | A kind of ink being applied on ultrawhite safety glass and preparation method thereof |
-
2017
- 2017-08-31 CN CN201710774507.6A patent/CN107502053A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011153208A (en) * | 2010-01-27 | 2011-08-11 | Toppan Printing Co Ltd | Ink produced by using pearlescent pigment |
| CN104893409A (en) * | 2015-07-03 | 2015-09-09 | 陈养生 | Light-resistant glass printing ink and preparation method thereof |
| CN105820653A (en) * | 2016-05-12 | 2016-08-03 | 东莞泰升玻璃有限公司 | High-adhesive-force pearlescent silver oil ink for glass and preparing technology |
| CN106118230A (en) * | 2016-07-18 | 2016-11-16 | 佛山市高明绿色德化工有限公司 | A kind of ink being applied on ultrawhite safety glass and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 贺英等: "《涂料树脂化学》", 31 August 2007, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108753165A (en) * | 2018-06-22 | 2018-11-06 | 东莞市尚艺玻璃制品有限公司 | The preparation method of glass manufacture cover gloss oil and marble grain glass |
| CN108753165B (en) * | 2018-06-22 | 2020-11-10 | 东莞市尚艺玻璃制品有限公司 | Finishing gloss oil for glass manufacturing and preparation method of marble texture glass |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105504969B (en) | A kind of offset ink and preparation method thereof | |
| CN103992690B (en) | Compound oil ink is printed in novel environment friendly high speed | |
| CN104449030B (en) | Solvent type gravure pearlescent ink and preparation method thereof | |
| CN111363403B (en) | Water-based thin film gravure composite ink and preparation method and application thereof | |
| CN104177917A (en) | Alcohol-soluble environment-friendly high-speed surface printing ink and preparation method thereof | |
| CN101319106A (en) | Hot-set soybean oil resin lithographic plate offset printing ink for rotary machine | |
| CN107502053A (en) | Pearl ink for glass and preparation method thereof | |
| CN103436098B (en) | Ultraviolet-curing offset printing ink and preparation method thereof | |
| CN102702848A (en) | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof | |
| CN103101342A (en) | Thermal transfer printing product printed by offset printing equipment | |
| CN104231731A (en) | Alcohol-soluble high-speed printing ink for PVDC (polyvinyl dichloride) film and preparation method of alcohol-soluble high-speed printing ink | |
| CN102732097B (en) | Method for preparing aluminum foil ink | |
| CN1392203B (en) | Engraved intaglo printing pearlite ink and producing technology | |
| CN107286731A (en) | A kind of gravure aqueous, environmental protective ink | |
| CN103923526B (en) | Semi-transparent grey environment-friendly ink | |
| CN103031021B (en) | Soy protein resin water-based gravure oil ink and preparation method thereof | |
| CN104312268A (en) | Environment-friendly printing ink with high adhesive force | |
| CN104559471A (en) | Blending modified polyacrylic ester printing ink | |
| CN105111819B (en) | A kind of intaglo printing pearlite ink and preparation method thereof | |
| CN110028806A (en) | A kind of water-based ink of PVC coloured silk film easily disperses red pigment and preparation method | |
| CN103923521B (en) | The preparation method of semi-transparent grey environment-friendly ink | |
| CN104559444B (en) | One kind printing simulating golden colour ink formulations and preparation method thereof | |
| CN107881809A (en) | A kind of preparation method of roseleaf powder print paste | |
| CN105713451A (en) | Benzene-free environment-friendly high-tolerance gravure ink | |
| CN115725228B (en) | Online roller coating UV matte environment-friendly surface oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 523000 No.8, Daji Industrial Zone, Shipai Avenue, Shipai town, Dongguan City, Guangdong Province Applicant after: Guangdong Xingxing Optoelectronics Technology Co., Ltd. Address before: 523330 Guangdong Province, Dongguan City Shipai town Shipai Road Industrial Zone No. 8 Keelung Applicant before: Guangdong Sinz Optoelectronic Technology Co., Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171222 |