CN105001711A - Preparation method for ink added with disproportionated rosin resin - Google Patents

Abstract

The invention discloses a preparation method for ink added with disproportionated rosin resin. Some acids in common rosin resin contain conjugation double bonds, and the rosin resin is added into ink. Due to the fact that the rosin resin is not stable and prone to oxidation, the stability of the ink is lowered. Due to the fact that the disproportionated rosin resin is added in the ink preparation process, the bonding strength of the ink is improved, the stability is good, and meanwhile the ink has the emulsifying effect and has the good application prospect.

Description

A kind of ink preparation method adding nilox resin resin

Technical field

The present invention relates to a kind of novel ink, particularly a kind of environment-friendlyink ink and preparation method thereof, belong to ink chemical field.

Summary of the invention

Along with the development of press, ink application is also increasingly extensive, output constantly increases, China's ink industry in 2010 is produced and is reached all-time high, " Chinese ink industry production and marketing demand and investment forecasting analysis report are looked forward to the prospect " adds up, whole nation ink gross annual output amount amounts to 58.99 ten thousand tons, accounts for 14% of the whole world, exceedes Germany first, Japan occupies the second in the world.

Ink is a kind of to be mixed equably by pigment, low-melting ink vehicle and auxiliary agent etc. and through the gluey fluid of a kind of viscosity of repeat-rolling.In China, what ink production was produced substantially is traditional synthetic resins ink, containing the high point petroleum solvent of 35% ~ 40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and 3,4-benzo pyrroles, 3-nitro benzo ketone etc. are wherein also containing carcinogenic components, on printed matter, residual quantity is large, the survival time is long, can endanger user's health, is also the important source of pollution in Printing ink producing process simultaneously.Along with the attention degree of environmental protection is increasing, the reinforcement of Green Packaging concept, have the regulation limitations such as heavy metal content, packing material solvent residues amount and other VOC limit standard in other related fields such as food product pack especially, exploitation non-toxic ink is the study hotspot of current ink.

Solvent is made with vegetables oil, not only environmental protection but also the resource of available regenerative replaced non-renewable petroleum solvent to the ink of preparation, and when reclaiming, than traditional ink, deinking is easier to useless printed matter process, little to the damage of paper, but vegetable oil solvent adhesive power is not strong, preparing in ink process by adding Gum Rosin, the viscosity of ink can be increased, improve the bonding strength of ink.Some acid in rosin is containing conjugated double bond, therefore reactivity is higher, unstable, oxidizable.Nilox resin is in the presence of a catalyst, by means of mineral acid and hot effect, make a part for rosin oxidized, another part is reduced, and namely there occurs the product of disproportionation reaction, add polymeric rosin resin preparing in ink process, as tackifying resin, ink adhesion intensity can be improved, and stability is good, also play the effect of emulsification simultaneously, there is good application prospect.

Summary of the invention

The invention provides a kind of preparation method adding nilox resin resin ink, this preparation method carries out as follows:

With one dispersion cylinder load 20% water, 25% vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and 1% soybean lecithin wetting agent;

(2) press the rotating speed of 500-600 r/min, dispersed 1-2 hour;

(3) after dispersion, by liquid filtering;

(4) collect the emulsion of filtration, then pour in dispersion cylinder, add the water soluble acrylic resin of 25%, the nilox resin resin of 3%, the water soluble acrylic acid mill base of 10% successively, by the rotating speed of 600-800r/min, dispersed 2-4 hour;

(5) filter after finally adding the silicone antifoam agent of 0.5%, a kind of interpolation nilox resin resin ink.

The present invention has following advantages and characteristic:

(1) this ink adhesion intensity is good;

(2) the Gum Rosin good stability added;

(3) raw material sources are extensive, with low cost.

Embodiment

Embodiment one:

The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 500 r/min, dispersed 2 hours, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the nilox resin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 600 r/min, dispersed 4 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation nilox resin resin ink.

Embodiment two:

The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 600 r/min, dispersed 1 hour, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the nilox resin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 600 r/min, dispersed 4 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation nilox resin resin ink.

Embodiment three:

The water of 20% is loaded by a dispersion cylinder, 25% part of vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and the soybean lecithin wetting agent of 1%, by the rotating speed of 500 r/min, dispersed 2 hours, after being uniformly dispersed, by liquid filtering, the emulsion of filtering is put in dispersion cylinder more again, add the water soluble acrylic resin of 25% successively, the nilox resin resin of 3%, the water soluble acrylic acid mill base of 10%, by the rotating speed of 800 r/min, dispersed 2 hours, filter after finally adding the silicone antifoam agent of 0.5 part, a kind of interpolation nilox resin resin ink.

Claims (1)

1. add an ink preparation method for nilox resin resin, the method comprises the steps:

With one dispersion cylinder load 20% water, 25% vegetables oil, the thanomin of 15%, the silicone antifoam agent of 0.5% and 1% soybean lecithin wetting agent;

(2) press the rotating speed of 500-600 r/min, dispersed 1-2 hour;

(3) after dispersion, by liquid filtering;

(4) collect the emulsion of filtration, then pour in dispersion cylinder, add the water soluble acrylic resin of 25%, the nilox resin resin of 3%, the water soluble acrylic acid mill base of 10% successively, by the rotating speed of 600-800r/min, dispersed 2-4 hour;

(5) filter after finally adding the silicone antifoam agent of 0.5%, a kind of interpolation nilox resin resin ink.