CN107523125A - A kind of cashew nut shell oil type ink adhesive and its ink composite - Google Patents
A kind of cashew nut shell oil type ink adhesive and its ink composite Download PDFInfo
- Publication number
- CN107523125A CN107523125A CN201710653360.5A CN201710653360A CN107523125A CN 107523125 A CN107523125 A CN 107523125A CN 201710653360 A CN201710653360 A CN 201710653360A CN 107523125 A CN107523125 A CN 107523125A
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- CN
- China
- Prior art keywords
- cashew nut
- nut shell
- shell oil
- type ink
- oil type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/32—Chemically modified polycondensates by organic acids or derivatives thereof, e.g. fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of cashew nut shell oil type ink adhesive and its ink composite, and by weight, the cashew nut shell oil type ink adhesive includes following components：First 35 45 parts of resin, 3 10 parts of the second resin, 0 30 parts of vegetable oil, 20 40 parts of cashew nut shell oil, 5 20 parts of mineral oil, 0.3 1.5 parts of alumina gel agent, 0.1 1 parts of antioxidant.The ink composite of described cashew nut shell oil type ink adhesive is included, by weight, including following components：55 75 parts of cashew nut shell oil type ink adhesive, 10 25 parts of pigment, 5 15 parts of ink oil, 15 parts of auxiliary agent.Glossiness is high after the ink product film forming of the present invention, and pigment wettability is good, and drying property is excellent, and production cost is relatively low, belongs to environmental type product, is adapted to large-scale production and promotes.
Description
Technical field
The present invention relates to technical field of ink, and in particular to a kind of cashew nut shell oil type ink adhesive and its ink combination
Thing.
Background technology
With the deterioration of environment, in the world, people are grown to even greater heights for the cry of environmental protection, especially in print line
In industry, environmental requirement for printed matter also more and more higher.In present printing industry, Soybean Oil Ink has been obtained for printing
Brush the accreditation of factory and be widely used.So-called Soybean Oil Ink refers to soybean oil content >=20% in ink formulations, soybean
Oil is semi-drying oil, if only using soybean oil as vegetable oil solvent, ink is difficult to reach normal dry speed on paper
Degree, and then cause product various abnormal printings occur, such as drag flower, viscous flower etc..So when preparing ink adhesive, one
As can arrange in pairs or groups dry vegetable oil use, improve its drying property.
From the point of view of current whole market situation, improve the feature of environmental protection, reduce the theme that cost is future market.Each ink
The scheme that manufacturer uses is exactly that cheap Petropols are introduced in ink adhesive, but not only smell is big for Petropols,
And contain more aromatic hydrocarbon, thus disagreed with present green printing, be unfavorable for promoting.
The content of the invention
The problem of existing for prior art, the invention provides a kind of cashew nut shell oil type ink adhesive and its ink group
Compound.
The present invention prepares ink adhesive using the cashew nut shell oil of low cost and belongs to industry forefront.Present invention price simultaneously
Cheap cashew nut shell oil substitutes dry vegetable oil (or reduce as far as possible and use vegetable oil), ensure that the drying property of binder
Meanwhile reduce the cost of binder.Therefore, wide market, the market risk are small.
The main component of cashew nut shell oil of the present invention is anacardol, and anacardol also has because of its special chemical constitution
There are following characteristics：
1. containing benzene ring structure, film forming gloss can be improved；
2. the hydroxyl of polarity can provide wetting and activity of the system to contact surface；
3. carbon 15 straight chain of the meta containing unsaturated double-bond, good toughness, excellent hydrophobicity and low can be provided for system
Permeability and from dryness.
The present invention is using cashew nut shell oil, vegetable oil, mineral oil, phenol-formaldehyde resin modified, alkyd resin, alumina gel agent, antioxygen
Agent prepares ink adhesive by high temperature polymerization reaction.
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described first resin is rosin modified phenolic resin, and it is synthesized by paraformaldehyde, aldehydes matter and polyalcohol.
The boiling range of the mineral oil is 250~320 DEG C, and the mineral oil in the range of this boiling range can preferably adapt to cashew nut shell oil system,
The pigment wettability of ink is improved, the mineral oil is that oil extracts mineral oil.
Further, the aldehydes matter be to tert-octylphenol, n nonylphenol, tert-butyl phenol, in dodecylphenol
One or more.
Further, the polyalcohol is glycerine and/or pentaerythrite.
Further, acid number≤50mgKOH/g of first resin；It is further preferred that the acid of first resin
It is worth for 10-50mgKOH/g.
Further, second resin is alkyd resin, its acid number≤50mgKOH/g；It is further preferred that described
The acid number of two resins is 10-50mgKOH/g.
Further, the vegetable oil is dryness or semi-drying vegetable oils, and it is included in tung oil, linseed oil, soybean oil
It is one or more.
Further, iodine number >=150g/100g of the cashew nut shell oil, its iodine number is suitable with dry vegetable oil, is advantageous to
The normal drying of ink.
Further, the alumina gel agent is AO-03 or NT-03 alumina gel agent.
Further, the antioxidant is BHT, DBHQ or HS09 type antioxidant.
A kind of ink composite for including described cashew nut shell oil type ink adhesive, by weight, including with the following group
Point：
The ink oil can be commercially available routine without aromatic solvent.
The auxiliary agent includes the one or more in pH adjusting agent, auxiliary rheological agents, defoamer.
Further, the pH adjusting agent is hydramine type organic.The pH adjusting agent can effective regulation system acid
Base number, and assign system good pH stability, there is no adverse reaction with resin, it is opposite that there is auxiliary dissolution, Ke Yifu
Give the water-thinned and good printing adaptability that ink is excellent.
Further, the hydramine type organic is monoethanolamine, diethanol amine, triethanolamine, dimethylethanolamine, second
One or more in glycol amine, propane diols amine.
Further, the auxiliary rheological agents are PPG and/or polyether-polyurethane.The auxiliary rheological agents have efficient
Rheology efficiency, preferable rheological characteristic, sag resistance and anti-settling are produced with efficient combine such as ink matrix resin, can be in life
Any stage addition of production process, is not influenceed by ink system pH value, will not also produce any harmful effect.
The PPG is preferably more than one or both of polyethylene glycol, polypropylene glycol and polytetramethylene glycol mixed
Compound.The PPG can be prepared by the addition reaction of low-molecular-weight diol and cycloalkane, can also be opened by cycloalkane
It is prepared by cyclopolymerization.The polyether-polyurethane can be by polyethylene glycol, polyoxypropyleneglycol, PPOX triol and isocyanic acid
It is prepared by ester reaction.
Further, the defoamer is modified polyalcohol and/or HMW alcohols material.It is further preferred that institute
Modified polyalcohol is stated by 50 parts of acetylenic glycols, 40 parts of alcohol-water mixture, 10 parts of organic amine compound, at a temperature of 50-80 DEG C, is stirred
Mixing scattered 10-30 minutes is made；Described acetylenic glycols be 1,4- butynediols, 2,5- dimethyl -3- hexins glycol, 2- methyl -
One or more in 3- butynediols, dimethylhexyne glycol；The ratio of alcohol is 40-70% in the alcohol-water mixture, its
In alcohol be one or more in ethanol, isopropanol, isobutanol；The organic amine compound be monoethanolamine, diethanol amine,
One or more in triethanolamine, dimethylethanolamine, ethylene glycol amine, propane diols amine；The HMW alcohols material is
One or more in tridecanol, tetradecyl alchohol, pentadecanol, hexadecanol.
The defoamer can be preferable with the compatibility of the other materials of system, can provide long-term defoaming effect, will not produce
The bad problem of the printing such as raw flake, pin hole.
Beneficial effects of the present invention：
(1) present invention uses the cheap cashew nut shell oil of cost as raw material, instead of the higher soybean oil of cost and part ore deposit
Thing oil, reduces binder and the cost of ink；
(2) iodine number for the cashew nut shell oil that the present invention uses is suitable with dry vegetable oil, is advantageous to accelerate the drying of ink；
(3) cashew nut shell oil that the present invention uses is different from the structure of other drying oil, and the structure of cashew nut shell oil is advantageous to carry
Gloss after high film forming, and other drying oil can not realize equivalent effect；
(4) for the present invention due to containing cashew nut shell oil, it has unique design feature, has more more preferable than common drying oil
Pigment wettability.
Embodiment
In order to preferably explain the present invention, it is described further in conjunction with specific examples below, but the present invention is unlimited
In specific embodiment.
Embodiment 1
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described rosin modified phenolic resin synthesizes by paraformaldehyde, to tert-octylphenol and glycerine；The mineral oil
Boiling range be 250~320 DEG C；Iodine number >=150g/100g of the cashew nut shell oil.
A kind of ink composite of the cashew nut shell oil type ink adhesive comprising the present embodiment, by weight, including with
Lower component：
Embodiment 2
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described rosin modified phenolic resin is synthesized by paraformaldehyde, n nonylphenol and pentaerythrite；The mineral oil
Boiling range be 250~320 DEG C；Iodine number >=150g/100g of the cashew nut shell oil.
A kind of ink composite of the cashew nut shell oil type ink adhesive comprising the present embodiment, by weight, including with
Lower component：
Embodiment 3
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described rosin modified phenolic resin is synthesized by paraformaldehyde, tert-butyl phenol and glycerine；The mineral oil evaporates
Journey is 250~320 DEG C；Iodine number >=150g/100g of the cashew nut shell oil.
A kind of ink composite of the cashew nut shell oil type ink adhesive comprising the present embodiment, by weight, including with
Lower component：
Comparative example 1
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described rosin modified phenolic resin to tert-octylphenol and glycerine by synthesizing；The boiling range of the mineral oil is
250~320 DEG C.
A kind of ink composite of the cashew nut shell oil type ink adhesive comprising the present embodiment, by weight, including with
Lower component：
Comparative example 2
A kind of cashew nut shell oil type ink adhesive, by weight, including following components：
Wherein described rosin modified phenolic resin synthesizes by paraformaldehyde, to tert-octylphenol and glycerine；The mineral oil
Boiling range be 320~400 DEG C.
A kind of ink composite of the cashew nut shell oil type ink adhesive comprising the present embodiment, by weight, including with
Lower component：
Performance detection：Viscosity is determined using sticky instrument, and mobility is determined using parallel plate viscometer, and drying time is using dry
Dry instrument measure.
Gloss：The brightness of printed matter is represented, numerical value more high glaze is higher.
Drying time：The time that printed matter is thoroughly dried is represented, the time is more short better.
(rosin modified phenolic resin is by Te Xinji benzene than common soybeans oil type ink, comparative example 1 for ink product of the present invention
Phenol and glycerine synthesis) and comparative example 2 (boiling range of mineral oil be 320~400 DEG C) ink mobile performance it is more preferable, drying time
Shorter, glossiness is more preferable after film forming, and color density is higher, and therefore, ink product of the present invention can more meet and adapt to market and client
Requirement, and cost substantially reduces, and is adapted to promote the use of.
The specific embodiment of the present invention is the foregoing is only, is not intended to limit the scope of the invention, every utilization
The equivalent transformation that the present invention makees, or other related technical fields are directly or indirectly used in, similarly it is included in the present invention's
Among scope of patent protection.
Claims (10)
- A kind of 1. cashew nut shell oil type ink adhesive, it is characterised in that by weight, including following components：Wherein described first resin is rosin modified phenolic resin, and it is synthesized by paraformaldehyde, aldehydes matter and polyalcohol；It is described The boiling range of mineral oil is 250~320 DEG C.
- 2. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the aldehydes matter is to special pungent Base phenol, n nonylphenol, tert-butyl phenol, to the one or more in dodecylphenol.
- 3. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the polyalcohol be glycerine and/ Or pentaerythrite.
- 4. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the acid number of first resin≤ 50mgKOH/g。
- 5. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that second resin is alkyd tree Fat, its acid number≤50mgKOH/g.
- 6. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the vegetable oil is dryness or half Dry vegetable oil, it includes the one or more in tung oil, linseed oil, soybean oil.
- 7. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the iodine number of the cashew nut shell oil >= 150g/100g。
- 8. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the alumina gel agent is AO-03 Or NT-03 alumina gel agent.
- 9. cashew nut shell oil type ink adhesive according to claim 1, it is characterised in that the antioxidant is BHT, DBHQ Or HS09 type antioxidant.
- 10. a kind of ink composite of the cashew nut shell oil type ink adhesive comprising any one of claim 1-9, it is special Sign is, by weight, including following components：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710653360.5A CN107523125A (en) | 2017-08-02 | 2017-08-02 | A kind of cashew nut shell oil type ink adhesive and its ink composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710653360.5A CN107523125A (en) | 2017-08-02 | 2017-08-02 | A kind of cashew nut shell oil type ink adhesive and its ink composite |
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|---|---|
| CN107523125A true CN107523125A (en) | 2017-12-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710653360.5A Pending CN107523125A (en) | 2017-08-02 | 2017-08-02 | A kind of cashew nut shell oil type ink adhesive and its ink composite |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112867280A (en) * | 2021-02-26 | 2021-05-28 | 浙江柳市线路板有限公司 | Solder mask process of double-sided circuit board |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
-
2017
- 2017-08-02 CN CN201710653360.5A patent/CN107523125A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
Non-Patent Citations (1)
| Title |
|---|
| 俞进福等: ""漆画数字化与实现技术研究"", 《闽江学院报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112867280A (en) * | 2021-02-26 | 2021-05-28 | 浙江柳市线路板有限公司 | Solder mask process of double-sided circuit board |
| CN112867280B (en) * | 2021-02-26 | 2022-07-01 | 浙江柳市线路板有限公司 | Solder mask process of double-sided circuit board |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171229 |