CN109735166A - A kind of aqueous pre-impregnated paper and the general printing ink of PVC and its synthesis technology - Google Patents
A kind of aqueous pre-impregnated paper and the general printing ink of PVC and its synthesis technology Download PDFInfo
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- CN109735166A CN109735166A CN201910115861.7A CN201910115861A CN109735166A CN 109735166 A CN109735166 A CN 109735166A CN 201910115861 A CN201910115861 A CN 201910115861A CN 109735166 A CN109735166 A CN 109735166A
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Abstract
The present invention provides a kind of aqueous pre-impregnated papers and the general printing ink of PVC, it is characterized by: according to the mass fraction, including following raw material: 30 parts of -50 parts of hydroxyl acrylic emulsion resins, water soluble acrylic resin's solution that 10 parts of -15 parts of mass fractions are 35%, 30 parts of -50 parts of water-based hydroxyl polyurethane resin liquid, enough organic amines, 5 parts of -10 parts of dispersant B YK-190, 2 parts of wetting agent Dynol-604, 0.5 part of defoaming agent Tego-902, several pieces deionized water, 17.3 part butyl glycol ether, 40 parts of toners, 0.3 part of -0.6 part of wetting agent Tego-270, 0.4 part of levelling agent, 0.3 part of anti skinning agent, 0.2 part of -0.5 part of defoaming agent, 4 parts of -6 parts of Blocked Isocyanate Curing Agents, 1 part of water Property antioxidant.The invention has the advantages that: 1) production processes and use process, and solvent usage amount is greatly reduced, and avoids security risk existing for production and use process；2) production and the discharge of use process VOC free；3) using the pre-impregnated paper printed of the present invention and PVC almost odorlessness, meet environmental requirement；4) good ink adhesion.
Description
Technical field
The present invention relates to pre-impregnated paper and PVC print field more particularly to a kind of aqueous pre-impregnated paper and the general printings of PVC
Ink and its synthesis technology.
Background technique
Existing pre-impregnated paper and PVC printing ink have following defects that 1) existing solvent based printing inks largely use
Solvent, there are security risk and not environmentally；2) since pre-impregnated paper and PVC are non-absorbent material, existing water-based printing oil
Ink not can be used directly in pre-impregnated paper and PVC, and Technological adaptability is poor；3) existing water-based printing ink is generally to pre-impregnated paper
There is no preferable adhesive force with PVC, printing effect is poor.
Summary of the invention
In order to solve the problems mentioned above in the background art, the present invention provides a kind of aqueous pre-impregnated paper and PVC are logical
With printing ink, it is characterised in that: according to the mass fraction, including following raw material: 30 parts of -50 parts of hydroxyl acrylic emulsion resins,
Water soluble acrylic resin's solution that 10 parts of -15 parts of mass fractions are 35%, 30 parts of -50 parts of water-based hydroxyl polyurethane resin liquid,
It is enough organic amines, 5 parts of -10 parts of dispersant B YK-190,2 parts of wetting agent Dynol-604,0.5 part of defoaming agent Tego-902, several
Part deionized water, 17.3 parts of butyl glycol ethers, 40 parts of toners, 0.3 part of -0.6 part of wetting agent Tego-270,0.4 part of levelling agent,
0.3 part of anti skinning agent, 0.2 part of -0.5 part of defoaming agent, 4 parts of -6 parts of Blocked Isocyanate Curing Agents, 1 part of aqueous antioxidant.
A kind of synthesis technology of the aqueous pre-impregnated paper and the general printing ink of PVC, it is characterised in that: press mass fraction
Meter, includes the following steps:
Step 1): varnish is prepared
1. by the mixing of 0.2 part of organic amine AMP-95 and 4.8 parts of deionized waters；
2. the water-soluble acrylic for being 35% by 30 parts of -50 parts of hydroxyl acrylic emulsion resins, 10 parts of -15 parts of mass fractions
Resin solution mixes；
3. after the solution 1. and 2. obtained in the step 1) is mixed, 30 parts of -50 parts of water-based hydroxyl polyurethane trees are added
Rouge liquid is dispersed 15 minutes with the mixing speed of 400r/min-500r/min in dispersion machine, obtains varnish；
Step 2): mill base is prepared
Successively by 5 parts of -10 parts of dispersant B YK-190,2 parts of wetting agent Dynol-604,0.5 part of defoaming agent Tego-902,30
Part deionized water, 17.3 parts of butyl glycol ethers mix, and 40 parts of toners are added, with 1000r/min-1200r/ in dispersion machine
The mixing speed dispersion of min grinding 40 minutes, obtains mill base；
Step 3): the preparation hot compound oil ink of PVC
Mill base that varnish that 75 parts of steps 1) obtain, 20 parts of steps 2) are obtained, 0.3 part of -0.6 part of wetting
Agent Tego-270,0.4 part of levelling agent, 0.3 part of anti skinning agent, 0.2 part of -0.5 part of defoaming agent, 4 parts of -6 parts of blocked isocyanates
After curing agent, 1 part of aqueous antioxidant mixing, disperse 10 points in dispersion machine with the mixing speed of 150r/min-200r/min
Clock obtains the hot compound oil ink of PVC.
The beneficial effects of the present invention are: 1) solvent usage amount is greatly reduced in production process and use process, production is avoided
With security risk existing for use process；2) production process and the discharge of use process VOC free；3) preimpregnation printed using the present invention
Stain paper and PVC almost odorlessness, meet environmental requirement；4) good ink adhesion.
Specific embodiment
The embodiment of the present invention is described in detail below, so that advantages and features of the invention can be easier to by ability
Field technique personnel understanding, so as to make a clearer definition of the protection scope of the present invention.
Embodiment 1
A kind of aqueous pre-impregnated paper and the general process black ink of PVC, including following raw material: 30g hydroxyl acrylic emulsion
Resin, water soluble acrylic resin's solution that 15g mass fraction is 35%, 50g waterborne polyurethane resin, enough organic amines, 10g
Dispersant B YK-190,2g wetting agent Dynol-604,0.5g defoaming agent Tego-902, several pieces deionized water, 17.3g ethylene glycol
Butyl ether, 40g carbon black, 0.6g wetting agent Tego-270,0.4g levelling agent, 0.3g anti skinning agent, 0.2g defoaming agent, 4.5g enclosed type
Isocyanate curing agent, 1g aqueous antioxidant.
A kind of synthesis technology of the aqueous pre-impregnated paper and the general process black ink of PVC, includes the following steps:
Step 1): varnish is prepared
1. by the mixing of 0.2g organic amine AMP-95 and 4.8g deionized water；
2. by 30g water based acrylic resin (Basf Joncryl 7266), 15g mass fraction be 35% it is water-soluble
Property acrylic resin (Hanwha Soluryl60) solution mix；
3. after the solution 1. and 2. obtained in the step 1) is mixed, 50g waterborne polyurethane resin liquid (Stahl is added
Relca PU-406), dispersed 15 minutes in dispersion machine with the mixing speed of 500r/min, obtains varnish；
Step 2): preparation black slurry
Successively by 10g dispersant B YK-190,2g wetting agent Dynol-604,0.5g defoaming agent Tego-902,30g deionization
Water, 17.3g butyl glycol ether mix, and add 40g carbon black, 20g zirconium pearl, with the mixing speed of 1200r/min in dispersion machine
Dispersion grinding 40 minutes, filters zirconium pearl, obtains black slurry；
Step 3): the preparation hot composite black ink of PVC
Black slurry that step 2) described in varnish that step 1) described in 75g obtains, 20g is obtained, 0.6g wetting agent Tego-
270,0.4g levelling agent, 0.3g anti skinning agent, 0.2g defoaming agent, 4.5g Blocked Isocyanate Curing Agents, 1g are aqueous anti-oxidant
After agent mixing, is dispersed 10 minutes in dispersion machine with the mixing speed of 200r/min, obtain the hot composite black ink of PVC.
The performance test results of embodiment 1 are as follows:
| Test item | Test result | Test method |
| Ink fineness | 50nm-150nm | Fineness plate and laser particle instrument detection |
| Practical print speed printing speed | Conventional 4 color overprinting machines, 70 meter per seconds | Actual measurement |
| Finished product ink adhesion | Well, it does not fall the effect of ink | It is torn after 3M tape-stripping |
| The test of PET overlay film | Well, overlay film can not be removed | Full-automatic laminating machine actual measurement |
| Ageing-resistant test | 1 week without obvious jaundice | Ultraviolet light and aging 1 week |
| Storage stability test | Without viscosity and cosmetic variation | 20 DEG C with 50 DEG C recycling storage one week |
| Resistance to ethanol test | Without precipitating without condensation, normally | 70% dilutes again with 95% alcohol list |
Common ink and 1 comparing result of embodiment are as follows:
| Project | Common ink | Embodiment 1 |
| Synthesize the solvent usage amount of 1Kg ink | 700g-800g | 30g-50g |
| VOC content | 700PPM-800PPM | 30PPM-50PPM |
| Smell characterization | Obvious smell | Extremely low smell |
The above the performance test results and the comparing result surface present invention have the advantage that: 1) production process and use process
Solvent usage amount is greatly reduced, avoids security risk existing for production and use process；2) production process and use process without
VOC emission；3) using the pre-impregnated paper printed of the present invention and PVC almost odorlessness, meet environmental requirement；4) good ink is attached
Put forth effort.
The foregoing description of the disclosed embodiments, only for can be realized professional and technical personnel in the field or use this
Invention.Various modifications to these embodiments will be readily apparent to those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention will not be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (2)
1. a kind of aqueous pre-impregnated paper and the general printing ink of PVC, it is characterised in that: according to the mass fraction, including following raw material:
30 parts of -50 parts of hydroxyl acrylic emulsion resins, water soluble acrylic resin's solution that 10 parts of -15 parts of mass fractions are 35%, 30
Part -50 parts of water-based hydroxyl polyurethane resin liquid, enough organic amines, 5 parts of -10 parts of dispersant B YK-190,2 parts of wetting agent Dynol-
604,0.5 part of defoaming agent Tego-902, several pieces deionized water, 17.3 parts of butyl glycol ethers, 40 parts of toners, 0.3 part -0.6 part
Wetting agent Tego-270,0.4 part of levelling agent, 0.3 part of anti skinning agent, 0.2 part of -0.5 part of defoaming agent, 4 parts of -6 parts of enclosed type isocyanides
Acid esters curing agent, 1 part of aqueous antioxidant.
2. the synthesis technology of a kind of aqueous pre-impregnated paper described in claim 1 and the general printing ink of PVC, it is characterised in that:
According to the mass fraction, include the following steps:
Step 1): varnish is prepared
1. by the mixing of 0.2 part of organic amine AMP-95 and 4.8 parts of deionized waters；
2. the water soluble acrylic resin for being 35% by 30 parts of -50 parts of hydroxyl acrylic emulsion resins, 10 parts of -15 parts of mass fractions
Solution mixes；
3. after the solution 1. and 2. obtained in the step 1) is mixed, 30 parts of -50 parts of water-based hydroxyl polyurethane resin liquid are added,
Dispersed 15 minutes in dispersion machine with the mixing speed of 400r/min-500r/min, obtains varnish；
Step 2): mill base is prepared
Successively 5 parts of -10 parts of dispersant B YK-190,2 parts of wetting agent Dynol-604,0.5 part of defoaming agent Tego-902,30 parts are gone
Ionized water, 17.3 parts of butyl glycol ethers mix, and 40 parts of toners are added, with 1000r/min-1200r/min's in dispersion machine
Mixing speed dispersion grinding 40 minutes, obtain mill base；
Step 3): the preparation hot compound oil ink of PVC
Mill base, 0.3 part of -0.6 part of wetting agent that varnish that 75 parts of steps 1) obtain, 20 parts of steps 2) are obtained
Tego-270,0.4 part of levelling agent, 0.3 part of anti skinning agent, 0.2 part of -0.5 part of defoaming agent, 4 parts of -6 parts of blocked isocyanates are solid
After agent, 1 part of aqueous antioxidant mixing, dispersed 10 minutes in dispersion machine with the mixing speed of 150r/min-200r/min,
Obtain the hot compound oil ink of PVC.
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| CN201910115861.7A CN109735166A (en) | 2019-02-15 | 2019-02-15 | A kind of aqueous pre-impregnated paper and the general printing ink of PVC and its synthesis technology |
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Cited By (4)
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| CN111334125A (en) * | 2020-04-22 | 2020-06-26 | 德化县新高圣包装彩印有限公司 | High-water-resistance environment-friendly water-based ink and preparation method thereof |
| CN115141512A (en) * | 2022-08-30 | 2022-10-04 | 山东东宇鸿翔装饰材料有限公司 | Water-based ink for pre-impregnated paper intaglio printing and synthesis process thereof |
| CN115584162A (en) * | 2022-11-23 | 2023-01-10 | 山东东宇鸿翔柜橱材料有限公司 | Water-based ink for gravure printing of PVC (polyvinyl chloride) seal strip and synthesis process thereof |
| CN115928494A (en) * | 2022-12-29 | 2023-04-07 | 福建省闽清双棱纸业有限公司 | High-wear-resistance impregnated paper and preparation method thereof |
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| CN115584162A (en) * | 2022-11-23 | 2023-01-10 | 山东东宇鸿翔柜橱材料有限公司 | Water-based ink for gravure printing of PVC (polyvinyl chloride) seal strip and synthesis process thereof |
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| CN115928494A (en) * | 2022-12-29 | 2023-04-07 | 福建省闽清双棱纸业有限公司 | High-wear-resistance impregnated paper and preparation method thereof |
| CN115928494B (en) * | 2022-12-29 | 2024-01-30 | 福建省闽清双棱纸业有限公司 | High-wear-resistance impregnated paper and preparation method thereof |
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Effective date of registration: 20200429 Address after: 276000 Kuang Keng Zhen Tang Lin Cun, Lanling County, Linyi City, Shandong Province Applicant after: Linyi Jiangyuan decoration materials Co., Ltd Address before: 276000 west section of Dashan Road, Lanshan District, Linyi City, Linyi City, Shandong Province Applicant before: LINYI LUYUAN IMPREGNATED PAPER Co.,Ltd. |
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Application publication date: 20190510 |