CN103666075A - UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink - Google Patents
UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink Download PDFInfo
- Publication number
- CN103666075A CN103666075A CN201310618312.4A CN201310618312A CN103666075A CN 103666075 A CN103666075 A CN 103666075A CN 201310618312 A CN201310618312 A CN 201310618312A CN 103666075 A CN103666075 A CN 103666075A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- curing
- curing performance
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- 238000001723 curing Methods 0.000 title abstract description 15
- 238000003848 UV Light-Curing Methods 0.000 title abstract 4
- 239000000843 powder Substances 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229920000728 polyester Polymers 0.000 claims abstract description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 7
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- 229920001971 elastomer Polymers 0.000 claims abstract description 4
- 239000000779 smoke Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- -1 Methyl stannum Chemical compound 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 2
- QBQSKYIIEGLPJT-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCOC(=O)C=C QBQSKYIIEGLPJT-UHFFFAOYSA-N 0.000 abstract 1
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- CVOFKRWYWCSDMA-UHFFFAOYSA-N 2-chloro-n-(2,6-diethylphenyl)-n-(methoxymethyl)acetamide;2,6-dinitro-n,n-dipropyl-4-(trifluoromethyl)aniline Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl.CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O CVOFKRWYWCSDMA-UHFFFAOYSA-N 0.000 description 1
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a UV (ultraviolet) curing ink with excellent curing performance. The UV curing ink is characterized by comprising raw materials in parts by weight as follows: 1-3 parts of organic pigments, 30-34 parts of polyester acrylate, 5-6 parts of carboxymethyl cellulose, 3-4 parts of sodium peroxide powder, 11-14 parts of phenyl glycidyl ether, 20-25 parts of aromatic polyester acrylate, 10-13 parts of epoxy acrylate, 2-3 parts of smoke sheet rubber, 10-12 parts of acrylic acid-2-hydroxyethyl acrylate, 5-9 parts of 184 photoinitiators, 1-2 parts of titanate coupling agents TMC-TTS, 1-2 parts of methyl tin mercaptide, 1-2 parts of tantalum boride, 1-2 parts of accelerants DM and 4-5 parts of aids. According to the UV curing ink with the excellent curing performance, the toughness of the ink is improved, the ink can be uniformly dispersed, and the ink stability is maintained; and the UV curing ink doesn't contain a volatile solvent, has no harm to a human body and the environment and excellent curing performance and can be used for silk-screen printing.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly good UV curable ink of a kind of curing performance and preparation method thereof.
Background technology
The curing mechanism of UV curable ink is, the light trigger in system directly or indirectly absorbs after ultraviolet luminous energy, from ground state transition to excited singlet, alters and jump to excited triplet state between being; After excited singlet or triplet state experience unit molecule or bimolecular chemical action, the biologically active fragment that generation can trigger monomer polymerization, these fragments can be free radical, positively charged ion, negatively charged ion or ion free radical.
There has been significant progress nearest for some time of UV curable ink, and its major advantage is: set time is short, therefore needn't use and dust, and can enhance productivity; Owing to just need not heating, can be dried, so do not need baking oven, compare with thermal fixation type ink, can significantly reduce time of drying, save energy consumption; The various resistances of printing are good, and dry rear ink film is solid; Due to the good stability of ink on machine, so the stable in properties of printed matter; Non-volatility organic solvent VOC in ink, can atmosphere pollution, and printed matter is odorless almost; Because be the ink of solids content 100%, so can carry out thick film screen printing; Can on cheap paper, print, also can non-absorbent material as metallic substance, plastics, silicate product etc. on printing.Like this, from the viewpoint of high speed printing, environment protection and save energy etc., UV curable ink is all better than other types ink.
Summary of the invention
The object of this invention is to provide good UV curable ink of a kind of curing performance and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The UV curable ink that curing performance is good, is made by the raw material of following weight part: pigment dyestuff 1-3, polyester acrylate 30-34, carboxymethyl cellulose 5-6, sodium peroxide powder 3-4, phenyl glycidyl ether 11-14, aromatic urethane acrylic acid ester 20-25, epoxy acrylate 10-13, smoke sheet rubber 2-3, vinylformic acid-2-hydroxy methacrylate 10-12,184 light trigger 5-9, titanate coupling agent TMC-TTS1-2, Methyl stannum mercaptide 1-2, tantalum boride 1-2, altax 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink that curing performance of the present invention is good, by following concrete steps, made: first add pigment dyestuff, polyester acrylate, carboxymethyl cellulose, sodium peroxide powder, phenyl glycidyl ether, aromatic urethane acrylic acid ester, epoxy acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Non-volatility solvent of the present invention, to human body and environmentally friendly, has good curing performance, can be used for silk screen printing.
Specific embodiments
Below by specific examples, the present invention is described in detail.
The UV curable ink that curing performance is good, by following weight part (kilogram) raw material make: pigment dyestuff 1, polyester acrylate 30, carboxymethyl cellulose 5, sodium peroxide powder 3, phenyl glycidyl ether 11, aromatic urethane acrylic acid ester 20, epoxy acrylate 10, smoke sheet rubber 2, vinylformic acid-2-hydroxy methacrylate 10,184 light triggers 5, titanate coupling agent TMC-TTS1, Methyl stannum mercaptide 1, tantalum boride 1, altax 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, Silane coupling agent KH550 1, linking agent TAC2, polyisobutene 2, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2, phenylformic acid amine 1, Viscoat 295 10, Tenox PG 3, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink that curing performance of the present invention is good, by following concrete steps, made: first add pigment dyestuff, polyester acrylate, carboxymethyl cellulose, sodium peroxide powder, phenyl glycidyl ether, aromatic urethane acrylic acid ester, epoxy acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curable ink that curing performance is good, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, polyester acrylate 30-34, carboxymethyl cellulose 5-6, sodium peroxide powder 3-4, phenyl glycidyl ether 11-14, aromatic urethane acrylic acid ester 20-25, epoxy acrylate 10-13, smoke sheet rubber 2-3, vinylformic acid-2-hydroxy methacrylate 10-12,184 light trigger 5-9, titanate coupling agent TMC-TTS1-2, Methyl stannum mercaptide 1-2, tantalum boride 1-2, altax 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, Silane coupling agent KH550 1-2, linking agent TAC2-3, polyisobutene 2-3, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester 2-3, phenylformic acid amine 1-2, Viscoat 295 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the good UV curable ink of curing performance according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, polyester acrylate, carboxymethyl cellulose, sodium peroxide powder, phenyl glycidyl ether, aromatic urethane acrylic acid ester, epoxy acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618312.4A CN103666075A (en) | 2013-11-29 | 2013-11-29 | UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310618312.4A CN103666075A (en) | 2013-11-29 | 2013-11-29 | UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666075A true CN103666075A (en) | 2014-03-26 |
Family
ID=50304881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310618312.4A Pending CN103666075A (en) | 2013-11-29 | 2013-11-29 | UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666075A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310618312.4A patent/CN103666075A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1415679A (en) * | 2001-11-02 | 2003-05-07 | 北京英力科技发展有限公司 | Visible light solidified compsn. |
| CN101250350A (en) * | 2008-03-26 | 2008-08-27 | 中国印钞造币总公司 | Soybean oil based protruding printing ink |
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106590162A (en) | Water-based gravure surface printing ink for plastic film and preparation method thereof | |
| CN103666032B (en) | A kind of ultraviolet light polymerization packaging ink and preparation method thereof | |
| CN102702848B (en) | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof | |
| CN103013222A (en) | Ultraviolet light cured ink and application and preparation method thereof | |
| CN103666053B (en) | A kind of UV curing transfer ink and preparation method thereof | |
| CN103819654B (en) | Special resin for water-based ultraviolet curing coating and preparation method and application thereof | |
| CN103666075A (en) | UV (ultraviolet) curing ink with excellent curing performance and preparation method of UV curing ink | |
| CN103666043B (en) | UV ink that a kind of quick solidifying sticking power is good and preparation method thereof | |
| CN103666065B (en) | A kind of UV curable ink for surface printing and preparation method thereof | |
| CN103666035B (en) | A kind of UV cured printing ink and preparation method thereof for serigraphy | |
| CN103666069A (en) | Ultraviolet light cured printing ink with good adhesive attraction and toughness and preparation method thereof | |
| CN105315783A (en) | Ink stone and preparation method thereof | |
| CN103666077A (en) | High-solid UV (ultraviolet) curing ink and preparation method thereof | |
| CN103666060A (en) | UV-curing printing ink with high flexibility and preparation method thereof | |
| CN101050334A (en) | Water paint solidified by ultraviolet light, preparation method and application | |
| CN103666044B (en) | A kind of environment-friendly type ultraviolet-curing ink and preparation method thereof | |
| CN103666034B (en) | UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof | |
| CN103666048A (en) | Ultraviolet light cured printing ink with good adhesive attraction and folding strength and preparation method thereof | |
| CN103666072B (en) | A kind of UV curable ink for electronic component mark and preparation method thereof | |
| CN103666063A (en) | Ultraviolet light curing silk-screen printing ink and preparation method thereof | |
| CN103666066A (en) | High-performance high-production-efficiency UV-cured printing ink and preparation method thereof | |
| CN104877440A (en) | Offset printing ink containing titanium dioxide nanofibers and preparation method thereof | |
| CN103666103B (en) | A kind of spraying type ultraviolet cured ink and preparation method thereof | |
| CN103666045A (en) | UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink | |
| CN103666031B (en) | A kind of ultraviolet light polymerization gravure printing ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140326 |