CN103666063A - Ultraviolet light curing silk-screen printing ink and preparation method thereof - Google Patents
Ultraviolet light curing silk-screen printing ink and preparation method thereof Download PDFInfo
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- CN103666063A CN103666063A CN201310601904.5A CN201310601904A CN103666063A CN 103666063 A CN103666063 A CN 103666063A CN 201310601904 A CN201310601904 A CN 201310601904A CN 103666063 A CN103666063 A CN 103666063A
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- screen printing
- ink
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- ultraviolet light
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- 238000007650 screen-printing Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000003999 initiator Substances 0.000 claims abstract description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 6
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims abstract description 4
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 6
- POLZHVHESHDZRD-UHFFFAOYSA-N 2-hydroxyethyl 2-methylprop-2-enoate;phosphoric acid Chemical compound OP(O)(O)=O.CC(=C)C(=O)OCCO POLZHVHESHDZRD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001723 curing Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- WDFFWUVELIFAOP-UHFFFAOYSA-N 2,6-difluoro-4-nitroaniline Chemical compound NC1=C(F)C=C([N+]([O-])=O)C=C1F WDFFWUVELIFAOP-UHFFFAOYSA-N 0.000 abstract 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 abstract 1
- 238000003848 UV Light-Curing Methods 0.000 abstract 1
- 238000007046 ethoxylation reaction Methods 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- CVOFKRWYWCSDMA-UHFFFAOYSA-N 2-chloro-n-(2,6-diethylphenyl)-n-(methoxymethyl)acetamide;2,6-dinitro-n,n-dipropyl-4-(trifluoromethyl)aniline Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl.CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O CVOFKRWYWCSDMA-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 241000533950 Leucojum Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- -1 aldehyde ketone Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses ultraviolet curing silk-screen printing ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 20-23 parts of UV curing polyurethane resin, 4-5 parts of polyvinyl alcohol, 1-2 parts of sodium dodecyl benzene sulfonate, 3-4 parts of 2-butoxy-ethanol, 10-12 parts of isopropanol, 10-12 parts of ethoxylation trimethylolpropane triacrylate, 2-3 parts of 2-hydroxyethyl methacrylate phosphate, 10-12 parts of tripropylene glycol diacrylate, 8-9 parts of glycidyl acrylate, 5-10 parts of 1173 initiator, 1-2 parts of sodium tungstate, 3-5 parts of 2,6-ditertiary butyl-4-methylphenol, 5-9 parts of tributyl citrate and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness, the ink can be uniformly dispersed; the component generally comprises no other excessive chemical auxiliaries, residual volatile substances can be reduced, and the ink is safe, environment-friendly and high in production efficiency.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet light polymerization silk screen printing ink for screen printing and preparation method thereof.
Background technology
There has been significant progress nearest for some time of UV curable ink, and its major advantage is: set time is short, therefore needn't use and dust, and can enhance productivity; Owing to just need not heating, can be dried, so do not need baking oven, compare with thermal fixation type ink, can significantly reduce time of drying, save energy consumption; The various resistances of printing are good, and dry rear ink film is solid; Due to the good stability of ink on machine, so the stable in properties of printed matter; Non-volatility organic solvent VOC in ink, can atmosphere pollution, and printed matter is odorless almost; Because be the ink of solids content 100%, so can carry out thick film screen printing; Can on cheap paper, print, also can non-absorbent material as metallic substance, plastics, silicate product etc. on printing.Due to the main component UV aldehyde ketone resin in current silk-screen snowflake printing ink raw material, UV acrylate resin etc., in by UV solidification process, can there is chemical reaction, produce benzene class material and letones, and give out larger peculiar smell, contaminate environment, affect HUMAN HEALTH, be a kind of ink of non-environmental protection, the VOC that does not also reach in addition tobacco bale controls requirement.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet light polymerization silk screen printing ink for screen printing and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of ultraviolet light polymerization silk screen printing ink for screen printing, raw material by following weight part is made: pigment dyestuff 1-3, UV ultraviolet curing urethane resin 20-23, polyvinyl alcohol 4-5, Sodium dodecylbenzene sulfonate 1-2, 2-butoxy-ethanol 3-4, Virahol 10-12, ethoxylated trimethylolpropane triacrylate 10-12, hydroxyethyl meth acrylate phosphoric acid ester 2-3, tri (propylene glycol) diacrylate 10-12, glycidyl acrylate 8-9, 1173 initiator 5-10, sodium wolframate 1-2, 2, 6-di-tert-butyl-4-methy phenol 3-5, tributyl citrate 5-9, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 1035 2-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization silk screen printing ink for screen printing of the present invention, by following concrete steps, made: first add pigment dyestuff, UV ultraviolet curing urethane resin, polyvinyl alcohol, Sodium dodecylbenzene sulfonate, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate, hydroxyethyl meth acrylate phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 initiators, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 initiators, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Component of the present invention does not contain other too much chemical assistant substantially, can reduce residual volatile matter, safety and environmental protection, and production efficiency is high.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of ultraviolet light polymerization silk screen printing ink for screen printing, by following weight part (kilogram) raw material make: pigment dyestuff 1, UV ultraviolet curing urethane resin 20, polyvinyl alcohol 4, Sodium dodecylbenzene sulfonate 1,2-butoxy-ethanol 3, Virahol 10, ethoxylated trimethylolpropane triacrylate 10, hydroxyethyl meth acrylate phosphoric acid ester 2, tri (propylene glycol) diacrylate 10, glycidyl acrylate 8,1173 initiators 5, sodium wolframate 1,2,6 di tert butyl 4 methyl phenol 3, tributyl citrate 5, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, methacrylic acid-2-hydroxy methacrylate 2, neopentyl glycol 5, vinyl acetate 12, linking agent TAC2, oxidation inhibitor 1,035 2, N hydroxymethyl acrylamide 1, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization silk screen printing ink for screen printing of the present invention, by following concrete steps, made: first add pigment dyestuff, UV ultraviolet curing urethane resin, polyvinyl alcohol, Sodium dodecylbenzene sulfonate, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate, hydroxyethyl meth acrylate phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 initiators, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 initiators, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet light polymerization silk screen printing ink for screen printing, it is characterized in that, raw material by following weight part is made: pigment dyestuff 1-3, UV ultraviolet curing urethane resin 20-23, polyvinyl alcohol 4-5, Sodium dodecylbenzene sulfonate 1-2, 2-butoxy-ethanol 3-4, Virahol 10-12, ethoxylated trimethylolpropane triacrylate 10-12, hydroxyethyl meth acrylate phosphoric acid ester 2-3, tri (propylene glycol) diacrylate 10-12, glycidyl acrylate 8-9, 1173 initiator 5-10, sodium wolframate 1-2, 2, 6-di-tert-butyl-4-methy phenol 3-5, tributyl citrate 5-9, auxiliary agent 4-5,
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 1035 2-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. ultraviolet light polymerization silk screen printing ink for screen printing according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, UV ultraviolet curing urethane resin, polyvinyl alcohol, Sodium dodecylbenzene sulfonate, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate, hydroxyethyl meth acrylate phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1173 initiators, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1173 initiators, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601904.5A CN103666063A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing silk-screen printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601904.5A CN103666063A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing silk-screen printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666063A true CN103666063A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310601904.5A Pending CN103666063A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing silk-screen printing ink and preparation method thereof |
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| Country | Link |
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| CN (1) | CN103666063A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572588A (en) * | 2017-09-08 | 2018-01-12 | 丁明 | A kind of environment-friendly type sodium tungstate preparation technology and its application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665641A (en) * | 2009-09-25 | 2010-03-10 | 林国顺 | Ultraviolet curing embossed printing ink |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102295858A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Photo-curable screen printing ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
-
2013
- 2013-11-25 CN CN201310601904.5A patent/CN103666063A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665641A (en) * | 2009-09-25 | 2010-03-10 | 林国顺 | Ultraviolet curing embossed printing ink |
| CN102295858A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Photo-curable screen printing ink and preparation method thereof |
| CN101974267A (en) * | 2010-11-04 | 2011-02-16 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
| CN102634251A (en) * | 2012-04-10 | 2012-08-15 | 中钞油墨有限公司 | Photo-curing silk screen pearly-luster ink applicable to different printing substrates and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572588A (en) * | 2017-09-08 | 2018-01-12 | 丁明 | A kind of environment-friendly type sodium tungstate preparation technology and its application |
| CN107572588B (en) * | 2017-09-08 | 2019-04-12 | 丁明 | A kind of environment-friendly type sodium tungstate preparation process and its application |
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Application publication date: 20140326 |