CN103666062A - Ultraviolet light curing embossment ink and preparation method thereof - Google Patents
Ultraviolet light curing embossment ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666062A CN103666062A CN201310601764.1A CN201310601764A CN103666062A CN 103666062 A CN103666062 A CN 103666062A CN 201310601764 A CN201310601764 A CN 201310601764A CN 103666062 A CN103666062 A CN 103666062A
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- ink
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- ultraviolet curing
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- 238000002360 preparation method Methods 0.000 title claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000007639 printing Methods 0.000 claims abstract description 13
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims abstract description 13
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229960001124 trientine Drugs 0.000 claims abstract description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 7
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- OOJBEQBXIJTMIN-UHFFFAOYSA-N europium 1,1,1-trifluoropentane-2,4-dione Chemical compound FC(C(=O)CC(C)=O)(F)F.[Eu] OOJBEQBXIJTMIN-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229920003987 resole Polymers 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007650 screen-printing Methods 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- SHXHPUAKLCCLDV-UHFFFAOYSA-N 1,1,1-trifluoropentane-2,4-dione Chemical compound CC(=O)CC(=O)C(F)(F)F SHXHPUAKLCCLDV-UHFFFAOYSA-N 0.000 abstract 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000003475 lamination Methods 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses ultraviolet curing embossment ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 10-12 parts of 196 unsaturated polyester resin, 10-12 parts of acrylic resin, 13-16 parts of phenolic resin, 2-3 parts of glycerin, 3-4 parts of N,N-dimethylformamide, 1-2 parts of trifluoroacetylacetone, 1-3 parts of tetrahydrofuran, 1-2 parts of monobutyltin oxide, 5-8 parts of triethylene tetramine, 6-9 parts of crylic acid-2-hydroxyethyl acrylate, 12-15 parts of tripropylene glycol, 12-15 parts of tripropylene glycol diacrylate, 5-8 parts of 184 photoinitiator and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the ink disclosed by the invention can be printed on golden and silver card paper, PVC (Polyvinyl Chloride) or matt lamination in a screen printing mode at one time, an embossment character effect with gorgeous color can be formed through printing at one time, and the ink is applied to high-class package.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet curing embossed printing ink and preparation method thereof.
Background technology
Ultraviolet curing embossed printing ink is a kind of screen printing ink, the irradiation of the ultraviolet lamp of process specific wavelength forms type effect lucuriant in design, this ink can be widely used in high-grade packing aspect, according to customer requirement, can be formulated into the embossed printing ink that shades of colour is bright-coloured, its curing speed and sticking power are all good.Existing ultraviolet curing embossed printing ink all needs repeatedly to print and could form type effect, the easy like this register trouble expense material consuming time that occurs.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet curing embossed printing ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of ultraviolet curing embossed printing ink, raw material by following weight part is made: pigment dyestuff 1-3,196 unsaturated polyester resin 10-12, acrylic resin 10-12, resol 13-16, glycerine 2-3, DMF 3-4, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Mono-n-butyltin 1-2, triethylene tetramine 5-8, vinylformic acid-2-hydroxy methacrylate 6-9, tripropylene glycol diacrylate 12-15, tri (propylene glycol) diacrylate 12-15,184 light trigger 5-8, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 1035 2-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet curing embossed printing ink of the present invention, by following concrete steps, made: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink provided by the invention can once be imprinted on it on gold and silver paperboard, PVC or mute film by screen painting mode, and it only needs one-step print just can form type effect lucuriant in design, for top grade, packs.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of ultraviolet curing embossed printing ink, by following weight part (kilogram) raw material make: pigment dyestuff 1,196 unsaturated polyester resins 10, acrylic resin 10, resol 13, glycerine 2, DMF 3, trifluoroacetylacetone europium 1, tetrahydrofuran (THF) 1, Mono-n-butyltin 1, triethylene tetramine 5, vinylformic acid-2-hydroxy methacrylate 6, tripropylene glycol diacrylate 12, tri (propylene glycol) diacrylate 12,184 light triggers 5, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, methacrylic acid-2-hydroxy methacrylate 2, neopentyl glycol 5, vinyl acetate 12, linking agent TAC2, oxidation inhibitor 1,035 2, N hydroxymethyl acrylamide 1, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet curing embossed printing ink of the present invention, by following concrete steps, made: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet curing embossed printing ink, it is characterized in that, raw material by following weight part is made: pigment dyestuff 1-3,196 unsaturated polyester resin 10-12, acrylic resin 10-12, resol 13-16, glycerine 2-3, DMF 3-4, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Mono-n-butyltin 1-2, triethylene tetramine 5-8, vinylformic acid-2-hydroxy methacrylate 6-9, tripropylene glycol diacrylate 12-15, tri (propylene glycol) diacrylate 12-15,184 light trigger 5-8, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 1035 2-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. ultraviolet curing embossed printing ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601764.1A CN103666062B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet curing embossed printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601764.1A CN103666062B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet curing embossed printing ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666062A true CN103666062A (en) | 2014-03-26 |
| CN103666062B CN103666062B (en) | 2016-04-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310601764.1A Active CN103666062B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet curing embossed printing ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666062B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN102300942A (en) * | 2009-01-29 | 2011-12-28 | 东海染工株式会社 | marking ink |
| CN102643568A (en) * | 2011-02-17 | 2012-08-22 | 富士胶片株式会社 | Ink composition, ink set and image forming method |
| CN102827513A (en) * | 2012-09-04 | 2012-12-19 | 上海蓝沛新材料科技股份有限公司 | Photopolymerisable catalytic printing ink and application thereof |
| CN102876113A (en) * | 2011-07-14 | 2013-01-16 | 纪州技研工业株式会社 | Inkjet ink and printing methods |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310601764.1A patent/CN103666062B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN102300942A (en) * | 2009-01-29 | 2011-12-28 | 东海染工株式会社 | marking ink |
| CN102643568A (en) * | 2011-02-17 | 2012-08-22 | 富士胶片株式会社 | Ink composition, ink set and image forming method |
| CN102876113A (en) * | 2011-07-14 | 2013-01-16 | 纪州技研工业株式会社 | Inkjet ink and printing methods |
| CN102827513A (en) * | 2012-09-04 | 2012-12-19 | 上海蓝沛新材料科技股份有限公司 | Photopolymerisable catalytic printing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666062B (en) | 2016-04-13 |
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