CN103666060B - UV curable ink of a kind of good toughness and preparation method thereof - Google Patents
UV curable ink of a kind of good toughness and preparation method thereof Download PDFInfo
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- CN103666060B CN103666060B CN201310601293.4A CN201310601293A CN103666060B CN 103666060 B CN103666060 B CN 103666060B CN 201310601293 A CN201310601293 A CN 201310601293A CN 103666060 B CN103666060 B CN 103666060B
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- ink
- auxiliary agent
- good toughness
- curable ink
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- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims abstract description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940119545 isobornyl methacrylate Drugs 0.000 claims abstract description 7
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 241000628997 Flos Species 0.000 claims abstract description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims abstract description 4
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 9
- YSVQGHIOJPVICX-UHFFFAOYSA-N 1-(1-hydroxycyclohexyl)-1-phenylpropan-2-one Chemical compound C1CCCCC1(O)C(C(=O)C)C1=CC=CC=C1 YSVQGHIOJPVICX-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000007639 printing Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 8
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of UV curable ink of good toughness, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-35, hydroxyethyl methylacrylate 30-35, isobornyl methacrylate 14-18,2-Hydroxylated acrylic resin 10-12,1-hydroxycyclohexylphenyl acetone 6-9, Flos Rosae Rugosae quintessence oil 1-2, coumarone 4-5, altax? 1-2, octadecyl trimethyl ammonium chloride 3-4, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; The present invention, improving cured film flexible while, ensures the good adhesion of double exposure ink film, improves quality product.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of UV curable ink and preparation method thereof of good toughness.
Background technology
At present, in screen printing process, the layer of ink that ink film thicknesses after film-forming compares other mode of printing is abundant, the ink film thicknesses of general single printing is 20 ~ 40 μm, for ensureing that ink is in the good adhesion on product surface of undertaking the printing of, hold the ink total thickness of printing product surface double exposure no more than 100 μm, i.e. ink on the product of undertaking the printing of general maximum overprintable 3 times.
Test finds, for needing double exposure more than 3 times to embody the product of undertaking the printing of of its unique printing effect, if use existing ink to print, then ink printing in the product of undertaking the printing of on the surface and solidification after, extruding or bending this undertake the printing of product time, significantly ftractureing and coming off appears in ink film surface usually, affects quality product.
Summary of the invention
The object of this invention is to provide UV curable ink of a kind of good toughness and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A UV curable ink for good toughness, is made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-35, hydroxyethyl methylacrylate 30-35, isobornyl methacrylate 14-18,2-Hydroxylated acrylic resin 10-12,1-hydroxycyclohexylphenyl acetone 6-9, Flos Rosae Rugosae quintessence oil 1-2, coumarone 4-5, altax 1-2, octadecyl trimethyl ammonium chloride 3-4, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curable ink of good toughness of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxycyclohexylphenyl acetone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxycyclohexylphenyl acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; The present invention, improving cured film flexible while, ensures the good adhesion of double exposure ink film, improves quality product.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A UV curable ink for good toughness, is made up of the raw material of following weight part (kilogram): pigment dyestuff 1, urethane acrylate 30, hydroxyethyl methylacrylate 30, isobornyl methacrylate 14,2-Hydroxylated acrylic resin 10,1-hydroxycyclohexylphenyl acetone 6, Flos Rosae Rugosae quintessence oil 1, coumarone 4, altax 1, octadecyl trimethyl ammonium chloride 3, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 10351, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV curable ink of good toughness of the present invention, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxycyclohexylphenyl acetone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxycyclohexylphenyl acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curable ink of a good toughness, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-35, hydroxyethyl methylacrylate 30-35, isobornyl methacrylate 14-18,2-Hydroxylated acrylic resin 10-12,1-hydroxycyclohexylphenyl acetone 6-9, Flos Rosae Rugosae quintessence oil 1-2, coumarone 4-5, altax 1-2, octadecyl trimethyl ammonium chloride 3-4, auxiliary agent 4-5; Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. the UV curable ink of good toughness according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 1-hydroxycyclohexylphenyl acetone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 1-hydroxycyclohexylphenyl acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601293.4A CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601293.4A CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666060A CN103666060A (en) | 2014-03-26 |
| CN103666060B true CN103666060B (en) | 2016-04-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310601293.4A Active CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103666060B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992239A (en) * | 2014-05-12 | 2014-08-20 | 洞头县恒立印刷材料有限公司 | A synthetic method of ultraviolet-curable amino methacrylate |
| CN111621197A (en) * | 2020-05-27 | 2020-09-04 | 江苏云合新材料科技有限公司 | Preparation method of water-based ink |
| CN116466512A (en) * | 2022-01-11 | 2023-07-21 | 京东方科技集团股份有限公司 | Backplane, backlight module and display device |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659809A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | Water-based UV black ink with super-high solid content and preparation method thereof |
| CN101824152A (en) * | 2010-04-13 | 2010-09-08 | 深圳职业技术学院 | Preparation method and application of resin having double curing groups |
| CN101962430A (en) * | 2010-08-27 | 2011-02-02 | 苏州嘉祥树脂有限公司 | Method for producing ultraviolet curable amino acrylate resin |
| CN102099427A (en) * | 2008-05-14 | 2011-06-15 | 玛莱宝两合公司 | Radiation-curable printing ink or printing lake |
| CN102977684A (en) * | 2012-12-07 | 2013-03-20 | 武汉大学 | Water-soluble (Ultra Violet) curing ink and preparation method thereof |
-
2013
- 2013-11-25 CN CN201310601293.4A patent/CN103666060B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102099427A (en) * | 2008-05-14 | 2011-06-15 | 玛莱宝两合公司 | Radiation-curable printing ink or printing lake |
| CN101659809A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | Water-based UV black ink with super-high solid content and preparation method thereof |
| CN101824152A (en) * | 2010-04-13 | 2010-09-08 | 深圳职业技术学院 | Preparation method and application of resin having double curing groups |
| CN101962430A (en) * | 2010-08-27 | 2011-02-02 | 苏州嘉祥树脂有限公司 | Method for producing ultraviolet curable amino acrylate resin |
| CN102977684A (en) * | 2012-12-07 | 2013-03-20 | 武汉大学 | Water-soluble (Ultra Violet) curing ink and preparation method thereof |
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| Publication number | Publication date |
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| CN103666060A (en) | 2014-03-26 |
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Effective date of registration: 20231211 Address after: No. 16, Nishan Road, Xianhua Street, Pujiang County, Jinhua City, Zhejiang Province, 322200 Patentee after: Pujiang Dazhong Printing Materials Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |
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