CN106318031A - Water-based multi-functional printing ink - Google Patents
Water-based multi-functional printing ink Download PDFInfo
- Publication number
- CN106318031A CN106318031A CN201610711054.8A CN201610711054A CN106318031A CN 106318031 A CN106318031 A CN 106318031A CN 201610711054 A CN201610711054 A CN 201610711054A CN 106318031 A CN106318031 A CN 106318031A
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- Prior art keywords
- water
- ink
- printing
- soluble multifunctional
- emulsification
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000007639 printing Methods 0.000 title claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000013530 defoamer Substances 0.000 claims abstract description 4
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 3
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 3
- 238000004945 emulsification Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 17
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 230000033228 biological regulation Effects 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 6
- 238000007689 inspection Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 230000000903 blocking effect Effects 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical compound CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 241001597008 Nomeidae Species 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 230000002349 favourable effect Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 230000001629 suppression Effects 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000008367 deionised water Substances 0.000 abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 abstract description 4
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000007644 letterpress printing Methods 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical group C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- -1 acrylic amine Chemical class 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Water-based multi-functional printing ink is preppared from DK- 182 resin, HF- 9 resin, pigment, filler, wetting agent, dispersing agent wax emulsion, adhesion promoter, flatting agent, defoamer, anti-blocking auxiliary agent, fortifier, ethyl alcohol, isopropanol and deionized water. The painting ink can be both used in intaglio printing or letterpress printing, and also used in outside or inside printing; the ink stained on the printer can be easily washed by deionized water and the clogging is rare, with good reproducibility and strength.
Description
Technical field
The present invention relates to a kind of water-soluble multifunctional printing-ink.
Background technology
The ink that existing market is popular is divided into base gravure ink, letterpress ink, inner print compound oil ink and table printing ink, and this gives raw
Producing and application producer all brings huge trouble, wide in variety, model is many, increases production process and the difficulty of storage, lets funds lie idle,
Taking storage space, give and produce and management increase difficulty, market demand one Multifunctional printing ink solves the problems referred to above, with
Time in order to adapt to the practical requirement of environmental protection and safety in production, development function admirable water-based printing ink be also current general trend of events institute
Become.
Summary of the invention
It is an object of the invention to: a kind of water-soluble multifunctional printing-ink is provided, can be not only used for intaglio printing it can also be used to convex
Version printing, can be used for Biao Yin it can also be used in print；Ink easily cleans, no with deionized water during using on the printer
The most stifled version, dot reproduction is good, and printing quality is exquisite, and intensity is good.
The present invention is achieved in that a kind of water-soluble multifunctional printing-ink, the percentage by weight of its formula composition are:
Each raw material weight percentage ratio sum is 100%.
Its preparation method comprises the steps:
Take HF-9 resin, wetting agent, dispersant and ethanol and put in pot, open stirring；Put into pigment and filler the most again
Being uniformly dispersed, jitter time is 20-30 minute；Then it is ground being dispersed to fineness≤10 micron with sand mill, remaining
Material puts into, and stirs 20-30 minute, regulation viscosity and form and aspect, qualified through inspection, filters with 120 mesh gauzes, is packaged into finished product.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described DK-182 resin is that water-based room temperature is handed over
Bipropenyl yogurt liquid, is the patent No.: the product of the patent of invention of ZL200910039807.5, has self-crosslinking performance, improves and is coated with
Film strength and adhesive force, be the main link stuff of the present invention；It is made up of following composition, and its percentage by weight is:
Its preparation method, comprises the steps:
(1) weigh the emulsifying agent of emulsifying agent total amount 0-30% in formula and account for the water of water gross weight 0-5%, being placed in pre-emulsification
In still, stirring；Weigh and account for the methyl methacrylate of total weight of monomer 0-30%, styrene, methacrylic acid, acrylic acid, N-hydroxyl
Base acrylic amine, hydroxyethyl methylacrylate, butyl methacrylate, be slowly added in pre-emulsification still carry out pre-emulsification, emulsifying
30-60 minute time, standby；
(2) emulsifying agent accounting for emulsifying agent total amount 80-100% and the water accounting for water gross weight 15-30%, monomer are weighed in formula
The butyl methacrylate of gross weight 70-100%, is slowly added in pre-emulsification still carry out pre-emulsification, and emulsification times 30-60 divides
Clock, standby；
(3) in a kettle., add in formula and account for the water of water gross weight 40-50% and the sodium bicarbonate of formula ratio, account for and draw
Send out agent total amount 30-40% initiator as still liquid, while stirring rise high reaction temperature to 70-85 DEG C；
Still liquid stirred after 30 minutes, added the seed monomer that lower step (1) pre-emulsification is good, then 70-85 DEG C of inside holding in
Blue streak occurs；
After being incubated half an hour, the initiator accounting for initiator total amount 40-50% is dissolved in the water accounting for water yield 20-30%, with
Step (2) ready pre-emulsification list is not respectively placed in head tank and is simultaneously added dropwise, and time for adding is 3-4H, then 70-85 DEG C
It is incubated 1 hour, is cooled to less than 35 DEG C, adjust pH value in 7.5-8.5 scope with nertralizer, suppression stabilizer is added stirring 10-
20 minutes, then propyleneimine derivant is added, obtain single component room temperature crosslinked polymer, i.e. water-based room temperature crosslinking emulsion.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described pigment is red, yellow, blue, white, black
One of which.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described filler is fineness≤3000 micron
Pulvis Talci.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described wetting agent (105), dispersant (104)
Produce for good history clean (Guangzhou) Chemical Co., Ltd..
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described adhesion promoter is DRL-6673
Producing for Lei Er chemistry, it mutually chelates conclusion with main link stuff DK-182 resin HF-9 resin and sill and self-crosslinking is made
With.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described anti-network blocking auxiliary agent (DRL7100) is thunder
You produce by chemistry, prevent from blocking half tone, make that printing process is smooth, unobstructed, site favorable reproducibility, and printing quality is good.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described wax emulsion (DRL5105), levelling agent
(DRL1015), defoamer (DRL3145) is that Lei Er company produces.
Described a kind of water-soluble multifunctional printing-ink, it is characterized in that described ethanol, isopropanol, deionized water are used
Make ink system regulation viscosity and rate of drying, make diluent and use.
Described a kind of water-soluble multifunctional printing-ink, its be characterized in that described printing-ink can be used as intaglio printing,
Letterpress, can print it can also be used to print is a kind of multifunction environment-protection type printing-ink in Fu He by tabulation.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of water-soluble multifunctional printing-ink, the percentage by weight of its formula composition is:
Its preparation method comprises the steps:
HF-9 resin, wetting agent, dispersant, ethanol, put in pot, open stirring；Pigment is put into and is uniformly dispersed, time
Between be 20-30 minute, then be ground being dispersed to fineness≤10 micron with sand mill, remaining material put into, stir 20-
30 minutes, regulation viscosity and form and aspect, qualified through inspection, filter with 120 mesh gauzes, be packaged into finished product.
Described pigment is primary color red.
Embodiment 2
A kind of water-soluble multifunctional printing-ink, it is characterised in that: the percentage by weight of its formula composition is:
Each raw material weight percentage ratio sum is 100%.
Its preparation method comprises the steps:
Take HF-9 resin, wetting agent, dispersant and ethanol and put in pot, open stirring；Put into pigment and filler the most again
Being uniformly dispersed, jitter time is 20-30 minute；Then it is ground being dispersed to fineness≤10 micron with sand mill, remaining
Material puts into, and stirs 20-30 minute, regulation viscosity and form and aspect, qualified through inspection, filters with 120 mesh gauzes, is packaged into finished product.
Described pigment is rutile titanium white lead.
Embodiment 3
A kind of water-soluble multifunctional printing-ink, it is characterised in that: the percentage by weight of its formula composition is:
Its preparation method comprises the steps:
Take HF-9 resin, wetting agent, dispersant and ethanol and put in pot, open stirring；Put into pigment and filler the most again
Being uniformly dispersed, jitter time is 20-30 minute；Then it is ground being dispersed to fineness≤10 micron with sand mill, remaining
Material puts into, and stirs 20-30 minute, regulation viscosity and form and aspect, qualified through inspection, filters with 120 mesh gauzes, is packaged into finished product.
Described pigment is high-carbon black pigment.
Above-described is only the preferred embodiments of the present invention.It should be pointed out that, for the ordinary skill of this area
For personnel, without departing from the principles of the present invention, it is also possible to make some improvement and modification, this is also considered as the present invention's
Protection domain.
Claims (10)
1. a water-soluble multifunctional printing-ink, it is characterised in that: the percentage by weight of its formula composition is:
Each raw material weight percentage ratio sum is 100%.
Its preparation method comprises the steps:
Take HF-9 resin, wetting agent, dispersant and ethanol and put in pot, open stirring；Put into pigment and filler dispersion the most again
Uniformly, jitter time is 20-30 minute；Then it is ground being dispersed to fineness≤10 micron with sand mill, remaining material
Put into, stir 20-30 minute, regulation viscosity and form and aspect, qualified through inspection, filter with 120 mesh gauzes, be packaged into finished product.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described DK-182 resin is aqueous
Room temperature crosslinking acrylic acid emulsion, has self-crosslinking performance, improves and is coated with film strength and adhesive force, is the main link stuff of the present invention；
It is made up of following composition, and its percentage by weight is:
Its preparation method, comprises the steps:
(1) weigh the emulsifying agent of emulsifying agent total amount 0-30% in formula and account for the water of water gross weight 0-5%, being placed in pre-emulsification still,
Stirring；Weigh and account for the methyl methacrylate of total weight of monomer 0-30%, styrene, methacrylic acid, acrylic acid, N-hydroxyl third
Olefin(e) acid amine, hydroxyethyl methylacrylate, butyl methacrylate, be slowly added in pre-emulsification still carry out pre-emulsification, emulsification times
30-60 minute, standby；
(2) emulsifying agent accounting for emulsifying agent total amount 80-100% and the water accounting for water gross weight 15-30%, total weight of monomer are weighed in formula
The butyl methacrylate of amount 70-100%, is slowly added in pre-emulsification still carry out pre-emulsification, and emulsification times 30-60 minute is standby
With；
(3) in a kettle., add in formula and account for the water of water gross weight 40-50% and the sodium bicarbonate of formula ratio, account for initiator
The initiator of total amount 30-40%, as still liquid, rises high reaction temperature to 70-85 DEG C while stirring；
After still liquid stirs 30 minutes, add the seed monomer that lower step (1) pre-emulsification is good, then at 70-85 DEG C of inside holding in blue streak
Occur；
After being incubated half an hour, the initiator accounting for initiator total amount 40-50% is dissolved in the water accounting for water yield 20-30%, with step
(2) ready pre-emulsification list is not respectively placed in head tank and is simultaneously added dropwise, and time for adding is 3-4H, then 70-85 DEG C of insulation 1
Hour, it is cooled to less than 35 DEG C, adjusts pH value in 7.5-8.5 scope with nertralizer, suppression stabilizer is added stirring 10-20 and divides
Clock, then adds propyleneimine derivant, obtains single component room temperature crosslinked polymer, i.e. water-based room temperature crosslinking emulsion.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described pigment be red, yellow, blue,
In vain, the one of which of black.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described filler is fineness≤3000
The Pulvis Talci of micron.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described wetting agent is wetting agent
105, described dispersant is that dispersant 104 is.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described adhesion promoter is type
Number it is: DRL-6673 that it mutually chelates conclusion with main link stuff DK-182 resin, HF-9 resin and sill and self-crosslinking is made
With.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described anti-network blocking auxiliary agent is model
For DRL7100, preventing from blocking half tone, make that printing process is smooth, unobstructed, site favorable reproducibility, printing quality is good.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described wax emulsion is wax emulsion
DRL5105, levelling agent are levelling agent DRL1015, defoamer is defoamer DRL3145.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described ethanol, isopropanol, go from
Sub-water is used as ink system regulation viscosity and rate of drying, makees diluent and uses.
A kind of water-soluble multifunctional printing-ink, it is characterised in that: described printing-ink can be used as
Intaglio printing, letterpress, can print it can also be used to print in Fu He by tabulation, is a kind of water-soluble multifunctional environment-friendly type printing-ink.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610711054.8A CN106318031B (en) | 2016-08-24 | 2016-08-24 | Water-based multifunctional printing ink |
| PCT/CN2016/101461 WO2018035933A1 (en) | 2016-08-24 | 2016-10-08 | Water-based multi-functional printing ink and manufacturing method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610711054.8A CN106318031B (en) | 2016-08-24 | 2016-08-24 | Water-based multifunctional printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106318031A true CN106318031A (en) | 2017-01-11 |
| CN106318031B CN106318031B (en) | 2020-04-07 |
Family
ID=57742612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610711054.8A Active CN106318031B (en) | 2016-08-24 | 2016-08-24 | Water-based multifunctional printing ink |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106318031B (en) |
| WO (1) | WO2018035933A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109397860A (en) * | 2018-12-08 | 2019-03-01 | 杭州多丽彩印有限公司 | Environment-friendly type Five-color printing machine |
| CN110054926A (en) * | 2019-04-23 | 2019-07-26 | 耿海宁 | A kind of soft version and the anti-paste of relief printing plate fill in net spray preparation method |
| CN112194754A (en) * | 2020-09-17 | 2021-01-08 | 广东德康化工实业有限公司 | Water-based acrylic emulsion, water-based halftone printing ink and preparation method thereof |
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| CN113025788A (en) * | 2021-02-03 | 2021-06-25 | 上海专一热处理有限公司 | Heat treatment process for rare metal and superhard metal parts |
| CN112662228A (en) * | 2021-02-05 | 2021-04-16 | 漯河樱花包装材料有限公司 | Water-soluble environment-friendly gravure ink and preparation method thereof |
| CN116021905A (en) * | 2022-12-20 | 2023-04-28 | 黄山万丽美油墨科技有限公司 | PVC (polyvinyl chloride) and ABS (Acrylonitrile butadiene styrene) edge banding 3D (three-dimensional) water-based ink-jet printing process |
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Also Published As
| Publication number | Publication date |
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| CN106318031B (en) | 2020-04-07 |
| WO2018035933A1 (en) | 2018-03-01 |
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Denomination of invention: A water-based multifunctional printing ink Effective date of registration: 20231213 Granted publication date: 20200407 Pledgee: Cuishanhu Technology Branch of Guangdong Kaiping Rural Commercial Bank Co.,Ltd. Pledgor: GUANGDONG DEKANG CHEMICAL INDUSTRY Co.,Ltd. Registration number: Y2023980071379 |
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