CN104669811B - Ink-jet printing photo film and preparation method thereof - Google Patents
Ink-jet printing photo film and preparation method thereof Download PDFInfo
- Publication number
- CN104669811B CN104669811B CN201410808196.7A CN201410808196A CN104669811B CN 104669811 B CN104669811 B CN 104669811B CN 201410808196 A CN201410808196 A CN 201410808196A CN 104669811 B CN104669811 B CN 104669811B
- Authority
- CN
- China
- Prior art keywords
- layer
- preparation
- adhesive
- blotting
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention provides an ink-jet printing photo film and a preparation method thereof. The preparation method comprises the following steps: taking a plastic film as a film base layer; coating the film base layer with an adhesive with hydrophilcity and lipophilicity, thus forming an adhesive layer; coating the adhesive layer with an ink absorption layer, wherein the adhesive layer can be fixedly adhered to the film base layer and also can be fixedly adhered with the ink absorption layer; and coating the ink absorption layer with an ink protection layer. The base paper in the prior art is replaced by a plastic base film, the obtained ink-jet printing photo film has the performances such as high smoothness, high glossiness, good transparency, water resistance, corrosion prevention and the like and has environment-preventing significance, and lots of energy is saved; and moreover, aiming at different plastic films, different adhesives with hydrophilcity and lipophilicity are adopted, and the plastic film and the ink absorption layer which cannot be combined are bridged together, so that the plastic film serving as a base material is possibly applied to ink-jet printing photos.
Description
Technical field
The present invention relates to a kind of inkjet printing photograph film and preparation method thereof.
Background technology
Digital photographic technology is connect rapidly because overturning traditional photography technology, considerably reducing production cost by consumer
Receive.The application of digital photographic technology, also makes the Related product for entirely imaging industry update rapidly, including member-retaining portion tradition
The photo paper of function.Due to the significantly lifting of digital photographing photo quality, make the photo paper of a new generation necessary and digital photographing
Interface differential technique, shortens the complicated process that egative film develops and prints enlarged color photograph, and the printer for being directly entered dedicated functions is directly printed as picture,
This requires that the final value of digital photographic technology is embodied in imaging support --- on photo paper.Digital printing photo paper compares biography
System photo paper, should have quick blotting, image analysis high resolution, the features such as imaging surface is highly polished, color emulator is high.
At present, existing inkjet printing photo paper is divided into bloom and sub- light from performance, and RC can be divided into from processing technology
Printing paper, cast-coated paper and paper-plastic stick printing paper.
, there is operation on best bright finish, high resolution factor, the technique of high-fidelity quality is ensured in existing ink jet printed photographic paper
The limitation of complicated, stability difference and water suction blotting technical support scope.Meanwhile, preservation, waterproof, anti-ultraviolet, anti-aging,
The features such as anti-ultraviolet aspect there is also defect.The deficiencies in the prior art have：(1) existing blotting printed photographic paper manufacturing technology,
It is main from how controlling to reach the effect wanted using the technology of base material water absorbing properties itself.RC printing paper, cast-coated photographic paper etc.
All it is, with paper as absorbent function base material, the purpose that dense micropore reaches quick water suction to be formed by repeatedly coating bonding, blotting
The speed of how many and blotting directly affects the image quality that blotting prints photo paper；Existing process is special using the water suction of base material itself
Point, by the compound quantity of base material blotting amount and blotting speed are adjusted, and the stability for obtaining photo paper can be caused uncontrollable.(2)
The best bright finish of printing paper is printing paper high-resolution, the essential condition of high anti-true imaging, and the gloss of existing photo paper mainly passes through
Casting cylinder transfer, therefore, the factor such as fineness, temperature, pressure of cylinder directly affects the gloss of the photo paper, so as to get beat
Print photo paper generally existing glossiness is not reached, the defect that gloss is unstable, so as to affect image quality.(3) it is existing mutually made of paper
Technique is made, with paper as base material, waterproof and preservation also need to overlay film picture frame additional process, complex process, base material list to photo printing paper
One.
The content of the invention
The technical problem to be solved in the present invention is how to make film class base material be applied to blotting to print on photograph, and makes what is obtained
Photograph can realize waterproof preservation, anti-aging, the function of anti-ultraviolet, but with quick blotting, image analysis high resolution, into
The features such as image planes are highly polished, color emulator is high；In order to solve the above problems, the invention provides a kind of inkjet printing phase
The preparation method of piece film, including：
Plastic sheeting is taken as film basic unit；
Existing hydrophilic is coated with the film basic unit oil loving adhesive again, forms adhesive layer；
Ink absorbing layer is coated with the adhesive layer；The adhesive layer can be adhesively fixed with film basic unit, and energy and ink absorbing layer
It is adhesively fixed；
The coating shield layer of ink in the ink absorbing layer.
Preferably, the plastic sheeting is PET film；The adhesive layer includes bonding bottom and bonding main stor(e)y, first in film
Coating bonding bottom in basic unit, then coating bonds main stor(e)y on bonding bottom；
The preparation method of the adhesive that the bonding bottom is adopted includes：By acrylic resin, EVA copolymer and deionization
Water is with 1.5～2.5:50～60:2～3 ratio, under the conditions of 90 DEG C mix homogeneously stirring make viscosity for 1269Pa.s～
The bottom adhesive of 1500Pa.s；
The preparation method of the adhesive that the bonding main stor(e)y is adopted includes：By thermoplastic elastomer (TPE), rosin glycerol resin,
EVA copolymer and ethanol are with 1.2～2:1～1.5:1～3:5～6 ratio makes main stor(e)y adhesive, in preparation process, first
Thermoplastic elastomer (TPE) is heated to into 90 DEG C, to it clear solution is melted into completely, be subsequently adding rosin glycerol resin heating for dissolving
40 DEG C～50 DEG C are cooled to after 1h, EVA copolymer stirring 3h～4h is added, ethanol are eventually adding and are diluted.
Preferably, the plastic sheeting is BOPP film；The adhesive layer includes bonding bottom and bonding main stor(e)y, first in film
Coating bonding bottom in basic unit, then coating bonds main stor(e)y on bonding bottom；
The preparation method of the adhesive that the bonding bottom is adopted includes：By flax gum, terpene resin, thermoplastic elastic
Body and ethanol are with 1:1:1.5:4～6 ratio is heated to after 90 DEG C of mixing dispersions, and with EVA uniform stirrings viscosity is made
The bottom adhesive of 1269Pa.s～2000Pa.s；
The preparation method of the adhesive that the bonding main stor(e)y is adopted includes：Thermoplastic elastomer (TPE), Petropols, EVA is common
Polymers and ethanol are with 1.2～2:1～1.5:1～3:5～6 ratio makes main stor(e)y adhesive, in preparation process, first by thermoplastic
Property elastomer is heated to 90 DEG C, and to it clear solution is melted into completely, is subsequently adding after Petropols heating for dissolving 1h and is cooled to
40 DEG C～50 DEG C, EVA copolymer stirring 3h～4h is added, be eventually adding ethanol and be diluted.
Preferably, the ink absorbing layer includes blotting main stor(e)y and blotting pair layer, first the even spread blotting main stor(e)y on adhesive layer,
Then blotting pair layer is coated with blotting main stor(e)y；
The preparation method of material includes used by the blotting main stor(e)y：Nano titanium dioxide powder is dispersed in into ethanol at a high speed molten
In liquid, nano titanium oxide concentration in ethanol is 12%, then adds in nano titanium oxide ethanol solution again and gathers dimension
Ketone iodine is prepared into 20% nano titanium oxide-povidone iodine ethanol solution, is eventually adding acrylic acid polyamide polymer, propylene
Sour polyamide polymer concentration in the solution is 0.05%～0.1%, that is, obtain blotting main stor(e)y material therefor；
The preparation method of material includes used by the blotting pair layer：Nano titanium dioxide powder is dispersed in into ethanol at a high speed molten
In liquid, nano titanium oxide concentration in ethanol is 9%, then in nano titanium oxide ethanol solution adds polyvidone again
Iodine is prepared into 18% nano titanium oxide-povidone iodine ethanol solution, as blotting pair layer material therefor.
Preferably, the specific surface area of nano titanium oxide used by the blotting main stor(e)y is 400m2/ g～600m2/ g, the suction
The specific surface area of nano titanium oxide is 100m used by black pair layer2/ g～200m2/g。
Preferably, the shield layer of ink adopts the aqueous solution of 15%～18% 30 POVIDONE K 30 BP/USP 90.
Preferably, the thickness of the bonding bottom is 1.5 μm～2 μm；The thickness of the bonding main stor(e)y is 1 μm～1.5 μm.
Preferably, the thickness of the blotting main stor(e)y is 9 μm～11 μm；The thickness of the blotting pair layer is 2.5 μm～3 μm.
Preferably, when being coated with adhesive layer in film basic unit, using gravure coating method, and in 12 meters of length, 80 DEG C of temperature
Drying tunnel in solidification；When being coated with ink absorbing layer on adhesive layer, using comma scraper coating process, and in 25 meters of length, temperature 80
DEG C drying tunnel in solidification.
A kind of inkjet printing photograph film of the present invention is obtained using said method.
Beneficial effects of the present invention are：1st, substrate paper of the prior art, the ink-jet for obtaining are replaced using plastic basic unit film
Photograph film is printed, with performances such as smoothness good, glossiness is high, the transparency good, water-tight corrosion-proofs, and the substantial amounts of energy has been saved,
Meaning with environmental protection；2nd, for different plastic sheetings, there is oil loving adhesive again using different existing hydrophilic,
The plastic sheeting that itself cannot be combined and ink absorbing layer bridge joint, make plastic sheeting be applied to blotting as base material and print photograph
It is possibly realized.
Specific embodiment
Technical scheme is further described below in conjunction with accompanying drawing.
Embodiment 1
A kind of preparation method of inkjet printing photograph film of the present invention, first takes PET film as film basic unit, the thickness of film basic unit
Spend for 9 μm～11 μm；Then it is coated with film basic unit and have hydrophilic and have oil loving adhesive again, forms adhesive layer；Bonding
Layer includes bonding bottom and bonding main stor(e)y, and first coating thickness is 1.5 μm～2 μm bonding bottoms in film basic unit, then at bonding bottom
Coating thickness is 1 μm～1.5 μm of bonding main stor(e)y on layer；The preparation method of the adhesive that bonding bottom is adopted includes：By propylene
Acid resin, EVA copolymer and deionized water are with 2:55:2.8 ratio, the mix homogeneously stirring under the conditions of 90 DEG C is made viscosity and is
The bottom adhesive of 1269Pa.s～1500Pa.s；Acrylic resin has the non-breakable compatibility to PET；Bonding main stor(e)y is adopted
The preparation method of adhesive includes：By thermoplastic elastomer (TPE), rosin glycerol resin, EVA copolymer and ethanol with 1.5:
1.3:2:5.2 ratio makes main stor(e)y adhesive, in preparation process, first thermoplastic elastomer (TPE) is heated to into 90 DEG C, complete to its
Clear solution is melted into entirely, is subsequently adding after rosin glycerol resin heating for dissolving 1h and is cooled to 40 DEG C～50 DEG C, add EVA copolymerization
Thing stirs 3h～4h, is eventually adding dehydrated alcohol and is diluted, and the bonding main stor(e)y is the technology of the present invention key point, Shi Mo basic units and
Ink absorbing layer is changed into the big docking of the compatibility from repellency, so this layer of adhesive needs both have water phase, and with oil phase.In film
When being coated with adhesive layer in basic unit, using gravure coating method, and solidify in 12 meters of length, the drying tunnel of 80 DEG C of temperature.Using micro-
The method of recessed coating to adhesive be coated solidification it is all right, carry out peel test with pressure sensitive adhesive tape, test result shows
Adhesive force is good.
Secondly ink absorbing layer is coated with bonding main stor(e)y, adhesive layer can be connected with film basic unit, can connect with ink absorbing layer again
Connect fixation；Ink absorbing layer includes blotting main stor(e)y and blotting pair layer, and first even spread thickness is 9 μm～11 μm of suction on bonding main stor(e)y
Black main stor(e)y, then even spread thickness is 2.5 μm～3 μm of blotting pair layer on blotting main stor(e)y；The system of material used by blotting main stor(e)y
Preparation Method includes：Nano titanium dioxide powder is dispersed in ethanol solution at a high speed, nano titanium oxide is in ethanol
Concentration is 12%, then again in nano titanium oxide ethanol solution add povidone iodine be prepared into 20% nanometer titanium dioxide
Titanium-povidone iodine ethanol solution, is eventually adding acrylic acid polyamide polymer, acrylic acid polyamide polymer in the solution dense
Spend for 0.05%～0.1%, as blotting main stor(e)y material therefor, wherein acrylic acid polyamide polymer is with many hydrophilic groups
The low crosslinking degree of group or the high molecular polymer of partially crystallizable, more than the mesh of granularity 300, adding in solution after milling can increase solution
Specific surface area and water suction sexual function, blotting main stor(e)y is the macromolecule of the low crosslinking degree with many hydrophilic groups or partially crystallizable
Polymer, the specific surface area of the nano titanium oxide of blotting main stor(e)y is 400m2/ g～450m2/g；The system of material used by blotting pair layer
Preparation Method includes：Nano titanium dioxide powder is dispersed in ethanol solution at a high speed, nano titanium oxide is in ethanol
Concentration is 9%, then again in nano titanium oxide ethanol solution add povidone iodine be prepared into 18% nano titanium oxide-
Povidone iodine ethanol solution, that is, obtain blotting pair layer material therefor, and the specific surface area of the nano titanium oxide of blotting pair layer is
100m2/ g～200m2/g。
The last coating thickness on blotting pair layer is 2 μm～2.5 μm of shield layer of ink, protect layer of ink using 15%～18% it is poly-
The aqueous solution of dimension ketone K90, PVP-K90 is porogen and binding agent excellent on membrane technology, with amphipathic characteristic；On adhesive layer
When coating ink absorbing layer and shield layer of ink, using comma scraper coating process, and solidify in 25 meters of length, the drying tunnel of 80 DEG C of temperature,
Ink absorbing layer not degumming, firm pasting after solidification, water-color paintbrush ink energy moment of writing is absorbed.
Existing blotting printing paper mainly uses the absorption function of hard copy body, but plastic sheeting itself does not have water suction work(
Energy, and height waterproof, the present invention realizes him by way of building bridge between the plastic sheeting without adhesion strength and ink absorbing layer
Connection, with phase paper membrane replace printing paper, with environment protection significance；And need not put into jumbo and complexity process,
As long as finding the bridging substance that plastic sheeting and blotting material are adhesively fixed, any plastic sheeting can become printing photograph
Film；The present invention printing photograph film can be applicable to medical imaging film, wedding photo, indoor and outdoor advertising poster, spraying paint
Deng.
Embodiment 2
A kind of preparation method of inkjet printing photograph film of the present invention, first takes BOPP film as film basic unit, film basic unit
Thickness is 9 μm～11 μm；Then it is coated with film basic unit and have hydrophilic and have oil loving adhesive again, forms adhesive layer；It is viscous
Closing layer includes bonding bottom and bonding main stor(e)y, and first coating thickness is 1.5 μm～2 μm bonding bottoms in film basic unit, then in bonding
Coating thickness is 1 μm～1.5 μm of bonding main stor(e)y on bottom；The preparation method of the adhesive that bonding bottom is adopted includes：By Asia
Numb resin, terpene resin, thermoplastic elastomer (TPE) and ethanol are with 1:1:1.5:5 ratio is heated to after 90 DEG C of mixing dispersions, with EVA
Copolymer uniform stirring makes the bottom adhesive of viscosity 1269Pa.s～2000Pa.s, and the consumption of EVA copolymer is according to viscosity
Require different and different；The preparation method of the adhesive that bonding main stor(e)y is adopted includes：By thermoplastic elastomer (TPE), Petropols, EVA
Copolymer and ethanol are with 1.5:1.2:2:5.5 ratio makes main stor(e)y adhesive, in preparation process, first by thermoplastic elastomer (TPE)
90 DEG C are heated to, to it clear solution are melted into completely, then 40 DEG C～50 DEG C will be cooled to after Petropols heating for dissolving 1h,
EVA copolymer stirring 3h～4h is added, dehydrated alcohol is eventually adding and is diluted.When being coated with adhesive layer in film basic unit, adopt
Gravure coating method, and solidify in 12 meters of length, the drying tunnel of 80 DEG C of temperature.The method being coated with using nick is carried out to adhesive
Coating solidification is all right, and peel test is carried out with pressure sensitive adhesive tape, and test result shows that adhesive force is good.
Secondly ink absorbing layer is coated with bonding main stor(e)y, adhesive layer can be connected with film basic unit, can connect with ink absorbing layer again
Connect fixation；Ink absorbing layer includes blotting main stor(e)y and blotting pair layer, and first even spread thickness is 9 μm～11 μm of suction on bonding main stor(e)y
Black main stor(e)y, then even spread thickness is 2.5 μm～3 μm of blotting pair layer on blotting main stor(e)y；The system of material used by blotting main stor(e)y
Preparation Method includes：Nano titanium dioxide powder is dispersed in ethanol solution at a high speed, nano titanium oxide is in ethanol
Concentration is 12%, then again in nano titanium oxide ethanol solution add povidone iodine be prepared into 20% nanometer titanium dioxide
Titanium-povidone iodine ethanol solution, is eventually adding acrylic acid polyamide polymer, acrylic acid polyamide polymer in the solution dense
Spend for 0.05%～0.1%, that is, obtain blotting main stor(e)y material therefor, wherein acrylic acid polyamide polymer is with many hydrophilic
The low crosslinking degree of group or the high molecular polymer of partially crystallizable, more than the mesh of granularity 300, after milling plus as increased molten in solution
The specific surface area and water suction sexual function of liquid, blotting main stor(e)y is the high score of the low crosslinking degree with many hydrophilic groups or partially crystallizable
Sub- polymer, the specific surface area of the nano titanium oxide of blotting main stor(e)y is 400m2/ g～450m2/g；Material used by blotting pair layer
Preparation method includes：Nano titanium dioxide powder is dispersed in ethanol solution at a high speed, nano titanium oxide is in ethanol
Concentration be 9%, then again in nano titanium oxide ethanol solution add povidone iodine be prepared into 18% nanometer titanium dioxide
Titanium-povidone iodine ethanol solution, as blotting pair layer material therefor.The specific surface area of nano titanium oxide of blotting pair layer is
100m2/ g～200m2/g。
The last coating thickness on blotting pair layer is 2 μm～2.5 μm of shield layer of ink, protect layer of ink using 15%～18% it is poly-
The aqueous solution of dimension ketone K90, PVP-K90 is porogen and binding agent excellent on membrane technology, with amphipathic characteristic；On adhesive layer
When coating ink absorbing layer and shield layer of ink, using comma scraper coating process, and solidify in 25 meters of length, the drying tunnel of 80 DEG C of temperature,
Ink absorbing layer not degumming, firm pasting after solidification, water-color paintbrush ink energy moment of writing is absorbed.
Existing blotting printing paper mainly uses the absorption function of hard copy body, but plastic sheeting itself does not have water suction work(
Energy, and height waterproof, the present invention realizes him by way of building bridge between the plastic sheeting without adhesion strength and ink absorbing layer
Connection, with phase paper membrane replace printing paper, with environment protection significance；And need not put into jumbo and complexity process,
As long as finding the bridging substance that plastic sheeting and blotting material are adhesively fixed, any plastic sheeting can become printing photograph
Film；The present invention printing photograph film can be applicable to medical imaging film, wedding photo, indoor and outdoor advertising poster, spraying paint
Deng.
Elaborate many details in order to fully understand the present invention in the above description.But above description is only
Presently preferred embodiments of the present invention, the present invention can be implemented with being much different from alternate manner described here, therefore this
Invention is not embodied as being limited by disclosed above.Simultaneously any those skilled in the art are without departing from the technology of the present invention
In the case of aspects, all make many possible to technical solution of the present invention using the methods and techniques content of the disclosure above
Change and modify, or the Equivalent embodiments for being revised as equivalent variations.Every content without departing from technical solution of the present invention, according to this
The technical spirit of invention still falls within skill of the present invention to any simple modification made for any of the above embodiments, equivalent variations and modification
In the range of the protection of art scheme.
Claims (8)
1. a kind of preparation method of inkjet printing photograph film, it is characterised in that include：
Plastic sheeting is taken as film basic unit；
Existing hydrophilic is coated with the film basic unit oil loving adhesive again, forms adhesive layer；
Ink absorbing layer is coated with the adhesive layer；The adhesive layer can be adhesively fixed with film basic unit, can bond with ink absorbing layer again
It is fixed；
The coating shield layer of ink in the ink absorbing layer；
The plastic sheeting is PET film；The adhesive layer includes bonding bottom and bonding main stor(e)y, is first coated with film basic unit viscous
Bottom is closed, then the coating bonding main stor(e)y on bonding bottom；
The preparation method of the adhesive that the bonding bottom is adopted includes：By acrylic resin, EVA copolymer and deionized water with
1.5~2.5:50~60:2 ~ 3 ratio, the mix homogeneously stirring under the conditions of 90 DEG C makes viscosity for 1269Pa.s ~ 1500Pa.s's
Bottom adhesive；
The preparation method of the adhesive that the bonding main stor(e)y is adopted includes：Thermoplastic elastomer (TPE), rosin glycerol resin, EVA is common
Polymers and ethanol are with 1.2 ~ 2:1~1.5:1~3:5 ~ 6 ratio makes main stor(e)y adhesive, in preparation process, first by thermoplastic elastomehc
Gonosome is heated to 90 DEG C, and to it clear solution is melted into completely, is subsequently adding after rosin glycerol resin heating for dissolving 1h and is cooled to
40 DEG C ~ 50 DEG C, EVA copolymer stirring 3h ~ 4h is added, be eventually adding ethanol and be diluted.
2. a kind of preparation method of inkjet printing photograph film, it is characterised in that include：
Plastic sheeting is taken as film basic unit；
Existing hydrophilic is coated with the film basic unit oil loving adhesive again, forms adhesive layer；
Ink absorbing layer is coated with the adhesive layer；The adhesive layer can be adhesively fixed with film basic unit, can bond with ink absorbing layer again
It is fixed；
The coating shield layer of ink in the ink absorbing layer；
The plastic sheeting is BOPP film；The adhesive layer includes bonding bottom and bonding main stor(e)y, is first coated with film basic unit
Bonding bottom, then coating bonds main stor(e)y on bonding bottom；
The preparation method of the adhesive that the bonding bottom is adopted includes：By flax gum, terpene resin, thermoplastic elastomer (TPE) and
Ethanol is with 1:1:1.5:4 ~ 6 ratio is heated to after 90 DEG C of mixing dispersions, and with EVA copolymer uniform stirring viscosity is made
The bottom adhesive of 1269Pa.s ~ 2000Pa.s；
The preparation method of the adhesive that the bonding main stor(e)y is adopted includes：By thermoplastic elastomer (TPE), Petropols, EVA copolymer
With ethanol with 1.2 ~ 2:1~1.5:1~3:5 ~ 6 ratio makes main stor(e)y adhesive, in preparation process, first by thermoplastic elastomer (TPE)
90 DEG C are heated to, to it clear solution is melted into completely, be subsequently adding after Petropols heating for dissolving 1h and be cooled to 40 DEG C ~ 50
DEG C, EVA copolymer stirring 3h ~ 4h is added, it is eventually adding ethanol and is diluted.
3. a kind of preparation method of inkjet printing photograph film according to claim 1, it is characterised in that the ink absorbing layer includes
Blotting main stor(e)y and blotting pair layer, first the even spread blotting main stor(e)y on adhesive layer, is then coated with blotting pair layer on blotting main stor(e)y；
The preparation method of material includes used by the blotting main stor(e)y：Nano titanium dioxide powder is dispersed in into ethanol solution at a high speed
In, nano titanium oxide concentration in ethanol is 12%, then in nano titanium oxide ethanol solution adds povidone iodine again
20% nano titanium oxide-povidone iodine ethanol solution is prepared into, acrylic acid polyamide polymer is eventually adding, acrylic acid gathers
Amide polymer concentration in the solution is 0.05% ~ 0.1%, that is, obtain blotting main stor(e)y material therefor；
The preparation method of material includes used by the blotting pair layer：Nano titanium dioxide powder is dispersed in into ethanol solution at a high speed
In, nano titanium oxide concentration in ethanol is 9%, then in nano titanium oxide ethanol solution adds povidone iodine again
It is prepared into 18% nano titanium oxide-povidone iodine ethanol solution, as blotting pair layer material therefor.
4. a kind of preparation method of inkjet printing photograph film according to claim 3, it is characterised in that the blotting main stor(e)y institute
It is 400m with the specific surface area of nano titanium oxide2/g~600 m2/ g, the ratio table of nano titanium oxide used by the blotting pair layer
Area is 100 m2/g ~200 m2/g。
5. a kind of preparation method of inkjet printing photograph film according to claim 1 or claim 2, it is characterised in that the bonding bottom
The thickness of layer is 1.5 μm ~ 2 μm；The thickness of the bonding main stor(e)y is 1 μm ~ 1.5 μm.
6. a kind of preparation method of inkjet printing photograph film according to claim 3, it is characterised in that the blotting main stor(e)y
Thickness is 9 μm ~ 11 μm；The thickness of the blotting pair layer is 2.5 μm ~ 3 μm.
7. a kind of preparation method of inkjet printing photograph film according to claim 1, it is characterised in that be coated with film basic unit
During adhesive layer, using gravure coating method, and solidify in 12 meters of length, the drying tunnel of 80 DEG C of temperature；The coating on adhesive layer is inhaled
During layer of ink, using comma scraper coating process, and solidify in 25 meters of length, the drying tunnel of 80 DEG C of temperature.
8. a kind of inkjet printing photograph film, it is characterised in that the inkjet printing photograph film is using as claim 1 ~ 7 is arbitrary
The item preparation method is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410808196.7A CN104669811B (en) | 2014-12-23 | 2014-12-23 | Ink-jet printing photo film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410808196.7A CN104669811B (en) | 2014-12-23 | 2014-12-23 | Ink-jet printing photo film and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104669811A CN104669811A (en) | 2015-06-03 |
| CN104669811B true CN104669811B (en) | 2017-04-12 |
Family
ID=53305623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410808196.7A Expired - Fee Related CN104669811B (en) | 2014-12-23 | 2014-12-23 | Ink-jet printing photo film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104669811B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106739612A (en) * | 2015-11-19 | 2017-05-31 | 南阳柯丽尔科技有限公司 | A kind of medical silver film and preparation method thereof |
| CN109263335B (en) * | 2018-08-22 | 2021-02-26 | 安徽文峰特种纸业有限公司 | Anti-aging film-covering-free ink-jet printing photo paper |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201769461U (en) * | 2010-08-24 | 2011-03-23 | 杭州华大海天科技有限公司 | Transparent highlight waterproof PET digital photographic paper |
| CN201792569U (en) * | 2010-08-24 | 2011-04-13 | 杭州华大海天科技有限公司 | High-brightness waterproof polypropylene digital photo paper |
| CN202847150U (en) * | 2012-10-19 | 2013-04-03 | 刘维春 | Digital image film |
| CN103228456A (en) * | 2010-10-22 | 2013-07-31 | 卡尔斯特里姆保健公司 | Transparent ink-jet recording films |
| CN203401826U (en) * | 2013-06-21 | 2014-01-22 | 深圳市君安康医疗器械有限公司 | Environment-friendly non-sliver digital medical laser printing film |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010221509A (en) * | 2009-03-23 | 2010-10-07 | Mitsubishi Paper Mills Ltd | Method for manufacturing inkjet recording material |
-
2014
- 2014-12-23 CN CN201410808196.7A patent/CN104669811B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201769461U (en) * | 2010-08-24 | 2011-03-23 | 杭州华大海天科技有限公司 | Transparent highlight waterproof PET digital photographic paper |
| CN201792569U (en) * | 2010-08-24 | 2011-04-13 | 杭州华大海天科技有限公司 | High-brightness waterproof polypropylene digital photo paper |
| CN103228456A (en) * | 2010-10-22 | 2013-07-31 | 卡尔斯特里姆保健公司 | Transparent ink-jet recording films |
| CN202847150U (en) * | 2012-10-19 | 2013-04-03 | 刘维春 | Digital image film |
| CN203401826U (en) * | 2013-06-21 | 2014-01-22 | 深圳市君安康医疗器械有限公司 | Environment-friendly non-sliver digital medical laser printing film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104669811A (en) | 2015-06-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103753997B (en) | A kind of D2T2 thermal dye sublimation print printing paper | |
| CN105131747B (en) | A kind of environmentally-frieweak weak solvent type inkjet medium and preparation method thereof | |
| CN106832136B (en) | Multiple cross-linked core/shell structure type polyacrylate dispersion ink and preparation method thereof | |
| CN105647367A (en) | Digital printing transfer paper surface coating liquid | |
| CN103820046B (en) | A kind of pad pasting and manufacture method thereof being applicable to ink-jet printer | |
| CN104877419A (en) | Gouache and acrylic painting pigment and method for manufacturing same | |
| CN104669811B (en) | Ink-jet printing photo film and preparation method thereof | |
| CN105925190A (en) | Anti-static and scratch-resisting transparent matte gloss oil | |
| CN108928086A (en) | A kind of adhesive label of inkjet printable and preparation method thereof | |
| CN107325654B (en) | A kind of air brushing coating and preparation method thereof adapting to Latex ink | |
| CN106916326B (en) | Printing material of synthetic paper and preparation method | |
| CN105936811A (en) | Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof | |
| CN103009860B (en) | Printing paper coated with gold-loaded resin for ink-jet printing | |
| CN104789063A (en) | Method for preparing compatible ink-jet printing coating | |
| CN104371411B (en) | A kind of hydrate colour ink-jet printing media and production method thereof | |
| CN106364207A (en) | Transparent film for waterproof inkjet printing plate-making for printing plate-making industry | |
| CN107699067A (en) | Mould release, mould release membrance, composite membrane, ink-jet printing media and its preparation method and application | |
| CN105620071A (en) | Transfer film with concave-convex effect and preparing method of transfer film | |
| US10300736B2 (en) | Method and device of transferring an impression from a substrate to a surface | |
| CN104629503B (en) | A kind of Portable blackboard film easily wiped and preparation method thereof | |
| CN204398558U (en) | A kind of inkjet printing photograph film | |
| CN104725577A (en) | Ink seepage glue for canvas inkjet printing as well as preparation method and application method thereof | |
| CN203063306U (en) | Gold-loaded resin coated paper for ink-jet printing | |
| CN203126163U (en) | Powdered ink bonding layer for laser printing | |
| CN102174774A (en) | Protective layer emulsion for temperature-sensitive label paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170412 Termination date: 20191223 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |