CN105936811A - Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof - Google Patents

Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof Download PDF

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Publication number
CN105936811A
CN105936811A CN201610409417.2A CN201610409417A CN105936811A CN 105936811 A CN105936811 A CN 105936811A CN 201610409417 A CN201610409417 A CN 201610409417A CN 105936811 A CN105936811 A CN 105936811A
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CN
China
Prior art keywords
adhesive tape
cleaning adhesive
layer
tears
environment protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610409417.2A
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Chinese (zh)
Inventor
许金章
刘忠建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Yongguan Zhongcheng New Material Science And Technology (group) Ltd By Share Ltd
Original Assignee
Shanghai Yongguan Zhongcheng New Material Science And Technology (group) Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Yongguan Zhongcheng New Material Science And Technology (group) Ltd By Share Ltd filed Critical Shanghai Yongguan Zhongcheng New Material Science And Technology (group) Ltd By Share Ltd
Priority to CN201610409417.2A priority Critical patent/CN105936811A/en
Publication of CN105936811A publication Critical patent/CN105936811A/en
Priority to JP2017059788A priority patent/JP6549628B2/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/32Water-activated adhesive, e.g. for gummed paper
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2483/00Presence of polysiloxane
    • C09J2483/005Presence of polysiloxane in the release coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses an environment-friendly and easily tearable cleaning adhesive tape. The cleaning adhesive tape comprises a cloth base serving as the substrate, a waterborne silicon release layer coated on one side of the cloth base and a glue layer coated on the other side of the cloth base, the cloth base comprises filler and gauze, and the filler includes PE plastic and CH-808 plastic. The invention also discloses a preparation method of the environment-friendly and easily tearable cleaning adhesive tape. The environment-friendly and easily tearable cleaning adhesive tape adopts the cloth base as the substrate, is easily tearable and difficult to damage, and is also not easy to have incomplete edges, the tear port is neat and uniform, the ash sticking effect is good and no residue exists, also the cleaning adhesive tape does not contain chemical substances harmful to the human body and environment, the cloth base can be recovered and reused, and the preparation process and the use process are more environmentally friendly.

Description

Environment protection type easy tears cleaning adhesive tape and preparation method thereof
Technical field
The invention belongs to adhesive tape area, be specifically related to a kind of environment protection type easy and tear cleaning adhesive tape and preparation side thereof Method.
Background technology
Existing cleaning adhesive tape, generally with paper as base material and scribble hot-melt glue, can play basic binding dust and make With, but shortcoming has a lot: first with paper as base material, make to be finished rear cleaning adhesive tape can not recycling, The waste of paper and consumption strengthen and environment are brought immense pressure;Secondly, the cleaning adhesive tape with paper as base material Face is thin easily broken, therefore the situations such as uneven, the paper break of tearing notch often occurs;Again, due to paper easily quilt Pulling open, glue is easily adhered and remains in floor or other surfaces to be cleaned, it is difficult to process;It addition, at present The glue formula in gluing market is different, and many glue exist human body and with serious pollutionization of bad environmental Study point.
Summary of the invention
Therefore, the present invention is directed to existing cleaning adhesive tape cracky fracture, tearing notch appearance uneven, easy residual Stay thing and technical problem not environmentally, it is therefore intended that offer one is the most broken, tearing notch neat thing residue Environment protection type easy tear cleaning adhesive tape.
The environment protection type easy of the present invention tears cleaning adhesive tape and includes the cloth base as base material, is coated in described cloth embryo one The aqueous silicon release layer in face and the glue layer being coated in described cloth embryo another side, described cloth embryo includes inserts And gauze, described inserts includes PE plastics and CH-808 plastics.
For avoiding the cracky of the cleaning adhesive tape with paper as base material to rupture, tearing notch uneven, easy occur residual The shortcoming of thing, the present invention study use the cloth that is not easily broken to replace paper, preferably gauze because along The warp of gauze or parallel can readily be torn, not cracky when tearing, and are also not easy residual limit occur, can Ensure that tearing notch is neat.But the two sides of cleaning adhesive tape needs to coat different coatings, and one side is for scribbling glue Viscous red dog, another side is release not glued, owing to the permeability of gauze is relatively strong, on gauze directly Coating glue is easy to penetrate into another side, it is impossible to realize one side coating glue.Therefore the present invention uses institute Stating the described cloth embryo that inserts and gauze be composited is base material, but described cloth embryo is not easily broken and easily tears Open, and can be with double plastic-coated, one side, as release, is coated with described aqueous silicon release layer, another Face is used for gluing ash and is coated with glue layer, aqueous silicon and glue and can readily be respectively coated with absorption at described cloth embryo Two sides and relative another side will not be penetrated into.
Described inserts: the weight ratio of described gauze is the preferred 6.67:1 of 5-10:1, warp in described gauze Line: the weight ratio of parallel is 0.4-1:1, preferably 0.67:1, horizontal more easily along parallel with this gauze Tear.
PE plastics: the weight ratio of CH-808 plastics is 1-3:1, preferably 1.3-2.5, more preferably 1.8:1.
CH-808 plastics are the compound of polyethylene, heavy calcium carbonate and multiple compounds, actual Commercially available prod CH-808 plastic pellet can be used when preparing described cloth embryo, as a kind of mould filling master batch, Add certain proportion and can increase stretching resistance and the anti-wear performance of described cloth embryo.
In one preferred embodiment of the present invention, described aqueous silicon release layer is waterborne organic silicon resin bed, institute Stating glue layer is acrylic glue layer, and waterborne organic silicon resin and acrylic glue are ep-type material, And the viscous ash effect of the release effect of waterborne organic silicon resin and acrylic glue is preferable.
In one preferred embodiment of the present invention, what it also included being coated in described cloth embryo one side is positioned at described water The water color ink of Xing Gui release layer lower floor.Various patterns can be printed at described release with this, improve described Environment protection type easy tears the apparent visual effect of cleaning adhesive tape.
Another object of the present invention is to provide a kind of and prepare the method that described environment protection type easy tears cleaning adhesive tape, It comprises the following steps:
(1) by multiple to the described inserts of 5-10 preferably 6.67 weight portion and the described gauze of 1 weight portion Synthesis can the cloth base of double plastic-coated;
(2) one side at described cloth embryo uniformly coats one layer of aqueous silicon mould release, and baking and curing;
(3) another side at described cloth embryo uniformly coats one layer of acrylic glue, and dries to obtain described ring Guarantor's type easily tears cleaning adhesive tape.
In the step (1) of the described method of one preferred embodiment of the present invention, described inserts is moulded by PE Material particle and CH-808 plastic pellet is melt-blended forms, PE plastic pellet: CH-808 plastic pellet Mixed weight is than for 1-3:1, preferably 1.3-2.5, more preferably 1.8:1;Described gauze middle longitude: parallel Weight ratio be the preferred 0.67:1 of 0.4-1:1;Fusing, combined temp are 260 DEG C-300 DEG C.
In the step (2) of the described method of one preferred embodiment of the present invention, the aqueous silicon of coating is release Agent be solid content be the waterborne organic silicon resin of 33%-45% preferably 40%, the coating of waterborne organic silicon resin Amount is 0.2-0.5 weight portion preferably 0.33 weight portion, dries through 90 DEG C of-100 DEG C of drying tunnels after coating.
In the step (3) of the described method of one preferred embodiment of the present invention, the glue of coating is for admittedly to contain Amount is the acrylic glue of 40%-60% preferably 50%, and the coated weight of acrylic glue is that 1-3 weight portion is excellent Select 2 weight portions, dry through 100 DEG C of-110 DEG C of drying tunnels after coating.
In the step (2) of the described method of one preferred embodiment of the present invention: in the one side of described cloth embryo First one layer of water color ink of coating, even print goes out water color ink air dry cure after predetermined pattern, then at water Property ink on uniform one layer of aqueous silicon mould release of coating, then by aqueous silicon mould release baking and curing.
The most progressive effect of the present invention is:
1, the environment protection type easy of the present invention tears the cloth that cleaning adhesive tape is composited with the gauze easily torn and inserts Embryo is base material, easily can tear from target location along reserved otch, be difficult to when tearing during use Breakage, is also not easy residual limit occur, and tearing notch is uniform, and uses the aqueous Asia of environment-friendly type high performance Gram force glue is as viscose glue, and cohesive force is strong, can easily stick out the dust on floor and without any residual during use Stay thing.
2, the described environment protection type easy of preparing of the present invention tears in the method technique of cleaning adhesive tape without increasing antiseepage Flow process, can directly coat aqueous silicon mould release and glue at described cloth embryo surface, with the aqueous silicon of environment-friendly type Silicon mould release realizes release technology, selects the acrylic glue of environment-friendly type high performance as viscose glue simultaneously, keeps away Exempt to use containing to human body and the chemical substance of bad environmental, whole preparation technology and follow-up use process more Add environmental protection, and described cloth embryo is more durable, can recycle and reuse, it is to avoid use a large amount of paper Open and alleviate ambient pressure.
3, with described cloth embryo as base material, can coat different water color inks for customer requirement, customization is not With adhesive tape pattern so that described environment protection type easy tear cleaning adhesive tape the most exquisite generous, be rich in individual character.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail:
Embodiment 1-3 environment protection type easy tears the preparation of cleaning adhesive tape
The environment protection type easy of preparation embodiment 1-3 tears required raw material and parameter such as table 1 institute of cleaning adhesive tape Showing, be wherein 1 weight portion with gauze, other components are relative weight part.
Preparation process is as follows:
Mix at temperature T1 after (1) PE plastic pellet being stirred with CH-808 plastic pellet, Fusing, and be combined into gauze can the cloth base of double plastic-coated;
(2) waterborne organic silicon resin is added in feed chute, drives cloth base to rotate by anilox roll in hopper, One side at cloth embryo is evenly coated with one layer of waterborne organic silicon resin, dries through the drying tunnel that excess temperature is T2, The surface being solidificated in cloth embryo forms release waterborne organic silicon stable resin;
(3) another side at cloth base coats one layer of aqueous acrylic glue uniformly by straight coating method, Dry through the drying tunnel that excess temperature is T3.
Obtain environment protection type easy after drying and tear cleaning adhesive tape, then can carry out rewinding, cutting and packaging.
Table 1 raw material and preparation parameter
Effect example
Tear cleaning adhesive tape with the environment protection type easy of embodiment 1 preparation and commercially available cleaning paper adhesive tape carries out performance Contrast test, result is as shown in table 2.
Table 2 the performance test results
Compared to existing product, the environment protection type easy of the present invention tear the adhesive property of cleaning adhesive tape, temperature tolerance, Stability is more preferable, and more environmentally-friendly.And the environment protection type easy of the present invention tear cleaning adhesive tape can be readily along Gauze parallel is torn, not cracky when tearing, and is also not easy residual limit occur, it is ensured that tearing notch is neat, enters And be difficult to when using leave dead angle and do not stay residue, improve viscous ash effect.
It addition, at release of cloth embryo, can first coat one layer of water color ink, even print goes out predetermined pattern After by water color ink air dry cure, more uniformly one layer of aqueous silicon mould release of coating on water color ink, then By aqueous silicon mould release baking and curing.Different water color inks, customization can be coated for customer requirement with this Different adhesive tape patterns so that described environment protection type easy tear cleaning adhesive tape the most exquisite generous, be rich in individual character.

Claims (10)

1. an environment protection type easy tears cleaning adhesive tape, it is characterised in that it include the cloth base as base material, It is coated in the aqueous silicon release layer of described cloth embryo one side and is coated in the glue layer of described cloth embryo another side, institute State cloth embryo and include that inserts and gauze, described inserts include PE plastics and CH-808 plastics.
2. environment protection type easy as claimed in claim 1 tears cleaning adhesive tape, it is characterised in that described filling Material: the weight ratio of described gauze is the preferred 6.67:1 of 5-10:1, described gauze middle longitude: the weight of parallel Amount ratio is 0.4-1:1, preferably 0.67:1.
3. environment protection type easy as claimed in claim 2 tears cleaning adhesive tape, it is characterised in that PE plastics: The weight ratio of CH-808 plastics is 1-3:1, preferably 1.3-2.5, more preferably 1.8:1.
4. environment protection type easy as claimed in claim 1 tears cleaning adhesive tape, it is characterised in that described aqueous Silicon release layer is waterborne organic silicon resin bed, and described glue layer is acrylic glue layer.
5. environment protection type easy as claimed in claim 1 tears cleaning adhesive tape, it is characterised in that it also includes It is coated in the water color ink being positioned at described aqueous silicon release layer lower floor of described cloth embryo one side.
6. prepare the method that the environment protection type easy described in any one of claim 1-4 tears cleaning adhesive tape, It is characterized in that, comprise the following steps:
(1) by multiple to the described inserts of 5-10 preferably 6.67 weight portion and the described gauze of 1 weight portion Synthesis can the cloth base of double plastic-coated;
(2) one side at described cloth embryo uniformly coats one layer of aqueous silicon mould release, and baking and curing;
(3) another side at described cloth embryo uniformly coats one layer of acrylic glue, and dries to obtain described ring Guarantor's type easily tears cleaning adhesive tape.
7. method as claimed in claim 6, it is characterised in that in step (1), described inserts By PE plastic pellet with CH-808 plastic pellet is melt-blended forms, PE plastic pellet: CH-808 moulds The mixed weight ratio of material particle is for 1-3:1, preferably 1.3-2.5, more preferably 1.8:1;In described gauze Warp: the weight ratio of parallel is the preferred 0.67:1 of 0.4-1:1;Fusing, combined temp are 260 DEG C-300 ℃。
8. method as claimed in claim 6, it is characterised in that in step (2), the aqueous of coating Silicon mould release be solid content be the waterborne organic silicon resin of 33%-45% preferably 40%, waterborne organic silicon resin Coated weight be 0.2-0.5 weight portion preferably 0.33 weight portion, through 90 DEG C of-100 DEG C of drying tunnels after coating Dry.
9. method as claimed in claim 6, it is characterised in that in step (3), the glue of coating For the acrylic glue that solid content is 40%-60% preferably 50%, the coated weight of acrylic glue is 1-3 weight Amount part preferably 2 weight portion, dries through 100 DEG C of-110 DEG C of drying tunnels after coating.
10. method as claimed in claim 6, it is characterised in that in step (2): at described cloth The one side of embryo first coats one layer of water color ink, and water color ink is air-dried solid by even print after going out predetermined pattern Change, more uniformly one layer of aqueous silicon mould release of coating on water color ink, then aqueous silicon mould release is dried Solidification.
CN201610409417.2A 2016-06-13 2016-06-13 Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof Pending CN105936811A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201610409417.2A CN105936811A (en) 2016-06-13 2016-06-13 Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof
JP2017059788A JP6549628B2 (en) 2016-06-13 2017-03-24 How to make eco-peel easy to clean tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610409417.2A CN105936811A (en) 2016-06-13 2016-06-13 Environment-friendly and easily tearable cleaning adhesive tape and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108997947A (en) * 2018-07-16 2018-12-14 上海晶华胶粘新材料股份有限公司 A kind of paper film cleaning adhesive tape and preparation method thereof
CN111040657A (en) * 2019-12-31 2020-04-21 上海永冠众诚新材料科技(集团)股份有限公司 Multicolor printing cloth-based adhesive tape and preparation method thereof
CN111117509A (en) * 2019-12-31 2020-05-08 上海永冠众诚新材料科技(集团)股份有限公司 Cloth base cleaning adhesive tape and preparation method thereof
CN117085985A (en) * 2023-10-19 2023-11-21 靖江瑞泰胶带有限公司 Deep cleaning equipment before rubberized fabric substrate rubber coating

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CN103320043A (en) * 2013-06-17 2013-09-25 昆山韩保胶带科技有限公司 Powerful adhesive tape
CN103725222A (en) * 2013-12-26 2014-04-16 广州市白云区麒胜装饰材料厂 Masking tape containing printing layer and preparation method thereof
CN104987845A (en) * 2015-07-17 2015-10-21 上海永冠胶粘制品股份有限公司 Environmentally-friendly easy tearing protection adhesive tape and production method thereof

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JPH07101603A (en) * 1993-10-12 1995-04-18 Dainippon Printing Co Ltd Paper connection preparation method for roll paper and connecting tape thereof
CN101619199A (en) * 2008-07-03 2010-01-06 李俊辉 Manufacture technique of easy tear tape
CN103254836A (en) * 2013-05-21 2013-08-21 昆山韩保胶带科技有限公司 Preparation method of novel adhesive tape
CN103320043A (en) * 2013-06-17 2013-09-25 昆山韩保胶带科技有限公司 Powerful adhesive tape
CN103725222A (en) * 2013-12-26 2014-04-16 广州市白云区麒胜装饰材料厂 Masking tape containing printing layer and preparation method thereof
CN104987845A (en) * 2015-07-17 2015-10-21 上海永冠胶粘制品股份有限公司 Environmentally-friendly easy tearing protection adhesive tape and production method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108997947A (en) * 2018-07-16 2018-12-14 上海晶华胶粘新材料股份有限公司 A kind of paper film cleaning adhesive tape and preparation method thereof
CN111040657A (en) * 2019-12-31 2020-04-21 上海永冠众诚新材料科技(集团)股份有限公司 Multicolor printing cloth-based adhesive tape and preparation method thereof
CN111117509A (en) * 2019-12-31 2020-05-08 上海永冠众诚新材料科技(集团)股份有限公司 Cloth base cleaning adhesive tape and preparation method thereof
CN117085985A (en) * 2023-10-19 2023-11-21 靖江瑞泰胶带有限公司 Deep cleaning equipment before rubberized fabric substrate rubber coating
CN117085985B (en) * 2023-10-19 2023-12-19 靖江瑞泰胶带有限公司 Deep cleaning equipment before rubberized fabric substrate rubber coating

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JP2017222836A (en) 2017-12-21

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Inventor before: Liu Zhongjian

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Application publication date: 20160914

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