CN105925190A - Anti-static and scratch-resisting transparent matte gloss oil - Google Patents
Anti-static and scratch-resisting transparent matte gloss oil Download PDFInfo
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- CN105925190A CN105925190A CN201610455900.4A CN201610455900A CN105925190A CN 105925190 A CN105925190 A CN 105925190A CN 201610455900 A CN201610455900 A CN 201610455900A CN 105925190 A CN105925190 A CN 105925190A
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- gloss oil
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- acetate resin
- transparent matte
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses anti-static and scratch-resisting transparent matte gloss oil. The anti-static and scratch-resisting transparent matte gloss oil is prepared from the following components in parts by mass: 62 to 68 parts of barium sulfate pulp of which the mass fractionis 20 percent, 10 to 12 parts of polyurethane resin, 0.5 to 1.5 parts of vinyl chloride and vinyl acetate resin liquid, 10 to 15 parts of wax, 0.01 to 0.05 part of antistatic agent, 0.4 to 0.6 part of 301 flatting agent, 0.4 to 0.6 part of slipping agent, 1.4 to 1.6 parts of 401LS flatting agent, 5.2 to 5.5 parts of cellulose acetate resin and 2.6 to 3.0 parts of N-propyl acetate, wherein the mass fraction of the vinyl chloride and vinyl acetate resin liquid is 20 percent, the vinyl chloride and vinyl acetate resin liquid is prepared by dissolving vinyl chloride and vinyl acetate resin powder in a solvent through stirring, and the solvent is prepared from the N-propyl acetate and isopropyl alcohol according to a mass ratio of 8:2. According to the anti-static and scratch-resisting transparent matte gloss oil disclosed by the invention, the defects in mechanic performance and weather resistance of transparent matte gloss oil are improved, a paint film on a printed product after coating of gloss oil is enabled to have good hardness, good scratch resistance, good impact resistance, good water resistance and good corrosion resistance, and meanwhile, the paint film has good anti-static performance, so that the using performance of the product is greatly improved.
Description
Technical field
The present invention relates to gloss oil technical field, particularly relate to a kind of transparent matte gloss oil of antistatic scratch-resistant.
Background technology
On the just important means of polish after print; mainly by being coated with (or spray, print) layer of transparent coating at printed matter surface; through levelling, it is dried, press polish, forms a kind of uniform and thin transparent optical bright layers at printed matter surface after solidification, play technique or the technology of the finish machining functions strengthening carrier surface smoothness, protection printing figure message.Glazing is possible not only to strengthen surface-brightening, protects printing figure message, and does not affect the recycling of paper.Therefore, the Surface Machining of the printings such as packing carton, books, picture album, pictorial poster it is widely used in.Nowadays, in transparent matte gloss oil product, there is product weatherability not enough, wearability, resistance to water are not enough more.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of antistatic scratch-resistant transparent dumb light ink.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is:
A kind of transparent matte gloss oil of antistatic scratch-resistant is provided, the composition of following mass fraction is prepared from: the barium sulfate slurry of 20% mass fraction 62 ~ 68 parts, polyurethane resin 10 ~ 12 parts, vinyl chloride-vinyl acetate resin liquid 0.5 ~ 1.5 part, 10 ~ 15 parts of wax, 0.01 ~ 0.05 part of antistatic additive, 301 levelling agent 0.4 ~ 0.6 part, slipping agent 0.4 ~ 0.6 part, 401LS levelling agent 1.4 ~ 1.6 parts, cellulose acetate resin 5.2 ~ 5.5 parts and n-propyl acetate 2.6 ~ 3.0 parts；The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
In a preferred embodiment of the present invention, the composition of following mass fraction it is prepared from: the barium sulfate slurry of 20% mass fraction 64 parts, polyurethane resin 11.2 parts, vinyl chloride-vinyl acetate resin liquid 1.05 parts, 13 parts of wax, 0.03 part of antistatic additive, 301 levelling agent 0.53 part, slipping agent 0.53 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, n-propyl acetate 2.86 parts.
In a preferred embodiment of the present invention, the model of described polyurethane resin is M-6638.
In a preferred embodiment of the present invention, the model of described vinyl chloride-vinyl acetate resin is VP-10.
In a preferred embodiment of the present invention, described wax is 50 wax slurries.
In a preferred embodiment of the present invention, described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%.
In a preferred embodiment of the present invention, described slipping agent is silicone oil.
In a preferred embodiment of the present invention, described cellulose acetate resin is cellulose acetate phthalate.
The invention has the beneficial effects as follows: the one transparent matte gloss oil of antistatic scratch-resistant of the present invention, improve the defect in transparent matte gloss oil mechanicalness and weatherability, after making coating gloss oil, the paint film on leaflet has good hardness, scratch resistance, resistance to impact, resistance to water and corrosion resistance, the most also there is good antistatic performance, substantially improve the serviceability of product.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1: a kind of transparent matte gloss oil of antistatic scratch-resistant, is prepared from by the composition of following mass fraction: the barium sulfate slurry of 20% mass fraction 64 parts, polyurethane resin 11.2 parts, vinyl chloride-vinyl acetate resin liquid 1.05 parts, 13 parts of wax, 0.03 part of antistatic additive, 301 levelling agent 0.53 part, slipping agent 0.53 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, n-propyl acetate 2.86 parts.
The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol；The model of described polyurethane resin is M-6638, and the model of described vinyl chloride-vinyl acetate resin is VP-10, and described wax is 50 wax slurries；Described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%；Described slipping agent is silicone oil, and described cellulose acetate resin is cellulose acetate phthalate.
Embodiment 2: a kind of transparent matte gloss oil of antistatic scratch-resistant, is prepared from by the composition of following mass fraction: the barium sulfate slurry of 20% mass fraction 63 parts, polyurethane resin 10.5 parts, vinyl chloride-vinyl acetate resin liquid 1.2 parts, 12.5 parts of wax, 0.03 part of antistatic additive, 301 levelling agent 0.55 part, slipping agent 0.55 part, 401LS levelling agent 1.4 parts, cellulose acetate resin 5.4 parts, n-propyl acetate 2.75 parts.
The model of each composition is with embodiment 1.
Embodiment 3: a kind of transparent matte gloss oil of antistatic scratch-resistant, is prepared from by the composition of following mass fraction: the barium sulfate slurry of 20% mass fraction 65 parts, polyurethane resin 11.5 parts, vinyl chloride-vinyl acetate resin liquid 0.88 part, 11.6 parts of wax, 0.035 part of antistatic additive, 301 levelling agent 0.5 part, slipping agent 0.6 part, 401LS levelling agent 1. 6 parts, cellulose acetate resin 5.3 parts, n-propyl acetate 2.85 parts.
The model of each composition is with embodiment 1.
The preparation method of above three embodiment is as follows:
1) get the raw materials ready, the constituent of formulation weight is weighed standby；
2) configuration vinyl chloride-vinyl acetate resin liquid, first mixes formation solvent by n-propyl acetate and isopropanol according to mass ratio 8:2, after vinyl chloride-vinyl acetate resin powder is mixed with solvent, obtain the vinyl chloride-vinyl acetate resin liquid that mass fraction is 20%；
3) stirring, is mixed and stirred for 2h by the barium sulfate slurry of formulation weight number, polyurethane resin, vinyl chloride-vinyl acetate resin liquid, wax, cellulose acetate resin and n-propyl acetate；
4) add adjuvant, antistatic additive, 301 levelling agents, slipping agent and 401LS levelling agent are added in the material that step 3) is formed, continue stirring 30min, obtain finished product.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, the most in like manner it is included in the scope of patent protection of the present invention.
Claims (8)
1. the transparent matte gloss oil of antistatic scratch-resistant, it is characterized in that, the composition of following mass fraction be prepared from: the barium sulfate slurry of 20% mass fraction 62 ~ 68 parts, polyurethane resin 10 ~ 12 parts, vinyl chloride-vinyl acetate resin liquid 0.5 ~ 1.5 part, 10 ~ 15 parts of wax, 0.01 ~ 0.05 part of antistatic additive, 301 levelling agent 0.4 ~ 0.6 part, slipping agent 0.4 ~ 0.6 part, 401LS levelling agent 1.4 ~ 1.6 parts, cellulose acetate resin 5.2 ~ 5.5 parts and n-propyl acetate 2.6 ~ 3.0 parts；The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1, it is characterized in that, the composition of following mass fraction be prepared from: the barium sulfate slurry of 20% mass fraction 64 parts, polyurethane resin 11.2 parts, vinyl chloride-vinyl acetate resin liquid 1.05 parts, 13 parts of wax, 0.03 part of antistatic additive, 301 levelling agent 0.53 part, slipping agent 0.53 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, n-propyl acetate 2.86 parts.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterised in that the model of described polyurethane resin is M-6638.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterised in that the model of described vinyl chloride-vinyl acetate resin is VP-10.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterised in that described wax is 50 wax slurries.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterized in that, described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterised in that described slipping agent is silicone oil.
The transparent matte gloss oil of antistatic scratch-resistant the most according to claim 1 and 2, it is characterised in that described cellulose acetate resin is cellulose acetate phthalate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610455900.4A CN105925190A (en) | 2016-06-22 | 2016-06-22 | Anti-static and scratch-resisting transparent matte gloss oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610455900.4A CN105925190A (en) | 2016-06-22 | 2016-06-22 | Anti-static and scratch-resisting transparent matte gloss oil |
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| CN105925190A true CN105925190A (en) | 2016-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610455900.4A Pending CN105925190A (en) | 2016-06-22 | 2016-06-22 | Anti-static and scratch-resisting transparent matte gloss oil |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022264A (en) * | 2017-02-14 | 2017-08-08 | 滁州金桥德克新材料有限公司 | The aqueous scratch resistance dumb paint of high rigidity |
| CN107384202A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of metope beautification oil polish and preparation method thereof |
| CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
| CN110565394A (en) * | 2019-09-12 | 2019-12-13 | 中山市中益油墨涂料有限公司 | Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof |
| CN116426204A (en) * | 2023-04-21 | 2023-07-14 | 浙江龙游道明光学有限公司 | Matte protective gloss oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333550A (en) * | 2013-07-09 | 2013-10-02 | 珠海市乐通化工股份有限公司 | Novel laminated steel ink and preparation method thereof |
| CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
| CN104004408A (en) * | 2014-05-27 | 2014-08-27 | 苏州创佳电子材料有限公司 | White transparent ink for electronic product and preparation method of white transparent ink |
-
2016
- 2016-06-22 CN CN201610455900.4A patent/CN105925190A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333550A (en) * | 2013-07-09 | 2013-10-02 | 珠海市乐通化工股份有限公司 | Novel laminated steel ink and preparation method thereof |
| CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
| CN104004408A (en) * | 2014-05-27 | 2014-08-27 | 苏州创佳电子材料有限公司 | White transparent ink for electronic product and preparation method of white transparent ink |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022264A (en) * | 2017-02-14 | 2017-08-08 | 滁州金桥德克新材料有限公司 | The aqueous scratch resistance dumb paint of high rigidity |
| CN107384202A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of metope beautification oil polish and preparation method thereof |
| CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
| CN110565394A (en) * | 2019-09-12 | 2019-12-13 | 中山市中益油墨涂料有限公司 | Anti-sticking gloss oil for case cloth with PVC coating and preparation method thereof |
| CN116426204A (en) * | 2023-04-21 | 2023-07-14 | 浙江龙游道明光学有限公司 | Matte protective gloss oil |
| CN116426204B (en) * | 2023-04-21 | 2024-04-02 | 浙江龙游道明光学有限公司 | Matte protective gloss oil |
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Application publication date: 20160907 |