CN105925189A - Nano microsphere scratching-resisting and high-covering matte gloss oil - Google Patents
Nano microsphere scratching-resisting and high-covering matte gloss oil Download PDFInfo
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- CN105925189A CN105925189A CN201610455620.3A CN201610455620A CN105925189A CN 105925189 A CN105925189 A CN 105925189A CN 201610455620 A CN201610455620 A CN 201610455620A CN 105925189 A CN105925189 A CN 105925189A
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- acetate resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses nano microsphere scratching-resisting and high-covering matte gloss oil. The nano microsphere scratching-resisting and high-covering matte gloss oil is prepared from the following components in parts by mass: 3 to 4 parts of matting agent, 3 to 5 parts of light diffusion microspheres, 0.5 to 1.5 parts of polyethylene wax, 10 to 15 parts of vinyl chloride-vinyl acetate resin liquid, 20 to 25 parts of polyurethane resin liquid with the mass fraction of 30 percent, 0.2 to 0.6 part of antistatic agent, 0.5 to 1.5 parts of dispersant, 22 to 28 parts of n-propyl acetate, 10 to 14 parts of isopropyl alcohol, 0.3 to 0.8 part of adhesion promoter, 1.2 to 1.8 parts of 401LS flatting agent, 5 to 6 parts of cellulose acetate resin, 10 to 12 parts of wax and 0.5 to 0.6 part of 301 flatting agent; the mass fraction of the vinyl chloride-vinyl acetate resin liquid is 20 percent and is prepared by dissolving vinyl chloride-vinyl acetate resin powder into a solvent and stirring; the solvent is prepared by mixing the n-propyl acetate and the isopropyl alcohol at the mass ratio of 8 to 2. The light diffusion microspheres disclosed by the invention have light unifying and transmitting effects so that the needed matte effect is obtained; meanwhile, a paint film has good hardness and scratching-resisting performance and also has a good antistatic performance, and the utilization performance of a product is greatly improved.
Description
Technical field
The present invention relates to gloss oil technical field, particularly relate to a kind of Nano microsphere scratch-resistant height and hide matte gloss oil.
Background technology
On the just important means of polish after print; mainly by being coated with (or spray, print) layer of transparent coating at printed matter surface; through levelling, it is dried, press polish, forms a kind of uniform and thin transparent optical bright layers at printed matter surface after solidification, play technique or the technology of the finish machining functions strengthening carrier surface smoothness, protection printing figure message.Glazing is possible not only to strengthen surface-brightening, protects printing figure message, and does not affect the recycling of paper.Therefore, the Surface Machining of the printings such as packing carton, books, picture album, pictorial poster it is widely used in.Dumb light ink now, should reach dumb light, reach high again and hide and the ink of mechanical performance of scratch-resistant is less, service life section, matte effect is not ideal enough.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of Nano microsphere scratch-resistant height and hides matte gloss oil.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is:
There is provided a kind of Nano microsphere scratch-resistant height to hide matte gloss oil, the composition of following mass fraction be prepared from: flatting silica 3 ~ 4 parts, light diffusion microsphere 3 ~ 5 parts, Tissuemat E 0.5 ~ 1.5 part, vinyl chloride-vinyl acetate resin liquid 10 ~ 15 parts, the polyurethane resin liquid 20 ~ 25 parts of 30% mass fraction, 0.2 ~ 0.6 part of antistatic additive, dispersant 0.5 ~ 1.5 part, n-propyl acetate 22 ~ 28 parts, isopropanol 10 ~ 14 parts, adhesion promoter 0.3 ~ 0.8 part, 401LS levelling agent 1.2 ~ 1.8 parts, cellulose acetate resin 5 ~ 6 parts, 10 ~ 12 parts of wax and 301 levelling agents 0.5 ~ 0.6 part；The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
In a preferred embodiment of the present invention, the composition of following mass fraction it is prepared from: flatting silica 3.5 parts, light diffusion microsphere 4 parts, Tissuemat E 1 part, vinyl chloride-vinyl acetate resin liquid 12 parts, the polyurethane resin liquid 23 parts of 30% mass fraction, 0.5 part of antistatic additive, dispersant 1 part, n-propyl acetate 25 parts, isopropanol 11.77 parts, adhesion promoter 0.5 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, 10.4 parts of wax and 301 levelling agents 0.53 part.
In a preferred embodiment of the present invention, the model of described light diffusion microsphere is LPS020.
In a preferred embodiment of the present invention, described Tissuemat E is 3620 polyethylene wax powder.
In a preferred embodiment of the present invention, the model of described vinyl chloride-vinyl acetate resin is VP-10.
In a preferred embodiment of the present invention, the model of described polyurethane resin is M-6638.
In a preferred embodiment of the present invention, described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%.
In a preferred embodiment of the present invention, described dispersant is 9375 dispersants.
In a preferred embodiment of the present invention, described adhesion promoter is modified chlorinated polypropylene.
In a preferred embodiment of the present invention, described cellulose acetate resin is cellulose acetate phthalate.
The invention has the beneficial effects as follows: one Nano microsphere scratch-resistant height of the present invention hides matte gloss oil, wherein add light scattering microsphere, light scattering microsphere is a kind of organic nano microballon light diffusing agent, this light of light diffusing agent material own can pass through, well solving the problem well solving even light and printing opacity, this kind of light diffusing agent is different with the refractive index of microballon by base material, reflects through light repeatedly, reaching soft light effect, the printing opacity loss of energy is less.This organic light scattering microsphere, it it is a kind of tiny transparent ball, in ink, can be uniformly dispersed in resin, the light injected can pass these transparent balls, through refraction many times in transparent ball, then penetrates, the strongest light is through superrefraction, uniform dispersion, makes point source become area source, expands light-emitting area, and make light become the softest, light can penetrate " glass " light diffusing agent spheroid simultaneously, so the loss of light is few, serves even light, the effect of printing opacity, thus reach the matte effect needed.Meanwhile, present invention also improves the defect in matte gloss oil mechanicalness and weatherability, make paint film have good hardness and scratch resistance, also there is good antistatic performance, substantially improve the serviceability of product.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1: a kind of Nano microsphere scratch-resistant height hides matte gloss oil, the composition of following mass fraction be prepared from: flatting silica 3.5 parts, light diffusion microsphere 4 parts, Tissuemat E 1 part, vinyl chloride-vinyl acetate resin liquid 12 parts, the polyurethane resin liquid 23 parts of 30% mass fraction, 0.5 part of antistatic additive, dispersant 1 part, n-propyl acetate 25 parts, isopropanol 11.77 parts, adhesion promoter 0.5 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, 10.4 parts of wax and 301 levelling agents 0.53 part.
The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol；The model of described flatting silica is TS100, and for silicon dioxide, the model of described light diffusion microsphere is LPS020, and described Tissuemat E is 3620 polyethylene wax powder, and the model of described vinyl chloride-vinyl acetate resin is VP-10, and the model of described polyurethane resin is M-6638；Described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%；Described dispersant is 9375 dispersants, and described adhesion promoter is modified chlorinated polypropylene, and described cellulose acetate resin is cellulose acetate phthalate.
Embodiment 2: a kind of Nano microsphere scratch-resistant height hides matte gloss oil, the composition of following mass fraction be prepared from: flatting silica 3.5 parts, light diffusion microsphere 4.5 parts, Tissuemat E 1.2 parts, vinyl chloride-vinyl acetate resin liquid 13 parts, the polyurethane resin liquid 24 parts of 30% mass fraction, 0.45 part of antistatic additive, dispersant 1.2 parts, n-propyl acetate 26 parts, isopropanol 11 parts, adhesion promoter 0.4 part, 401LS levelling agent 1.45 parts, cellulose acetate resin 5.55 parts, 11.3 parts of wax and 301 levelling agents 0.55 part.
The model of each composition is with embodiment 1.
Embodiment 3: a kind of Nano microsphere scratch-resistant height hides matte gloss oil, the composition of following mass fraction be prepared from: flatting silica 3.6 parts, light diffusion microsphere 4.5 parts, Tissuemat E 0.8 part, vinyl chloride-vinyl acetate resin liquid 12.5 parts, the polyurethane resin liquid 22.5 parts of 30% mass fraction, 0.45 part of antistatic additive, dispersant 0.9 part, n-propyl acetate 26 parts, isopropanol 12.5 parts, adhesion promoter 0.65 part, 401LS levelling agent 1.8 parts, cellulose acetate resin 5.4 parts, 10.5 parts of wax and 301 levelling agents 0.5 part.
The model of each composition is with embodiment 1.
The preparation method of above three embodiment is as follows:
1) get the raw materials ready, the constituent of formulation weight is weighed standby；
2) configuration vinyl chloride-vinyl acetate resin liquid, first mixes formation solvent by n-propyl acetate and isopropanol according to mass ratio 8:2, after vinyl chloride-vinyl acetate resin powder is mixed with solvent, obtain the vinyl chloride-vinyl acetate resin liquid that mass fraction is 20%；
3) stirring, is mixed and stirred for 2h by the flatting silica of formulation weight number, light diffusion microsphere, Tissuemat E, vinyl chloride-vinyl acetate resin liquid, polyurethane resin liquid, dispersion machine, n-propyl acetate, isopropanol, cellulose acetate resin and wax；
4) add adjuvant, antistatic additive, adhesion promoter, 401LS levelling agent and 301 levelling agents are added in the material that step 3) is formed, continue stirring 30min, obtain finished product.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, the most in like manner it is included in the scope of patent protection of the present invention.
Claims (10)
1. a Nano microsphere scratch-resistant height hides matte gloss oil, it is characterized in that, the composition of following mass fraction be prepared from: flatting silica 3 ~ 4 parts, light diffusion microsphere 3 ~ 5 parts, Tissuemat E 0.5 ~ 1.5 part, vinyl chloride-vinyl acetate resin liquid 10 ~ 15 parts, the polyurethane resin liquid 20 ~ 25 parts of 30% mass fraction, 0.2 ~ 0.6 part of antistatic additive, dispersant 0.5 ~ 1.5 part, n-propyl acetate 22 ~ 28 parts, isopropanol 10 ~ 14 parts, adhesion promoter 0.3 ~ 0.8 part, 401LS levelling agent 1.2 ~ 1.8 parts, cellulose acetate resin 5 ~ 6 parts, 10 ~ 12 parts of wax and 301 levelling agents 0.5 ~ 0.6 part；The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
Nano microsphere scratch-resistant height the most according to claim 1 hides matte gloss oil, it is characterized in that, the composition of following mass fraction be prepared from: flatting silica 3.5 parts, light diffusion microsphere 4 parts, Tissuemat E 1 part, vinyl chloride-vinyl acetate resin liquid 12 parts, the polyurethane resin liquid 23 parts of 30% mass fraction, 0.5 part of antistatic additive, dispersant 1 part, n-propyl acetate 25 parts, isopropanol 11.77 parts, adhesion promoter 0.5 part, 401LS levelling agent 1.5 parts, cellulose acetate resin 5.3 parts, 10.4 parts of wax and 301 levelling agents 0.53 part.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that the model of described light diffusion microsphere is LPS020.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that described Tissuemat E is 3620 polyethylene wax powder.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that the model of described vinyl chloride-vinyl acetate resin is VP-10.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that the model of described polyurethane resin is M-6638.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterized in that, described antistatic additive is to be grouped into by the one-tenth of following mass fraction: the quaternary cationics of 45% ~ 50%, the ethylaminoethanol of 15% ~ 18%, the acetic acid of 15% ~ 18%, the isopropanol of 15% ~ 18% and the water of 3% ~ 5%.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that described dispersant is 9375 dispersants.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that described adhesion promoter is modified chlorinated polypropylene.
Nano microsphere scratch-resistant height the most according to claim 1 and 2 hides matte gloss oil, it is characterised in that described cellulose acetate resin is cellulose acetate phthalate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610455620.3A CN105925189A (en) | 2016-06-22 | 2016-06-22 | Nano microsphere scratching-resisting and high-covering matte gloss oil |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610455620.3A CN105925189A (en) | 2016-06-22 | 2016-06-22 | Nano microsphere scratching-resisting and high-covering matte gloss oil |
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| CN105925189A true CN105925189A (en) | 2016-09-07 |
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| CN201610455620.3A Pending CN105925189A (en) | 2016-06-22 | 2016-06-22 | Nano microsphere scratching-resisting and high-covering matte gloss oil |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384202A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of metope beautification oil polish and preparation method thereof |
| CN109082222A (en) * | 2018-07-14 | 2018-12-25 | 广东富特化工有限公司 | A kind of alcohol water intaglio plate table print dumb paint and preparation method thereof |
| CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
| CN109370304A (en) * | 2018-10-12 | 2019-02-22 | 安徽徽合台智能科技有限公司 | A kind of light diffusion printing ink and preparation method thereof |
| CN110641118A (en) * | 2019-10-17 | 2020-01-03 | 厦门长塑实业有限公司 | High-barrier scratch-resistant biaxially oriented polyamide film and preparation method thereof |
| CN113004795A (en) * | 2021-03-02 | 2021-06-22 | 宝盛材料科技(苏州)有限公司 | Colored light diffusing ink coating |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384202A (en) * | 2017-08-15 | 2017-11-24 | 南宁东印时代广告有限公司 | A kind of metope beautification oil polish and preparation method thereof |
| CN109082222A (en) * | 2018-07-14 | 2018-12-25 | 广东富特化工有限公司 | A kind of alcohol water intaglio plate table print dumb paint and preparation method thereof |
| CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
| CN109370304A (en) * | 2018-10-12 | 2019-02-22 | 安徽徽合台智能科技有限公司 | A kind of light diffusion printing ink and preparation method thereof |
| CN110641118A (en) * | 2019-10-17 | 2020-01-03 | 厦门长塑实业有限公司 | High-barrier scratch-resistant biaxially oriented polyamide film and preparation method thereof |
| CN110641118B (en) * | 2019-10-17 | 2021-07-27 | 厦门长塑实业有限公司 | High-barrier scratch-resistant biaxially oriented polyamide film and preparation method thereof |
| CN113004795A (en) * | 2021-03-02 | 2021-06-22 | 宝盛材料科技(苏州)有限公司 | Colored light diffusing ink coating |
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Application publication date: 20160907 |
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