CN106675269A - Waterborne archaized art paint and preparation method thereof - Google Patents
Waterborne archaized art paint and preparation method thereof Download PDFInfo
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- CN106675269A CN106675269A CN201710005895.1A CN201710005895A CN106675269A CN 106675269 A CN106675269 A CN 106675269A CN 201710005895 A CN201710005895 A CN 201710005895A CN 106675269 A CN106675269 A CN 106675269A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of art coatings, in particular to waterborne archaized art paint and a preparation method thereof. The waterborne archaized art paint is prepared from components in parts by weight as follows: 15-25 parts of nano-silica modified acrylic resin, 10-20 parts of acrylic acid modified alkyd resin, 8-15 parts of silver-containing Soben pre-expended microspheres, 1-5 parts of a coalescing agent, 1-3 parts of a levelling agent, 1-5 parts of a dispersant, 3-10 parts of a thickener, 0.1-0.5 parts of a defoaming agent, 3-5 parts of waterborne acrylic acid color paste and the balance of deionized water. The prepared waterborne archaized art paint has good water resistance, stain resistance, weather fastness and stability, has a full paint film and is natural, environment-friendly and high in drying speed, and the construction period is shortened. The preparation method is simple, low in cost and easy to operate.
Description
Technical field
The present invention relates to art coatings technical field, and in particular to a kind of aqueouss antique artistic paint and preparation method thereof.
Background technology
With the development and progress of society, people's environmental protection, the consciousness of health are strengthening.Water paint was also long in recent years
The development of foot, at present still based on solvent based coating application, solvent based coating coating process is shown in woodwork coating market
Painting effect, coating aqueous carpentry can not be substituted completely, and this is also that the development of restriction water-borne wood coating and water paint are general as early as possible
And a factor.The research and development and production of aqueouss antiquing paint make water-borne wood coating have very big expansion in terms of painting effect
Space, aqueouss antiquing paint can be such that the natural texture of timber more presents to three-dimensional, gentle so as to mould the natural texture of timber
Matter, traditional irritant taste of solvent-borne type antiquing paint, containing substantial amounts of VOC (VOC), and pollution environment,
Infringement painter is healthy, inflammable and explosive, waste petroleum resources, is all a kind of harm to resource and environment for human survival；And it is stained with
The cloth waste closing accumulation for having antiquing paint is easy to generation dieseling and causes fire.In environmental consciousness surging epoch today, water
Property antiquing paint will gradually replace solvent-borne type antiquing paint to become main flow.Aqueouss antiquing paint dilute with water, without free TDI, safety not
Burning, has absolute advantagess in environmental protection performance and receives much concern.But the application property of aqueouss antiquing paint (is such as dried speed
Degree) and physical and chemical performance (such as hardness, water-fast, resistance to ethanol and household chemical resistance) relative solvent type is poor also limit
Its application in batch production application.So, how water paint selects oneself suitable field of coating and coating process, right
The sustainable development of aqueouss antiquing paint has very important significance.
The content of the invention
Present invention aims to the deficiencies in the prior art, disclose that a kind of natural environmental-protective, color be soft, adhesive force
By force, damage resistant, with excellent resistance to water, abrasion resistance, polluting proofing property, a kind of aqueouss antique artistic paint of weatherability and its system
Preparation Method.
To realize the purpose of the present invention, the present invention is adopted the following technical scheme that：
A kind of aqueouss antique artistic paint, by weight, is made up of following component：
Nano-silicon dioxide modified acrylic resin 15-25 parts, acrylic acid modified alkyd resin 10-20 parts, sheet containing silver pino
Pre-expanded microballoons 8-15 part, coalescents 1-5 parts, levelling agent 1-3 parts, dispersant 1-5 parts, thickening agent 3-10 parts, defoamer
0.1-0.5 parts, water soluble acrylic acid mill base 3-5 parts, deionized water surplus.
Specifically, the water soluble acrylic acid mill base that pigment of the invention is selected, on the one hand can have good profit to base material
Wet performance, especially for wood substrate, pigment is easier in the little pore of infiltration wood substrate, is had after cured later
There is very strong adhesive force, allow wood grain that there is good third dimension.
Shared using nano-silicon dioxide modified acrylic resin and acrylic acid modified alkyd resin, in the acrylic acid of early stage
The solidification of modified alkyd resin, nano-silicon dioxide modified acrylic resin keeps not solidifying, it is ensured that antique artistic paint
Erasable, after antique artistic paint is adjusted into corresponding effect on base material, then carries out heat cure, makes film further solid
Change, and pigment has also assisted in reaction, with good stability.
Specifically, described this pre-expanded microballoons containing silver pino is prepared as follows：By 1-5 part silver nitrate, 10-30 parts pine
This pre-expanded microballoons, 3-5 segregation ethylene glycol, water surplus, stir in homogenizer；And with ultraviolet light solution 30-
60min；Centrifugation, is drying to obtain this pre-expanded microballoons containing silver pino.
This pre-expanded microballoons containing silver pino is introduced in art paint, not only gives art paint lasting anti-microbial property, can also be made
Artistic paint weight saving is obtained, cost-effective, drying time shortens, and water absorption is reduced, mechanical strength and hardness increase.
Specifically, described silver-colored particle diameter is 5-20nm, and the particle diameter of loose this pre-expanded microballoons is 10-40 μm.
Specifically, described coalescents are one or more in benzyl alcohol, ethylene glycol, Propylene Glycol, hexanediol.
Specifically, described levelling agent be azo polyether polyeste, optional model HY333.Levelling agent selects organic silica
Alkane, it is ensured that the homogeneity of the cured film of antique artistic paint, it is also possible to adjusted by the consumption of levelling agent acrylic acid modified
The curing rate of alkyd resin.
Specifically, described dispersant is the one kind in dodecylbenzene sodium sulfonate, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate.
Specifically, described thickening agent is the one kind in cellulose, sodium alginate.
Specifically, described defoamer is the one kind in BYK-024, BYK028.
Further, the preparation method of described aqueouss antiquing paint, comprises the steps：
(1) by nano-silicon dioxide modified acrylic resin, acrylic acid modified alkyd resin, dispersant, levelling agent, froth breaking
Agent and portions of de-ionized water are added sequentially in stirred tank, under 500-800r/min speed conditions, stir 10-20min；
(2) this pre-expanded microballoons containing silver pino and water soluble acrylic acid mill base are added, under 100~1200r/min speed conditions,
Dispersed with stirring 20-30min；
(3) coalescents and thickening agent are sequentially added, under 800~1000r/min speed conditions, dispersed with stirring 20-
30min；
(4) remaining deionized water is added, adjusts viscosity, under 800~1000r/min speed conditions, stir 10-
20min, after censorship is qualified, filters and packages, as aqueouss antique artistic paint.
The device have the advantages that：
(1) nano-silicon dioxide modified acrylic resin and acrylic acid modified alkyd resin that the present invention is used has with base material
There is preferable adhesive force, fast drying is not easy to crack, may penetrate into wood internal, prevent the infiltration of hydrone, with preferably resistance to
Aqueouss, stain resistance, weatherability, abrasion resistance.
(2) present invention will contain silver pino this pre-expanded microballoons and be introduced in art paint, not only give art paint lasting antibiotic property
Can, it is also possible that art paint weight saving, cost-effective, drying time shortens, and water absorption is reduced, and mechanical strength and hardness increase
Plus.
(3) preparation method of the present invention is simple, with low cost, easily operated, preparation art paint have good resistance to water,
Stain resistance, weatherability, good stability, paint film are full, natural environmental-protective, rate of drying fast, shorten construction period.
(4) the water soluble acrylic acid mill base that pigment of the invention is selected, on the one hand can have good wettability to base material
Can, especially for wood substrate, pigment is easier in the little pore of infiltration wood substrate, is had very after cured later
Strong adhesive force, allows wood grain to have good third dimension.
(5) present invention is shared using nano-silicon dioxide modified acrylic resin and acrylic acid modified alkyd resin, front
The solidification of the acrylic acid modified alkyd resin of phase, nano-silicon dioxide modified acrylic resin keeps not solidifying, it is ensured that imitative
The erasable of ancient art paint, after antique artistic paint is adjusted into corresponding effect on base material, then carries out heat cure, makes painting
Film further solidifies, and pigment has also assisted in reaction, with good stability.
Specific embodiment
Presently in connection with embodiment, the present invention is further detailed explanation.
Embodiment 1
A kind of aqueouss antique artistic paint, is made up of by weight following component：
20 parts of nano-silicon dioxide modified acrylic resin, 15 parts of acrylic acid modified alkyd resin, this preexpanding containing silver pino
10 parts of microsphere, its silver-colored particle diameter is 10nm, and the particle diameter of loose this pre-expanded microballoons is 25 μm, 3 parts of ethylene glycol, levelling agent HY333 2
Part, 3 parts of dodecylbenzene sodium sulfonate, 5 parts of cellulose, 0.3 part of defoamer BYK-024,4 parts of water soluble acrylic acid mill base, deionization
Water surplus.
This pre-expanded microballoons containing silver pino described above is prepared as follows：By 1-5 part silver nitrate, 10-30 parts pine originally
Pre-expanded microballoons, 3-5 segregation ethylene glycol, water surplus, stir in homogenizer；And with ultraviolet light solution 30-
60min；Centrifugation, is drying to obtain this pre-expanded microballoons containing silver pino.
Further, it is to realize described aqueouss antiquing paint, its preparation method comprises the steps：
(1) by nano-silicon dioxide modified acrylic resin, acrylic acid modified alkyd resin, dispersant, levelling agent, froth breaking
Agent and portions of de-ionized water are added sequentially in stirred tank, under 500-800r/min speed conditions, stir 10-20min；
(2) this pre-expanded microballoons containing silver pino and water soluble acrylic acid mill base are added, in 1000~1200r/min speed conditions
Under, dispersed with stirring 20-30min；
(3) coalescents and thickening agent are sequentially added, under 800~1000r/min speed conditions, dispersed with stirring 20-
30min；
(4) remaining deionized water is added, adjusts viscosity, under 800~1000r/min speed conditions, stir 10-
20min, after censorship is qualified, filters and packages, as aqueouss antique artistic paint.
Embodiment 2-8, comparative example 1-3 is substantially the same manner as Example 1, and difference is table 1.
A kind of preparation method of aqueouss antique artistic paint of embodiment 2-8 and comparative example 1 is completed with reference to embodiment 1.
Aqueouss art paint paint film property test
With the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Entirely various change and modification can be carried out in the range of without departing from this invention technological thought.The technology of this invention
Property scope is not limited to the content in description, it is necessary to its technical scope is determined according to right.
Claims (9)
1. a kind of aqueouss antique artistic paint, it is characterised in that：It is made up of following component by weight：Nano-silicon dioxide modified third
Olefin(e) acid resin 15-25 parts, acrylic acid modified alkyd resin 10-20 parts, the 8-15 parts of this pre-expanded microballoons containing silver pino, coalescents 1-
5 parts, levelling agent 1-3 parts, dispersant 1-5 parts, thickening agent 3-10 parts, defoamer 0.1-0.5 parts, water soluble acrylic acid mill base 3-5 parts,
Deionized water surplus.
2. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described this pre-expanded microballoons containing silver pino
It is prepared as follows：By 1-5 part silver nitrate, loose this pre-expanded microballoons of 10-30 parts, 3-5 part Polyethylene Glycol, water surplus, in height
Stir in fast blender；And with ultraviolet light solution 30-60min；Centrifugation, is drying to obtain this pre-expanded microballoons containing silver pino.
3. a kind of aqueouss antique artistic paint as claimed in claim 1 or 2, it is characterised in that described silver-colored particle diameter is 5-
20nm, the particle diameter of loose this pre-expanded microballoons is 10-40 μm.
4. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described coalescents be benzyl alcohol,
One or more in ethylene glycol, Propylene Glycol, hexanediol.
5. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described levelling agent is modified organic silicon
Oxygen alkane.
6. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described dispersant is detergent alkylate
One kind in sodium sulfonate, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate.
7. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described thickening agent is cellulose, sea
One kind in sodium alginate.
8. a kind of aqueouss antique artistic paint as claimed in claim 1, it is characterised in that described defoamer be BYK-024,
One kind in BYK028.
9. a kind of preparation method of aqueouss antiquing paint as claimed in claim 1, it is characterised in that comprise the steps：
（1）By nano-silicon dioxide modified acrylic resin, acrylic acid modified alkyd resin, dispersant, levelling agent, defoamer and
Portions of de-ionized water is added sequentially in stirred tank, under 500-800 r/min speed conditions, stirs 10-20 min；
（2）This pre-expanded microballoons containing silver pino and water soluble acrylic acid mill base are added, under 1000 ~ 1200r/min speed conditions, is stirred
Mix dispersion 20-30 min；
（3）Coalescents and thickening agent are sequentially added, under 800 ~ 1000r/min speed conditions, dispersed with stirring 20-30
min；
（4）Remaining deionized water is added, viscosity is adjusted, under 800 ~ 1000r/min speed conditions, 10-20 min is stirred,
After censorship is qualified, filter and package, as aqueouss antique artistic paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710005895.1A CN106675269B (en) | 2017-01-05 | 2017-01-05 | A kind of aqueous antique artistic paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710005895.1A CN106675269B (en) | 2017-01-05 | 2017-01-05 | A kind of aqueous antique artistic paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106675269A true CN106675269A (en) | 2017-05-17 |
| CN106675269B CN106675269B (en) | 2018-08-31 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151505A (en) * | 2017-05-19 | 2017-09-12 | 合肥荣事达电子电器集团有限公司 | A kind of water-fast timber paint of quick-dry type nanometer water and its preparation technology |
| CN108384430A (en) * | 2018-02-08 | 2018-08-10 | 常熟古建园林股份有限公司 | A kind of ancient architecture and gardens are used as old coating and preparation method thereof |
| CN108384388A (en) * | 2018-03-14 | 2018-08-10 | 合肥尚涵装饰工程有限公司 | A kind of environmental protection modelled after an antique is high to glue weather-resistant coating and preparation method thereof |
| CN111363435A (en) * | 2020-04-29 | 2020-07-03 | 泉州市美尔奇装饰材料有限公司 | Environment-friendly high-weather-resistance high-hardness sand-coated sand stone-like paint and preparation process thereof |
| CN111393934A (en) * | 2020-04-29 | 2020-07-10 | 泉州市美尔奇装饰材料有限公司 | Environment-friendly artistic paint and preparation method thereof |
| CN112111201A (en) * | 2020-09-02 | 2020-12-22 | 广西标牌化学科技有限公司 | Environment-friendly latex paint and preparation method thereof |
| CN113621287A (en) * | 2021-09-01 | 2021-11-09 | 广东美涂士建材股份有限公司 | Water-based environment-friendly artistic paint |
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| CN102827547A (en) * | 2012-09-07 | 2012-12-19 | 鹤山市奎地涂料有限公司 | Aqueous antique paint |
| CN103937402A (en) * | 2013-01-17 | 2014-07-23 | 合众（佛山）化工有限公司 | scratch resistant polyurethane woodenware glossy black finish paint |
| CN105602410A (en) * | 2016-03-28 | 2016-05-25 | 东莞市榴花艺术有限公司 | Antique paint and manufacturing technique thereof |
-
2017
- 2017-01-05 CN CN201710005895.1A patent/CN106675269B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827547A (en) * | 2012-09-07 | 2012-12-19 | 鹤山市奎地涂料有限公司 | Aqueous antique paint |
| CN103937402A (en) * | 2013-01-17 | 2014-07-23 | 合众（佛山）化工有限公司 | scratch resistant polyurethane woodenware glossy black finish paint |
| CN105602410A (en) * | 2016-03-28 | 2016-05-25 | 东莞市榴花艺术有限公司 | Antique paint and manufacturing technique thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151505A (en) * | 2017-05-19 | 2017-09-12 | 合肥荣事达电子电器集团有限公司 | A kind of water-fast timber paint of quick-dry type nanometer water and its preparation technology |
| CN108384430A (en) * | 2018-02-08 | 2018-08-10 | 常熟古建园林股份有限公司 | A kind of ancient architecture and gardens are used as old coating and preparation method thereof |
| CN108384388A (en) * | 2018-03-14 | 2018-08-10 | 合肥尚涵装饰工程有限公司 | A kind of environmental protection modelled after an antique is high to glue weather-resistant coating and preparation method thereof |
| CN111363435A (en) * | 2020-04-29 | 2020-07-03 | 泉州市美尔奇装饰材料有限公司 | Environment-friendly high-weather-resistance high-hardness sand-coated sand stone-like paint and preparation process thereof |
| CN111393934A (en) * | 2020-04-29 | 2020-07-10 | 泉州市美尔奇装饰材料有限公司 | Environment-friendly artistic paint and preparation method thereof |
| CN112111201A (en) * | 2020-09-02 | 2020-12-22 | 广西标牌化学科技有限公司 | Environment-friendly latex paint and preparation method thereof |
| CN113621287A (en) * | 2021-09-01 | 2021-11-09 | 广东美涂士建材股份有限公司 | Water-based environment-friendly artistic paint |
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| Publication number | Publication date |
|---|---|
| CN106675269B (en) | 2018-08-31 |
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