CN111393934A - Environment-friendly artistic paint and preparation method thereof - Google Patents
Environment-friendly artistic paint and preparation method thereof Download PDFInfo
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- CN111393934A CN111393934A CN202010358761.XA CN202010358761A CN111393934A CN 111393934 A CN111393934 A CN 111393934A CN 202010358761 A CN202010358761 A CN 202010358761A CN 111393934 A CN111393934 A CN 111393934A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C—CHEMISTRY; METALLURGY
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08L2205/00—Polymer mixtures characterised by other features
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
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Abstract
The invention relates to the technical field of wall paint, in particular to an environment-friendly artistic paint and a preparation method thereof, wherein the environment-friendly artistic paint is environment-friendly, and the six-ring stone is innovatively used as a filler, so that the physical property of a paint film can be improved, the paint film has the capability of releasing negative ions, the air can be purified, the environment-friendly artistic paint has practical significance and popularization value, and good economic benefit can be generated, and the environment-friendly artistic paint comprises, by weight, 60-80 parts of modified acrylic resin emulsion, 12-20 parts of six-ring stone, 10-20 parts of bamboo carbon fiber, 20-30 parts of deionized water, 0.1-1 part of a wetting agent, 5-10 parts of a dispersing agent, 0.1-1 part of a pH regulator, 0.5-1 part of a flatting agent, 0.2-1 part of a defoaming agent, 1-5 parts of a film forming assistant and 2-.
Description
Technical Field
The invention relates to the technical field of wall paint, in particular to environment-friendly artistic paint and a preparation method thereof.
Background
The wall paint is a high molecular paint which can firmly cover the surface of an object and has the functions of protection, decoration, marking and other special purposes, is an organic chemical high molecular material, belongs to a fine chemical product, is gradually changed into a functional material along with the development of the society, derives various novel wall paints such as weather-resistant wall paint, conductive wall paint, heat-resistant wall paint, antifouling wall paint, anticorrosion wall paint and the like on the basis of the traditional waterproof wall paint, and is an important industry in the chemical industry.
The origin of the art paint can be traced back to Europe, unique patterns and decorative patterns can be formed on the surface of the art paint, the wall surface can fully show three-dimensional aesthetic feeling, the decorative effect of the art paint cannot be achieved by common wall finish, the art paint is widely advocated by people, the performance of the paint film is relatively common although the art paint is prepared from environment-friendly water-based synthetic emulsion at present, the paint film only has a decorative function, the VOC (volatile organic compound) of the art paint containing an organic solvent is relatively large, the environment is not friendly, the potential harm can be caused to the health of people, if the art paint is researched and developed on the basis of the prior art, the physical property of the art paint is good, and the environment-friendly art paint has positive significance.
Disclosure of Invention
The invention aims to provide an environment-friendly artistic paint and a preparation method thereof, and aims to solve the problems of relatively common physical properties and single function of a paint film of the existing water-based artistic paint in the background art.
In order to achieve the purpose, the invention provides an environment-friendly art paint which comprises, by weight, 60-80 parts of modified acrylic resin emulsion, 12-20 parts of hexacyclic stone, 10-20 parts of bamboo charcoal fiber, 20-30 parts of deionized water, 0.1-1 part of a wetting agent, 5-10 parts of a dispersing agent, 0.1-1 part of a pH regulator, 0.5-1 part of a flatting agent, 0.2-1 part of a defoaming agent, 1-5 parts of a film forming additive and 2-10 parts of a thickening agent.
Preferably, the modified acrylic resin emulsion specifically adopts nano-silica modified acrylic resin emulsion.
Preferably, HY-1608A is used as the humectant.
Preferably, the dispersant is an anionic dispersant.
Preferably, the pH regulator is SI L RES BS 198.
Preferably, the leveling agent is specifically modified organic siloxane.
Preferably, BYK-024 is specifically adopted as the defoaming agent.
Preferably, Texanol is specifically used as the film-forming aid.
Preferably, the thickening agent is hydroxyethyl cellulose.
The nano-silica modified acrylic resin emulsion is prepared from nano-silica modified acrylic resin in the prior art, and the nano-silica and the acrylic resin form a uniform inorganic-organic crosslinking structure through physical and chemical actions, so that the thermal stability and the mechanical property of the acrylic resin can be improved, and the scrubbing resistance of the coating, the adhesive force of a coating film, the impact resistance and the thermal stability are improved;
the hexacyclic ring stone is a natural mineral, which can permanently generate negative ions, the valence-variable metal Fe in the hexacyclic ring stone is easy to generate oxidation-reduction reaction, forms negative ions by combining with water molecules in the environment, and can play a role in purifying air, in addition, the hexacyclic ring stone can release 8-15 μm far infrared rays at 20 ℃, has a certain health care effect, can be used as a filler to enhance the physical properties of a paint film, such as impact resistance, wear resistance, heat resistance, surface hardness and the like, can be filled in gaps on the rough surface of a substrate, and can improve the adhesive force between the paint film and the substrate, and in the actual production of the invention, the particle size of hexacyclic ring stone powder particles is not more than 30 μm;
the bamboo charcoal fiber is made from moso bamboos through pure oxygen high temperature and nitrogen blocking calcination, the bamboo charcoal and the polyester modified slice are melt spun to obtain the fiber, both the bamboo charcoal and the polyurethane modified slice have honeycomb microporous structures which penetrate through the inside and the outside, the combination degree of the bamboo charcoal fiber and other components can be improved, and in addition, the bamboo charcoal fiber and the acrylic resin also have good compatibility;
deionized water refers to pure water obtained after removing impurities in the form of ions;
HY-1608A is a nonionic surfactant, has good water solubility, good fluidity at low temperature, improved dispersibility of wall paint and gloss of paint film, and no APEO, and is environmentally friendly.
Most of the anionic dispersing agents are composed of nonpolar negatively charged hydrocarbon chain parts and hydrophilic groups, have asymmetric oleophylic and hydrophilic structures, have good compatibility, are widely applied to water-based coatings, and adopt carboxylate in specific production;
SI L RES BS198 is a reactive type PH regulator containing synthetic organosilicon in the prior art, it is colorless, tasteless transparent aqueous solution, regard potassium methyl siliconate as the principal ingredients, the compound has organosilicon with moistening and dispersing function, potassium methyl siliconate can ionize and form hydroxide ion in water, thus realize the purpose of regulating PH value, can also improve the characteristic of scrubbing resistance and water resistance of the paint film, in addition SI L RES BS198 has very low VOC, it is comparatively friendly to the environment;
the modified organic siloxane is polyether polyester modified organic siloxane, has good compatibility, and can improve the surface tension of the wall paint, thereby eliminating the surface defects of a paint film;
BYK-024 has excellent defoaming effect, is effective to microbubbles as well, has long-acting stability, does not reduce the surface gloss of a paint film, and is widely used in water-based acrylic resin wall paint;
texanol is an excellent film-forming assistant, has low volatilization speed, is insoluble in water, and has certain promotion on the scrub resistance and the storage stability of a paint film.
The thickening mechanism of the hydroxyethyl cellulose is mainly that a hydrophobic main chain of the hydroxyethyl cellulose forms a hydrogen bond with water, and polar groups on the mechanism interact to form a space network structure, so that the polymer rheological volume can be improved, the free movement of the polymer is limited, the viscosity of the coating is improved, the space network structure is destroyed when a shearing force is applied, intermolecular hydrogen bonds are destroyed, the viscosity is reduced, the hydrogen bond is reformed after the shearing force is removed, the space network structure is reformed, and the wall finish has good rheological property.
In addition, the invention also provides a preparation method of the environment-friendly artistic paint, which comprises the following steps:
(1) grinding the hexacyclic ring stone into powder particles, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the modified acrylic resin emulsion, the soaked hexacyclic stone, the wetting agent, the dispersing agent, the pH regulator, the flatting agent, the defoaming agent and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding a film forming aid and a thickening agent, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to the environment-friendly artistic paint and the preparation method thereof, the components are environment-friendly, the bamboo charcoal fiber forms unique three-dimensional patterns on the surface of the paint film after being dried and formed into a film, the paint has aesthetic feeling, and the six-ring stone is innovatively used as the filler, so that the physical property of the artistic paint film can be improved, the paint film has the capability of releasing negative ions, the paint has practical significance and popularization value, and good economic benefit can be expected to be generated.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
The environment-friendly artistic paint comprises, by weight, 60 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 2
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 3
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
The environment-friendly artistic paint comprises, by weight, 80 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 4
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly artistic paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 12 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 5
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 14 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 6
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 18 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 7
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 20 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 8
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 10 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 9
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 20 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 10
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly artistic paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 20 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 11
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly artistic paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 30 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol3 parts and 6 parts of hydroxyethyl cellulose.
Example 12
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol1 parts and 6 parts of hydroxyethyl cellulose.
Example 13
A method for preparing an environment-friendly artistic paint, comprising the steps of:
(1) grinding the hexacyclic ring stone into powder particles with the particle size not more than 30 μm, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the nano silicon dioxide modified acrylic resin emulsion, the soaked hexacyclic stone, HY-1608A, an anionic dispersant, SI L RES BS198, the polyether polyester modified organosiloxane, BYK-024 and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding Texanol and hydroxyethyl cellulose, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
According to parts by weight, the environment-friendly art paint comprises 70 parts of nano silicon dioxide modified acrylic resin emulsion, 16 parts of hexacyclic stone, 15 parts of bamboo charcoal fiber, 25 parts of deionized water, 0.5 part of HY-1608A, 5 parts of anionic dispersant, SI L RES BS1980.5 parts, 0.5 part of polyether polyester modified organosiloxane, BYK-0240.4 parts, Texanol5 parts and 6 parts of hydroxyethyl cellulose.
TABLE 1 paint film Property testing
TABLE 2 ageing resistance test of paint film (refer to national standard GB-T1865-
With the combination of the examples 1-3, it can be seen that with the increase of the proportion of the modified acrylic resin emulsion, the drying and film-forming time of the paint film is increased, and the hardness and the adhesive force of the paint film have no obvious difference; combining example 2 with examples 4-7, it can be seen that as the proportion of hexacyclic stone increases, the hardness of the paint film increases; combining example 2 and examples 8-9, it can be seen that the number of paint film patterns is increased with the increase of bamboo charcoal fiber; by combining example 2, example 10 and example 11, it can be seen that the drying film-forming time of the paint film increases with the increase of the proportion of deionized water, but the physical properties of the paint film are not significantly affected; by combining example 2, example 12 and example 13, it can be seen that the film-forming time for drying the paint film is significantly reduced as the proportion of the film-forming assistant is increased.
It will be understood by those skilled in the art that the foregoing is merely exemplary of the present invention, and is not intended to limit the invention to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
Claims (10)
1. An environment-friendly artistic paint is characterized in that: the paint comprises, by weight, 60-80 parts of modified acrylic resin emulsion, 12-20 parts of hexacyclic stone, 10-20 parts of bamboo charcoal fiber, 20-30 parts of deionized water, 0.1-1 part of wetting agent, 5-10 parts of dispersing agent, 0.1-1 part of pH regulator, 0.5-1 part of flatting agent, 0.2-1 part of defoaming agent, 1-5 parts of film forming additive and 2-10 parts of thickening agent.
2. An environmental-friendly artistic paint as claimed in claim 1, wherein: the modified acrylic resin emulsion specifically adopts nano silicon dioxide modified acrylic resin emulsion.
3. An environmental-friendly artistic paint as claimed in claim 1, wherein: HY-1608A is specifically adopted as the humectant.
4. An environmental-friendly artistic paint as claimed in claim 3, wherein: the dispersant is specifically anionic dispersant.
5. The environment-friendly artistic paint as claimed in claim 1, wherein the pH regulator is SI L RESBS 198.
6. An environmental-friendly artistic paint as claimed in claim 1, wherein: the leveling agent specifically adopts modified organic siloxane.
7. An environmental-friendly artistic paint as claimed in claim 1, wherein: the defoaming agent specifically adopts BYK-024.
8. An environmental-friendly artistic paint as claimed in claim 1, wherein: the film-forming aid is Texanol.
9. An environmental-friendly artistic paint as claimed in claim 1, wherein: the thickening agent specifically adopts hydroxyethyl cellulose.
10. The method for preparing the environment-friendly art paint as claimed in any one of claims 1 to 9, wherein the method comprises the following steps: the method comprises the following steps:
(1) grinding the hexacyclic ring stone into powder particles, soaking in deionized water for 30min for complete infiltration, and crushing the bamboo charcoal fiber to ensure that the length of the bamboo charcoal fiber is not more than 3 CM;
(2) slowly adding the modified acrylic resin emulsion, the soaked hexacyclic stone, the wetting agent, the dispersing agent, the pH regulator, the flatting agent, the defoaming agent and the rest deionized water into a stirring kettle in sequence, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(3) sequentially adding a film forming aid and a thickening agent, and stirring for 30-40 min at the rotating speed of 800-1000 r/min;
(4) adding bamboo charcoal fiber, and stirring at the rotating speed of 1000-1200 r/min for 20-30 min to obtain the required environment-friendly artistic paint.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112831210A (en) * | 2020-12-31 | 2021-05-25 | 江苏极信环保科技有限公司 | Flame-retardant acrylic resin coating capable of slowly releasing negative oxygen ions and preparation method thereof |
| CN113861809A (en) * | 2021-11-24 | 2021-12-31 | 泉州加士涂环保科技有限公司 | Environment-friendly artistic paint and preparation method thereof |
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