CN108384430A - A kind of ancient architecture and gardens are used as old coating and preparation method thereof - Google Patents
A kind of ancient architecture and gardens are used as old coating and preparation method thereof Download PDFInfo
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- CN108384430A CN108384430A CN201810125579.2A CN201810125579A CN108384430A CN 108384430 A CN108384430 A CN 108384430A CN 201810125579 A CN201810125579 A CN 201810125579A CN 108384430 A CN108384430 A CN 108384430A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of ancient architecture and gardens to be used as old coating and preparation method thereof, which is made of following component according to weight ratio：32~44 parts of polyurethane modified acrylic resin, 4~6 parts of wetting dispersing agent, 0.5~0.6 part of antifoaming agent, 2~4 parts of sodium trimetaphosphate, 1~3 part of lithium sulfate, 20~25 parts of acetate, 10~13 parts of clay, 1~2 part of adhesive, 24~29 parts of water；The raw material of described adhesive includes by weight：4~6 parts of fire retardant, 30~42 parts of paraffin, 10~14 parts of oleic acid, 13~15 parts of polyvinyl alcohol；The raw material of the wetting dispersing agent includes by weight：8~12 parts of alkyl acrylate, 6~8 parts of styrene, 4~6 parts of acrylic acid.It is good that the coating of the present invention does old effect, is suitable for ancient building outer surface and repairs, wearability is good, and ethanol-tolerant, acidproof, alkaline-resisting, water-fast, oil resistant, shock resistance is strong, effectively reduces distributing for pernicious gas, safety and environmental protection.
Description
Technical field
The present invention relates to old coating material production technical field is done, specifically a kind of ancient architecture and gardens are used as old coating and its preparation side
Method.
Background technology
Ancient building refers to the civil buildings and public building having before the foundation of historic significance comprising Republic
Building.In China, many Gu towns and most big city also maintain some ancient buildings.However, showing in busy at putting up installations
In the cultural trait that we treat and protected with the eye of development ancient architecture and its contain；Accomplish both ancient times to be allowed to build
It builds culture and is stored in generation, ancient civilization legacy is also allowed to generate Modern Value.
In recent years, Tourism in China flourishes, to solicit tourist, scenic spot overhauls one after another, build ancient building or timber structure,
The pseudo-classic architecture of wood and stone structure.But for the reparation of antiquated building, there are problems in the prior art.
Best repair mode is to repair old, that is, repair materials inherently other antiquated buildings with old in the prior art
The remaining useful raw materials after damage；Use by it is old repair it is old in a manner of, can farthest restore it is antiquated building now from
Right looks, due to the use of raw material be also antiquated material, can it is true, antiquated building is repaired naturally；But it is this
Repair mode is not an approach that can be carried out for a long time, itself requires to use antiquated building material, this is depended on constantly
It was found that antiquated building traces, clear up its useful raw materials, raw material deposits generation limited amount, and will increasingly with using
Few, antiquated material cost itself is higher, and as the reduction of quantity will be higher and higher, this will be greatly improved to antiquated building
Rehabilitation cost.In addition, do old coating in coating interlayer attachment, in conjunction with bad, will produce pull-away, peelings, play bulging, peeling
It Deng ill phenomenon, seriously reduces the service life, needs to carry out continually repair to ancient building.
Invention content
The purpose of the present invention is to provide a kind of ancient architecture and gardens to be used as old coating and preparation method thereof, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of ancient architecture and gardens are used as old coating, are made of according to weight ratio following component：Polyurethane modified acrylic resin
32~44 parts, 4~6 parts of wetting dispersing agent, 0.5~0.6 part of antifoaming agent, 2~4 parts of sodium trimetaphosphate, 1~3 part of lithium sulfate, acetic acid
20~25 parts of ester, 10~13 parts of clay, 1~2 part of adhesive, 24~29 parts of water；The raw material of described adhesive wraps by weight
It includes：4~6 parts of fire retardant, 30~42 parts of paraffin, 10~14 parts of oleic acid, 13~15 parts of polyvinyl alcohol；The original of the wetting dispersing agent
Material include by weight：8~12 parts of alkyl acrylate, 6~8 parts of styrene, 4~6 parts of acrylic acid.
As a further solution of the present invention：The fire retardant is in antimony oxide, magnesium hydroxide or aluminium hydroxide
One or more are mixed.
As a further solution of the present invention：The raw material of the acetate includes by weight：5~7 parts of butyl acetate,
14~17 parts of 7~9 parts of isopropyl acetate and sec-Butyl Acetate vinegar.
As a further solution of the present invention：The antifoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxy
Ethylene polyoxy propyl alcohol amidogen ether.
A kind of any of the above-described ancient architecture and gardens are used as the preparation method of old coating, include the following steps：
1) acetate, water, antifoaming agent and wetting dispersing agent are put into shear mixer by weight formula, shearing is stirred
Mix rotating speed is 4500~5000r/min, and the shear agitation time is 20~25min；
2) material mixed in step 1) is imported in water-bath, sodium trimetaphosphate is then added, is heated to 55~60 DEG C,
Simultaneously with stirring paddle stirring, speed of agitator is 200~300r/min, continues 5~10min；
3) clay is crushed, after vibrosieve, it is 500~550 mesh to be ground to mesh number with ultra-fine ball mill；
4) mixed material Jing Guo heating stirring in step 2) is imported in homogenizer, meanwhile, by weight formula
It will import in homogenizer, be mixed by the clay after step 3) grinding, speed of agitator is 4500~5000r/
Min, mixing time are 5~10min；
5) the middle material by stirring of step 4) is imported into nano-dispersed machine, added by weight matching in the nano-dispersed machine of direction
Enter polyurethane modified acrylic resin, lithium sulfate and adhesive, into high speed dispersion, jitter time is 30~40min, you can
To doing old coating products.
As a further solution of the present invention：The rate of dispersion of high speed dispersion is 8000~9000r/min, emulsion dispersion
Speed is 3000r/min.
Compared with prior art, the beneficial effects of the invention are as follows：It is matched colors using clay so that coating surface reaches good
Antique-imitation effect；It is strong using Inter layer adsorption ability when coating, it is not easy to which that peeling, blistering, rate of drying are fast；The coating of the present invention
It is repaired suitable for ancient building outer surface, wearability is good, and ethanol-tolerant, acidproof, alkaline-resisting, water-fast, oil resistant, shock resistance is strong, effectively
Reduce distributing for pernicious gas, safety and environmental protection；The coating of the present invention has good heat-resistant stability, storage stability very good
It is good, there is good color fastness to light.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1：
A kind of ancient architecture and gardens are used as old coating, are made of according to weight ratio following component：Polyurethane modified acrylic resin
32 parts, it is 4 parts of wetting dispersing agent, 0.5 part of antifoaming agent, 2 parts of sodium trimetaphosphate, 1 part of lithium sulfate, 20 parts of acetate, 10 parts of clay, viscous
1 part of mixture, 24 parts of water；The raw material of described adhesive includes by weight：4 parts of fire retardant, 10 parts of oleic acid, gathers 30 parts of paraffin
13 parts of vinyl alcohol；The raw material of the wetting dispersing agent includes by weight：8 parts of alkyl acrylate, 6 parts of styrene, propylene
4 parts of acid.
Wherein, the fire retardant is that one or more of antimony oxide, magnesium hydroxide or aluminium hydroxide are mixed；
The raw material of the acetate includes by weight：14 parts of 5 parts of butyl acetate, 7 parts of isopropyl acetate and sec-Butyl Acetate vinegar；
The antifoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of ancient architecture and gardens described above are used as the preparation method of old coating, include the following steps：
1) acetate, water, antifoaming agent and wetting dispersing agent are put into shear mixer by weight formula, shearing is stirred
Mix rotating speed is 4500~5000r/min, and the shear agitation time is 20~25min；
2) material mixed in step 1) is imported in water-bath, sodium trimetaphosphate is then added, is heated to 55 DEG C, simultaneously
With stirring paddle stirring, speed of agitator is 200~300r/min, continues 5~10min；
3) clay is crushed, after vibrosieve, it is 500~550 mesh to be ground to mesh number with ultra-fine ball mill；
4) mixed material Jing Guo heating stirring in step 2) is imported in homogenizer, meanwhile, by weight formula
It will import in homogenizer, be mixed by the clay after step 3) grinding, speed of agitator is 4500~5000r/
Min, mixing time are 5~10min；
5) the middle material by stirring of step 4) is imported into nano-dispersed machine, added by weight matching in the nano-dispersed machine of direction
Enter polyurethane modified acrylic resin, lithium sulfate and adhesive, into high speed dispersion, jitter time is 30~40min, you can
To doing old coating products.Wherein, the rate of dispersion of high speed dispersion is 8000~9000r/min, and the speed of emulsion dispersion is
3000r/min。
The old coating that does that embodiment 1 obtains is coated in building concrete block surface, at a temperature of being placed on 60 DEG C after 1 week,
Coating is bright and clean smooth, tack-free；Selection natural daylight is exposed to the sun method, is exposed to the sun in the sunlight after 1 week, and the product hierarchy of test is 7 grades,
With good color fastness to light；Shock resistance is tested：50-60(GB/T4893.9-92)；Corrosion resistance is tested：Resistance to wine
Smart, acidproof, alkaline-resisting, water-fast, oil resistant.
Embodiment 2：
A kind of ancient architecture and gardens are used as old coating, are made of according to weight ratio following component：Polyurethane modified acrylic resin
44 parts, it is 6 parts of wetting dispersing agent, 0.6 part of antifoaming agent, 4 parts of sodium trimetaphosphate, 3 parts of lithium sulfate, 25 parts of acetate, 13 parts of clay, viscous
2 parts of mixture, 29 parts of water；The raw material of described adhesive includes by weight：6 parts of fire retardant, 14 parts of oleic acid, gathers 42 parts of paraffin
15 parts of vinyl alcohol；The raw material of the wetting dispersing agent includes by weight：12 parts of alkyl acrylate, 8 parts of styrene, propylene
6 parts of acid.
Wherein, the fire retardant is that one or more of antimony oxide, magnesium hydroxide or aluminium hydroxide are mixed；
The raw material of the acetate includes by weight：17 parts of 7 parts of butyl acetate, 9 parts of isopropyl acetate and sec-Butyl Acetate vinegar；
The antifoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of ancient architecture and gardens described above are used as the preparation method of old coating, include the following steps：
1) acetate, water, antifoaming agent and wetting dispersing agent are put into shear mixer by weight formula, shearing is stirred
Mix rotating speed is 4500~5000r/min, and the shear agitation time is 20~25min；
2) material mixed in step 1) is imported in water-bath, sodium trimetaphosphate is then added, is heated to 60 DEG C, simultaneously
With stirring paddle stirring, speed of agitator is 200~300r/min, continues 5~10min；
3) clay is crushed, after vibrosieve, it is 500~550 mesh to be ground to mesh number with ultra-fine ball mill；
4) mixed material Jing Guo heating stirring in step 2) is imported in homogenizer, meanwhile, by weight formula
It will import in homogenizer, be mixed by the clay after step 3) grinding, speed of agitator is 4500~5000r/
Min, mixing time are 5~10min；
5) the middle material by stirring of step 4) is imported into nano-dispersed machine, added by weight matching in the nano-dispersed machine of direction
Enter polyurethane modified acrylic resin, lithium sulfate and adhesive, into high speed dispersion, jitter time is 30~40min, you can
To doing old coating products.Wherein, the rate of dispersion of high speed dispersion is 8000~9000r/min, and the speed of emulsion dispersion is
3000r/min。
The old coating that does that embodiment 2 obtains is coated in building concrete block surface, at a temperature of being placed on 60 DEG C after 1 week,
Coating is bright and clean smooth, tack-free；Selection natural daylight is exposed to the sun method, is exposed to the sun in the sunlight after 1 week, and the product hierarchy of test is 7 grades,
With good color fastness to light；Shock resistance is tested：50-60(GB/T4893.9-92)；Corrosion resistance is tested：Resistance to wine
Smart, acidproof, alkaline-resisting, water-fast, oil resistant.
Embodiment 3：
A kind of ancient architecture and gardens are used as old coating, are made of according to weight ratio following component：Polyurethane modified acrylic resin
38 parts, it is 5 parts of wetting dispersing agent, 0.5 part of antifoaming agent, 3 parts of sodium trimetaphosphate, 2 parts of lithium sulfate, 23 parts of acetate, 12 parts of clay, viscous
2 parts of mixture, 26 parts of water；The raw material of described adhesive includes by weight：5 parts of fire retardant, 12 parts of oleic acid, gathers 38 parts of paraffin
14 parts of vinyl alcohol；The raw material of the wetting dispersing agent includes by weight：10 parts of alkyl acrylate, 7 parts of styrene, propylene
5 parts of acid.
Wherein, the fire retardant is that one or more of antimony oxide, magnesium hydroxide or aluminium hydroxide are mixed；
The raw material of the acetate includes by weight：16 parts of 6 parts of butyl acetate, 8 parts of isopropyl acetate and sec-Butyl Acetate vinegar；
The antifoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of any of the above-described ancient architecture and gardens are used as the preparation method of old coating, include the following steps：
1) acetate, water, antifoaming agent and wetting dispersing agent are put into shear mixer by weight formula, shearing is stirred
Mix rotating speed is 4500~5000r/min, and the shear agitation time is 20~25min；
2) material mixed in step 1) is imported in water-bath, sodium trimetaphosphate is then added, is heated to 60 DEG C, simultaneously
With stirring paddle stirring, speed of agitator is 200~300r/min, continues 5~10min；
3) clay is crushed, after vibrosieve, it is 500~550 mesh to be ground to mesh number with ultra-fine ball mill；
4) mixed material Jing Guo heating stirring in step 2) is imported in homogenizer, meanwhile, by weight formula
It will import in homogenizer, be mixed by the clay after step 3) grinding, speed of agitator is 4500~5000r/
Min, mixing time are 5~10min；
5) the middle material by stirring of step 4) is imported into nano-dispersed machine, added by weight matching in the nano-dispersed machine of direction
Enter polyurethane modified acrylic resin, lithium sulfate and adhesive, into high speed dispersion, jitter time is 30~40min, you can
To doing old coating products.Wherein, the rate of dispersion of high speed dispersion is 8000~9000r/min, and the speed of emulsion dispersion is
3000r/min。
The old coating that does that embodiment 3 obtains is coated in building concrete block surface, at a temperature of being placed on 60 DEG C after 1 week,
Coating is bright and clean smooth, tack-free；Selection natural daylight is exposed to the sun method, is exposed to the sun in the sunlight after 1 week, and the product hierarchy of test is 7 grades,
With good color fastness to light；Shock resistance is tested：50-60(GB/T4893.9-92)；Corrosion resistance is tested：Resistance to wine
Smart, acidproof, alkaline-resisting, water-fast, oil resistant.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
Claims (6)
1. a kind of ancient architecture and gardens are used as old coating, which is characterized in that be made of according to weight ratio following component：Polyurethane-modified third
32~44 parts of olefin(e) acid resin, 4~6 parts of wetting dispersing agent, 0.5~0.6 part of antifoaming agent, 2~4 parts of sodium trimetaphosphate, lithium sulfate 1~
3 parts, 20~25 parts of acetate, 10~13 parts of clay, 1~2 part of adhesive, 24~29 parts of water；The raw material of described adhesive is by weight
Amount compares meter：4~6 parts of fire retardant, 30~42 parts of paraffin, 10~14 parts of oleic acid, 13~15 parts of polyvinyl alcohol；The wetting point
The raw material of powder includes by weight：8~12 parts of alkyl acrylate, 6~8 parts of styrene, 4~6 parts of acrylic acid.
2. a kind of ancient architecture and gardens according to claim 1 are used as old coating, which is characterized in that the fire retardant is three oxidations
One or more of two antimony, magnesium hydroxide or aluminium hydroxide are mixed.
3. a kind of ancient architecture and gardens according to claim 1 are used as old coating, which is characterized in that the raw material of the acetate is pressed
Weight ratio meter includes：14~17 parts of 5~7 parts of butyl acetate, 7~9 parts of isopropyl acetate and sec-Butyl Acetate vinegar.
4. a kind of ancient architecture and gardens according to claim 1 are used as old coating, which is characterized in that the antifoaming agent uses polyoxy
Ethylene polyoxypropylene pentaerythrite ether or polyoxyethylene polyoxy propyl alcohol amidogen ether.
5. being used as the preparation method of old coating according to a kind of any ancient architecture and gardens of claim 1-4, which is characterized in that packet
Include following steps：
1) acetate, water, antifoaming agent and wetting dispersing agent are put into shear mixer by weight formula, shear agitation turns
Speed is 4500~5000r/min, and the shear agitation time is 20~25min；
2) material mixed in step 1) is imported in water-bath, sodium trimetaphosphate is then added, is heated to 55~60 DEG C, simultaneously
With stirring paddle stirring, speed of agitator is 200~300r/min, continues 5~10min；
3) clay is crushed, after vibrosieve, it is 500~550 mesh to be ground to mesh number with ultra-fine ball mill；
4) mixed material Jing Guo heating stirring in step 2) is imported in homogenizer, meanwhile, it will be through by weight being formulated
The clay crossed after step 3) grinding imports in homogenizer, is mixed, and speed of agitator is 4500~5000r/min,
Mixing time is 5~10min；
5) material by stirring in step 4) is imported into nano-dispersed machine, by weight poly- with being added in the nano-dispersed machine of direction
Urethane modified acrylic resin, lithium sulfate and adhesive, into high speed dispersion, jitter time is 30~40min, you can is done
Old coating products.
6. a kind of ancient architecture and gardens according to claim 5 are used as the preparation method of old coating, which is characterized in that high speed dispersion
Rate of dispersion be 8000~9000r/min, the speed of emulsion dispersion is 3000r/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810125579.2A CN108384430A (en) | 2018-02-08 | 2018-02-08 | A kind of ancient architecture and gardens are used as old coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810125579.2A CN108384430A (en) | 2018-02-08 | 2018-02-08 | A kind of ancient architecture and gardens are used as old coating and preparation method thereof |
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| CN108384430A true CN108384430A (en) | 2018-08-10 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571597A (en) * | 2020-11-12 | 2021-03-30 | 上海城建物资有限公司 | Concrete antiquing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827545A (en) * | 2011-12-31 | 2012-12-19 | 常熟古建园林建设集团有限公司 | Coating for antique finishing of surface of fair-faced concrete |
| CN105176147A (en) * | 2015-09-29 | 2015-12-23 | 彭耀根 | Archaistic coating and preparation method thereof |
| CN106675269A (en) * | 2017-01-05 | 2017-05-17 | 广东绿色大地化工有限公司 | Waterborne archaized art paint and preparation method thereof |
| CN107418428A (en) * | 2017-09-22 | 2017-12-01 | 苏州振振好新型建材科技有限公司 | A kind of durable texture paint of height used for building exterior wall and preparation method thereof |
-
2018
- 2018-02-08 CN CN201810125579.2A patent/CN108384430A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827545A (en) * | 2011-12-31 | 2012-12-19 | 常熟古建园林建设集团有限公司 | Coating for antique finishing of surface of fair-faced concrete |
| CN105176147A (en) * | 2015-09-29 | 2015-12-23 | 彭耀根 | Archaistic coating and preparation method thereof |
| CN106675269A (en) * | 2017-01-05 | 2017-05-17 | 广东绿色大地化工有限公司 | Waterborne archaized art paint and preparation method thereof |
| CN107418428A (en) * | 2017-09-22 | 2017-12-01 | 苏州振振好新型建材科技有限公司 | A kind of durable texture paint of height used for building exterior wall and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112571597A (en) * | 2020-11-12 | 2021-03-30 | 上海城建物资有限公司 | Concrete antiquing method |
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Application publication date: 20180810 |