CN107162486A - A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof - Google Patents

A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof Download PDF

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Publication number
CN107162486A
CN107162486A CN201710414265.XA CN201710414265A CN107162486A CN 107162486 A CN107162486 A CN 107162486A CN 201710414265 A CN201710414265 A CN 201710414265A CN 107162486 A CN107162486 A CN 107162486A
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China
Prior art keywords
trowelling
mineral varnish
true mineral
reflective insulation
agent
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CN201710414265.XA
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Chinese (zh)
Inventor
姜年超
林富聪
姜向阳
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Xiamen First New Material Technology Co Ltd
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Xiamen First New Material Technology Co Ltd
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Priority to CN201710414265.XA priority Critical patent/CN107162486A/en
Publication of CN107162486A publication Critical patent/CN107162486A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of true mineral varnish of reflective insulation trowelling and preparation method thereof, wherein, the true mineral varnish of reflective insulation trowelling includes following components in percentage by weight:Natural colour sand 55 65%;Polymer emulsion 19 25%;Hollow glass micro-ball 5 10%;Protecting colloid salt 1 2%;Hydroxyethyl cellulose 0.2 0.5%;Bactericide 0.3 0.5%;Antifreezing agent 0.5 1%;Auxiliary agent 1 2%;Water 5 8%.The present invention is creatively by adjusting true mineral varnish formula, the special true mineral varnish of reflective insulation that have developed using trowelling form of construction work, reduce the loss of hollow glass micropearl, enhance application property, back reflection effect of heat insulation construct more preferably, the air-conditioning power consumption of southern area, energy-saving and emission-reduction, environmental protection can effectively be reduced.

Description

A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof
Technical field
The present invention relates to paint field, more particularly to decoration of exterior wall coating, a kind of reflective insulation trowelling is specifically referred to true Mineral varnish, and the method for preparing the true mineral varnish.
Background technology
In recent years, real estate industry develops rapidly, and as a kind of new application mode, the color true mineral varnish of sand is by industry Pay high attention to.
True mineral varnish is mainly made up of high molecular polymer, natural colour sand and related auxiliaries, as hard as flint after dry and hard solidification, tool There is the effect as imitative natural real stone, adhesive force is strong, weather-proof, water-fast, and repairing is easy;After the coating construction of true mineral varnish is solid very Hard, nail can not be scratched, be mainly used in construction and decoration, terrazzo aggregate etc..Because it has unique outward appearance and performance, much High-end residential, garden even high buildings and large mansions are all very close with the natural stone appearance such as natural granite, marble using covering with paint, lacquer, colour wash, etc. True mineral varnish, the use scope of true mineral varnish is also more and more wider.
Moreover, architectural reflective heat-insulation paint can reflect the sun heat radiation of summer, and film has very low lead in itself Hot property.Therefore, after this kind of coating of exterior wall surface application, film coated surface temperature will not be raised significantly, so as to reduce by wall Heat transfer of the body into building.In hot summer and warm winter zone and hot-summer and cold-winter area, external wall is covered with paint, lacquer, colour wash, etc. after architectural reflective heat-insulation paint, the summer Season, film coated surface temperature can at most reduce nearly 20 DEG C than such coating of non-application or the common coating surface temperature of application.Therefore, The true mineral varnish of color sand and reflective insulation are combined, the effect of decoration has both been reached, there can be the work(of reflective insulation, energy-conserving and environment-protective again Effect, kills two birds with one stone, with great realistic meaning.
Traditional true mineral varnish, it is not good to the effect of heat insulation of wall because voidage is larger.In existing process, be by The reflective insulation function of adding glass microballoon in the composition of true mineral varnish to realize, however, the true mineral varnish of general reflective insulation, past Toward the construction method using spraying, hollow glass micropearl density itself is relatively low, using spraying application, substantial amounts of hollow glass micropearl It can spray and be flown away less than metope in the air, lose larger, and air pressure is sprayed during site construction greatly, can also cause hollow glass micro- Pearl rupture loss, therefore, spraying application, hollow glass micropearl material consumption and the proportion of goods damageds are especially high.Meanwhile, true mineral varnish spraying application pair The requirement of construction worker is higher, easily causes metope to grow dim because the skills in the process of construction of construction worker is immature in spraying, and right Construction environment requires higher.If the true mineral varnish of usual spray is directly constructed using trowelling, construction effect is not good, easily sends out Flower phenomenon, because the state for spraying true mineral varnish requirement paint is that fluffy space is big, mobility can not be very good, when so spraying Stifled rifle is difficult, is difficult to hang arms.
In addition, requirement of the spraying application to workmen's construction technique and collaboration construction ability is higher, spraying gimmick, construction The execution conditions such as air pressure difference can all cause metope to grow dim.Meanwhile, strong wind weather is run into, spraying application is also not available for.
Therefore, how to improve by the way that on the premise of the function of reflective insulation is ensured, Optimizing construction mode, reduction glass is micro- The loss of pearl, has become those skilled in the art's technical problem urgently to be resolved hurrily.
The content of the invention
In order to solve the above technical problems, present invention offer is a kind of can to reduce the damage of glass microballoon effectively in work progress Consumption, optimizes coating reflective insulation effect, and imitation stone effect is good, the ornamental strong true mineral varnish of trowelling, and provides a kind of trowelling true stone The preparation method of paint.
To achieve the above object, concrete scheme of the invention is as follows:
The present invention provides a kind of true mineral varnish of reflective insulation trowelling, including following components in percentage by weight:
Further, the true mineral varnish of reflective insulation trowelling includes following components in percentage by weight:
Further, the granularity of the natural colour sand is 40-120 mesh.
Further, the polymer emulsion is acrylic emulsion or silicon Acrylote emulsion.
Further, the hollow glass micro-ball is the hollow glass micro-ball that 3M companies produce people's model VS5500, S15 In one or more.
Further, the protecting colloid salt be the LAPONITE-S482 of Bi Ke chemical companies, LAPONITE-RDS, One or more in LAPONIE-RD.
Further, the hydroxyethyl cellulose is non-ionic water-soluble cellulose ether;
Optional, the bactericide is isothiazolinone biocide agent;
Optional, the antifreezing agent is at least one of ethylene glycol, propane diols, glycerine.
Further, described auxiliary agent includes coalescents, defoamer, dispersant, thickener;
Optional, the coalescents are propane diols phenylate, butyl, dipropylene glycol monomethyl ether and TEXANOL In any one or two kinds of mixtures;
Optional, the defoamer is mineral oil antifoam agent;
Optional, the dispersant is ammonium polyacrylate salt;
Optional, the thickener is that polyacrylate alkali soluble rises type thickener.
Further, the auxiliary agent is that coalescents, defoamer, dispersant, thickener are 10 by weight:10:2:5 groups Into mixture.
The present invention also provides a kind of method for preparing the above-mentioned true mineral varnish of reflective insulation trowelling, comprises the following steps:
Each component raw material is weighed by weight percentage;
Water, protecting colloid salt, hydroxyethyl cellulose are sequentially added in agitator, is stirred at room temperature with 400-600 revs/min Mix uniform to without goose pimples;
The rotating speed of device is kept stirring for, auxiliary agent, antifreezing agent is added;
The rotating speed of agitator is improved to 600-800 revs/min, after stirring, polymer emulsion, bactericide is added, stirs Mix uniform;
The rotating speed of agitator is reduced to 300-500 revs/min, natural colour sand is added, is uniformly dispersed;
Hollow glass micro-ball is added, 200-300 revs/min of low speed is stirred 5 minutes, you can obtain reflective insulation trowelling true Mineral varnish.
Wherein,
The granularity for the natural colour sand that the present invention is used is 40-120 mesh, and the main function of natural colour sand is, as skeleton, to carry For good imitative stone effect.Therefore the consumption of color sand can not be very few, must at least reach 55%;And in order to ensure that true mineral varnish is good Good application property, color sand ratio should be in OK range, therefore the upper limit is 65%.
The polymer emulsion that the present invention is used is acrylic emulsion or silicon Acrylote emulsion.The main function of polymer emulsion It is that, as film forming matter, it is related to the adhesive force of true mineral varnish, the multinomial performance such as water resistance, therefore, the addition of polymer emulsion Amount can not be less than 19%;And the addition of polymer emulsion increase can cause true mineral varnish imitate stone effect reduction, therefore, the present invention The addition of polymer emulsion is controlled below 25%.
The present invention hollow glass micro-ball select be 3M companies production model VS5500, S15 hollow glass it is micro- One or more in ball.Hollow glass micro-ball is the main provider of reflective insulation performance, 5% hollow glass micro-ball addition Amount is that its performance meets the minimum addition of national standard, and adds that hollow glass micro-ball is more, and the viscosity of its finished product paint is higher, Stability is poorer, after the addition of the hollow glass micro-ball more than 10%, and the stability of finished product paint is greatly reduced, viscosity mistake Height, application property is deteriorated.
What the protecting colloid salt of the present invention was selected be the LAPONITE-S482 of Bi Ke chemical companies, LAPONITE-RDS, One or more in LAPONIE-RD.Protecting colloid salt can improve the application property of coating so that more compliant during construction, special The composition is not added in the true mineral varnish of reflective insulation trowelling, the true mineral varnish of reflective insulation trowelling can be caused to overcome its grained matte, The problem of feel of constructing is poor.Conventional true mineral varnish uses spraying application, it is desirable to which mobility is poor, is so difficult to grow dim;And trowelling is true Mineral varnish, due to the addition of protecting colloid salt, low-shear viscosity is high, is conducive to storage, and middle shear viscosity is low, it is easy to construct, and With certain mobility, reduce and easily arrange uneven in construction sand grains and cause situation about growing dim.
The hydroxyethyl cellulose that the present invention is used for non-ionic water-soluble cellulose ether, hydroxyethyl cellulose mainly as Anti-settling agent is present, and increases the stability of product system.
The bactericide that the present invention is used for isothiazolinone biocide agent, by add bactericide can reduce it is putrid and deteriorated Situation.
The antifreezing agent that the present invention is used is at least one of ethylene glycol, propane diols, glycerine, and antifreezing agent can be widened and applied The temperature range of work.
The auxiliary agent that the present invention is used is at least one of coalescents, defoamer, dispersant, wetting agent, thickener;It is logical Addition auxiliary agent is crossed, the performance of true mineral varnish can be done and adjusted slightly, control foam is between suitable scope, regulation heterogeneity Wetting and compatibility etc..
The present invention also provides a kind of method for preparing the above-mentioned true mineral varnish of reflective insulation trowelling, comprises the following steps:
Each component raw material is weighed by weight percentage;
Water, protecting colloid salt, hydroxyethyl cellulose are sequentially added in agitator, is stirred at room temperature with 400-600 revs/min Mix uniform to without goose pimples.Disperse protecting colloid salt, hydroxyethyl cellulose before addition auxiliary agent, it can be prevented rapid thick after adding Caused scattered uneven, jitter time is to be just uniformly dispersed as suitable time;
The rotating speed of device is kept stirring for, auxiliary agent, antifreezing agent is added;
The rotating speed of agitator is improved to 600~800 revs/min, after stirring, polymer emulsion, bactericide is added, Stir.Auxiliary agent is first added, water and auxiliary agent can be caused fully to merge, is disperseed more uniform;
The rotating speed of agitator is reduced to 300-500 revs/min, natural colour sand is added, is uniformly dispersed.Color sand is in later Addition, it is possible to reduce abrasion of the machine to its particle, must keep the effect of its imitative stone material, reduce agitator speed to greatest extent It is to reduce abrasion;
Hollow glass micro-ball is added, 200-300 revs/min of low speed is stirred 5 minutes, you can obtain reflective insulation trowelling true Mineral varnish.Hollow glass micro-ball compression strength itself is general, is added finally, it is possible to reduce hollow glass micropearl is produced because of abrasion Loss.
The beneficial effects of the present invention are:
The present invention creatively by adjusting true mineral varnish formula, specially have developed reflection using trowelling form of construction work every The true mineral varnish of heat, reduces the loss of hollow glass micropearl, enhances application property, constructs back reflection effect of heat insulation more preferably, Ke Yiyou The air-conditioning power consumption of effect reduction southern area, energy-saving and emission-reduction, environmental protection.
The true mineral varnish of trowelling of the present invention has stronger mobility, and emulsion distribution can be made more uniform, will not be because of emulsion point Cloth is uneven and causes to grow dim, and imitation stone effect is good after trowelling, ornamental strong, is provided simultaneously with reflective insulation efficiency, reduces building energy consumption, It is energy saving and environment friendly product.
The present invention efficiently solves reflective insulation in true mineral varnish construction effective in the case where ensure that the effect of true mineral varnish height emulation The problem of component damages are larger, effectively reduces the loss of glass microballoon, enhances the functional effect of reflective insulation, reduces and apply Requirement of the work to workmen's quality and execution conditions, suitable for promoting the use of.
Embodiment
Embodiments of the invention are described below in detail, the example of the embodiment is intended to be used to explain the present invention, and can not It is interpreted as limitation of the present invention.In the examples where no specific technique or condition is specified, according to described by document in the art Technology or condition or carried out according to product description.Agents useful for same or the unreceipted production firm person of instrument, are to lead to Cross the conventional products of acquisition purchased in market.
Embodiment 1:A kind of preparation of the true mineral varnish of reflective insulation trowelling
The true mineral varnish formula table (w/w%) of embodiment 1-3 reflective insulation trowellings of table 1
Embodiment 1 Embodiment 2 Embodiment 3
Natural colour sand 65 55 59
Polymer emulsion 19 25 19
Hollow glass micro-ball 5 9 10
Protecting colloid salt 1 2 1.5
Hydroxyethyl cellulose 0.5 0.5 0.5
Bactericide 0.3 0.3 0.3
Antifreezing agent 1 0.8 0.8
Auxiliary agent 1 2 2
Water 7.2 5.4 6.9
Composition of raw materials is shown in Table 1, wherein:
The granularity of natural colour sand is 40-120 mesh;Polymer emulsion is acrylic acid pure-acrylic emulsion;Hollow glass micro-ball is 3M In company's production, model VS5500 hollow glass micro-balls;The LAPONITE- for the Bi Ke chemical companies that protecting colloid salt is selected S482;Hydroxyethyl cellulose is non-ionic water-soluble cellulose ether;Antifreezing agent is ethylene glycol;Bactericide is isothiazolinone Bactericide;Auxiliary agent is that coalescents, defoamer, wetting agent and thickener are 10 in mass ratio:10:2:5 mixture, film forming is helped Agent is the mixture of ethylene glycol monobutyl ether and butyl;Defoamer is mineral oil antifoam agent;Thickener is polyacrylic acid Saline and alkaline swelling type thickener.
Preparation method:
Each component raw material is weighed by weight percentage;
Water, protecting colloid salt, hydroxyethyl cellulose are sequentially added in agitator, is stirred at room temperature with 400-600 revs/min Mix uniform to without goose pimples;
The rotating speed of device is kept stirring for, auxiliary agent, antifreezing agent is added;
The rotating speed of agitator is improved to 600-800 revs/min, after stirring, polymer emulsion, bactericide is added, stirs Mix uniform;
The rotating speed of agitator is reduced to 300-500 revs/min, natural colour sand is added, is uniformly dispersed;
Hollow glass micro-ball is added, 200-300 revs/min of low speed is stirred 5 minutes, you can obtain reflective insulation trowelling true Mineral varnish.
Embodiment 2:A kind of preparation of the true mineral varnish of reflective insulation trowelling
Composition of raw materials is shown in Table 1, wherein:
The granularity of natural colour sand is 40-120 mesh;Polymer emulsion is silicon Acrylote acrylic emulsion;Hollow glass micro-ball is 3M Company's production, model S15 hollow glass micro-ball;The LAPONITE-RDS for the Bi Ke chemical companies that protecting colloid salt is selected; Hydroxyethyl cellulose is non-ionic water-soluble cellulose ether;Antifreezing agent is glycerine;Bactericide is isothiazolinone biocide Agent;Auxiliary agent is that coalescents, defoamer, wetting agent and thickener are 10 in mass ratio:10:2:5 mixture, coalescents are The mixture of dipropylene glycol monomethyl ether and butyl;Defoamer is mineral oil antifoam agent;Thickener is polyacrylate Alkali soluble rises type thickener.
Preparation method be the same as Example 1.
Embodiment 3:A kind of preparation of the true mineral varnish of reflective insulation trowelling
Composition of raw materials is shown in Table 1, wherein:
The granularity of natural colour sand is 40-120 mesh;Polymer emulsion is silicon Acrylote acrylic emulsion;Hollow glass micro-ball is 3M Company's production, model S15 hollow glass micro-ball;The LAPONITE-RDS for the Bi Ke chemical companies that protecting colloid salt is selected; Hydroxyethyl cellulose is non-ionic water-soluble cellulose ether;Antifreezing agent is propane diols;The bactericide is isothiazolinone Bactericide;Auxiliary agent is that coalescents, defoamer, wetting agent and thickener are 10 in mass ratio:10:2:5 mixture;Defoamer For mineral oil antifoam agent;Thickener is that polyacrylate alkali soluble rises type thickener;Coalescents be dipropylene glycol monomethyl ether and TEXANOL mixture.
Preparation method be the same as Example 1.
Experiment effect:
The product of the present invention, and the production according to national standard to 1-3 of the embodiment of the present invention are used using trowelling form of construction work Effect after product trowelling is detected that testing result is as shown in table 2:
The embodiment 1-3 Product checking result tables of table 2
Detection project National standard Embodiment 1 Embodiment 2 Embodiment 3
Initial dry cracking resistance Flawless Flawless Flawless Flawless
Water resistance 96H is unchanged 96H is unchanged 96H is unchanged 96H is unchanged
Alkali resistance 96H is unchanged 96H is unchanged 96H is unchanged 96H is unchanged
Coating temperature-change resistance 10 times unchanged 10 times unchanged 10 times unchanged 10 times unchanged
The heat-insulated temperature difference - 15℃ 19℃ 16℃
Sun luminous reflectance (white light) ≥0.80 0.88 0.89 0.88
As seen from the above table, the true mineral varnish reflective insulation excellent effect of reflective insulation trowelling of the invention, durability are good;And this Invention optimizes form of construction work, expands the temperature range of construction, is conducive to promoting the use of.
Although specifically showing and describing the present invention with reference to preferred embodiment, those skilled in the art should be bright In vain, do not departing from the spirit and scope of the present invention that appended claims are limited, in the form and details can be right The present invention makes a variety of changes, and is protection scope of the present invention.

Claims (10)

1. a kind of true mineral varnish of reflective insulation trowelling, it is characterised in that including following components in percentage by weight:
2. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that include the group of following percentage by weight Point:
3. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the granularity of the natural colour sand is 40-120 mesh.
4. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the polymer emulsion is acrylic acid Emulsion or silicon Acrylote emulsion.
5. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the hollow glass micro-ball is 3M public One or more in the hollow glass micro-ball of department's production people's model VS5500, S15.
6. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the protecting colloid salt is Bi Kehua One or more in LAPONITE-S482, LAPONITE-RDS, LAPONIE-RD of company.
7. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the hydroxyethyl cellulose for it is non-from Subtype water-soluble cellulose ether;
Optional, the bactericide is isothiazolinone biocide agent;
Optional, the antifreezing agent is at least one of ethylene glycol, propane diols, glycerine.
8. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that described auxiliary agent is helped including film forming Agent, defoamer, dispersant, thickener;
Optional, the coalescents is in propane diols phenylate, butyl, dipropylene glycol monomethyl ether and TEXANOL Any one or two kinds of mixtures;
Optional, the defoamer is mineral oil antifoam agent;
Optional, the dispersant is ammonium polyacrylate salt;
Optional, the thickener is that polyacrylate alkali soluble rises type thickener.
9. the true mineral varnish of reflective insulation trowelling according to claim 1, it is characterised in that the auxiliary agent is coalescents, disappeared Infusion, dispersant, thickener are 10 by weight:10:2:The mixture of 5 compositions.
10. a kind of method for preparing any described true mineral varnish of reflective insulation trowelling in claim 1 to 9, it is characterised in that bag Include following steps:
Each component raw material is weighed by weight percentage;
Water, protecting colloid salt, hydroxyethyl cellulose are sequentially added in agitator, it is equal with 400-600 revs/min of stirring at room temperature It is even to without goose pimples;
The rotating speed of device is kept stirring for, auxiliary agent, antifreezing agent is added;
The rotating speed of agitator is improved to 600-800 revs/min, after stirring, polymer emulsion, bactericide is added, stirring is equal It is even;
The rotating speed of agitator is reduced to 300-500 revs/min, natural colour sand is added, is uniformly dispersed;
Hollow glass micro-ball is added, 200-300 revs/min of low speed is stirred 5 minutes, you can obtain the true mineral varnish of reflective insulation trowelling.
CN201710414265.XA 2017-06-06 2017-06-06 A kind of true mineral varnish of reflective insulation trowelling and preparation method thereof Pending CN107162486A (en)

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CN107935451A (en) * 2017-12-04 2018-04-20 江苏永宸建材科技有限公司 A kind of lacquer and preparation method thereof
CN110372266A (en) * 2019-07-22 2019-10-25 和东正环保科技有限公司 A kind of lacquer and preparation method thereof
CN112300650A (en) * 2020-11-18 2021-02-02 福州居家逸涂料科技有限公司 Scraping type stone-like paint and application thereof
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CN107935451A (en) * 2017-12-04 2018-04-20 江苏永宸建材科技有限公司 A kind of lacquer and preparation method thereof
CN110372266A (en) * 2019-07-22 2019-10-25 和东正环保科技有限公司 A kind of lacquer and preparation method thereof
CN112300650A (en) * 2020-11-18 2021-02-02 福州居家逸涂料科技有限公司 Scraping type stone-like paint and application thereof
CN115093763A (en) * 2022-07-04 2022-09-23 中华制漆(深圳)有限公司 Anti-blooming stone-like paint and preparation method thereof
CN115093763B (en) * 2022-07-04 2023-07-04 中华制漆(深圳)有限公司 Anti-bloom stone-like paint and preparation method thereof

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