CN105602410A - Antique paint and manufacturing technique thereof - Google Patents

Antique paint and manufacturing technique thereof Download PDF

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Publication number
CN105602410A
CN105602410A CN201610182770.1A CN201610182770A CN105602410A CN 105602410 A CN105602410 A CN 105602410A CN 201610182770 A CN201610182770 A CN 201610182770A CN 105602410 A CN105602410 A CN 105602410A
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China
Prior art keywords
parts
paint
antiquing
pigment
powder
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Granted
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CN201610182770.1A
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Chinese (zh)
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CN105602410B (en
Inventor
陈飞
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Dongguan Liuhua Art Co Ltd
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Dongguan Liuhua Art Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24Homopolymers or copolymers of amides or imides
    • C09D133/26Homopolymers or copolymers of acrylamide or methacrylamide
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention provides an antique paint and a manufacturing technique thereof, relating to the field of paints. The antique paint is composed of the following components in parts by weight: 5-25 parts of epoxy resin, 2-6 parts of phthalic anhydride, 10-15 parts of polyacrylamide, 8-20 parts of isopropanol, 4-10 parts of titanium white, 2-5 parts of nano silver oxide, 0.1-0.4 part of sodium soap, 5-8 parts of light calcium carbonate powder, 3-5 parts of kaolin, 0.7-2 parts of coupling agent, 0.5-6 parts of dispersing agent, 4-8 parts of defoaming agent, 3-10 parts of anti-settling agent, 3-8 parts of thickener, 1-3 parts of pigment, 5-25 parts of thinner, 5-15 parts of metal powder, 5-8 parts of alkyd resin and 55-75 parts of turpentine. The coated antique paint provided by the invention has the advantages of low cracking tendency, favorable glossiness and favorable decorative effect.

Description

A kind of antiquing paint and manufacture craft thereof
Technical field
The invention belongs to paint field, specifically relate to a kind of antiquing paint and manufacture craft thereof.
Background technology
Paint is that one can firmly cover body surface, plays the chemical mixing of protection, decoration, mark and other specific usesThing coating. In present household and handicraft market, the direction that the people of being modelled after an antique pursue, general household is applying after paint modelled after an antique,Do not need too much do old technology and just can obtain pseudo-classic furniture. Therefore antiquing paint is by widespread demand. China's ancient building wonderful workmanship excelling nature, essenceWonderful human relations, but as time goes by, a lot of ancient buildings are scarred, are badly in need of repairing. But the antiquing paint on market is because executingThe specificity of work conditions and environment, often exists easily cracking, glossiness low, the shortcoming that decorative effect is not strong.
Summary of the invention
In view of this, the invention provides a kind of antiquing paint and manufacture craft thereof, to improve, existing antiquing paint easily ftractures, lightPool degree is low, the problem that decorative effect is poor.
For achieving the above object, the technical solution used in the present invention is:
A kind of antiquing paint, meter by weight, is made up of following component: epoxy resin 5-25 part, phthalic anhydride 2-6 part, poly-Acrylamide 10-15 part, isopropyl alcohol 8-20 part, titanium dioxide 4-10 part, nano phase ag_2 o 2-5 part, sodium soap 0.1-0.4Part, light calcium carbonate powder 5-8 part, kaolin 3-5 part, coupling agent 0.7-2 part, dispersant 0.5-6 part, defoamer 4-8Part, anti-settling agent 3-10 part, thickener 3-8 part, pigment 1-3 part, Tianna solution 5-25, metal powder 5-15 part, alkyd resins 5-8Part, turpentine 55-75 part.
Preferably, in preferred embodiment of the present invention, described pigment color is ultramarine or viridescent, and the use of these colors has moreGood antique effect.
Preferably, in preferred embodiment of the present invention, described metal powder is copper bronze and silver powder mixture, and ratio is 1-2:2-5 adds metal dust can make finish paint stereovision strengthen in finish paint, has better decorative effect.
The present invention also provides a kind of manufacture craft of above-mentioned antiquing paint, comprises the following steps:
(1) take according to quantity described epoxy resin, described phthalic anhydride, described polyacrylamide and described isopropyl alcohol and pour reactor intoIn, adjusting described reactor rotating speed is 300-500r/min, rotates and stir 5-10min at 60-80 DEG C;
(2) continue to add described titanium dioxide, described nano phase ag_2 o, described sodium soap, described lightweight carbonic acid in described reactorCalcium powder, described kaolin, stir 3-8min;
(3) treat that the mixture that step (2) obtains is cooled to 45-60 DEG C, in described mixture, add described coupling agent, described dispersionAgent, described defoamer, described anti-settling agent, described thickener, adjusting described reactor rotating speed is 350-450r/min, stirs 1.5-2h,Be cooled to 20-35 DEG C and can obtain semi-finished product;
(4) modulation priming paint: drop into described semi-finished product, described pigment, described Tianna solution at homogenizer 700-900r/min by proportioningUnder mix;
(5) modulation finish paint: drop into described alkyd resins, described metal powder, described turpentine at homogenizer 700-900r/min by proportioningUnder mix;
(6) coating process: with 400 order sand paper, wood product surface is polished, described surface uniform is sprayed to described priming paint, wait to doAfter dry, again repair polishing, evenly spray described finish paint.
Preferably, in preferred embodiment of the present invention, described priming paint applies woodwork, and coating thickness is0.4-0.5mm, polishes with 2000 object sand paper after applying.
With respect to prior art, beneficial effect of the present invention: paint pigment coating provided by the invention is strong, fast drying, noEasy to crack. Appropriately choose pigment, strengthened the antique effect of antiquing paint. In finish paint, add metal powder and make finish paint apply rear increasingStrong lacquer painting stereovision, has better decorative effect.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme of the present invention is further described.
Embodiment 1:
Embodiments of the invention 1 provide a kind of antiquing paint, and meter, is made up of following component: 5 parts of epoxy resin, neighbour by weight2 parts of phthalate anhydrides, 10 parts of polyacrylamides, 8 parts of isopropyl alcohols, 4 parts of titanium dioxides, 2 parts of nano phase ag_2 os, sodium soap0.1 part, 5 parts of light calcium carbonate powder, 3 parts of kaolin, 0.7 part of coupling agent, 0.5 part of dispersant, 4 parts of defoamers, anti-3 parts of heavy agent, 3 parts of thickeners, 1 part of pigment, Tianna solution 5,5 parts of metal powders, 5 parts of alkyd resins, 55 parts of turpentine.
The selected pigment color of antiquing paint is ultramarine or viridescent, and the use of these colors has better antique effect.
In antiquing paint, metal powder is copper bronze and silver powder mixture, and ratio is 1:2, adds metal dust can make face in finish paintPaint stereovision strengthens, and has better decorative effect.
The present embodiment also provides a kind of preparation method of antiquing paint, comprises the following steps:
(1) take according to quantity epoxy resin, phthalic anhydride, polyacrylamide and isopropyl alcohol and pour in reactor, adjust reactor and turnSpeed is 300r/min, rotates and stir 5min at 60 DEG C;
(2) continue to add titanium dioxide, nano phase ag_2 o, sodium soap, light calcium carbonate powder, kaolin in reactor, stir3min;
(3) treat that the mixture that step (2) obtains is cooled to 45 DEG C, in mixture, add coupling agent, dispersant, defoamer, anti-Heavy agent, thickener, adjusting reactor rotating speed is 350r/min, stirs 1.5h, is cooled to 20 DEG C and can obtains semi-finished product;
(4) modulation priming paint: mix under homogenizer 700r/min by proportioning input semi-finished product, pigment, Tianna solution;
(5) modulation finish paint: mix under homogenizer 700r/min by proportioning input alkyd resins, metal powder, turpentine;(6) coating process: with 400 order sand paper, wood product surface is polished, effects on surface evenly sprays priming paint, to be dried after againRepair polishing, evenly spray paint.
The priming paint of modulation applies woodwork, and coating thickness is 0.4mm, after applying, polishes with 2000 object sand paper.
Embodiment 2:
Embodiments of the invention 2 provide a kind of antiquing paint, and meter, is made up of following component: 25 parts of epoxy resin, neighbour by weight6 parts of phthalate anhydrides, 15 parts of polyacrylamides, 20 parts of isopropyl alcohols, 10 parts of titanium dioxides, 5 parts of nano phase ag_2 os, aliphatic acid0.4 part, sodium, 8 parts of light calcium carbonate powder, 5 parts of kaolin, 2 parts of coupling agents, 6 parts of dispersants, 8 parts of defoamers, anti-settling10 parts of agent, 8 parts of thickeners, 3 parts of pigment, Tianna solution 25,15 parts of metal powders, 8 parts of alkyd resins, 75 parts of turpentine.
The selected pigment color of antiquing paint is ultramarine or viridescent. The use of these colors has better antique effect.
In antiquing paint, metal powder is copper bronze and silver powder mixture, and ratio is 2:5, adds metal dust can make face in finish paintPaint stereovision strengthens, and has better decorative effect.
The present embodiment also provides a kind of preparation method of antiquing paint, comprises the following steps:
(1) take according to quantity epoxy resin, phthalic anhydride, polyacrylamide and isopropyl alcohol and pour in reactor, adjust reactor and turnSpeed is 500r/min, rotates and stir 10min at 80 DEG C;
(2) continue to add titanium dioxide, nano phase ag_2 o, sodium soap, light calcium carbonate powder, kaolin in reactor, stir8min;
(3) treat that the mixture that step (2) obtains is cooled to 60 DEG C, in mixture, add coupling agent, dispersant, defoamer, anti-Heavy agent, thickener, adjusting reactor rotating speed is 450r/min, stirs 2h, is cooled to 35 DEG C and can obtains semi-finished product;
(4) modulation priming paint: mix under homogenizer 900r/min by proportioning input semi-finished product, pigment, Tianna solution;
(5) modulation finish paint: mix under homogenizer 900r/min by proportioning input alkyd resins, metal powder, turpentine.
(6) coating process: with 400 order sand paper, wood product surface is polished, effects on surface evenly sprays priming paint, to be driedAfter again repair polishing, evenly spray paint.
The priming paint of modulation applies woodwork, and coating thickness is 0.5mm, after applying, polishes with 2000 object sand paper.
Embodiment 3:
Embodiments of the invention 3 provide a kind of antiquing paint, and meter, is made up of following component: 15 parts of epoxy resin, neighbour by weight4 parts of phthalate anhydrides, 12 parts of polyacrylamides, 14 parts of isopropyl alcohols, 7 parts of titanium dioxides, 3 parts of nano phase ag_2 os, aliphatic acid0.2 part, sodium, 6 parts of light calcium carbonate powder, 4 parts of kaolin, 1.3 parts of coupling agents, 3.3 parts of dispersants, 6 parts of defoamers,7 parts of anti-settling agents, 5 parts of thickeners, 2 parts of pigment, Tianna solution 15,10 parts of metal powders, 7 parts of alkyd resins, turpentine 65Part.
The selected pigment color of antiquing paint is ultramarine or viridescent. The use of these colors has better antique effect.
In antiquing paint, metal powder is copper bronze and silver powder mixture, and ratio is 1.5:3.5, adds metal dust meeting in finish paintFinish paint stereovision is strengthened, have better decorative effect.
The present embodiment also provides a kind of preparation method of antiquing paint, comprises the following steps:
(1) take according to quantity epoxy resin, phthalic anhydride, polyacrylamide and isopropyl alcohol and pour in reactor, adjust reactor and turnSpeed is 400r/min, rotates and stir 7min at 70 DEG C;
(2) continue to add titanium dioxide, nano phase ag_2 o, sodium soap, light calcium carbonate powder, kaolin in reactor, stir5min;
(3) treat that the mixture that step (2) obtains is cooled to 52 DEG C, in mixture, add coupling agent, dispersant, defoamer, anti-Heavy agent, thickener, adjusting reactor rotating speed is 4000r/min, stirs 1.2h, is cooled to 27 DEG C and can obtains semi-finished product;
(4) modulation priming paint: mix under homogenizer 800r/min by proportioning input semi-finished product, pigment, Tianna solution;
(5) modulation finish paint: mix under homogenizer 800r/min by proportioning input alkyd resins, metal powder, turpentine.
(6) coating process: with 400 order sand paper, wood product surface is polished, effects on surface evenly sprays priming paint, to be driedAfter again repair polishing, evenly spray paint.
The priming paint of modulation applies woodwork, and coating thickness is 0.45mm, after applying, beats with 2000 object sand paperMill.
The adhesive force that finished product after the prepared paint application of embodiment 1-3 is carried out and 24 hours salt spray tests, salt spray testEffect is represented by defect area A (sample surfaces defect accounts for the percentage of the gross area). Find embodiment 3 gained by contrastFinished product strong adhesion, not easy to crack, there is better glossiness.
Embodiment Adhesive force (degree comes off) Defect area A (%)
Embodiment 1 6% 0.11
Embodiment 2 7% 0.12
Embodiment 3 5% 0.09

Claims (5)

1. an antiquing paint, is characterized in that, meter, is made up of following component: epoxy resin 5-25 part, O-phthalic by weightAcid anhydrides 2-6 part, polyacrylamide 10-15 part, isopropyl alcohol 8-20 part, titanium dioxide 4-10 part, nano phase ag_2 o 2-5 part, fatFat acid sodium 0.1-0.4 part, light calcium carbonate powder 5-8 part, kaolin 3-5 part, coupling agent 0.7-2 part, dispersant 0.5-6 part,Defoamer 4-8 part, anti-settling agent 3-10 part, thickener 3-8 part, pigment 1-3 part, Tianna solution 5-25, metal powder 5-15 part,Alkyd resins 5-8 part, turpentine 55-75 part.
2. an antiquing paint as claimed in claim 1, is characterized in that: described pigment color is ultramarine or viridescent.
3. an antiquing paint as claimed in claim 1, is characterized in that: described metal powder is copper bronze and silver powder mixture, qualityThan being 1-2:2-5.
4. a manufacture craft for antiquing paint as described in claim 1-3 any one, is characterized in that, comprises the following steps:
(1) take according to quantity described epoxy resin, described phthalic anhydride, described polyacrylamide and described isopropyl alcohol and pour reactor intoIn, adjusting described reactor rotating speed is 300-500r/min, rotates and stir 5-10min at 60-80 DEG C;
(2) continue to add described titanium dioxide, described nano phase ag_2 o, described sodium soap, described lightweight carbonic acid in described reactorCalcium powder, described kaolin, stir 3-8min;
(3) treat that the mixture that step (2) obtains is cooled to 45-60 DEG C, in described mixture, add described coupling agent, described dispersionAgent, described defoamer, described anti-settling agent, described thickener, adjusting described reactor rotating speed is 350-450r/min, stirs 1.5-2h,Be cooled to 20-35 DEG C and can obtain semi-finished product;
(4) modulation priming paint: drop into described semi-finished product, described pigment, described Tianna solution at homogenizer 700-900r/min by proportioningUnder mix;
(5) modulation finish paint: drop into described alkyd resins, described metal powder, described turpentine at homogenizer 700-900r/min by proportioningUnder mix;
(6) coating process: with 400 order sand paper, wood product surface is polished, described surface uniform is sprayed to described priming paint, wait to doAfter dry, again repair polishing, evenly spray described finish paint.
5. a manufacture craft for antiquing paint as claimed in claim 4, described priming paint applies woodwork, and coating thickness is0.4-0.5mm, polishes with 2000 object sand paper after applying.
CN201610182770.1A 2016-03-28 2016-03-28 A kind of antiquing paint and its manufacture craft Active CN105602410B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610182770.1A CN105602410B (en) 2016-03-28 2016-03-28 A kind of antiquing paint and its manufacture craft

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Application Number Priority Date Filing Date Title
CN201610182770.1A CN105602410B (en) 2016-03-28 2016-03-28 A kind of antiquing paint and its manufacture craft

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380913A (en) * 2016-09-26 2017-02-08 笪亚臣 Wardrobe surface environment-friendly paint and preparation method thereof
CN106675269A (en) * 2017-01-05 2017-05-17 广东绿色大地化工有限公司 Waterborne archaized art paint and preparation method thereof
CN106752731A (en) * 2017-02-24 2017-05-31 东莞市榴花艺术有限公司 A kind of imitative wood paint
CN110484092A (en) * 2019-08-09 2019-11-22 湖州南浔鑫荣木业有限公司 A kind of fire-retardant paint for wood furniture
CN110564298A (en) * 2019-08-09 2019-12-13 湖州南浔鑫荣木业有限公司 antique paint with repairing function
CN111361342A (en) * 2020-04-16 2020-07-03 邢台市洛宸牌匾碑刻艺术有限公司 Method for engraving convex book body
CN115260898A (en) * 2022-07-29 2022-11-01 武汉雅美佳联合新材料有限公司 High-temperature-resistant water-based multi-layer antique paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103305096A (en) * 2013-07-09 2013-09-18 湖南太子化工涂料有限公司 Multifunctional undercoat and preparation method thereof
CN104384088A (en) * 2014-11-13 2015-03-04 厦门建霖工业有限公司 Electroplating-free antique metal surface treatment method
CN104449272A (en) * 2014-10-09 2015-03-25 安徽省孟府家工艺品有限公司 Archaistic paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103305096A (en) * 2013-07-09 2013-09-18 湖南太子化工涂料有限公司 Multifunctional undercoat and preparation method thereof
CN104449272A (en) * 2014-10-09 2015-03-25 安徽省孟府家工艺品有限公司 Archaistic paint
CN104384088A (en) * 2014-11-13 2015-03-04 厦门建霖工业有限公司 Electroplating-free antique metal surface treatment method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380913A (en) * 2016-09-26 2017-02-08 笪亚臣 Wardrobe surface environment-friendly paint and preparation method thereof
CN106675269A (en) * 2017-01-05 2017-05-17 广东绿色大地化工有限公司 Waterborne archaized art paint and preparation method thereof
CN106752731A (en) * 2017-02-24 2017-05-31 东莞市榴花艺术有限公司 A kind of imitative wood paint
CN110484092A (en) * 2019-08-09 2019-11-22 湖州南浔鑫荣木业有限公司 A kind of fire-retardant paint for wood furniture
CN110564298A (en) * 2019-08-09 2019-12-13 湖州南浔鑫荣木业有限公司 antique paint with repairing function
CN111361342A (en) * 2020-04-16 2020-07-03 邢台市洛宸牌匾碑刻艺术有限公司 Method for engraving convex book body
CN115260898A (en) * 2022-07-29 2022-11-01 武汉雅美佳联合新材料有限公司 High-temperature-resistant water-based multi-layer antique paint and preparation method thereof

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