CN102627005B - Carbon tetrafluoride aluminum single board - Google Patents
Carbon tetrafluoride aluminum single board Download PDFInfo
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- CN102627005B CN102627005B CN 201210104677 CN201210104677A CN102627005B CN 102627005 B CN102627005 B CN 102627005B CN 201210104677 CN201210104677 CN 201210104677 CN 201210104677 A CN201210104677 A CN 201210104677A CN 102627005 B CN102627005 B CN 102627005B
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- tetrafluoro
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- carbon
- aluminum veneer
- carbon tetrafluoride
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- -1 Carbon tetrafluoride aluminum Chemical compound 0.000 title abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- XGQJGMGAMHFMAO-UHFFFAOYSA-N 1,3,4,6-tetrakis(methoxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound COCN1C(=O)N(COC)C2C1N(COC)C(=O)N2COC XGQJGMGAMHFMAO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- 238000005254 chromizing Methods 0.000 claims abstract description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 12
- 229920002313 fluoropolymer Polymers 0.000 claims description 11
- 239000004811 fluoropolymer Substances 0.000 claims description 11
- 239000004411 aluminium Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000012241 calcium silicate Nutrition 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 238000007590 electrostatic spraying Methods 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000015511 Liquidambar orientalis Nutrition 0.000 claims description 4
- 239000004870 Styrax Substances 0.000 claims description 4
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 4
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical group [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 244000028419 Styrax benzoin Species 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000003973 paint Substances 0.000 abstract description 3
- YAIQCYZCSGLAAN-UHFFFAOYSA-N [Si+4].[O-2].[Al+3] Chemical compound [Si+4].[O-2].[Al+3] YAIQCYZCSGLAAN-UHFFFAOYSA-N 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
- 239000002585 base Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 241000736148 Styrax Species 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- WZKSXHQDXQKIQJ-UHFFFAOYSA-N F[C](F)F Chemical compound F[C](F)F WZKSXHQDXQKIQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- LTVOKYUPTHZZQH-UHFFFAOYSA-N difluoromethane Chemical compound F[C]F LTVOKYUPTHZZQH-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Abstract
The invention relates to an aluminum single board, in particular to a carbon tetrafluoride aluminum single board. The carbon tetrafluoride aluminum single board comprises an aluminum base board layer, a chromizing film layer and a carbon tetrafluoride layer which are sequentially arranged from inside to outside. The carbon tetrafluoride aluminum single board is formed by electrostatically spraying carbon tetrafluoride powder coatings which are composed of the following components in part by weight: 30-60 parts of arcarbon tetrafluoride resin, 5-20 parts of acrylic resin, 1-5 parts of hydroxyl alkyl acyl, 3-8 parts of tetramethoxy methyl glycoluril, 1-8 parts of zirconium oxide, 2-6 parts of calcium silicate, 2-5 parts of magnesium oxide, 1-3 parts of silicon-aluminum oxide, 1-25 parts of paint and 1-5 parts of accessory ingredient. The carbon tetrafluoride aluminum single board provided by the invention has excellent chemical resistance, weather resistance, adhesive force and gloss.
Description
Technical field
The present invention relates to a kind of aluminum veneer, particularly relate to a kind of tetrafluoro carbon aluminum veneer.
Background technology
The aluminum veneer that sprays out with fluorocarbon powder paint is because its quality is light; install easily; and because fluorocarbon powder paint does not contain solvent fully; can all convert to and film, and coating efficiency is high, protection and decoration good combination property; thereby having good chemical resistance, heat resistance, weatherability makes fluorine carbon aluminum veneer have the advantages such as nontoxic, anticorrosion, anti-oxidation, attractive in appearance, that cleaning is easy; be widely used in decoration material field, be subject to global extensive attention, thereby obtained development at full speed.
The tetrafluoro carbon coating is because its main component fluorocarbon resin contains four fluorine carbon bonds, be heated, the fluorine carbon bond is difficult to fracture under the condition such as light, therefore have more the weatherability of overlength and superpower resistant to chemical media anti-corrosive properties than difluoro carbon and trifluoro carbon, its aluminium base for preparing has good resistance to ag(e)ing and chemical resistance, but fluorocarbon coating, particularly existing tetrafluoro Fluoropolymer Powder Coatings but exists poor adhesive force after film forming aborning, the problem that hardness is inadequate.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of tetrafluoro carbon aluminum veneer.
Technical scheme of the present invention is as follows: a kind of tetrafluoro carbon aluminum veneer, comprise the aluminium base flaggy that outwards sets gradually from inner, chromizing film layer and tetrafluoro carbon-coating, described tetrafluoro carbon-coating is formed by the tetrafluoro Fluoropolymer Powder Coatings electrostatic spraying that following parts by weight of component forms: tetrafluoro carbon resin 30-60, acrylic resin 5-20, hydroxyalkylamides 1-5, tetramethoxymethylglycoluril 3-8, zirconia 1-8, calcium silicates 2-6, magnesia 2-5, oxidation sial 1-3, pigment 1-25, auxiliary agent 1-5.
Described pigment is that titanium white, titanium are red, one or more in lead chromate yellow, iron oxide, aluminium powder, carbon black.
Described auxiliary agent is one or more in levelling agent, dispersant or defoamer.
Preferably, described defoamer is styrax.
Preferably, described levelling agent is fluorine-carbon modified polyacrylate.
Preferably, described dispersant is modified polyorganosiloxane.
The granularity of described tetrafluoro carbon dust is the 5-25 micron.
The preparation method of tetrafluoro carbon powder coating:
Take by weight above each component, put into mixer, mixing, rear grinder to granularity excessively is the 5-25 micron.
in the present invention, the main component of the prescription of the tetrafluoro Fluoropolymer Powder Coatings of preparation tetrafluoro carbon aluminum veneer tetrafluoro carbon-coating is tetrafluoro carbon resin and acrylic resin, the tetrafluoro carbon resin has high temperature resistant, low temperature resistant, corrosion-resistant, do not adhere to, the good characteristics such as nonhazardous, in this prescription, hydroxyalkylamides has the effect of solidifying carboxyl, and tetramethoxymethylglycoluril has the effect of solidifying hydroxyl, add simultaneously zirconia, calcium silicates, magnesia, these inorganic raw materials of oxidation sial, hardness and the gloss of rete have been increased, add pigment and auxiliary agent, the appearance such as the color of further enhancing rete and smoothness, make tetrafluoro carbon aluminium base provided by the invention have good chemical resistance, weatherability, adhesive force and gloss.
The specific embodiment
The present invention is described further below in conjunction with embodiment.
Embodiment 1
Preparation tetrafluoro Fluoropolymer Powder Coatings: take tetrafluoro carbon resin 30g, acrylic resin 5g, hydroxyalkylamides 1g, tetramethoxymethylglycoluril 3g, zirconia 1g, calcium silicates 2g, magnesia 2g, oxidation sial 1g, styrax 1g, put into mixer, stir, cross grinding body mill, to granularity be 10 microns.
Get aluminium base degreasing, cleaning, chromaking, electrostatic spraying tetrafluoro Fluoropolymer Powder Coatings, baking, roll off the production line after cooling.
Embodiment 2
Preparation tetrafluoro Fluoropolymer Powder Coatings: take tetrafluoro carbon resin 60g, acrylic resin 20g, hydroxyalkylamides 5g, tetramethoxymethylglycoluril 8 g, zirconia 8g, calcium silicates 6g, magnesia 5g, oxidation sial 3g, titanium dioxide 25g, styrax 1g, fluorine-carbon modified polyacrylate 1g, put into mixer, stirring, cross the grinding body mill, is the 5-25 micron to granularity.
Get aluminium base degreasing, cleaning, chromaking, electrostatic spraying tetrafluoro Fluoropolymer Powder Coatings, baking, roll off the production line after cooling.
Embodiment 3
Preparation tetrafluoro Fluoropolymer Powder Coatings: take tetrafluoro carbon resin 50g, acrylic resin 12g, hydroxyalkylamides 3g, tetramethoxymethylglycoluril 5g, zirconia 5g, calcium silicates 4g, magnesia 3g, oxidation sial 2g, titanium dioxide 10g,, modified polyorganosiloxane 2g, put into mixer, stir, crossing the grinding body mill, is the 5-25 micron to granularity.
Get aluminium base degreasing, cleaning, chromaking, electrostatic spraying tetrafluoro Fluoropolymer Powder Coatings, baking, roll off the production line after cooling.
Coating with the preparation in above-described embodiment sprays aluminium base, and each measurement of technical parameter result is as follows.
?
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Acid resistance (5% sulfuric acid 10 days) | Unchanged | Unchanged | Unchanged |
| Alkali resistance (5% NaOH 10 days) | Unchanged | Unchanged | Unchanged |
| Salt spray resistance | 4000h is unchanged | 4000h is unchanged | 4000h is unchanged |
| Adhesive force (cross-hatching) level | 0 | 0 | 0 |
| Pencil hardness | 2H | 2H | 2H |
| Gloss | 75 | 78 | 72 |
Claims (7)
1. tetrafluoro carbon aluminum veneer, comprise the aluminium base flaggy that outwards sets gradually from inner, chromizing film layer and tetrafluoro carbon-coating, it is characterized in that, described tetrafluoro carbon-coating is formed by the tetrafluoro Fluoropolymer Powder Coatings electrostatic spraying that following parts by weight of component forms: tetrafluoro carbon resin 30-60, acrylic resin 5-20, hydroxyalkylamides 1-5, tetramethoxymethylglycoluril 3-8, zirconia 1-8, calcium silicates 2-6, magnesia 2-5, oxidation sial 1-3, pigment 1-25, auxiliary agent 1-5.
2. tetrafluoro carbon aluminum veneer according to claim 1, is characterized in that, described pigment is that titanium white, titanium are red, one or more in lead chromate yellow, iron oxide, aluminium powder, carbon black.
3. tetrafluoro carbon aluminum veneer according to claim 1, is characterized in that, described auxiliary agent is one or more in levelling agent, dispersant or defoamer.
4. tetrafluoro carbon aluminum veneer according to claim 3, is characterized in that, described defoamer is styrax.
5. tetrafluoro carbon aluminum veneer according to claim 3, is characterized in that, described levelling agent is fluorine-carbon modified polyacrylate.
6. tetrafluoro carbon aluminum veneer according to claim 3, is characterized in that, described dispersant is modified polyorganosiloxane.
7. tetrafluoro carbon aluminum veneer according to claim 1, the granularity that it is characterized in that described tetrafluoro Fluoropolymer Powder Coatings is the 5-25 micron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210104677 CN102627005B (en) | 2012-04-11 | 2012-04-11 | Carbon tetrafluoride aluminum single board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210104677 CN102627005B (en) | 2012-04-11 | 2012-04-11 | Carbon tetrafluoride aluminum single board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102627005A CN102627005A (en) | 2012-08-08 |
| CN102627005B true CN102627005B (en) | 2013-05-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201210104677 Active CN102627005B (en) | 2012-04-11 | 2012-04-11 | Carbon tetrafluoride aluminum single board |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107245273A (en) * | 2017-07-06 | 2017-10-13 | 上海博丽铝幕墙材料制造有限公司 | A kind of fluorine carbon dust powder formulation and preparation method and spraying coating process based on aluminum veneer |
| CN109054259B (en) * | 2018-07-04 | 2021-01-19 | 安徽省浦菲尔建材有限公司 | Ceramic aluminum veneer processing technology |
| CN111171612B (en) * | 2020-03-02 | 2022-03-08 | 江苏成功材料科技有限公司 | Environment-friendly fluorocarbon aluminum veneer and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101397435A (en) * | 2008-07-10 | 2009-04-01 | 上海三银制漆有限公司 | Environment friendly water-soluble metal fluorocarbon coatings |
| CN101955712B (en) * | 2009-09-01 | 2012-11-07 | 老虎粉末涂料制造（太仓）有限公司 | Oil-repellent thermosetting powder coating and preparation method and application thereof |
| CN201902818U (en) * | 2010-10-09 | 2011-07-20 | 江阴标榜装饰材料有限公司 | Fluorine-carbon aluminum single plate |
| CN202099962U (en) * | 2011-06-09 | 2012-01-04 | 佛山市中茂金属建材有限公司 | Aluminum plate with self-cleaning function |
| CN202163061U (en) * | 2011-07-30 | 2012-03-14 | 常州安达幕墙有限公司 | Fluorine-carbon aluminum single plate |
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- 2012-04-11 CN CN 201210104677 patent/CN102627005B/en active Active
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| CN102627005A (en) | 2012-08-08 |
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| C06 | Publication | ||
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| C10 | Entry into substantive examination | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Tetrafluorocarbon aluminum veneer Effective date of registration: 20231225 Granted publication date: 20130508 Pledgee: Shandong Dong'a Rural Commercial Bank Co.,Ltd. Pledgor: DONG E BLUE SKY AND SEVEN COLOR BUILDING MATERIAL CO.,LTD. Registration number: Y2023980074331 |
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