CN104449278A - Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof - Google Patents
Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof Download PDFInfo
- Publication number
- CN104449278A CN104449278A CN201410568535.9A CN201410568535A CN104449278A CN 104449278 A CN104449278 A CN 104449278A CN 201410568535 A CN201410568535 A CN 201410568535A CN 104449278 A CN104449278 A CN 104449278A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- acid
- add
- glass door
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/918—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an acid and alkali corrosion resistant glass door water-based paint with good smoothness. The paint is characterized by being prepared from the following raw materials in parts by weight: 42-46 parts of modified water-based vegetable oil alkyd resin, 12-14 parts of a water-based polyurethane resin emulsion, 14-17 parts of epoxy resin, 0.4-0.8 part of isocyanate, 1-2 parts of titanium pigment, 0.6-1.2 parts of talc powder, 0.7-1.4 parts of zinc borate, 2-3 parts of propanediol butyl ether, 0.2-0.5 part of a polyether defoamer, 0.4-0.7 part of stearyl amino propyl dimethyl tertiary amine, 1-2 parts of alkylolamide, 0.3-0.6 part of phenethyl naphthol polyoxyethylene ether, 0.2-0.4 part of a fluorocarbon polymer leveling agent, 0.3-0.6 part of gamma-(2,3-epoxypropoxy)propyl trimethoxy silane, 1-2 parts of a bamboo leaf extract, 1-2 parts of a garlic extract, 1-2 parts of a pigment and 12-16 parts of deionized water. The acid and alkali corrosion resistant glass door water-based paint disclosed by the invention, after solidification, has good film-coating smoothness, high hardness, good flexibility, good adhesive force, and functions in the aspects of acid resistance, alkali resistance, static electricity resistance and the like. By virtue of home-made modified water-based vegetable oil alkyd resin, the properties of water resistance, yellowing resistance, antifouling property, luster and color preservation and the like of the paint are further improved.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, glass door use coating that particularly a kind of acid-alkali-corrosive-resisting smoothness is good and preparation method thereof.
Background technology
Since 20 century 70s, each industrially developed country is devoted to develop pollution-free, less energy-consumption type coating, thus provides wide market for the Application and Development of water-borne coatings.Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings, using water as dispersion medium, only adopts a small amount of hypotoxicity alcohol ether organic solvent, safety and environmental protection, economizes on resources, and eliminates the danger of presence of fire during construction, is conducive to reducing topsoil.Water-borne coatings is very good to material surface adaptability, and can construct equally at wet environment, coating adhesion is strong.Glass and glasswork, because of attractive in appearance and needs that are performance, need apply coating thereon, glass paint is developed by solvent-borne type hydrotropisms, be the inexorable trend adapting to environment protection requirement development, replace traditional solvent-borne coating gradually at present, main flow field, occuping market.
The most important coating resin of Synolac, its consumption accounts for the first place of coatings industry resin always, it is good that phthalic resin coating has paint film adhesion, the feature such as bright, plentiful, and there is good application property, but film is softer, water-fast, alkali resistance is not good enough, for the performance improving it can improve its performance with different vegetables oil, the present invention adopts semi-drying oil refined soybean oil and siccative oil tung oil to mix common modified alkyd resin, effectively can improve the water tolerance of resin, protect the features such as look gloss retention.Along with the reinforcement of people's environmental consciousness, and organic solvent expense is surging, water soluble paint is more and more paid attention to, in order to adapt to day by day fierce market competition, modified water-soluble vegetables oil Synolac prepared by the present invention, meets the developing direction of modern coatings Industrial Green, environmental protection.
Summary of the invention
The object of this invention is to provide good glass door use coating of a kind of acid-alkali-corrosive-resisting smoothness and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The glass door use coating that a kind of acid-alkali-corrosive-resisting smoothness is good, be made up of the raw material of following weight part: modified water-soluble vegetables oil Synolac 42-46, aqueous polyurethane resin emulsion 12-14, epoxy resin 14-17, isocyanic ester 0.4-0.8, titanium dioxide 1-2, talcum powder 0.6-1.2, zinc borate 0.7-1.4, propandiol butyl ether 2-3, polyether antifoam agent 0.2-0.5, stearamidopropyl tertiary amine 0.4-0.7, alkylol amide 1-2, styroyl naphthols Soxylat A 25-7 0.3-0.6, fluorocarbon polymer flow agent 0.2-0.4, γ-(2, 3-epoxy third oxygen) propyl trimethoxy silicane 0.3-0.6, Folium Bambosae extract 1-2, Bulbus Allii extract 1-2, pigment 1-2, deionized water 12-16,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part: refined soybean oil 6-8, nano-calcium carbonate 1-2, nm-class rutile-type TiO 2 3-5, nano diatomite 3-5, distearyl acyl-oxygen aluminum isopropoxide acid esters 1-2, tung oil 8-12, dehydrated alcohol 8-12, dimethylethanolamine 7-9, tetramethylolmethane 18-22, antioxidant 1010 0.3-0.6, lithium hydroxide 0.01-0.1,1,2-PD 18-21, maleic anhydride 10-14, propylene glycol monobutyl ether 4-6, distilled water 50-80; Nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use.By tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
The glass door use coating that a kind of acid-alkali-corrosive-resisting smoothness of the present invention is good, be made up of following concrete steps:
(1) deionized water, polyether antifoam agent, styroyl naphthols Soxylat A 25-7, fluorocarbon polymer flow agent, Bulbus Allii extract, Folium Bambosae extract mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propandiol butyl ether, stearamidopropyl tertiary amine, alkylol amide stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, aqueous polyurethane resin emulsion, epoxy resin, isocyanic ester stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, pigment, zinc borate, titanium dioxide, talcum powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: after paint solidification of the present invention, film smoothness is good, hardness is high, snappiness is good, sticking power is good, also there is the function of the aspect such as acidproof, alkaline-resisting, antistatic, the present invention, also by homemade modified water-soluble vegetables oil Synolac, further increases the water resisting property of coating, yellowing resistance, didirtresistance and guarantor's light and protects the performances such as look.
specific embodiments
Below by specific examples, the present invention is described in detail.
The glass door use coating that a kind of acid-alkali-corrosive-resisting smoothness is good, be made up of the raw material of following weight part (kilogram): modified water-soluble vegetables oil Synolac 44, aqueous polyurethane resin emulsion 13, epoxy resin 16, isocyanic ester 0.6, titanium dioxide 1, talcum powder 0.9, zinc borate 1.2, propandiol butyl ether 3, polyether antifoam agent 0.4, stearamidopropyl tertiary amine 0.5, alkylol amide 2, styroyl naphthols Soxylat A 25-7 0.3, fluorocarbon polymer flow agent 0.3, γ-(2, 3-epoxy third oxygen) propyl trimethoxy silicane 0.5, Folium Bambosae extract 1, Bulbus Allii extract 1, pigment 2, deionized water 15,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part (kilogram): refined soybean oil 7, nano-calcium carbonate 2, nm-class rutile-type TiO 24, nano diatomite 3, distearyl acyl-oxygen aluminum isopropoxide acid esters 1, tung oil 11, dehydrated alcohol 12, dimethylethanolamine 8, tetramethylolmethane 20, antioxidant 1010 0.3, lithium hydroxide 0.07,1,2-PD 20, maleic anhydride 13, propylene glycol monobutyl ether 5, distilled water 70; Nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use.By tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
The glass door use coating that a kind of acid-alkali-corrosive-resisting smoothness of the present invention is good, be made up of following concrete steps:
(1) deionized water, polyether antifoam agent, styroyl naphthols Soxylat A 25-7, fluorocarbon polymer flow agent, Bulbus Allii extract, Folium Bambosae extract mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propandiol butyl ether, stearamidopropyl tertiary amine, alkylol amide stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, aqueous polyurethane resin emulsion, epoxy resin, isocyanic ester stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, pigment, zinc borate, titanium dioxide, talcum powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
After paint solidification of the present invention, hardness of paint film is 3H, and sticking power experiment is 1 grade, wear resistance experiment (0.5g/r)/mg:5.2, shock resistance is tested: 50cm, water tolerance experiment (800h): without exception, resistance to boiling water experiment (12h): unchanged, solvent resistant experiment (20h): unchanged, alcohol resistance experiment (dehydrated alcohol 32h): unchanged, artificial ageing resistance is tested: 1000h is non-foaming, does not peel off, flawless, chalk rating 0 grade, variable color grade 1 grade.
Claims (2)
1. the glass door use coating that an acid-alkali-corrosive-resisting smoothness is good, it is characterized in that, be made up of the raw material of following weight part: modified water-soluble vegetables oil Synolac 42-46, aqueous polyurethane resin emulsion 12-14, epoxy resin 14-17, isocyanic ester 0.4-0.8, titanium dioxide 1-2, talcum powder 0.6-1.2, zinc borate 0.7-1.4, propandiol butyl ether 2-3, polyether antifoam agent 0.2-0.5, stearamidopropyl tertiary amine 0.4-0.7, alkylol amide 1-2, styroyl naphthols Soxylat A 25-7 0.3-0.6, fluorocarbon polymer flow agent 0.2-0.4, γ-(2, 3-epoxy third oxygen) propyl trimethoxy silicane 0.3-0.6, Folium Bambosae extract 1-2, Bulbus Allii extract 1-2, pigment 1-2, deionized water 12-16,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part: refined soybean oil 6-8, nano-calcium carbonate 1-2, nm-class rutile-type TiO 2 3-5, nano diatomite 3-5, distearyl acyl-oxygen aluminum isopropoxide acid esters 1-2, tung oil 8-12, dehydrated alcohol 8-12, dimethylethanolamine 7-9, tetramethylolmethane 18-22, antioxidant 1010 0.3-0.6, lithium hydroxide 0.01-0.1,1,2-PD 18-21, maleic anhydride 10-14, propylene glycol monobutyl ether 4-6, distilled water 50-80, nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use, by tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
2. the glass door use coating that a kind of acid-alkali-corrosive-resisting smoothness is good according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, polyether antifoam agent, styroyl naphthols Soxylat A 25-7, fluorocarbon polymer flow agent, Bulbus Allii extract, Folium Bambosae extract mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propandiol butyl ether, stearamidopropyl tertiary amine, alkylol amide stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, aqueous polyurethane resin emulsion, epoxy resin, isocyanic ester stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane, pigment, zinc borate, titanium dioxide, talcum powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568535.9A CN104449278A (en) | 2014-10-23 | 2014-10-23 | Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568535.9A CN104449278A (en) | 2014-10-23 | 2014-10-23 | Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104449278A true CN104449278A (en) | 2015-03-25 |
Family
ID=52896057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410568535.9A Pending CN104449278A (en) | 2014-10-23 | 2014-10-23 | Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104449278A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273465A (en) * | 2015-10-09 | 2016-01-27 | 浙江新迪在龙涂料科技有限公司 | Environment-friendly glass paint and preparation method thereof |
| CN107337944A (en) * | 2017-08-01 | 2017-11-10 | 惠安县科联农业科技有限公司 | A kind of building coating with Air purification and preparation method thereof |
| CN107573838A (en) * | 2017-09-12 | 2018-01-12 | 天途路业集团有限公司 | A kind of normal temperature waterborne road line paint |
| CN110218481A (en) * | 2019-06-04 | 2019-09-10 | 浙江天地化工有限公司 | Aqueous oil of a kind of PVC film printing and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
-
2014
- 2014-10-23 CN CN201410568535.9A patent/CN104449278A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
Non-Patent Citations (2)
| Title |
|---|
| 朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版社 成都 * |
| 陈治良: "《现代涂装手册》", 31 January 2010, 化学工业出版社 北京 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273465A (en) * | 2015-10-09 | 2016-01-27 | 浙江新迪在龙涂料科技有限公司 | Environment-friendly glass paint and preparation method thereof |
| CN107337944A (en) * | 2017-08-01 | 2017-11-10 | 惠安县科联农业科技有限公司 | A kind of building coating with Air purification and preparation method thereof |
| CN107573838A (en) * | 2017-09-12 | 2018-01-12 | 天途路业集团有限公司 | A kind of normal temperature waterborne road line paint |
| CN110218481A (en) * | 2019-06-04 | 2019-09-10 | 浙江天地化工有限公司 | Aqueous oil of a kind of PVC film printing and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104449273A (en) | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint | |
| CN103319971B (en) | A kind of metallic travel aqueous fluorocarbon coating and preparation method thereof for exterior wall | |
| CN101747818B (en) | Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof | |
| CN107163812B (en) | A kind of extra-weather-proof corrosion-resistant engineering machinery finishing coat of low VOC and preparation method | |
| CN110894394A (en) | Water-based polyester amino baking varnish coating and preparation method and application thereof | |
| CN104356798A (en) | Intumescent flame-retardant coating for glass door and preparing method of coating | |
| CN104449282A (en) | Antibacterial and antifouling waterborne coating for glass doors and preparation method thereof | |
| CN107057536B (en) | A kind of body of a motor car special coating and its preparation method and application | |
| CN104449278A (en) | Acid and alkali corrosion resistant glass door water-based paint with good smoothness and preparation method thereof | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN104327568A (en) | Bacteriostasis, sterilization and air purification type aqueous coating for glass doors, and its preparation method | |
| CN103342950A (en) | Alkyd ship hull paint and preparation method thereof | |
| CN102746768A (en) | Water-borne colorful glass paint and preparation method and application thereof | |
| CN106318143A (en) | Wooden transfer power paint for aluminium profile | |
| CN112592654A (en) | Water-based high-temperature-resistant, anticorrosive and weather-resistant colorful orange-peel paint and preparation method thereof | |
| CN105505093A (en) | Environment-friendly glass baking paint and preparation method thereof | |
| CN109082184A (en) | A kind of elastic emulsion paint of high adhesion force | |
| CN100366686C (en) | Silicon fluoride super-amphiphobic non-stick coating material | |
| CN109354955A (en) | A kind of scratch-resistant paint of timber Environment-friendlywear-resistant wear-resistant | |
| CN103952067A (en) | Production process of oil alkyd baking varnish | |
| CN104327631A (en) | Improved-hardness heat-radiation aqueous coating for glass doors, and its preparation method | |
| CN102391753A (en) | Water emulsion polymer camouflage color decorative coating and preparation method and use thereof | |
| CN111349391A (en) | High-temperature-resistant coating and preparation method thereof | |
| CN104449274A (en) | Water paint with high hardness and excellent endurance property for glass door and preparation method thereof | |
| CN104449275A (en) | Rustproof and scratching-resistant waterborne coating for glass door and preparation method of waterborne coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |