CN100366686C - Silicon fluoride super-amphiphobic non-stick coating material - Google Patents
Silicon fluoride super-amphiphobic non-stick coating material Download PDFInfo
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- CN100366686C CN100366686C CNB2006100421487A CN200610042148A CN100366686C CN 100366686 C CN100366686 C CN 100366686C CN B2006100421487 A CNB2006100421487 A CN B2006100421487A CN 200610042148 A CN200610042148 A CN 200610042148A CN 100366686 C CN100366686 C CN 100366686C
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- Prior art keywords
- amphiphobic
- coating material
- resin
- stick coating
- fluorine
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- 239000000463 material Substances 0.000 title claims abstract description 22
- 239000011248 coating agent Substances 0.000 title claims description 27
- 238000000576 coating method Methods 0.000 title claims description 27
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 title claims description 16
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 13
- 239000011737 fluorine Substances 0.000 claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 7
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 5
- 229920002050 silicone resin Polymers 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 14
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 claims description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 229960002703 undecylenic acid Drugs 0.000 claims description 6
- 239000003595 mist Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000011863 silicon-based powder Substances 0.000 claims description 5
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 3
- -1 ether ester Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 14
- 238000001035 drying Methods 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002210 silicon-based material Substances 0.000 abstract description 3
- 238000011049 filling Methods 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract 4
- 239000010703 silicon Substances 0.000 abstract 4
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 8
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 8
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 8
- 238000006253 efflorescence Methods 0.000 description 5
- 206010037844 rash Diseases 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007605 air drying Methods 0.000 description 3
- 229940043232 butyl acetate Drugs 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001814 protein method Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to a non-sticking paint containing fluorine-silicon material, which is composed of a paint part and a solidifying agent part. The dosage of the solidifying agent is from 6.5% to 12% of the weight of the paint part. The paint part mainly comprises fluorocarbon resin, 10% to 20% organic silicon resin, 3% to 30% of color filling material, 1% to 5% of silicon miropowder, 3% to 10% of fluorine miropowder, etc. The solidifying agent is at least one of biuret, HDI trimer and organic tin. The fluorocarbon resin is formed by the copolymerization of tetrafluoroethylene monomers, alkyl vinyl ester and functional monomers, wherein the fluorine content is not lower than wt 35%, and the solidifying content is not lower than 50%. The organic silicon resin is end-hydroxyl organic silicon resin. The non-sticking paint of the present invention has the advantages of good non-sticking performance, normal temperature drying, aging resistance and easy construction.
Description
(1) technical field under
The present invention relates to a kind of non-adhesive coating, particularly a kind of non-viscous paint of fluorine silicon material.
(2) background technology
The existing non-viscous paint in market can roughly be divided into two classes: a class is cooker and household electrical appliances non-viscous paint, and another kind of is anti-graffiti class non-viscous paint.Last class is representative with Du Pont's " teflon ", owing to be subjected to the influence of carcinogenic substance Perfluorocaprylic Acid amine, its safety performance is just being endured common people's suspection to the fullest extent, and the second class coating owing to be subjected to the influence of various factors, also has the following disadvantages:
1, viscosity not there is no special salient point;
2, the product that has can not Air drying, and its construction is affected by environment big;
3, range of product is single, and decorative effect is relatively poor;
4, product for a long time not viscosity can't guarantee.
(3) summary of the invention
The present invention is in order to overcome the deficiency of above technology, provide a kind of not viscosity can be good, Air drying, ageing-resistant, the silicon fluoride super-amphiphobic non-stick coating material that is easy to construct.
The present invention realizes by following measure:
Silicon fluoride super-amphiphobic non-stick coating material of the present invention is made up of base-material part and solidifying agent two portions, and hardener dose accounts for the 6.5-12% of coating part weight,
Described base-material partly is made up of following raw materials by weight percent:
Fluorocarbon resin 30～50%
Silicone resin 10～20%
Color stuffing 3～30%
Silicon powder 1～5%
Fluorine micro mist 3～10%
Auxiliary agent 0.01～3%
Organic solvent 5～30%;
Described solidifying agent is at least a of biuret, HDI tripolymer and organotin;
Described fluorocarbon resin is to be formed its fluorine content 〉=wt35%, solid content 〉=50% by tetrafluoroethylene monomer, alkyl vinyl ester and function monomer copolymerization; Described function monomer is one or both of vinyl carbinol and undecylenic acid;
Described silicone resin is the terminal hydroxy group silicone resin;
Described fluorine micro mist is a ptfe micropowder, particle diameter≤5um; Described silicon powder is an aerosil, particle diameter≤5um.
Non-viscous paint of the present invention, described alkyl vinyl ester is a vinyl acetate.
Silicon fluoride super-amphiphobic non-stick coating material of the present invention, described organic solvent are ester class, ketone or solvent of ether ester type.
Non-viscous paint of the present invention, with tetrafluoro resin and terminal hydroxy group silicone resin is matrix resin, the main low surface energy characteristic of using the fluorine silicon materials, thereby macro manifestations is for scolding water, scold the two thin performance of oil, cooperate particle diameter less than 5 microns fluorine micro mist, silicon powder, in order to strengthen the two thin performances and the lubricity of filming, certain pigment filler realizes multiple ornamental, functional agent and ketone, the needs in production and the construction process have been satisfied in the application of organic solvents such as ester class, cooperate biuret, the HDI tripolymer, solidifying agent such as organotin, in concrete construction application, both can in warm forced drying, also normal temperature solidified, enlarged the range of application of product.
Silicon fluoride super-amphiphobic non-stick coating material of the present invention can adopt the preparation method under recognizing: add part organic solvent, fluorocarbon resin, silicone resin, auxiliary agent in the jar of a constant volume, using dispersion machine simultaneously is uniformly dispersed with certain speed, according to different requirements, add color stuffing, requirement difference according to color stuffing, determine whether sand milling, really need sand milling, control sand mill discharging fineness.Then, remaining fluorocarbon resin, silicone resin, auxiliary agent and organic solvent add paint mixing tank in will filling a prescription, and obtain the coating part of described silicon fluoride super-amphiphobic non-stick coating material after stirring.In above-mentioned preparation technology's method, equipment is the normal temperature and pressure state.
The coating part of getting above-mentioned preparation mixes with an amount of solidifying agent, adds a certain amount of thinner and adjusts viscosity, can construct.
Silicon fluoride super-amphiphobic non-stick coating material of the present invention has following performance:
1, range of product is abundant, and real chromatic effect, metallic travel, pearl effect and transparent effect are arranged;
2, ultra-amphosphobic, after the dried coating film, not sticking to any water-based and oily matter, the small advertisement that shows as stickups such as glue, paste all can come off in 10-30 minute automatically, and the small advertisement that uses non-setting adhesive to paste is easy to peel off, and does not stay any stain;
But 3, product Air drying, also can in warm forced drying, construction can be adopted spraying, roller coat and brush multiple mode;
4, anti-outdoor aging, outdoor use can not produce efflorescence, variable color more than 20 years;
5, be applicable to multiple base materials such as cement, metal matrix, plastics, timber, pottery.
(4) embodiment
Embodiment 1: real look white paint
Add the 400g tetrafluoro resin in the stainless cylinder of steel of 1.5L, tetrafluoro resin is to be formed by tetrafluoroethylene monomer, vinyl acetate, vinyl carbinol and undecylenic acid copolymerization, and solvent is a N-BUTYL ACETATE, and its solid content is that wt55%, fluorine content are the tetrafluoro resin of wt38%; 100g silicone resin, silicone resin are that solid content 52%, molecular-weight average are 400,000 terminal hydroxy group silicone resin; And 5g dispersant B YK-163,230g rutile titanium white powder, 30g median size are that 5 microns aerosils, 100g median size are 5 microns ptfe micropowders, after high speed dispersion, through the sand mill sand milling to fineness≤15um discharging, add 2g flow agent BYK-300,30g butylacetate, 40g methyl iso-butyl ketone (MIBK), 63g propylene glycol methyl ether acetate, being uniformly dispersed obtains white silicon fluoride super-amphiphobic non-stick coating material.Get the 100g above-mentioned coating and the 8.5g biuret mixes, add thinner and adjust viscosity to 22 second (4# flow cup), spraying making sheet detects performance.
Embodiment 2: metal flash paint
Adding 300g in the stainless cylinder of steel of 1.5L is formed by tetrafluoroethylene monomer, vinyl acetate, vinyl carbinol and undecylenic acid copolymerization, solvent is MIBK and N-BUTYL ACETATE, the tetrafluoro resin of its solid content wt52%, fluorine content 36%, 200g solid content are 48%, molecular-weight average is that 650,000 terminal hydroxy group silicone resin, 10g median size are that 0.8 micron aerosil, 100g median size are 2 microns ptfe micropowders, even through high speed dispersion, get resin dispersion liquid.It is even through stirring at low speed to add 40um aluminum paste 80g, 1g dispersant B YK-163,2g flow agent BYK-306,100g butylacetate, 187g methyl iso-butyl ketone (MIBK) in another container, and adding above-mentioned resin dispersion liquid behind the immersion certain hour, the stirring at low speed homodisperse evenly obtains the flash metal luster silicon fluoride super-amphiphobic non-stick coating material.Get the 100g above-mentioned coating and the 6.5gHDI tripolymer mixes, add thinner and adjust viscosity to 22 second (4# flow cup), spraying making sheet detects performance.
Embodiment 3: pearlescent lacquer
Adding 500g in the stainless cylinder of steel of 1.5L is formed by tetrafluoroethylene monomer, vinyl acetate, vinyl carbinol and undecylenic acid copolymerization, solvent is PMA and MIBK, the tetrafluoro resin of its solid content wt50%, fluorine content wt35%, the 200g solid content is 50%, molecular-weight average is that 520,000 terminal hydroxy group silicone resin, 10g median size are that 5 microns aerosils, 80g median size are 2 microns ptfe micropowders, even through high speed dispersion, get resin dispersion liquid.It is even through stirring at low speed to add 15um pearlescence 60g, 1g dispersant B YK-163,2g flow agent BYK-306,120g butylacetate, 17g propylene glycol methyl ether acetate in another container, and adding above-mentioned resin dispersion liquid behind the immersion certain hour, the stirring at low speed homodisperse evenly obtains the pearly-lustre silicon fluoride super-amphiphobic non-stick coating material.Get 100g above-mentioned coating and 0.4g organotin and 8.6g biuret and mix, add thinner and adjust viscosity to 22 second (4# flow cup), spraying making sheet detects performance.
Embodiment 4: transparent varnish
In the stainless cylinder of steel of 1.5L, add 500g by tetrafluoroethylene monomer, vinyl acetate, vinyl carbinol and undecylenic acid copolymerization form, solvent is a N-BUTYL ACETATE, its solid content is wt55%, fluorine content is the tetrafluoro resin of wt38%, the 200g solid content is 48%, molecular-weight average is 620,000 terminal hydroxy group silicone resin, the 30g median size is 2 microns a aerosil, the 100g median size is 0.2 micron ptfe micropowder, 2g dispersant B YK-163,2g flow agent BYK-300, the 130g methyl iso-butyl ketone (MIBK), the 56g propylene glycol methyl ether acetate evenly obtains transparent silicon fluoride super-amphiphobic non-stick coating material through high speed dispersion.Get the 100g above-mentioned coating and the 11gHDI tripolymer mixes, add thinner and adjust viscosity to 22 second (4# flow cup), spraying making sheet detects performance.
Silicon fluoride super-amphiphobic non-stick coating material to the foregoing description has carried out performance test, and data are as follows:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Condition in container | Stirring is uniform state | Stirring is uniform state | Stirring is uniform state | Stirring is uniform state |
| Dry | Surface drying 20min does solid work 24h or 80 ℃ of X30min | Surface drying 20min does solid work 24h or 80 ℃ of X30min | Surface drying 20min does solid work 24h or 80 ℃ of X30min | Surface drying 20min does solid work 24h or 80 ℃ of X30min |
| Hardness | ?≥H | ?≥H | ?≥H | ?≥H |
| Sticking power | 1 grade | 1 grade | 1 grade | 1 grade |
| Freeze-thawing resistant circulation (20 times) | The no change of filming | The no change of filming | The no change of filming | The no change of filming |
| Alkali resistance 10% NaOH, 14d | It is no abnormal to film | It is no abnormal to film | It is no abnormal to film | It is no abnormal to film |
| Contamination resistance 10 times, reflectivity descends | ?0.6 | ?0.4 | ?0.4 | |
| Resistance to bond (protein method) | 0 grade | 0 grade | 0 grade | 0 grade |
| Weathering resistance, artificial accelerated aging 5000h | Variable color≤2 grade, efflorescence≤1 grade does not have be full of cracks | Variable color≤2 grade, efflorescence≤1 grade does not have be full of cracks | Variable color≤2 grade, efflorescence≤1 grade does not have be full of cracks | Variable color≤2 grade, efflorescence≤1 grade does not have be full of cracks |
Claims (3)
1. silicon fluoride super-amphiphobic non-stick coating material is characterized in that: be made up of base-material part and solidifying agent two portions, hardener dose accounts for the 6.5-12% of coating part weight,
Described base-material partly is made up of following raw materials by weight percent:
Fluorocarbon resin 30～50%
Silicone resin 10～20%
Color stuffing 3～30%
Silicon powder 1～5%
Fluorine micro mist 3～10%
Auxiliary agent 0.01～3%
Organic solvent 5～30%;
Described solidifying agent is at least a of biuret, HDI tripolymer and organotin;
Described fluorocarbon resin is to be formed its fluorine content 〉=wt35%, solid content 〉=50% by tetrafluoroethylene monomer, alkyl vinyl ester and function monomer copolymerization; Described function monomer is one or both of vinyl carbinol and undecylenic acid;
Described silicone resin is the terminal hydroxy group silicone resin;
Described fluorine micro mist is a ptfe micropowder, particle diameter≤5um; Described silicon powder is an aerosil, particle diameter≤5um.
2. silicon fluoride super-amphiphobic non-stick coating material according to claim 1 is characterized in that: described alkyl vinyl ester is a vinyl acetate.
3. silicon fluoride super-amphiphobic non-stick coating material according to claim 1 is characterized in that: described organic solvent is ester class, ketone or solvent of ether ester type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100421487A CN100366686C (en) | 2006-01-12 | 2006-01-12 | Silicon fluoride super-amphiphobic non-stick coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100421487A CN100366686C (en) | 2006-01-12 | 2006-01-12 | Silicon fluoride super-amphiphobic non-stick coating material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1807526A CN1807526A (en) | 2006-07-26 |
| CN100366686C true CN100366686C (en) | 2008-02-06 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100421487A Active CN100366686C (en) | 2006-01-12 | 2006-01-12 | Silicon fluoride super-amphiphobic non-stick coating material |
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| CN (1) | CN100366686C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627967A (en) * | 2018-10-29 | 2019-04-16 | 裴泽民 | A kind of dirt resistance coatings for building |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100551980C (en) * | 2007-09-18 | 2009-10-21 | 深圳市明远氟涂料有限公司 | A kind of normal temperature solidifying fluorine-carbon coating for rubber roller |
| CN102277047B (en) * | 2011-07-25 | 2013-04-17 | 苏州金近幕墙有限公司 | Finish for building curtain wall aluminum veneer, and preparation method thereof |
| CN103045029B (en) * | 2012-12-26 | 2015-06-10 | 安徽科瑞克保温材料有限公司 | Corrosion-resistant fluorocarbon resin coating |
| CN103555173B (en) * | 2013-10-22 | 2015-05-13 | 东南大学 | Normal temperature curing solvent type two-component erasable coating and preparation method thereof |
| CN104893562A (en) * | 2015-05-25 | 2015-09-09 | 巨化集团技术中心 | Non-adhesive coating material for rubber product forming mold and preparation method thereof |
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|---|---|---|---|---|
| CN1016785B (en) * | 1987-07-09 | 1992-05-27 | 美国辉瑞有限公司 | Azithromycin dihydrate |
| CN1125920A (en) * | 1993-06-24 | 1996-07-03 | 大金工业株式会社 | Abherent composition |
| CN1343144A (en) * | 1999-03-16 | 2002-04-03 | Seb公司 | Antiadhesive coating with improved scratch resistance |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
-
2006
- 2006-01-12 CN CNB2006100421487A patent/CN100366686C/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1016785B (en) * | 1987-07-09 | 1992-05-27 | 美国辉瑞有限公司 | Azithromycin dihydrate |
| CN1125920A (en) * | 1993-06-24 | 1996-07-03 | 大金工业株式会社 | Abherent composition |
| CN1343144A (en) * | 1999-03-16 | 2002-04-03 | Seb公司 | Antiadhesive coating with improved scratch resistance |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627967A (en) * | 2018-10-29 | 2019-04-16 | 裴泽民 | A kind of dirt resistance coatings for building |
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| Publication number | Publication date |
|---|---|
| CN1807526A (en) | 2006-07-26 |
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