CN105038489B - A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can - Google Patents
A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can Download PDFInfo
- Publication number
- CN105038489B CN105038489B CN201510552466.7A CN201510552466A CN105038489B CN 105038489 B CN105038489 B CN 105038489B CN 201510552466 A CN201510552466 A CN 201510552466A CN 105038489 B CN105038489 B CN 105038489B
- Authority
- CN
- China
- Prior art keywords
- parts
- acrylic resin
- product packaging
- environment
- saving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can, the coating uses polyurethane modified acrylic resin, so that the coating has excellent fire-retardant and anti-wear performance, and curing rate is fast, also there is preferable mechanical property, ageing-resistant performance and resistance to chemical corrosion, adhesive force is strong, ductility is good, high temperature resistant, long service life, change processing technology, concentrated on product packaging can slab and complete roller coat processing, simplify machining clearance, without being separately provided painting workshop.
Description
Technical field
The present invention relates to a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can.
Background technology
Acrylic resin is the resin being made up of acrylate and methacrylate and other olefinic type monomers copolymerization, with
Other synthetic macromolecule resins are compared, and acrylic resin has the advantages that many protrusions, such as excellent fast light, weatherability, outdoor
Durability of being exposed to the sun is strong, and ultraviolet resistance irradiation is not easily decomposed and turned yellow, and original gloss and color and luster can be kept for a long time, heat-resist,
There are the chemicals such as preferable acid and alkali resistance, salt, grease and detergent to stain and corrosive nature, fabulous pliability and minimum pigment
Reactivity.Therefore, automobile, household electrical appliances, metal furniture, coiled material industry, instrument and meter, building, textile, woodwork, papermaking and
Plastic products etc. industrially have a wide range of applications.
However, the shortcomings of heat sticks cold short, anti-after-tackiness and not good heat resistance caused by the linear structure of acrylic resin pair
Its application has certain limitations.The equal phase structure of acrylic resin make it that its cold tolerance and heat resistance is difficult to take into account,
Such as to increase resistance to low temperature, then can lose resistance to elevated temperatures, vice versa, thus common acrylic compounds coating material is just not
There is disadvantages mentioned above with can avoiding.
Overcome the shortcoming of acrylic resin " hot sticky cold crisp ", widen its weather resistance, optimal method is to change material
Aggregated structure, the glass transition temperature and flow temperature of material is no longer interrelated.Wherein use polyurethane-modified propylene
Acid resin is a kind of method preferably, be also study both at home and abroad more at present, more deep method.
Polyurethane is high by the block constituted made from stepwise polymerization reaction, by polyester soft segment and carbamate hard section
Molecular material, its unique aggregated structure imparts the excellent weather resistance of polyurethane.The two phase structure of polyurethane carries for it
Splendid weather resistance is supplied.It is that, by corresponding modification technology, will gather using the purpose of polyurethane modified acrylic resin
Urethane strand is introduced into acrylic resin, and it is in two-phase or multiphase structure to make modified material, so that the vitrifying of material
Temperature and flow temperature are determined by different phase regions, to widen the weather resistance of material.
At present, there is following polyurethane modified acrylic resin coating in the country：
Chinese patent CN201010269992.X, discloses a kind of acrylic resin-polyurethane resin heat preservation coating, and it leads
If being made up of following raw materials according according to weight proportion stirring：60 parts of acrylic resins, 30 parts of closed perlites, 25 parts of aphthenic acids
Cobalt, 10 parts of methylcellulose, 75 parts of polyurethane resins, 12 parts of powdered whitings, 10 parts of diatomite, 6 parts of mortar kings, 10 portions of bananas
Water, 65 parts of water, 2 parts of defoamers, 8 parts of thickeners, 6 parts of coalescents.However, it only enumerates acrylic resin and polyurethane
Resin, but the two does not organically combine to form polyurethane modified acrylic resin, still can not realize polyurethane-modified acrylic acid
The performance of resin.
In addition, the application mode of existing acrylic resin paint uses spray-coating, such as Chinese patent mostly
CN201310607469.7, discloses a kind of thermosetting acrylic resin used for powder coating, and the resin ester is equipped with unclassified stores system
Into thermosetting powder coating, the film formed after spraying, with excellent weatherability, good flow leveling, excellent
Case hardness and high-luster, durability and decoration performance；Available for indoor or outdoors shape or construction material.Can be
TGIC is substituted to a certain extent, it is to avoid the use of toxic substance.
However, wherein, spraying be by spray gun or dish-style atomizer, by means of pressure or centrifugal force, be dispersed into it is uniform and
Fine droplet, is applied over the coating process on coated article surface.Subject matter in spraying is coating cloud and the volatilization of high degree of dispersion
Solvent (i.e. volatile organic contaminant, VOCs) out, both pollutes environment, is unfavorable for health, and coating is wasted again, is caused
Economic loss.The coating for volatilizing, being diffused into air, then form volatile organic contaminant, is detrimental to health.In spraying car
Between, coating is as the main source of volatile organic contaminant, VOC concentration mistake in air in painting workshop
It is easy to cause acute poisoning when high, headache, dizziness, cough, Nausea and vomiting or in dead drunk liquor-saturated shape occurs in the lighter；Severe one can go out
Existing hepatotoxicity is even gone into a coma quickly, and what is had there may also be life danger.The long-term spraying for staying in VOC pollution
In workshop, slow poisoning can be caused, liver and nervous system is damaged, cause general weakness, drowsiness, pruitus etc..What is had goes back
Endocrinopathy, influence sexual function may be caused；Benzene and dimethylbenzene can also damage system, so that trigger leukaemia.
The content of the invention
It is an object of the invention to provide a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can, institute
State coating and use polyurethane modified acrylic resin so that the coating has excellent fire-retardant and anti-wear performance, and solidification
Speed is fast, and also with preferable mechanical property, ageing-resistant performance and resistance to chemical corrosion, adhesive force is strong, ductility is good, resistance to height
Temperature, long service life, change processing technology, are concentrated on product packaging can slab and complete roller coat processing, simplify processing hand
It is continuous, without being separately provided painting workshop.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：
Each composition quality point in a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can, the coating
Number is as follows：Polyurethane modified acrylic resin：70~80 parts, hydroxypropyl cellulose：3~5 parts, amino resins：5~10 parts, two
Aminocyclohexane：10~15 parts, diaminodiphenyl-methane：3~8 parts, sodium silicate water glass：5~15 parts, cetyl front three
Base ammonium bromide：1~5 part, alumina silicate：10~20 parts, kaolin：15~20 parts, dimethyl silicone polymer：2~6 parts, polyethers disappears
Infusion：2~5 parts, micaceous iron oxide gray：5~8 parts, sodium carboxymethylcellulose：4~8 parts, polyamide wax pulp：5~10 parts, second two
Alcohol butyl ether：30~40 parts, water：90~100 parts.
Further, each composition quality fraction is as follows in the coating：Polyurethane modified acrylic resin：70~73 parts, hydroxyl
Propyl cellulose：3~5 parts, amino resins：5~7 parts, diaminocyclohexane：10~13 parts, diaminodiphenyl-methane：3~4
Part, sodium silicate water glass：5~8 parts, cetyl trimethylammonium bromide：1~3 part, alumina silicate：10~13 parts, kaolin：15
~18 parts, dimethyl silicone polymer：2~5 parts, polyether antifoam agent：2~3 parts, micaceous iron oxide gray：5~7 parts, carboxymethyl cellulose
Plain sodium：4~5 parts, polyamide wax pulp：5~6 parts, butyl glycol ether：30~34 parts, water：90~94 parts.
Preferably, each composition quality fraction is as follows in the coating：Polyurethane modified acrylic resin：70 parts, hydroxypropyl
Cellulose：3 parts, amino resins：7 parts, diaminocyclohexane：13 parts, diaminodiphenyl-methane：4 parts, sodium silicate water glass：6
Part, cetyl trimethylammonium bromide：2 parts, alumina silicate：10 parts, kaolin：15 parts, dimethyl silicone polymer：3 parts, polyethers disappears
Infusion：2 parts, micaceous iron oxide gray：6 parts, sodium carboxymethylcellulose：5 parts, polyamide wax pulp：6 parts, butyl glycol ether：32 parts,
Water：90 parts.
Separately, the preparation of the polyurethane modified acrylic resin, comprises the following steps：
1) nucleus emulsion is prepared
The end OH based polyurethanes performed polymers of 30~40 mass point are taken, in the water for being added to 60~80 mass point, are stirred and evenly mixed,
Obtain nucleus emulsion；
2) shell emulsion is prepared
By the methyl methacrylate of 50~60 mass point, the EMA of 5~10 mass point, 5~10 mass
The styrene divided, the water that the emulsifying agent and 40~50 mass of 1~3 mass point divide is mixed, and is stirred, is emulsified, obtain shell emulsion；
3) polyurethane modified acrylic resin is prepared
Reaction bulb is taken, the water of 30~40 mass point, the initiator of 1~5 mass point, the breast of 1~3 mass point are added into bottle
Agent, the buffer of 0.5~2 mass point, is stirred and evenly mixed, and then adds the nucleus emulsion, and addition is warming up to after 70~80 DEG C,
40~60min is incubated, shell emulsion is then added dropwise into the reaction bulb, is at the uniform velocity added dropwise, completion of dropping in 1.5~2h, wherein,
When shell emulsion surplus is 1/5~1/3, add after reducing agent, shell emulsion completion of dropping, at 75~80 DEG C, insulation 1~
1.5h, is cooled to room temperature, filters to obtain the polyurethane modified acrylic resin.
Separately have, the step 2) and step 3) in emulsifying agent be selected from ethyoxyl phenolic ether ammonium sulfate, Nonyl pheno
One kind in ether, allyl ether hydroxypropyl azochlorosulfonate acid sodium.
Again, step 3) described in initiator be azodiisobutyronitrile, peroxidating two acyl, persulfate in one kind.
Further, step 3) described in the one kind of buffer in dibastic sodium phosphate, disodium hydrogen phosphate and sodium acid carbonate.
And, step 3) described in reducing agent be sodium sulfate salt or sodium hypophosphite.
Separately, the coating is coated to product packaging can steel slab surface, roller coat temperature 230~240 by roll coating model
DEG C, roller coat number of times is 1~2 time.
The beneficial effects of the present invention are：
The coating uses polyurethane modified acrylic resin, and with excellent fire-retardant and anti-wear performance, and solidification is fast
Degree is fast, and also with preferable mechanical property, ageing-resistant performance and resistance to chemical corrosion, adhesive force is strong, ductility is good, resistance to height
Temperature, long service life, change processing technology, are concentrated on product packaging can slab and complete roller coat processing, simplify processing hand
It is continuous, without being separately provided painting workshop.
The product packaging can slab stage can by roller coat by paint spraying provided by the present invention in product bag
Can steel slab surface is filled, coating is formed, can directly carry out following process, shaped article packaging can is obtained, even if structure is multiple
Miscellaneous product packaging can structure, also completes paint spraying in the slab stage, without follow-up application, instead of existing process
In " be first processed into required shape, then spray again and obtain shaped article " technique, coating and product packaging can slab are attached
Put forth effort strong, will not crack or come off because of processing technology.Because the roller coating technology for being roller coat shaping quick-drying replaces spraying work
Skill, the availability of coating can reach more than 90% during application, reduce the volatilization and waste in air, effectively reduce because spraying is led
Coating is caused to volatilize the VOCs to be formed, VOCs discharge capacitys≤420ppm in roller coat workshop, coating environment protecting is good.Roller coat is applied and installed
Into product packaging can product be processed, the curved performances of product packaging can T are up to 0T (the finished product slabs after roller coat
After 180 ° of bendings, completely seamless to close up, coating, which does not burst, to come off) or 1T (slab is outermost to apply twice after 180 ° of bendings
Charge level is not fallen off, and is not burst), it is ensured that product packaging can quality.
The polyurethane modified acrylic resin is prepared from by way of core-shell emulsion polymerization, obtains heterogeneous latex
Particle, can effectively lift anti-after tack when film formation at low temp performance, the high temperature of coating, and make it that coating has excellent storage steady
It is qualitative, it is coated in after steel slab surface formation film, higher hardness can be kept at high temperature, the anti-wear performance of coating obtains very big
Lifting.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
Table 1 be a kind of product packaging can described in the embodiment of the present invention with acrylic resin modified energy-saving and environment-friendly paint into
Divide mass fraction list.Table 2 is that polyurethane modified acrylic resin ingredient lists are prepared described in the embodiment of the present invention.Table 3 is this
A kind of product packaging can described in inventive embodiments is with acrylic resin modified energy-saving and environment-friendly paint performance parameter list.Table 4
Described in the embodiment of the present invention a kind of product packaging can with acrylic resin modified energy-saving and environment-friendly paint roller coat in product bag
Fill the coating performance parameter list after can steel slab surface.
The product packaging can is as follows with acrylic resin modified energy-saving and environment-friendly paint compound method：
By in each component addition high speed dispersor, after stirring, 30~60min is disperseed at a high speed, stir, discharge, filtering,
Packaging, storage.
The polyurethane modified acrylic resin process for preparation is as follows：
Reaction bulb is taken, the water of 30~40 mass point, the initiator of 1~5 mass point, the breast of 1~3 mass point are added into bottle
Agent, the buffer of 0.5~2 mass point, is stirred and evenly mixed, and then adds the nucleus emulsion, and addition is warming up to after 70~80 DEG C,
40~60min is incubated, shell emulsion is then added dropwise into the reaction bulb, is at the uniform velocity added dropwise, completion of dropping in 1.5~2h, wherein,
When shell emulsion surplus is 1/5~1/3, add after reducing agent, shell emulsion completion of dropping, at 75~80 DEG C, insulation 1~
1.5h, is cooled to room temperature, filters to obtain the polyurethane modified acrylic resin.
Wherein, the emulsifying agent is selected from ethyoxyl phenolic ether ammonium sulfate, NPE, allyl ether hydroxypropyl sulphur
One kind in sour sodium.The initiator is one kind in azodiisobutyronitrile, peroxidating two acyl, persulfate.The buffer
One kind in dibastic sodium phosphate, disodium hydrogen phosphate and sodium acid carbonate.The reducing agent is sodium sulfate salt or sodium hypophosphite.
(the unit of table 1：Part)
(the unit of table 2：Quality point)
Table 3
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Tensile strength (MPa) | 40 | 35 | 36 | 37 | 38 |
| Elongation at break (%) | 9.5 | 8.5 | 8.8 | 9.3 | 9.2 |
| Shore hardness | 70 | 65 | 60 | 68 | 62 |
A kind of product packaging can described in the embodiment of the present invention is passed through with acrylic resin modified energy-saving and environment-friendly paint
Roll coating model is coated in product packaging can steel slab surface, after solidifying at 200 DEG C, is cooled to room temperature, places 48 hours, surveys
Fixed board base face coat performance is as shown in table 4.Wherein, impact resistance method of testing is with reference to standard GB/T/T1732-93 rule
The method of fixed measure paint film impact resistance, is fallen within test plate (panel) without causing paint film to destroy with the weight of fixed mass (1kg)
Maximum height (cm) represent paint film impact resistance.
Table 4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Impact resistance (cm) | 120 | 110 | 118 | 116 | 114 |
| Salt spray resistance duration (h) | 3150 | 3100 | 2900 | 2950 | 3130 |
| Artificial accelerated aging duration (h) | 3200 | 3250 | 3280 | 3100 | 3190 |
| Heat resistance | 780 | 740 | 750 | 700 | 760 |
Using a kind of product packaging can provided by the present invention with acrylic resin modified energy-saving and environment-friendly paint application
Obtained product packaging can after product packaging can slab, the curved performances of T are up to 0T or 1T.Utilization efficiency of coatings is high, often
30 kilograms of coating can 1 ton of slab of application.Do not ftractureed under 230 DEG C of high temperature, nondiscolouring, ageing resistance is strong, and placement connects out of doors
Continuous sunshine not yellowing, nondiscolouring in 10~15 years.Acidproof corrosion resistance is strong, and the good product of roller coat is put into 85 DEG C of water and boils 2H lifes
It is progressively heated at 100 DEG C again, product is without changing colour, fall paint, foaming.Soaked at normal temperatures with 5% Nad solution after 24H, product table
Face non-corroding, discoloration and coating come off.Pure cotton cloth is dipped in full 95% alcohol bag on 500g counterweights, with per minute 40-60 times
The stroke of speed (20mm) left and right wipes 50 circulations in product surface, without de-oiling of fading.The inspection of X methods is drawn according in U.S. ASTM
The shaped article packaging can product for being coated with coating provided by the present invention is surveyed, the 0=ASTM grades of ISO grades are can reach,
Notching edge is completely smooth, the peeling that edge has not a particle of.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (8)
1. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can, it is characterised in that each in the coating
Composition mass fraction is as follows：
Polyurethane modified acrylic resin：70 ~ 80 parts, hydroxypropyl cellulose：3 ~ 5 parts, amino resins：5 ~ 10 parts, diamino basic ring
Hexane：10 ~ 15 parts, diaminodiphenyl-methane：3 ~ 8 parts, sodium silicate water glass：5 ~ 15 parts, cetyl trimethylammonium bromide：
1 ~ 5 part, alumina silicate：10 ~ 20 parts, kaolin：15 ~ 20 parts, dimethyl silicone polymer：2 ~ 6 parts, polyether antifoam agent：2 ~ 5 parts, cloud
Female iron oxide ash：5 ~ 8 parts, sodium carboxymethylcellulose：4 ~ 8 parts, polyamide wax pulp：5 ~ 10 parts, butyl glycol ether：30 ~ 40 parts,
Water：90 ~ 100 parts；
The preparation of the polyurethane modified acrylic resin, comprises the following steps：
1) nucleus emulsion is prepared
Take in the end OH based polyurethanes performed polymers of 30 ~ 40 mass parts, the water for being added to 60 ~ 80 mass parts, stir and evenly mix, obtain core breast
Change liquid；
2) shell emulsion is prepared
By the methyl methacrylate of 50 ~ 60 mass parts, the EMA of 5 ~ 10 mass parts, the benzene second of 5 ~ 10 mass parts
The water mixing of alkene, the emulsifying agent of 1 ~ 3 mass parts and 40 ~ 50 mass parts, is stirred, and emulsification obtains shell emulsion；
3) polyurethane modified acrylic resin is prepared
Reaction bulb is taken, the water of 30 ~ 40 mass parts of addition into bottle, the initiator of 1 ~ 5 mass parts, the emulsifying agent of 1 ~ 3 mass parts,
The buffer of 0.5 ~ 2 mass parts, is stirred and evenly mixed, and then adds the nucleus emulsion, and addition is warming up to after 70 ~ 80 DEG C, and insulation 40 ~
60min, shell emulsion is then added dropwise into the reaction bulb, is at the uniform velocity added dropwise, completion of dropping in 1.5 ~ 2h, wherein, in shell emulsification
When liquid surplus is 1/5 ~ 1/3, add after reducing agent, shell emulsion completion of dropping, at 75 ~ 80 DEG C, be incubated 1 ~ 1.5h, be cooled to
Room temperature, filters to obtain the polyurethane modified acrylic resin.
2. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, each composition mass fraction is as follows in the coating：Polyurethane modified acrylic resin：70 ~ 73 parts, hydroxy propyl cellulose
Element：3 ~ 5 parts, amino resins：5 ~ 7 parts, diaminocyclohexane：10 ~ 13 parts, diaminodiphenyl-methane：3 ~ 4 parts, sodium metasilicate water
Glass：5 ~ 8 parts, cetyl trimethylammonium bromide：1 ~ 3 part, alumina silicate：10 ~ 13 parts, kaolin：15 ~ 18 parts, poly dimethyl
Siloxanes：2 ~ 5 parts, polyether antifoam agent：2 ~ 3 parts, micaceous iron oxide gray：5 ~ 7 parts, sodium carboxymethylcellulose：4 ~ 5 parts, polyamide
Wax liquor：5 ~ 6 parts, butyl glycol ether：30 ~ 34 parts, water：90 ~ 94 parts.
3. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, each composition mass fraction is as follows in the coating：Polyurethane modified acrylic resin：70 parts, hydroxypropyl cellulose：3
Part, amino resins：7 parts, diaminocyclohexane：13 parts, diaminodiphenyl-methane：4 parts, sodium silicate water glass：6 parts, 16
Alkyl trimethyl ammonium bromide：2 parts, alumina silicate：10 parts, kaolin：15 parts, dimethyl silicone polymer：3 parts, polyether antifoam agent：2
Part, micaceous iron oxide gray：6 parts, sodium carboxymethylcellulose：5 parts, polyamide wax pulp：6 parts, butyl glycol ether：32 parts, water：90
Part.
4. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, the step 2) and step 3) in emulsifying agent be selected from ethyoxyl phenolic ether ammonium sulfate, NPE, allyl
One kind in base ether hydroxypropyl azochlorosulfonate acid sodium.
5. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, step 3) described in initiator be one kind in azodiisobutyronitrile, peroxidating two acyl, persulfate.
6. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, step 3) described in the one kind of buffer in dibastic sodium phosphate, disodium hydrogen phosphate and sodium acid carbonate.
7. a kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can according to claim 1, it is special
Levy and be, step 3) described in reducing agent be sodium sulfate salt or sodium hypophosphite.
8. a kind of acrylic resin modified energy-conserving and environment-protective of product packaging can according to any one of claim 1 ~ 7
Coating, it is characterised in that the coating is coated to product packaging can steel slab surface by roll coating model, roller coat temperature 230 ~
240 DEG C, roller coat number of times is 1 ~ 2 time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510552466.7A CN105038489B (en) | 2015-09-02 | 2015-09-02 | A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510552466.7A CN105038489B (en) | 2015-09-02 | 2015-09-02 | A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105038489A CN105038489A (en) | 2015-11-11 |
| CN105038489B true CN105038489B (en) | 2017-07-18 |
Family
ID=54445476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510552466.7A Active CN105038489B (en) | 2015-09-02 | 2015-09-02 | A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105038489B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505026A (en) * | 2016-02-19 | 2016-04-20 | 徐冉 | Water-based ultra-thin expansive type steel structure fire-retardant coating and preparation method thereof |
| CN108546475A (en) * | 2018-03-21 | 2018-09-18 | 合肥初慕科技有限公司 | Appliance plate is painted with energy conservation and environmental protection |
| TWI720415B (en) * | 2018-10-24 | 2021-03-01 | 財團法人中華民國紡織業拓展會 | Thermoplastic polyurethane composition without added diisocyanate |
| CN111087875B (en) * | 2019-12-30 | 2022-02-08 | 湖南金化科技集团有限公司 | Water-based fireproof coating for steel member and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60182017A (en) * | 1984-02-29 | 1985-09-17 | Ricoh Co Ltd | Magnetic recording medium |
| CN101407654A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | High peeling environment-friendly type aqueous transfer coating and use thereof |
| CN103555114B (en) * | 2013-10-25 | 2017-05-10 | 广州慧谷化学有限公司 | Coating composition for hydrophilic treatment of air-conditioning parallel flow heat exchanger |
| CN103866607B (en) * | 2014-03-25 | 2016-03-02 | 广州慧谷化学有限公司 | A kind of high-strength direct is aluminized aqueous basecoat and its preparation method and application |
-
2015
- 2015-09-02 CN CN201510552466.7A patent/CN105038489B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105038489A (en) | 2015-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105038489B (en) | A kind of acrylic resin modified energy-saving and environment-friendly paint of product packaging can | |
| CN101885943B (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN104140732B (en) | A kind of water paint of high salt fog high durable and preparation method thereof | |
| CN105038474A (en) | Modified acrylic resin energy conservation and environment protection coating for suspended ceiling print-coating plate | |
| CN104761934A (en) | Antimicrobial non-viscous aqueous inorganic nano coating finishing paint and application thereof | |
| CN101121841A (en) | Water exterior wall paint and its preparing process | |
| CN103881497A (en) | Method for preparing fingerprint resisting matte stainless steel decorative sheet | |
| CN109423149A (en) | A kind of fire-type Environmental Protective Water-paint and its manufacturing method | |
| CN106047013A (en) | Environment-friendly high-hardness acrylic acid amino baking varnish and preparation method thereof | |
| CN105038479A (en) | Modified acrylic resin energy-saving and environment-friendly coating for microwave oven shell | |
| CN103788831A (en) | Corrosion-proof ice-covering-proof coating | |
| CN100366686C (en) | Silicon fluoride super-amphiphobic non-stick coating material | |
| CN101914344B (en) | Non-chrome water-based organic fingerprint-resistant coating and preparation method thereof | |
| CN105111871A (en) | Modified acrylic resin energy-saving environment-friendly paint for suspended ceiling metal sheets | |
| CN105111881B (en) | A kind of acrylic resin modified energy-saving and environment-friendly paint of antitheft door door-plate | |
| CN109370342A (en) | A kind of water nano imitation porcelain coating and preparation method thereof | |
| CN105038344A (en) | Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator | |
| CN105038352A (en) | Energy-saving environment-friendly coating adopting modified acrylic resin and used for knurled decoration plate | |
| CN103589248A (en) | Coating with marble-like texture | |
| CN105038524B (en) | Modified acrylic resin energy-saving environment-friendly coating for oil drum body | |
| CN105038480A (en) | Energy-saving environment-friendly coating adopting modified acrylic resin and used for washing machine box | |
| CN103627280B (en) | A kind of mono-component aqueous outdoor top-coat varnish | |
| CN104817950B (en) | Energy-saving and environment-friendly roller coating paint for printing plate and application method of energy-saving and environment-friendly roller coating paint | |
| CN104804607B (en) | A kind of slab energy conservation and environmental protection roller coating paint and its application method | |
| CN108034308A (en) | A kind of cationoid reaction type priming paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210209 Address after: Room 01, building 13, No.1, Zhaoyan Road, Shaxi Town, Taicang City, Jiangsu Province Patentee after: Suzhou Xineng Environmental Protection Technology Co.,Ltd. Address before: 215427 Shaxi Town Zhitang Banjing village Taicang City Suzhou City Jiangsu Province Patentee before: TAICANG JINXIN PAINT Co.,Ltd. |