CN105038344A - Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator - Google Patents

Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator Download PDF

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Publication number
CN105038344A
CN105038344A CN201510552500.0A CN201510552500A CN105038344A CN 105038344 A CN105038344 A CN 105038344A CN 201510552500 A CN201510552500 A CN 201510552500A CN 105038344 A CN105038344 A CN 105038344A
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parts
acrylic resin
coating
saving
environment
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CN201510552500.0A
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Chinese (zh)
Inventor
王觉明
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Taicang Gold Coating Material Co Ltd
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Taicang Gold Coating Material Co Ltd
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Priority to CN201510552500.0A priority Critical patent/CN105038344A/en
Publication of CN105038344A publication Critical patent/CN105038344A/en
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Abstract

The invention provides a modified acrylic resin energy conservation and environment protection coating for a back plate of a refrigerator. The coating adopts bisphenol A epoxy resin modified acrylic resin, and therefore the coating has the advantages that the excellent flame retardance and wear resistance property are achieved, the curing speed is high, the better mechanical property, aging resistance property and chemical corrosion resistance property are achieved, the adhesive force is high, the ductility is good, the high temperature resistance property is achieved, the service life is long, the processing technology is changed, roller coating processing is concentratedly completed on a plate blank of the black plate of the refrigerator, the processing procedure is simplified, and a painting workshop does not need to be separately arranged.

Description

The acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard
Technical field
The present invention relates to the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard.
Background technology
Acrylic resin is the resin be made up of acrylate and methacrylic ester and other olefinic type monomers copolymerization, compared with other synthetic macromolecule resins, acrylic resin has many outstanding advantages, as fast light, the weathering resistance of excellence, open air weather resistance of being exposed to the sun is strong, ultraviolet resistance irradiates and not easily decomposes and turn yellow, original gloss and color and luster can be kept for a long time, good heat resistance, the chemical such as good acid-and base-resisting, salt, grease and washing composition are had to stain and corrosive nature, fabulous snappiness and minimum pigment reactivity.Therefore, have a wide range of applications automobile, household electrical appliances, art metal furniture, coiled material industry, instrument, building, textiles, woodwork, papermaking and plastics etc. are industrial.
But the heat that the linear structure of acrylic resin causes sticks cold short, anti-after-tackiness and thermotolerance is not good etc. that shortcoming has a definite limitation to its range of application.The equal phase structure of acrylic resin makes its cold tolerance and resistance toheat be difficult to take into account, and as increased resistance to low temperature, then can lose resistance to elevated temperatures, vice versa, and thus common acrylic acid or the like coating and decorating material just inevitably exists above-mentioned shortcoming.
By with other monomers, resin copolymerization and modification, the various aspects of performance of coating can be changed, make the coating of multiple different performance and Application Areas.Epoxy modified acrylic resin introduces propenyl unsaturated double-bond at the two ends of epoxy molecule chain, then with other monomer copolymerizations, like this, just make the various premium properties (fullness ratio of epoxy resin, gloss, hardness, sticking power etc.) be not fully exerted in acrylic resin, over-all properties respectively gets the chief, its dryness, fullness ratio, gloss, the over-all propertieies such as hardness are better than general acrylic resin, be applicable to the extra high occasion of cosmetic requirement, as frosting application, to meet the use of plastics, the course of processing is as surface treatment, plating, gold stamping, the needs of plated film etc.
At present, the following epoxy modified acrylic resin coating of domestic existence:
Chinese patent CN201210564995.5, disclosing a kind of take acrylic resin as the coating of raw material, is grouped into: epoxy resin 30 ~ 60 by the one-tenth of following weight part; Thermoplastic acrylic resin 20 ~ 30; Fire retardant 10 ~ 15; Zinc oxide 10 ~ 20; Pigment 10 ~ 15; Methyl alcohol 1 ~ 3; Deionized water 10 ~ 15.But, although this patent lists epoxy resin and thermoplastic acrylic resin, do not form the combination of epoxy modified acrylic resin, coating cannot be made to possess the premium properties of epoxy modified acrylic resin.
In addition, the application mode of existing acrylic resin paint adopts spray-coating mostly, such as Chinese patent CN201310607469.7, disclose a kind of thermosetting acrylic resin used for powder coating, this resin ester is equipped with the thermosetting powder coating(s) that unclassified stores is made, the film formed after spraying, has excellent weathering resistance, good flow leveling, excellent surface hardness and high-luster, weather resistance and decorate properties; Can be used for indoor or outdoors shape or material of construction.TGIC can be substituted to a certain extent, avoid the use of toxic substance.
But spraying is by spray gun or dish-style spraying gun, by means of pressure or centrifugal force, is dispersed into even and fine droplet, is applied over the coating process on coated article surface.Subject matter in spraying is the coating cloud of high dispersing and the solvent (i.e. volatile organic contaminant, VOCs) evaporated, and both contaminate environment, are unfavorable for HUMAN HEALTH, waste coating again, cause financial loss.Volatilization, the coating be diffused in air, then form volatile organic contaminant, be detrimental to health.At painting workshop, coating, as the main source of volatile organic contaminant, is easy to cause acute poisoning during volatile organic compounds excessive concentration in air in painting workshop, and the lighter there will be headache, dizziness, cough, Nausea and vomiting or is dead drunk liquor-saturated shape; Severe one there will be liver poisoning and even goes into a coma very soon, and what have also may be in peril of one's life.Treat for a long time, in the painting workshop of volatile organic compounds pollution, can chronic poisoning be caused, damage liver and neural system, cause general weakness, drowsiness, skin pruritus etc.What have also may cause endocrine disturbance, affects sexual function; Benzene and dimethylbenzene can also damage system, so that cause leukemia.
Summary of the invention
The object of the present invention is to provide the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard, described coating adopts bisphenol A epoxide resin acrylic resin modified, described coating is made to have excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by refrigerator backboard slab, simplify machining clearance, without the need to arranging painting workshop separately.
For achieving the above object, the technical solution used in the present invention is:
The acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 80 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, methylene-bis hexamethylene alkanamine: 10 ~ 15 parts, diaminodiphenyl-methane: 3 ~ 8 parts, cetyl benzenesulfonic acid sodium: 5 ~ 10 parts, dioctyl succinate disulfonate acid: 1 ~ 5 part, kaolin: 15 ~ 20 parts, PSI: 2 ~ 6 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, vinylbenzene: 30 ~ 40 parts, water: 90 ~ 100 parts.
Further, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 75 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 7 parts, methylene-bis hexamethylene alkanamine: 10 ~ 13 parts, diaminodiphenyl-methane: 3 ~ 5 parts, cetyl benzenesulfonic acid sodium: 5 ~ 7 parts, dioctyl succinate disulfonate acid: 1 ~ 4 part, kaolin: 15 ~ 18 parts, PSI: 2 ~ 4 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 6 parts, diatomite: 4 ~ 6 parts, polyamide wax pulp: 5 ~ 7 parts, vinylbenzene: 30 ~ 35 parts, water: 90 ~ 94 parts.
Preferably, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 parts, Natvosol: 4 parts, aminoresin: 6 parts, methylene-bis hexamethylene alkanamine: 12 parts, diaminodiphenyl-methane: 4 parts, cetyl benzenesulfonic acid sodium: 5 parts, dioctyl succinate disulfonate acid: 3 parts, kaolin: 15 parts, PSI: 3 parts, silicone emulsion: 4 parts, aluminum phosphate: 5 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, vinylbenzene: 30 parts, water: 92 parts.
Separately, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 30 parts, vinylformic acid, methyl methacrylate 20 ~ 25 parts, Methacrylamide 10 ~ 15 parts, ethyl acrylate 10 ~ 15 parts, Dodecyl Mercaptan 1 ~ 5 part, pimelinketone 2 ~ 7 parts, bisphenol A epoxide resin 20 ~ 30 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 10 parts, 90 ~ 100 parts, water.
Separately have, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 25 parts, vinylformic acid, methyl methacrylate 20 ~ 23 parts, Methacrylamide 10 ~ 13 parts, ethyl acrylate 10 ~ 12 parts, Dodecyl Mercaptan 1 ~ 3 part, pimelinketone 2 ~ 5 parts, bisphenol A epoxide resin 20 ~ 25 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 8 parts, 90 ~ 95 parts, water.
Preferably, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 parts, vinylformic acid, methyl methacrylate 22 parts, Methacrylamide 12 parts, ethyl acrylate 10 parts, Dodecyl Mercaptan 3 parts, pimelinketone 4 parts, bisphenol A epoxide resin 25 parts, Viscoat 295 3 parts, t-butyl per(oxy)benzoate 6 parts, 90 parts, water.
And, the preparation of described epoxy modified acrylic resin, comprise the steps: reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
Again, described coating is coated to refrigerator backboard steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
Beneficial effect of the present invention is:
Described coating adopts bisphenol A epoxide resin acrylic resin modified, there is excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by refrigerator backboard slab, simplify machining clearance, without the need to arranging painting workshop separately.
In the refrigerator backboard slab stage namely by roller coat by paint spraying provided by the present invention in refrigerator backboard steel slab surface, form coating, directly can carry out following process, obtain shaping refrigerator backboard, even if baroque refrigerator rear panel structure, also paint spraying is completed in the slab stage, without the need to follow-up application, to instead of in existing technique " be first processed into desired shape; and then spraying obtains moulding product " technique, coating and refrigerator backboard slab strong adhesion, can not crack because of complete processing or come off.Owing to being the roller coating technology replacement spraying coating process of the shaping quick-drying of roller coat, during application, the availability of coating can reach more than 90%, decrease the volatilization in air and waste, the VOCs that effective reduction causes coating volatilization to be formed because of spraying, VOCs quantity discharged≤420ppm in roller coat workshop, coating environment protecting is good.The refrigerator backboard goods that roller coat application completes are processed, the curved performance of refrigerator backboard T can reach 0T (after the finished product slab after roller coat 180 ° bending, completely seamlessly to close up, coating does not burst and comes off) or 1T (after slab twice 180 ° of bendings, outermost painting charge level does not come off, do not burst), ensure refrigerator backboard quality.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment does not limit the scope of the invention.
Table 1 is refrigerator backboard a kind of described in the embodiment of the present invention acrylic resin modified energy-saving and environment-friendly paint composition quality mark list.Table 2 is epoxy modified acrylic resin composition quality mark list described in the embodiment of the present invention.Table 3 is refrigerator backboard acrylic resin modified energy-saving and environment-friendly paint performance perameter list a kind of described in the embodiment of the present invention.Table 4 is refrigerator backboard a kind of described in the embodiment of the present invention coating performance parameter list of acrylic resin modified energy-saving and environment-friendly paint roller coat after refrigerator backboard steel slab surface.
Described refrigerator backboard is as follows by acrylic resin modified energy-saving and environment-friendly paint compound method:
Each component is added in high speed dispersor, after stirring, high speed dispersion 30 ~ 60min, stirring, discharging, filtration, packaging, warehouse-in.
The preparation of described epoxy modified acrylic resin, comprise the steps: reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
Table 1 (unit: part)
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Epoxy modified acrylic resin 70 68 80 75 73
Natvosol 4 3 5 4 5
Aminoresin 6 5 10 7 6
Methylene-bis hexamethylene alkanamine 12 10 13 15 14
Diaminodiphenyl-methane 4 7 8 3 5
Cetyl benzenesulfonic acid sodium 5 8 9 10 6
Dioctyl succinate disulfonate acid 3 1 2 5 4
Kaolin 15 18 16 20 17
PSI 3 5 4 6 2
Silicone emulsion 4 2 5 2 3
Aluminum phosphate 5 6 8 5 7
Diatomite 4 8 7 5 6
Polyamide wax pulp 6 8 5 10 7
Vinylbenzene 30 35 40 32 38
Water 92 90 95 100 98
Table 2 (unit: part)
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Vinylformic acid 20 25 28 30 22
Methyl methacrylate 22 21 20 25 24
Methacrylamide 12 13 10 15 14
Ethyl acrylate 10 12 13 15 14
Dodecyl Mercaptan 3 2 5 4 1
Pimelinketone 4 6 5 7 2
Bisphenol A epoxide resin 25 22 20 28 30
Viscoat 295 3 5 4 2 3
T-butyl per(oxy)benzoate 6 5 8 10 9
Water 90 98 95 100 92
Table 3
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Tensile strength (MPa) 45 40 38 35 42
Elongation at break (%) 9.5 8.8 8.5 8.7 9.1
Shore hardness 70 60 63 65 66
The acrylic resin modified energy-saving and environment-friendly paint of refrigerator backboard a kind of described in the embodiment of the present invention is coated in refrigerator backboard steel slab surface by roll coating model, at 200 DEG C after solidification, be cooled to room temperature, place 48 hours, measure slab top coat performance as shown in table 4.Wherein, the method of the mensuration paint film impact resistance that impact resistance testing method specifies with reference to standard GB/T/T1732-93, falls within the weight of fixed mass (1kg) maximum height (cm) that test plate (panel) does not cause paint film to destroy and represents paint film impact resistance.
Table 4
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Impact resistance (cm) 120 115 113 110 112
Salt spray resistance duration (h) 3150 3100 3120 3130 3140
Artificial accelerated aging duration (h) 3200 3180 3100 3170 3160
Resistance toheat 780 775 760 750 740
Adopt a kind of refrigerator backboard provided by the present invention packing of product can obtained after acrylic resin modified energy-saving and environment-friendly paint application refrigerator backboard slab, the curved performance of T can reach 0T or 1T.Utilization efficiency of coatings is high, and every 30 kilograms of coating can application 1 ton of slab.Do not ftracture under 230 DEG C of high temperature, nondiscoloration, resistance of aging is strong, is placed on the not yellowing in 10 ~ 15 years of outdoor consecutive sunlight, nondiscoloration.Acidproof corrosion resistance is strong, the product that roller coat is good is put into 85 DEG C of water and boils that 2H is raw is heated to 100 DEG C more gradually, product without variable color, fall paint, bubble.After using the Nad solution soaking 24H of 5% at normal temperatures, product surface non-corroding, variable color and coating come off.Pure cotton cloth is dipped in full 95% alcohol to be wrapped on 500g counterweight, wipes examination 50 circulation with the stroke of speed (20mm) left and right of per minute 40-60 time at product surface, and nothing fades de-oiling.Detect according to the X method of drawing in U.S. ASTM the shaping refrigerator backboard goods being coated with coating provided by the present invention, can reach the 0=ASTM grade of ISO grade, notching edge is completely smooth, and what edge had not a particle of peels off.
It should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted.Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to the technical scheme of invention or equivalent replacement, and not depart from the scope of technical solution of the present invention, it all should be encompassed in right of the present invention.

Claims (8)

1. the acrylic resin modified energy-saving and environment-friendly paint of refrigerator backboard, is characterized in that, in described coating, each composition quality mark is as follows:
Epoxy modified acrylic resin: 70 ~ 80 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, methylene-bis hexamethylene alkanamine: 10 ~ 15 parts, diaminodiphenyl-methane: 3 ~ 8 parts, cetyl benzenesulfonic acid sodium: 5 ~ 10 parts, dioctyl succinate disulfonate acid: 1 ~ 5 part, kaolin: 15 ~ 20 parts, PSI: 2 ~ 6 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, vinylbenzene: 30 ~ 40 parts, water: 90 ~ 100 parts.
2. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 75 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 7 parts, methylene-bis hexamethylene alkanamine: 10 ~ 13 parts, diaminodiphenyl-methane: 3 ~ 5 parts, cetyl benzenesulfonic acid sodium: 5 ~ 7 parts, dioctyl succinate disulfonate acid: 1 ~ 4 part, kaolin: 15 ~ 18 parts, PSI: 2 ~ 4 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 6 parts, diatomite: 4 ~ 6 parts, polyamide wax pulp: 5 ~ 7 parts, vinylbenzene: 30 ~ 35 parts, water: 90 ~ 94 parts.
3. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 parts, Natvosol: 4 parts, aminoresin: 6 parts, methylene-bis hexamethylene alkanamine: 12 parts, diaminodiphenyl-methane: 4 parts, cetyl benzenesulfonic acid sodium: 5 parts, dioctyl succinate disulfonate acid: 3 parts, kaolin: 15 parts, PSI: 3 parts, silicone emulsion: 4 parts, aluminum phosphate: 5 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, vinylbenzene: 30 parts, water: 92 parts.
4. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 30 parts, vinylformic acid, methyl methacrylate 20 ~ 25 parts, Methacrylamide 10 ~ 15 parts, ethyl acrylate 10 ~ 15 parts, Dodecyl Mercaptan 1 ~ 5 part, pimelinketone 2 ~ 7 parts, bisphenol A epoxide resin 20 ~ 30 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 10 parts, 90 ~ 100 parts, water.
5. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 25 parts, vinylformic acid, methyl methacrylate 20 ~ 23 parts, Methacrylamide 10 ~ 13 parts, ethyl acrylate 10 ~ 12 parts, Dodecyl Mercaptan 1 ~ 3 part, pimelinketone 2 ~ 5 parts, bisphenol A epoxide resin 20 ~ 25 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 8 parts, 90 ~ 95 parts, water.
6. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 parts, vinylformic acid, methyl methacrylate 22 parts, Methacrylamide 12 parts, ethyl acrylate 10 parts, Dodecyl Mercaptan 3 parts, pimelinketone 4 parts, bisphenol A epoxide resin 25 parts, Viscoat 295 3 parts, t-butyl per(oxy)benzoate 6 parts, 90 parts, water.
7. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, the preparation of described epoxy modified acrylic resin, comprises the steps:
Reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
8. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to any one of claim 1 ~ 7, it is characterized in that, described coating is coated to refrigerator backboard steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
CN201510552500.0A 2015-09-02 2015-09-02 Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator Pending CN105038344A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118302A (en) * 2016-07-19 2016-11-16 宜兴市巨人涂料有限公司 A kind of preparation method for outdoor type water-based anticorrosive paint
CN107118311A (en) * 2017-06-08 2017-09-01 华伦纳路新材料有限公司 A kind of epoxy modified acrylic resin and preparation method thereof
CN107312368A (en) * 2016-04-26 2017-11-03 芜湖艾蔓设备工程有限公司 A kind of automobile engine oil pan energy-saving and environment-friendly paint

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103146278A (en) * 2013-03-25 2013-06-12 扬州大学 Preparation method of low-temperature curing water-based acrylic amino baking coating
CN103725146A (en) * 2014-01-20 2014-04-16 天津市新丽华色材有限责任公司 Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103146278A (en) * 2013-03-25 2013-06-12 扬州大学 Preparation method of low-temperature curing water-based acrylic amino baking coating
CN103725146A (en) * 2014-01-20 2014-04-16 天津市新丽华色材有限责任公司 Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312368A (en) * 2016-04-26 2017-11-03 芜湖艾蔓设备工程有限公司 A kind of automobile engine oil pan energy-saving and environment-friendly paint
CN106118302A (en) * 2016-07-19 2016-11-16 宜兴市巨人涂料有限公司 A kind of preparation method for outdoor type water-based anticorrosive paint
CN107118311A (en) * 2017-06-08 2017-09-01 华伦纳路新材料有限公司 A kind of epoxy modified acrylic resin and preparation method thereof

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