CN101407654A - High peeling environment-friendly type aqueous transfer coating and use thereof - Google Patents
High peeling environment-friendly type aqueous transfer coating and use thereof Download PDFInfo
- Publication number
- CN101407654A CN101407654A CNA2008102027450A CN200810202745A CN101407654A CN 101407654 A CN101407654 A CN 101407654A CN A2008102027450 A CNA2008102027450 A CN A2008102027450A CN 200810202745 A CN200810202745 A CN 200810202745A CN 101407654 A CN101407654 A CN 101407654A
- Authority
- CN
- China
- Prior art keywords
- transfer coating
- agent
- resin
- friendly type
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a high peeling-off environment-friendly waterborne transfer coating and an application thereof, wherein, the waterborne transfer coating takes the following components with the contents (parts by weight) as raw materials: 10 to 60 parts of waterborne resin; 0 to 10 parts of auxiliary agent; 0 to 10 parts of rheological control agent; 0 to 30 parts of cosolvent; 0 to 10 parts of pigment; 30 to 80 parts of deionized water; and 0 to 5 parts of pH value regulator. Compared with the prior art, the waterborne transfer coating has the following advantages of: (1) environmental protection and cost advantages: the waterborne transfer coating takes water as a main dispersion medium and has no organic solvent basically, very low content of volatile organic compounds (VOCs) and low production cost; (2) good printing adaptability: compared with a the solvent system, a waterborne system is different on the resin and the polarity from the solvent, thereby having good solvent resistance and being more applicable to the printing modes (such as gravure printing and screen printing) with higher requirements on the solvent resistance; and (3) the waterborne transfer coating can be directly used for replacing the existing solvent high peeling-off transfer coating by the pilot scale production confirmation.
Description
Technical field
The present invention relates to aqueous transfer coating, relate in particular to a kind of high peeling environment-friendly type aqueous transfer coating and application thereof.
Background technology
Since the eighties in 20th century, transfer aluminum plated technology relies on advantages such as its technology is simpler, cost is lower, has started a revolution at wrapping material circle, has transfer aluminum platedly obtained a large amount of applying with coating (hereinafter to be referred as transfer coatings) for what it was customized.The basic property of transfer coatings is its separability, i.e. the easy degree totally peeled off of itself and basement membrane (PET polyester film, OPP stretched polypropene film etc.).The quality of separability generally can characterize by the peeling force of transfer coatings and basement membrane.A large amount of practical experiences show, the transfer coatings that peeling force is bigger, when stripping machine travelling speed high slightly (being often referred to more than the 120m/min), occur peeling off unclear problem easily, stay fragmentarily defective, directly have influence on quality product and production efficiency at finished surface.In addition, slim paper (refers generally to 50～90g/m
2Quantitatively, the interior lining paper of using as common cigarette) because its material is softer, also high especially to the requirement of separability.Therefore, transfer coatings with high separability (peeling force is very little), be a big difficult point of transfer coatings research and development and Application Areas, particularly (peeling rate can reach 120～180m/min) popularizations gradually of using, and it is particularly outstanding that this problem seems along with the high speed stripping machine always.
Existing high separability transfer coatings is a solvent-based system, and in a large number with an organic solvent, volatile organic matter (VOCs) content height causes severe contamination to producing with environment for use on the one hand, also exists the high problem of production cost on the other hand.
Water-borne coatings has the unrivaled environment-friendly advantage of solvent based coating has become extensive common recognition, and the road that transfer coatings is walked Water-borne modification also is trend of the times, therefore, is badly in need of the aqueous transfer coating that exploitation has high separability.
Summary of the invention
Purpose of the present invention is exactly high peeling environment-friendly type aqueous transfer coating and the application thereof that a kind of safety non-toxic, cheap, excellent property are provided in order to overcome the defective that above-mentioned prior art exists.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of high peeling environment-friendly type aqueous transfer coating is characterized in that, this aqueous transfer coating is a raw material by following component and content (weight part):
Water-base resin 10～60;
Auxiliary agent 0～10;
Rheology control agent 0～10;
Solubility promoter 0～30;
Colorant 0～10;
Deionized water 30～80;
PH value conditioning agent 0～5.
Described water-base resin is selected from water-borne acrylic resin, aqueous acrylic modified urethane resin, waterborne polyurethane resin, polyvinyl alcohol.
The weight-average molecular weight Mw scope of described water-borne acrylic resin, aqueous acrylic modified urethane resin, waterborne polyurethane resin is 10,000～100,000; The glass transition temperature Tg scope of described water-borne acrylic resin is-20 ℃～110 ℃; The softening point range of described aqueous acrylic modified urethane resin, waterborne polyurethane resin is 100～250 ℃; The alcoholysis degree scope of described polyvinyl alcohol is 70%～100%.
Described water-borne acrylic resin is selected from one or more in phenylpropyl alcohol modified aqueous acrylic acid resin, the vinegar third modified aqueous acrylic acid resin, the silicon third modified aqueous acrylic acid resin.
Described auxiliary agent is selected from one or more in wetting agent, defoamer, anti scuffing agent, film coalescence aid, the linking agent; Described rheology control agent is selected from one or both in hydrophobically-modified alkali swelling type ACRYLIC EMULSION or the association type polyaminoester emulsion.
Described wetting agent is selected from one or more in anionic wetting agent, the non-ionic wetting agent; Described defoamer is selected from one or more in modified polyorganosiloxane, modified silicone class, the interfacial agent; Described anti scuffing agent is selected from one or more in polyethylene emulsifying wax, organic silicon modified by polyether, the silicon sol; Described film coalescence aid is selected from one or more in propoxy-alcohol ether, propyl carbinol, propyl carbonate, the ten diester alcohol; Described linking agent is selected from one or more in aminoresin, titanate coupling agent, the silane coupling agent.
Described anionic wetting agent is selected from one or more in polyacrylic acid sodium salt, polycarboxylate sodium, the Sodium hexametaphosphate 99; Described non-ionic wetting agent is selected from one or more in Voranol EP 2001, acetylene ethylene glycol, the polyoxyethylene glycol alkyl ester.
Described solubility promoter is selected from one or more in ethanol, Virahol, the propylene glycol; Described colorant is selected from one or more in water-based paint, water-based metal complex dyestuff, the alcohol solube metallic complex dyestuff; Described pH value conditioning agent is selected from one or more in ammoniacal liquor, triethylamine, dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol, the dimethylethanolamine.
A kind of application of high peeling environment-friendly type aqueous transfer coating, it is characterized in that, this application comprises directly coats membrane surface with transfer coatings, through 90 ℃～140 ℃ of temperature, 6 seconds～20 seconds time continuous drying, film-forming enters vacuum aluminum-coated machine and aluminizes, then with paper compound and oven dry by glue commonly used, after being cooled to room temperature,, can obtain having the transfer aluminum plated wrapping paper of bright-coloured metalluster through peeling off the basement membrane that the top layer is peelled off by workshop section.
Described basement membrane comprises polyester PET thin film; Described paper comprises 50～90g/m
2Quantitative slim paper; The described workshop section of peeling off adopts at a high speed 120～180m/min stripping machine to peel off, during operation and basement membrane totally peel off no any unclear phenomenon of peeling off.
Compared with prior art, aqueous transfer coating of the present invention is a main dispersing medium with water, has the following advantages:
(1) environmental protection and cost advantage: with water is main dispersing medium, does not contain organic solvent substantially, and volatile organic matter (VOCs) content is extremely low, and production cost is low;
(2) printing adaptability is good: compare solvent-based system, water-based system different on resin and solvent polarity have been given its good solvent resistance, more are applicable to the mode of printing (as intaglio printing, silk screen printing) that solvent resistance is had relatively high expectations;
(3) trial production confirms to be directly used in the alternative existing high separability transfer coatings of solvent-borne type in the warp.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| The water-base resin waterborne polyurethane resin | 30 |
| The special hydrogen carbon compound of defoamer | 2 |
| Solubility promoter ethanol | 30 |
| Deionized water | 37.7 |
| PH value conditioning agent trolamine | 0.3 |
The weight-average molecular weight Mw of waterborne polyurethane resin is 10,000, and softening temperature is 100 ℃;
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology, is applicable to the extra high application scenario of separability requirement.
The above-mentioned aqueous transfer coating that obtains is directly coated polyester (PET) film surface, behind 90 ℃, 20 seconds continuous drying film-forming, enter vacuum aluminum-coated machine and aluminize, then with common cigarette lining paper (60g/m
2Quantitatively) compound and oven dry by glue commonly used, treat that complex body is cooled to room temperature after, peel off outermost PET film (repeatedly repeated application is in this technology) through 150m/min high speed stripping machine, promptly get transfer aluminum plated cigarette lining paper.
Embodiment 2
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| Water-base resin waterborne polyurethane resin water-borne acrylic resin | 20 10 |
| Anti scuffing auxiliary agent polyethylene emulsifying wax | 7 |
| Solubility promoter ethanol | 20 |
| Colorant alcohol solube metallic complex dyestuff | 2 |
| Deionized water | 41 |
The weight-average molecular weight Mw of water-base resin is 100,000, and the softening temperature of waterborne polyurethane resin is 250 ℃, and the glass transition temperature Tg of water-borne acrylic resin is-20 ℃;
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology, is applicable to application scenario high to the separability requirement and that have colouring to require.
The above-mentioned aqueous transfer coating that obtains is directly coated polyester (PET) film surface, behind 120 ℃ of temperature, 12 seconds continuous drying film-forming, enter vacuum aluminum-coated machine and aluminize, then with common cigarette lining paper (50g/m
2Quantitatively) compound and oven dry by glue commonly used, after treating that complex body is cooled to room temperature, peel off outermost PET film (repeatedly repeated application is in this technology) through 120m/min high speed stripping machine, promptly get have bright-coloured metalluster, surperficial scuff resistance and the good transfer aluminum plated cigarette lining paper of printing adaptability.
Embodiment 3
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| Water-base resin waterborne polyurethane resin water-borne acrylic resin | 25 5 |
| The wetting agent polyacrylic acid sodium salt | 5 |
| Rheology control agent association type polyaminoester emulsion | 2 |
| Solubility promoter ethanol propyl carbinol | 15 10 |
| Deionized water | 38 |
The weight-average molecular weight Mw of water-base resin is 40,000, and the softening temperature of waterborne polyurethane resin is 150 ℃, and the glass transition temperature Tg of water-borne acrylic resin is 110 ℃;
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology, is applicable to coating apparatus speed production occasion faster.
The above-mentioned aqueous transfer coating that obtains is directly coated polyester (PET) film surface, behind 140 ℃ of temperature, the continuous drying film-forming of 6 seconds time, enter vacuum aluminum-coated machine and aluminize, then with common cigarette lining paper (90g/m
2Quantitatively) compound and oven dry by glue commonly used, after treating that complex body is cooled to room temperature, peel off outermost PET film (repeatedly repeated application is in this technology) through 180m/min high speed stripping machine, promptly get have bright-coloured metalluster, surperficial scuff resistance and the good transfer aluminum plated cigarette lining paper of printing adaptability.
Embodiment 4
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| The water-base resin polyvinyl alcohol | 10 |
| Amino resin of cross-linking agent | 2 |
| Rheology control agent hydrophobically-modified alkali swelling type ACRYLIC EMULSION | 2 |
| Coloring material aqueous transparent yellow pigment | 5 |
| Deionized water | 80 |
| PH value conditioning agent 2-amino-2-methyl-1-propanol | 1 |
The alcoholysis degree of polyvinyl alcohol 〉=70%;
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology.
Embodiment 5
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| The water-base resin water-borne acrylic resin | 15 |
| The defoamer modified polyorganosiloxane | 10 |
| Rheology control agent hydrophobically-modified alkali swelling type ACRYLIC EMULSION | 10 |
| Solubility promoter ethanol Virahol | 10 5 |
| Coloring material aqueous transparent red pigment | 10 |
| Deionized water | 35 |
| PH value conditioning agent trolamine triethylamine | 3 2 |
Water-borne acrylic resin comprises phenylpropyl alcohol, the vinegar third modified aqueous acrylic acid resin (the two weight ratio 1: 1), and weight-average molecular weight Mw is 80,000, and glass transition temperature Tg is 60 ℃ (by Fox Equation for Calculating);
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology.
Embodiment 6
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
| Component | Weight part |
| Water-base resin waterborne polyurethane resin water-borne acrylic resin | 30 30 |
| Rheology control agent hydrophobically-modified alkali swelling type ACRYLIC EMULSION | 5 |
| Solubility promoter ethanol | 5 |
| Deionized water | 30 |
The weight-average molecular weight Mw of water-base resin is 50,000, and the softening temperature of waterborne polyurethane resin is 120 ℃, and the glass transition temperature Tg of water-borne acrylic resin is 80 ℃;
Above-mentioned raw materials promptly can be made into high peeling environment-friendly type aqueous transfer coating through synthetic, dispersion, allocating technology.
Above-mentioned aqueous transfer coating is directly coated polyester (PET) film surface, behind 90～140 ℃ of temperature, 6～12 seconds continuous drying film-forming, entering vacuum aluminum-coated machine aluminizes, pack the compound and oven dry of glue with all kinds of paper by using always then, after treating that complex body is cooled to room temperature, peel off the PET film on top layer through 150m/min high speed stripping machine, promptly get transfer aluminum plated wrapping paper.
Claims (10)
1. a high peeling environment-friendly type aqueous transfer coating is characterized in that, this aqueous transfer coating is a raw material by following component and content (weight part):
Water-base resin 10～60;
Auxiliary agent 0～10;
Rheology control agent 0～10;
Solubility promoter 0～30;
Colorant 0～10;
Deionized water 30～80;
PH value conditioning agent 0～5.
2. high peeling environment-friendly type aqueous transfer coating according to claim 1 is characterized in that, described water-base resin is selected from water-borne acrylic resin, aqueous acrylic modified urethane resin, waterborne polyurethane resin, polyvinyl alcohol.
3. high peeling environment-friendly type aqueous transfer coating according to claim 2 is characterized in that, the weight-average molecular weight Mw scope of described water-borne acrylic resin, aqueous acrylic modified urethane resin, waterborne polyurethane resin is 10,000～100,000; The glass transition temperature Tg scope of described water-borne acrylic resin is-20 ℃～110 ℃; The softening point range of described aqueous acrylic modified urethane resin, waterborne polyurethane resin is 100～250 ℃; The alcoholysis degree scope of described polyvinyl alcohol is 70%～100%.
4. high peeling environment-friendly type aqueous transfer coating according to claim 2, it is characterized in that described water-borne acrylic resin is selected from one or more in phenylpropyl alcohol modified aqueous acrylic acid resin, the vinegar third modified aqueous acrylic acid resin, the silicon third modified aqueous acrylic acid resin.
5. high peeling environment-friendly type aqueous transfer coating according to claim 1 is characterized in that, described auxiliary agent is selected from one or more in wetting agent, defoamer, anti scuffing agent, film coalescence aid, the linking agent; Described rheology control agent is selected from one or both in hydrophobically-modified alkali swelling type ACRYLIC EMULSION or the association type polyaminoester emulsion.
6. high peeling environment-friendly type aqueous transfer coating according to claim 5 is characterized in that described wetting agent is selected from one or more in anionic wetting agent, the non-ionic wetting agent; Described defoamer is selected from one or more in modified polyorganosiloxane, modified silicone class, the interfacial agent; Described anti scuffing agent is selected from one or more in polyethylene emulsifying wax, organic silicon modified by polyether, the silicon sol; Described film coalescence aid is selected from one or more in propoxy-alcohol ether, propyl carbinol, propyl carbonate, the ten diester alcohol; Described linking agent is selected from one or more in aminoresin, titanate coupling agent, the silane coupling agent.
7. high peeling environment-friendly type aqueous transfer coating according to claim 6 is characterized in that, described anionic wetting agent is selected from one or more in polyacrylic acid sodium salt, polycarboxylate sodium, the Sodium hexametaphosphate 99; Described non-ionic wetting agent is selected from one or more in Voranol EP 2001, acetylene ethylene glycol, the polyoxyethylene glycol alkyl ester.
8. high peeling environment-friendly type aqueous transfer coating according to claim 1 is characterized in that described solubility promoter is selected from one or more in ethanol, Virahol, the propylene glycol; Described colorant is selected from one or more in water-based paint, water-based metal complex dyestuff, the alcohol solube metallic complex dyestuff; Described pH value conditioning agent is selected from one or more in ammoniacal liquor, triethylamine, dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol, the dimethylethanolamine.
9. the application of a high peeling environment-friendly type aqueous transfer coating as claimed in claim 1, it is characterized in that, this application comprises directly coats membrane surface with transfer coatings, through 90 ℃～140 ℃ of temperature, 6 seconds～20 seconds time continuous drying, film-forming enters vacuum aluminum-coated machine and aluminizes, then with paper compound and oven dry by glue commonly used, after being cooled to room temperature,, can obtain having the transfer aluminum plated wrapping paper of bright-coloured metalluster through peeling off the basement membrane that the top layer is peelled off by workshop section.
10. the application of high peeling environment-friendly type aqueous transfer coating according to claim 9 is characterized in that, described basement membrane comprises polyester PET thin film; Described paper comprises 50～90g/m
2Quantitative slim paper; The described workshop section of peeling off adopts at a high speed 120～180m/min stripping machine to peel off, during operation and basement membrane totally peel off no any unclear phenomenon of peeling off.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102027450A CN101407654A (en) | 2008-11-14 | 2008-11-14 | High peeling environment-friendly type aqueous transfer coating and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102027450A CN101407654A (en) | 2008-11-14 | 2008-11-14 | High peeling environment-friendly type aqueous transfer coating and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101407654A true CN101407654A (en) | 2009-04-15 |
Family
ID=40570872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008102027450A Pending CN101407654A (en) | 2008-11-14 | 2008-11-14 | High peeling environment-friendly type aqueous transfer coating and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101407654A (en) |
Cited By (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020905A (en) * | 2010-12-14 | 2011-04-20 | 惠州市长润发涂料有限公司 | One-component water-based semi-gloss varnish and preparation method thereof |
| CN102031048A (en) * | 2010-12-15 | 2011-04-27 | 惠州市长润发涂料有限公司 | Flat varnish for waterborne wood |
| CN102040871A (en) * | 2010-12-15 | 2011-05-04 | 惠州市长润发涂料有限公司 | Aqueous UV (ultraviolet curing) paint with strengthened adhesion |
| CN102085977A (en) * | 2009-12-07 | 2011-06-08 | 住友橡胶工业株式会社 | Roller for office automation equipment and coating agent therefor |
| CN102127343A (en) * | 2011-04-25 | 2011-07-20 | 大连市轻化工研究所 | High-fineness aqueous color paste and preparation method thereof |
| CN102146236A (en) * | 2011-04-22 | 2011-08-10 | 大连市轻化工研究所 | High-stability aqueous color paste and preparation method thereof |
| CN102220079A (en) * | 2011-05-21 | 2011-10-19 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Aqueous polyurethane coating suitable for automotive interior-decorating polyvinyl chloride material and preparation method thereof |
| CN102363934A (en) * | 2011-06-30 | 2012-02-29 | 上海乘鹰新材料有限公司 | Environmentally-friendly quick drying aqueous glass imitation card transfer paint and preparation method as well as application thereof |
| CN102367348A (en) * | 2011-06-29 | 2012-03-07 | 上海乘鹰新材料有限公司 | Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof |
| CN102367359A (en) * | 2011-06-30 | 2012-03-07 | 成都倍大涂料有限公司 | Water-based sealing primer and its preparation method |
| CN102391702A (en) * | 2011-09-08 | 2012-03-28 | 江西洪都航空工业集团有限责任公司 | Formula and using method of organic glass surface protective coating |
| CN102458646A (en) * | 2009-05-26 | 2012-05-16 | 3M创新有限公司 | Process for making filled resins |
| CN102676036A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based matte touch gloss oil and preparation method thereof |
| CN102719185A (en) * | 2012-06-27 | 2012-10-10 | 安徽灵达化工科技有限公司 | Benzene and homolog thereof-free waterborne polyurethane laser transfer coating and preparation method thereof |
| CN101701117B (en) * | 2009-12-01 | 2012-10-10 | 上海凯兰达实业有限公司 | Laser mould pressing alcohol soluble aluminizing transfer paint and preparation method and application thereof |
| CN102757694A (en) * | 2012-06-11 | 2012-10-31 | 山西精华科工贸有限公司 | Water-based ink for cork paper bobbin intaglio printing and preparation method thereof |
| CN102864684A (en) * | 2012-08-21 | 2013-01-09 | 湖南中烟工业有限责任公司 | Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process |
| CN102863888A (en) * | 2011-07-07 | 2013-01-09 | 上海大通高科技材料有限责任公司 | Strippable heat-proof antirust protective film coating and preparation method thereof |
| CN101905622B (en) * | 2009-06-02 | 2013-02-06 | 陈武 | Decorative coating transfer film |
| CN102965032A (en) * | 2012-12-05 | 2013-03-13 | 中南林业科技大学 | Silicon-based wood adhesive with interpenetrating polymer network structure and preparation method thereof |
| CN103360931A (en) * | 2013-07-01 | 2013-10-23 | 华南理工大学 | Waterborne strippable coating for temporarily protecting metal |
| CN103540210A (en) * | 2013-09-30 | 2014-01-29 | 上海乘鹰新材料有限公司 | Environment-friendly water-based OP protective paint composition, and preparation and use thereof |
| CN103555105A (en) * | 2013-10-24 | 2014-02-05 | 上海维凯化学品有限公司 | Environment-friendly anti-copy holographic transfer coating composition and preparation method thereof |
| CN103666166A (en) * | 2013-11-27 | 2014-03-26 | 湖州立方农艺科技发展有限公司 | Environment-friendly painting coating |
| CN103694872A (en) * | 2012-09-27 | 2014-04-02 | 比亚迪股份有限公司 | Water-based strippable coating composition |
| CN103965785A (en) * | 2013-02-06 | 2014-08-06 | 佛山市明泰化工有限公司 | Sulfonated lignin aqueous paint |
| CN104059576A (en) * | 2014-03-20 | 2014-09-24 | 台州市万创夜光明工贸有限公司 | Single-component aqueous aluminized glass bead coating transfer glue and preparation method thereof |
| CN104099804A (en) * | 2014-07-09 | 2014-10-15 | 曲靖乾坤纸制品有限公司 | Vacuum direct plating production technology for high-gram-weight paperboard |
| CN104109429A (en) * | 2014-06-27 | 2014-10-22 | 江苏金恒新型包装材料有限公司 | Water-based transferring back coating, and preparation method and application thereof |
| CN104403534A (en) * | 2014-11-06 | 2015-03-11 | 广州擎天材料科技有限公司 | Aqueous primer matched with UV finish on electronic product plastic shell, and preparation method thereof |
| CN104449144A (en) * | 2014-12-11 | 2015-03-25 | 深圳市深赛尔股份有限公司 | Environment-friendly water glass paperboard transfer coating and preparation method thereof |
| CN104497743A (en) * | 2014-12-14 | 2015-04-08 | 安徽顺彤包装材料有限公司 | Environment-friendly waterborne transfer coating |
| CN104562848A (en) * | 2015-01-30 | 2015-04-29 | 杭州添丽装饰纸有限公司 | 3D science paper as well as production method and production equipment thereof |
| CN104652167A (en) * | 2015-03-05 | 2015-05-27 | 大亚科技股份有限公司 | Direct-plating coating and application thereof in inner liner for cigarette |
| CN104927510A (en) * | 2014-03-17 | 2015-09-23 | 深圳市格莱特印刷材料有限公司 | Novel water-based peelable glue and preparation method thereof |
| CN105038489A (en) * | 2015-09-02 | 2015-11-11 | 太仓市金新涂料有限公司 | Modified acrylic resin energy-conservation and environmental-friendly coating for product packing metal box |
| CN105038554A (en) * | 2015-08-04 | 2015-11-11 | 上海乘鹰新材料有限公司 | Low-dry-measure strippable vacuum aluminizing waterborne transfer coating and preparation method thereof |
| CN105038560A (en) * | 2015-09-11 | 2015-11-11 | 上海睿途新材料科技有限公司 | Golden water-borne coating for vacuum aluminum-plating paper and application method thereof |
| CN105062346A (en) * | 2015-09-02 | 2015-11-18 | 上海睿途新材料科技有限公司 | Golden water-based paint for vacuum aluminized paper and preparation method thereof |
| CN105153844A (en) * | 2015-09-14 | 2015-12-16 | 江苏乘鹰新材料股份有限公司 | Water-based environment-friendly transfer paint with high smoothness on transfer layer surface and preparation method thereof |
| CN105400406A (en) * | 2015-11-04 | 2016-03-16 | 上海维凯光电新材料有限公司 | Anti-flower sticking water-based transfer coating and preparation method thereof |
| CN105419546A (en) * | 2015-12-02 | 2016-03-23 | 安徽省通达包装材料有限公司 | Ultraviolet-resistant anti-radiation double-side coated polyester aluminized film and production method thereof |
| CN105500947A (en) * | 2015-12-23 | 2016-04-20 | 昆山市生力包装材料有限公司 | Optical variability color hot stamping foil and production method thereof |
| CN106189772A (en) * | 2016-07-20 | 2016-12-07 | 江苏新光镭射包装材料股份有限公司 | Water paint and the method utilizing this water paint preparation decoration mold pressing drawing film |
| CN106519944A (en) * | 2016-11-09 | 2017-03-22 | 深圳市金升彩包装材料有限公司 | Water-based transfer paint composition for printing and application method thereof |
| CN107266986A (en) * | 2017-07-20 | 2017-10-20 | 江苏乘鹰新材料股份有限公司 | A kind of cigarette bag radium-shine coating of aqueous transfer directly-plating and preparation method |
| CN107675554A (en) * | 2017-11-15 | 2018-02-09 | 上海顺灏新材料科技股份有限公司 | A kind of environmental security transfer paper and its manufacture craft |
| CN107780295A (en) * | 2017-09-12 | 2018-03-09 | 昆明理工大学 | It is a kind of to be used to allocate water paint of cigarette liner paper and coating and preparation method thereof |
| CN107828322A (en) * | 2017-11-13 | 2018-03-23 | 上海韦奇化工有限公司 | A kind of water-based Stripable paint and preparation method thereof |
| CN108084816A (en) * | 2017-12-29 | 2018-05-29 | 张继华 | A kind of water paint and preparation method thereof |
| CN108329813A (en) * | 2017-12-29 | 2018-07-27 | 上海维凯光电新材料有限公司 | A kind of bend resistance aqueous transfer coating and preparation method thereof |
| CN110256711A (en) * | 2019-06-21 | 2019-09-20 | 浙江兆泽实业有限公司 | A kind of water-fastness film of aqueous quick-drying and preparation method thereof |
| CN110700008A (en) * | 2019-09-12 | 2020-01-17 | 东莞光群雷射科技有限公司 | Varnish for sheet-type paper for digital printing machine and preparation process and application method thereof |
| CN112411250A (en) * | 2020-08-18 | 2021-02-26 | 昆山市生力包装材料有限公司 | Preparation process of ultra-smooth lining paper for cigarettes |
| CN112553965A (en) * | 2020-12-02 | 2021-03-26 | 玉溪市大营街铝箔纸有限责任公司 | Water-based gloss oil coating lining paper and processing technology thereof |
| CN112920698A (en) * | 2021-04-08 | 2021-06-08 | 广东邦固化学科技有限公司 | Printable water-based transfer coating and preparation method thereof |
| CN112969760A (en) * | 2018-08-30 | 2021-06-15 | Dic株式会社 | Urethane resin composition and laminate |
| CN113930141A (en) * | 2020-06-29 | 2022-01-14 | 广州慧谷化学有限公司 | Water-based aluminized transfer coating, preparation method and application thereof |
| CN114736580A (en) * | 2022-04-13 | 2022-07-12 | 滁州金桥德克新材料有限公司无锡分公司 | Water-based release adhesive and preparation method and application thereof |
-
2008
- 2008-11-14 CN CNA2008102027450A patent/CN101407654A/en active Pending
Cited By (81)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102458646B (en) * | 2009-05-26 | 2014-12-03 | 3M创新有限公司 | Process for making filled resins |
| CN102458646A (en) * | 2009-05-26 | 2012-05-16 | 3M创新有限公司 | Process for making filled resins |
| CN101905622B (en) * | 2009-06-02 | 2013-02-06 | 陈武 | Decorative coating transfer film |
| CN101701117B (en) * | 2009-12-01 | 2012-10-10 | 上海凯兰达实业有限公司 | Laser mould pressing alcohol soluble aluminizing transfer paint and preparation method and application thereof |
| CN102085977B (en) * | 2009-12-07 | 2015-12-02 | 住友橡胶工业株式会社 | Business automation equipment roller and business automation equipment roller coating agent |
| CN102085977A (en) * | 2009-12-07 | 2011-06-08 | 住友橡胶工业株式会社 | Roller for office automation equipment and coating agent therefor |
| CN102020905A (en) * | 2010-12-14 | 2011-04-20 | 惠州市长润发涂料有限公司 | One-component water-based semi-gloss varnish and preparation method thereof |
| CN102020905B (en) * | 2010-12-14 | 2012-10-24 | 惠州市长润发涂料有限公司 | One-component water-based semi-gloss varnish and preparation method thereof |
| CN102031048B (en) * | 2010-12-15 | 2012-12-26 | 惠州市长润发涂料有限公司 | Matt varnish for waterborne wood |
| CN102040871A (en) * | 2010-12-15 | 2011-05-04 | 惠州市长润发涂料有限公司 | Aqueous UV (ultraviolet curing) paint with strengthened adhesion |
| CN102031048A (en) * | 2010-12-15 | 2011-04-27 | 惠州市长润发涂料有限公司 | Flat varnish for waterborne wood |
| CN102040871B (en) * | 2010-12-15 | 2012-10-24 | 惠州市长润发涂料有限公司 | Aqueous UV (ultraviolet curing) paint with strengthened adhesion |
| CN102146236A (en) * | 2011-04-22 | 2011-08-10 | 大连市轻化工研究所 | High-stability aqueous color paste and preparation method thereof |
| CN102146236B (en) * | 2011-04-22 | 2014-05-14 | 大连市轻化工研究所 | High-stability aqueous color paste and preparation method thereof |
| CN102127343A (en) * | 2011-04-25 | 2011-07-20 | 大连市轻化工研究所 | High-fineness aqueous color paste and preparation method thereof |
| CN102127343B (en) * | 2011-04-25 | 2014-05-14 | 大连市轻化工研究所 | High-fineness aqueous color paste and preparation method thereof |
| CN102220079A (en) * | 2011-05-21 | 2011-10-19 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Aqueous polyurethane coating suitable for automotive interior-decorating polyvinyl chloride material and preparation method thereof |
| CN102367348A (en) * | 2011-06-29 | 2012-03-07 | 上海乘鹰新材料有限公司 | Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof |
| CN102367359A (en) * | 2011-06-30 | 2012-03-07 | 成都倍大涂料有限公司 | Water-based sealing primer and its preparation method |
| CN102363934A (en) * | 2011-06-30 | 2012-02-29 | 上海乘鹰新材料有限公司 | Environmentally-friendly quick drying aqueous glass imitation card transfer paint and preparation method as well as application thereof |
| CN102863888A (en) * | 2011-07-07 | 2013-01-09 | 上海大通高科技材料有限责任公司 | Strippable heat-proof antirust protective film coating and preparation method thereof |
| CN102863888B (en) * | 2011-07-07 | 2015-04-08 | 上海大通高科技材料有限责任公司 | Strippable heat-proof antirust protective film coating and preparation method thereof |
| CN102391702A (en) * | 2011-09-08 | 2012-03-28 | 江西洪都航空工业集团有限责任公司 | Formula and using method of organic glass surface protective coating |
| CN102676036A (en) * | 2012-05-22 | 2012-09-19 | 东莞市英科水墨有限公司 | Water-based matte touch gloss oil and preparation method thereof |
| CN102676036B (en) * | 2012-05-22 | 2014-12-03 | 东莞市英科水墨有限公司 | Water-based matte touch gloss oil and preparation method thereof |
| CN102757694B (en) * | 2012-06-11 | 2014-10-15 | 山西精华科工贸有限公司 | Water-based ink for cork paper bobbin intaglio printing and preparation method thereof |
| CN102757694A (en) * | 2012-06-11 | 2012-10-31 | 山西精华科工贸有限公司 | Water-based ink for cork paper bobbin intaglio printing and preparation method thereof |
| CN102719185A (en) * | 2012-06-27 | 2012-10-10 | 安徽灵达化工科技有限公司 | Benzene and homolog thereof-free waterborne polyurethane laser transfer coating and preparation method thereof |
| CN102719185B (en) * | 2012-06-27 | 2015-02-11 | 安徽灵达化工科技有限公司 | waterborne polyurethane laser transfer coating free of benzene and homolog and preparation method thereof |
| CN102864684B (en) * | 2012-08-21 | 2015-03-11 | 湖南中烟工业有限责任公司 | Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process |
| CN102864684A (en) * | 2012-08-21 | 2013-01-09 | 湖南中烟工业有限责任公司 | Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process |
| CN103694872A (en) * | 2012-09-27 | 2014-04-02 | 比亚迪股份有限公司 | Water-based strippable coating composition |
| CN103694872B (en) * | 2012-09-27 | 2016-11-23 | 比亚迪股份有限公司 | A kind of aqueous Stripable paint compositions |
| CN102965032A (en) * | 2012-12-05 | 2013-03-13 | 中南林业科技大学 | Silicon-based wood adhesive with interpenetrating polymer network structure and preparation method thereof |
| CN103965785A (en) * | 2013-02-06 | 2014-08-06 | 佛山市明泰化工有限公司 | Sulfonated lignin aqueous paint |
| CN103360931A (en) * | 2013-07-01 | 2013-10-23 | 华南理工大学 | Waterborne strippable coating for temporarily protecting metal |
| CN103540210B (en) * | 2013-09-30 | 2017-02-08 | 上海乘鹰新材料有限公司 | Environment-friendly water-based OP protective paint composition, and preparation and use thereof |
| CN103540210A (en) * | 2013-09-30 | 2014-01-29 | 上海乘鹰新材料有限公司 | Environment-friendly water-based OP protective paint composition, and preparation and use thereof |
| CN103555105A (en) * | 2013-10-24 | 2014-02-05 | 上海维凯化学品有限公司 | Environment-friendly anti-copy holographic transfer coating composition and preparation method thereof |
| CN103555105B (en) * | 2013-10-24 | 2016-01-27 | 上海维凯光电新材料有限公司 | The holographic transfer coatings composition and method of making the same of environment-friendly type anti-copying |
| CN103666166A (en) * | 2013-11-27 | 2014-03-26 | 湖州立方农艺科技发展有限公司 | Environment-friendly painting coating |
| CN104927510A (en) * | 2014-03-17 | 2015-09-23 | 深圳市格莱特印刷材料有限公司 | Novel water-based peelable glue and preparation method thereof |
| CN104059576A (en) * | 2014-03-20 | 2014-09-24 | 台州市万创夜光明工贸有限公司 | Single-component aqueous aluminized glass bead coating transfer glue and preparation method thereof |
| CN104109429A (en) * | 2014-06-27 | 2014-10-22 | 江苏金恒新型包装材料有限公司 | Water-based transferring back coating, and preparation method and application thereof |
| CN104099804B (en) * | 2014-07-09 | 2016-12-07 | 曲靖乾坤纸制品有限公司 | High grammes per square metre paperboard vacuum directly plates production technology |
| CN104099804A (en) * | 2014-07-09 | 2014-10-15 | 曲靖乾坤纸制品有限公司 | Vacuum direct plating production technology for high-gram-weight paperboard |
| CN104403534A (en) * | 2014-11-06 | 2015-03-11 | 广州擎天材料科技有限公司 | Aqueous primer matched with UV finish on electronic product plastic shell, and preparation method thereof |
| CN104449144A (en) * | 2014-12-11 | 2015-03-25 | 深圳市深赛尔股份有限公司 | Environment-friendly water glass paperboard transfer coating and preparation method thereof |
| CN104497743A (en) * | 2014-12-14 | 2015-04-08 | 安徽顺彤包装材料有限公司 | Environment-friendly waterborne transfer coating |
| CN104562848A (en) * | 2015-01-30 | 2015-04-29 | 杭州添丽装饰纸有限公司 | 3D science paper as well as production method and production equipment thereof |
| CN104652167A (en) * | 2015-03-05 | 2015-05-27 | 大亚科技股份有限公司 | Direct-plating coating and application thereof in inner liner for cigarette |
| CN105038554A (en) * | 2015-08-04 | 2015-11-11 | 上海乘鹰新材料有限公司 | Low-dry-measure strippable vacuum aluminizing waterborne transfer coating and preparation method thereof |
| CN105038489A (en) * | 2015-09-02 | 2015-11-11 | 太仓市金新涂料有限公司 | Modified acrylic resin energy-conservation and environmental-friendly coating for product packing metal box |
| CN105062346A (en) * | 2015-09-02 | 2015-11-18 | 上海睿途新材料科技有限公司 | Golden water-based paint for vacuum aluminized paper and preparation method thereof |
| CN105038560A (en) * | 2015-09-11 | 2015-11-11 | 上海睿途新材料科技有限公司 | Golden water-borne coating for vacuum aluminum-plating paper and application method thereof |
| CN105153844B (en) * | 2015-09-14 | 2018-07-10 | 江苏乘鹰新材料股份有限公司 | With the high slipping aqueous environment protection transfer coatings of transfer layer surface and preparation method |
| CN105153844A (en) * | 2015-09-14 | 2015-12-16 | 江苏乘鹰新材料股份有限公司 | Water-based environment-friendly transfer paint with high smoothness on transfer layer surface and preparation method thereof |
| CN105400406A (en) * | 2015-11-04 | 2016-03-16 | 上海维凯光电新材料有限公司 | Anti-flower sticking water-based transfer coating and preparation method thereof |
| CN105419546A (en) * | 2015-12-02 | 2016-03-23 | 安徽省通达包装材料有限公司 | Ultraviolet-resistant anti-radiation double-side coated polyester aluminized film and production method thereof |
| CN105500947A (en) * | 2015-12-23 | 2016-04-20 | 昆山市生力包装材料有限公司 | Optical variability color hot stamping foil and production method thereof |
| CN106189772B (en) * | 2016-07-20 | 2018-06-05 | 江苏新光镭射包装材料股份有限公司 | Water paint and the method using water paint preparation decoration molding drawing film |
| CN106189772A (en) * | 2016-07-20 | 2016-12-07 | 江苏新光镭射包装材料股份有限公司 | Water paint and the method utilizing this water paint preparation decoration mold pressing drawing film |
| CN106519944A (en) * | 2016-11-09 | 2017-03-22 | 深圳市金升彩包装材料有限公司 | Water-based transfer paint composition for printing and application method thereof |
| CN107266986A (en) * | 2017-07-20 | 2017-10-20 | 江苏乘鹰新材料股份有限公司 | A kind of cigarette bag radium-shine coating of aqueous transfer directly-plating and preparation method |
| CN107266986B (en) * | 2017-07-20 | 2019-08-02 | 江苏乘鹰新材料股份有限公司 | A kind of cigarette the packet radium-shine coating of aqueous transfer directly-plating and preparation method |
| CN107780295A (en) * | 2017-09-12 | 2018-03-09 | 昆明理工大学 | It is a kind of to be used to allocate water paint of cigarette liner paper and coating and preparation method thereof |
| CN107828322A (en) * | 2017-11-13 | 2018-03-23 | 上海韦奇化工有限公司 | A kind of water-based Stripable paint and preparation method thereof |
| CN107828322B (en) * | 2017-11-13 | 2020-06-12 | 上海韦奇化工有限公司 | Water-based strippable coating and preparation method thereof |
| CN107675554A (en) * | 2017-11-15 | 2018-02-09 | 上海顺灏新材料科技股份有限公司 | A kind of environmental security transfer paper and its manufacture craft |
| CN108329813A (en) * | 2017-12-29 | 2018-07-27 | 上海维凯光电新材料有限公司 | A kind of bend resistance aqueous transfer coating and preparation method thereof |
| CN108084816A (en) * | 2017-12-29 | 2018-05-29 | 张继华 | A kind of water paint and preparation method thereof |
| CN108329813B (en) * | 2017-12-29 | 2020-09-08 | 上海维凯光电新材料有限公司 | Bending-resistant water-based transfer coating and preparation method thereof |
| CN112969760A (en) * | 2018-08-30 | 2021-06-15 | Dic株式会社 | Urethane resin composition and laminate |
| CN112969760B (en) * | 2018-08-30 | 2023-05-12 | Dic株式会社 | Urethane resin composition and laminate |
| CN110256711A (en) * | 2019-06-21 | 2019-09-20 | 浙江兆泽实业有限公司 | A kind of water-fastness film of aqueous quick-drying and preparation method thereof |
| CN110700008A (en) * | 2019-09-12 | 2020-01-17 | 东莞光群雷射科技有限公司 | Varnish for sheet-type paper for digital printing machine and preparation process and application method thereof |
| CN113930141A (en) * | 2020-06-29 | 2022-01-14 | 广州慧谷化学有限公司 | Water-based aluminized transfer coating, preparation method and application thereof |
| CN112411250A (en) * | 2020-08-18 | 2021-02-26 | 昆山市生力包装材料有限公司 | Preparation process of ultra-smooth lining paper for cigarettes |
| CN112553965A (en) * | 2020-12-02 | 2021-03-26 | 玉溪市大营街铝箔纸有限责任公司 | Water-based gloss oil coating lining paper and processing technology thereof |
| CN112920698A (en) * | 2021-04-08 | 2021-06-08 | 广东邦固化学科技有限公司 | Printable water-based transfer coating and preparation method thereof |
| CN114736580A (en) * | 2022-04-13 | 2022-07-12 | 滁州金桥德克新材料有限公司无锡分公司 | Water-based release adhesive and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101407654A (en) | High peeling environment-friendly type aqueous transfer coating and use thereof | |
| CN101407656B (en) | Environment-friendly type moldable aqueous transfer coating, preparation and use thereof | |
| CN101402818B (en) | Environment-friendly watersoluble tintage paint, preparation and uses thereof | |
| EP2657308B1 (en) | Aqueous radiation curable coating composition | |
| CN101905553B (en) | Spray-painting advertising lamp box cloth | |
| CN1315872C (en) | Usage of carboxymethyl cellulose acetate butyrate | |
| CN101384676B (en) | Aqueous primer composition and method for coating plastic molded article by using such composition | |
| CN104497743A (en) | Environment-friendly waterborne transfer coating | |
| US9631111B2 (en) | Primerless base painting composition for parts of vehicle, kit comprising the same, painted parts of vehicle comprising the same and method for painting and varnishing parts of vehicle using the same | |
| CN105131747B (en) | A kind of environmentally-frieweak weak solvent type inkjet medium and preparation method thereof | |
| CN109868050A (en) | A kind of aqueous dumb paint of resistance to scratch and preparation method thereof | |
| CN103045038A (en) | Curing transfer coating capable of embossing laser information layer and preparation method thereof | |
| CN102241923A (en) | Shifted Al-plating paint for offset printing, preparation method and application thereof | |
| CN105482728A (en) | Scratch resistant precoating film | |
| CN110105861A (en) | Complete aqueous release coating and preparation method thereof for alumite thermoprinting foil | |
| CN114025888B (en) | Method for producing a multilayer coating comprising a flash coating and multilayer coating obtained by said method | |
| CN101314685A (en) | Water-based finishing coat with various colors for automobile | |
| CN109594347A (en) | A kind of aluminium system waterproof glossy canvas and preparation method thereof | |
| EP3938447B1 (en) | Digitally printed labels | |
| WO2020166474A1 (en) | Method for recycling plastic container and transfer film to be applied to plastic container | |
| US20150346621A1 (en) | Primer coatings for use on substrates | |
| JP5550059B2 (en) | Image forming method and image formed product | |
| CN107400411B (en) | High-speed printing water-based gravure ink for non-absorbent substrate | |
| US10882326B2 (en) | Inkjet receptive compositions and methods therefor | |
| KR100242754B1 (en) | Aqueous emulsion-based coating composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090415 |