CN104449144A - Environment-friendly water glass paperboard transfer coating and preparation method thereof - Google Patents
Environment-friendly water glass paperboard transfer coating and preparation method thereof Download PDFInfo
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- CN104449144A CN104449144A CN201410763474.1A CN201410763474A CN104449144A CN 104449144 A CN104449144 A CN 104449144A CN 201410763474 A CN201410763474 A CN 201410763474A CN 104449144 A CN104449144 A CN 104449144A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an environment-friendly aqueous glass paperboard transfer coating and a preparation method thereof. The coating is prepared from the following components in percentage by weight: 60-95% of an aqueous acrylic non-film forming emulsion, 0.2-2% of an aqueous wetting flatting agent, 0.1-0.5% of an aqueous deforming agent, 0.1-5% of an aqueous scratching resistant, 0.5-5% of a coalescing agent and 0.1-0.5% of a pH adjustor, totaling 100%. The coating is an aqueous system which is environment-friendly, non-toxic, pollution-free and free of harmful gas discharge. The glass paperboard produced by the coating is level and smooth, good in reductivity of printing dots, free of point drop and plate pasting and bright in color and luster. The raw materials used for the coating are purchased at home, so that the product is low in cost.
Description
Technical field
The present invention relates to the material technology field in printing industry, particularly relate to a kind of environment-friendly type aqueous cast-coated paperboard transfer coatings and preparation method thereof.
Background technology
Cast-coated paperboard is a kind of surface as the printing paperboard of flat smooth as glass.Cast-coated paperboard is by being coated with on a plastic film by transfer coatings, and then pigment transfer mill is pressed onto in paperboard and forms one deck smooth coating.Cast-coated paperboard is compared with common paperboard: more smooth, bright; During printing site reduce, bright in colour.
Current cast-coated paperboard transfer coatings adopts solvent-borne type substantially.Containing the solvent of 60-80% in solvent based coating, these solvents evaporate in air in large quantities in production and printing process, thus contaminate environment, and harm operator and user's is healthy, and brings serious disaster hidden-trouble.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environment-friendly type aqueous cast-coated paperboard transfer coatings and preparation method thereof, the object of volatile organic compounds zero release in production and printing process.
For solving the problems of the technologies described above, the object of the invention is to be achieved through the following technical solutions.
A kind of environment-friendly type aqueous cast-coated paperboard transfer coatings, its composition is by weight ratio:
It is 100% that above-mentioned each component meets weight proportion sum.
It is water 0-30% by weight ratio that described coating composition also comprises; Alcoholic solvent 0-20%.
Described alcoholic solvent is any one or multiple combination of ethanol or Virahol, propylene glycol.
It is waterborne film-forming breast 0-20% by weight ratio that described coating composition also comprises.
Described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
Described scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent.
Described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester.
Described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
Described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
A kind of environment-friendly type aqueous cast-coated paperboard transfer coatings preparation method as above, comprises step:
A: in the stirred opening cylinder of a constant volume, first drops into weight percent 60-95% water soluble acrylic acid not filming emulsion, the 0-20% waterborne film-forming emulsion of each component, dispersing speed 500-1200rpm/min, jitter time 8-15 minute;
B: then drop into 0.2-2% water-based moistening flatting agent, 0.1-0.5% water-based defoamer while stirring, 0.1-5% water-based is anti-draws together agent, 0.5-5% film coalescence aid, dispersing speed 800-1500rpm/min, jitter time 8-30 minute;
C: the mixed alcohols solvent then dropping into 0-20% alcoholic solvent and 0-30% water while stirring, 1000rpm/min disperses 10 minutes, dispersing speed 500-1300rpm/min, jitter time 5-15 minute;
D: adjust pH value between 8-9 with 0.1-0.5%PH conditioning agent again, finally check the viscosity of output, outward appearance qualified, be finished product.
The present invention has following beneficial effect:
Environment-friendly type aqueous cast-coated paperboard transfer coatings provided by the invention and preparation method thereof, tool has the following advantages:
1, this coating be aqueous solution systems, environmental protection, nontoxic, pollution-free, without noxious gas emission.
2, Well-recovered with the cast-coated paperboard flat smooth of this coating material production, printing net-point, do not fall point, not scumming, lovely luster.
3, this coating raw materials all can be purchased at home, low cost product.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with specific embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
A kind of environment-friendly type aqueous cast-coated paperboard transfer coatings and preparation method thereof, its composition of this coating is by weight ratio: water soluble acrylic acid is filming emulsion 60-95% not; Water-based moistening flatting agent 0.2-2%; Water-based defoamer 0.1-0.5%; Water-based is anti-draws together agent 0.1-5%; Film coalescence aid 0.5-5%; PH conditioning agent 0.1-0.5%; It is 100% that above-mentioned each component meets weight proportion sum.
Embodiment 1:
In the stirred opening cylinder of a constant volume, first drop into weight percent 60% water soluble acrylic acid not filming emulsion (NeoCryl A-1091), the 20% waterborne film-forming emulsion (NeoCryl A-1092) of each component, 500rpm/min disperses 15 minutes;
Then drop into 0.2% water-based moistening flatting agent (TG), 0.2% water-based defoamer (DC65) while stirring, 2% water-based is anti-draws together agent (WE6), 0.5% film coalescence aid (DPM), 1500rpm/min disperses 8 minutes;
Then drop into the mixed alcohols solvent of 2% ethanol and 15% water while stirring, 1000rpm/min disperses 10 minutes;
Adjust pH value between 8-9 with 0.1% diethanolamine again, finally check the viscosity of output, outward appearance qualified, be finished product.
In the present embodiment, the optional second-order transition temperature of filming emulsion is not between 65-95 DEG C for described water soluble acrylic acid, and the described optional second-order transition temperature of waterborne film-forming emulsion is between 30-50 DEG C.
Described alcoholic solvent is any one or multiple combination of ethanol or Virahol, propylene glycol; Described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
Described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
Described water-based scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent; Described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester; Described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
Embodiment 2:
In the stirred opening cylinder of a constant volume, first drop into weight percent 75% water soluble acrylic acid not filming emulsion (NeoCryl A-1091);
Then drop into 1% water-based moistening flatting agent (TG), 0.3% water-based defoamer (DC65) while stirring, 0.5% water-based is anti-draws together agent (WE6), 5% film coalescence aid (DPM), 1000rpm/min disperses 30 minutes;
Then drop into the mixed alcohols solvent of 10.5% Virahol, 4% propylene glycol and 3.5% water while stirring, 1000rpm/min disperses 10 minutes;
Adjust pH value between 8-9 with 0.2% diethanolamine again, finally check the viscosity of output, outward appearance qualified, be finished product.
In the present embodiment, the optional second-order transition temperature of filming emulsion is not between 65-95 DEG C for described water soluble acrylic acid, and the described optional second-order transition temperature of waterborne film-forming emulsion is between 30-50 DEG C.
Described alcoholic solvent is any one or multiple combination of ethanol or Virahol, propylene glycol; Described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
Described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
Described water-based scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent; Described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester; Described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
Embodiment 3:
In the stirred opening cylinder of a constant volume, first drop into weight percent 90% water soluble acrylic acid not filming emulsion (NeoCryl A-1091), the 5% waterborne film-forming emulsion (NeoCryl A-1092) of each component, 1000rpm/min disperses 5 minutes;
Then drop into 0.5% water-based moistening flatting agent (TG), 0.1% water-based defoamer (DC65) while stirring, 1% water-based is anti-draws together agent (WE6), 3% film coalescence aid (lauryl alcohol ester), 1000rpm/min disperses 15 minutes;
Adjust pH value between 8-9 with 0.4% ammoniacal liquor again, finally check the viscosity of output, outward appearance qualified, be finished product.
In the present embodiment, the optional second-order transition temperature of filming emulsion is not between 65-95 DEG C for described water soluble acrylic acid, and the described optional second-order transition temperature of waterborne film-forming emulsion is between 30-50 DEG C.
Described alcoholic solvent is any one or multiple combination of ethanol or Virahol, propylene glycol; Described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
Described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
Described water-based scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent; Described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester; Described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
Embodiment 4:
In the stirred opening cylinder of a constant volume, first drop into weight percent 80% water soluble acrylic acid not filming emulsion (NeoCryl A-1091), the 10% waterborne film-forming emulsion (NeoCryl A-1092) of each component, 800rpm/min disperses 12 minutes;
Then drop into 0.2% water-based moistening flatting agent (TG), 0.2% water-based defoamer (DC65) while stirring, 2% water-based is anti-draws together agent (WE6), 0.5% film coalescence aid (DPM), 1500rpm/min disperses 8 minutes;
Then drop into the mixed alcohols solvent of 2% ethanol and 5% water while stirring, 1000rpm/min disperses 10 minutes;
Adjust pH value between 8-9 with 0.1% diethanolamine again, finally check the viscosity of output, outward appearance qualified, be finished product.
In the present embodiment, the optional second-order transition temperature of filming emulsion is not between 65-95 DEG C for described water soluble acrylic acid, and the described optional second-order transition temperature of waterborne film-forming emulsion is between 30-50 DEG C.
Described alcoholic solvent is any one or multiple combination of ethanol or Virahol, propylene glycol; Described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
Described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
Described water-based scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent; Described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester; Described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
In an embodiment, all starting material are technical grade.
Environment-friendly type aqueous cast-coated paperboard transfer coatings manufacture method provided by the invention, this transfer coatings thoroughly can change the residue problem of organism in printed matter, reach pollution-free in production and dry process simultaneously, the object of volatile organic compounds zero release, can reduce volatile organic compounds to the harm of operator and the Harmful Residue confrontation user harm.
Above environment-friendly type aqueous cast-coated paperboard transfer coatings manufacture method provided by the present invention is described in detail, apply specific case herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; Meanwhile, for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1. an environment-friendly type aqueous cast-coated paperboard transfer coatings, is characterized in that, its composition is by weight ratio:
2. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: it is water 0-30% by weight ratio that described coating composition also comprises; Alcoholic solvent 0-20%.
3. alcoholic solvent as claimed in claim 2 is any one or multiple combination of ethanol or Virahol, propylene glycol.
4. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: it is waterborne film-forming breast 0-20% by weight ratio that described coating composition also comprises.
5. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: described water-based defoamer is any one or multiple combination of aqueous mineral oils defoamer or waterborne organic silicon defoamer, compound defoamer.
6. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: described scratch resistance agent is PP wax powder, wax emulsion; PE wax powder, wax emulsion; Any one or multiple combination in organosilicon scratch resistance agent.
7. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: described film coalescence aid is any one or two kinds in DPM or lauryl alcohol ester.
8. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: described PH conditioning agent is any one or two kinds of combinations of ammoniacal liquor or diethanolamine.
9. environment-friendly type aqueous cast-coated paperboard transfer coatings as claimed in claim 1, is characterized in that: described water-based moistening flatting agent be silicane water-based levelling moistening flatting agent, negatively charged ion perfluorocarbon surface promoting agent or diisooctyl amber semi-annular jade pendant acid sodium solution any one, multiple combination.
10. an environment-friendly type aqueous cast-coated paperboard transfer coatings preparation method as claimed in claim 1, is characterized in that, comprise step:
A: in the stirred opening cylinder of a constant volume, first drops into weight percent 60-95% water soluble acrylic acid not filming emulsion, the 0-20% waterborne film-forming emulsion of each component, dispersing speed 500-1200rpm/min, jitter time 8-15 minute;
B: then drop into 0.2-2% water-based moistening flatting agent, 0.1-0.5% water-based defoamer while stirring, 0.1-5% water-based is anti-draws together agent, 0.5-5% film coalescence aid, dispersing speed 800-1500rpm/min, jitter time 8-30 minute;
C: the mixed alcohols solvent then dropping into 0-20% alcoholic solvent and 0-30% water while stirring, 1000rpm/min disperses 10 minutes, dispersing speed 500-1300rpm/min, jitter time 5-15 minute;
D: adjust pH value between 8-9 with 0.1-0.5%PH conditioning agent again, finally check the viscosity of output, outward appearance qualified, be finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410763474.1A CN104449144A (en) | 2014-12-11 | 2014-12-11 | Environment-friendly water glass paperboard transfer coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410763474.1A CN104449144A (en) | 2014-12-11 | 2014-12-11 | Environment-friendly water glass paperboard transfer coating and preparation method thereof |
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| CN104449144A true CN104449144A (en) | 2015-03-25 |
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| CN201410763474.1A Pending CN104449144A (en) | 2014-12-11 | 2014-12-11 | Environment-friendly water glass paperboard transfer coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105887559A (en) * | 2016-04-07 | 2016-08-24 | 中山市博海精细化工有限公司 | Novel water-based paint for environment-friendly glassine and preparation method of novel water-based paint |
| CN110424187A (en) * | 2019-06-24 | 2019-11-08 | 湖南和锐镭射科技有限公司 | Environment-friendly water-based back painting and preparation method thereof, high viscose performance transfer paper jam and resist blocking and that shift paper jam |
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| CN101407654A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | High peeling environment-friendly type aqueous transfer coating and use thereof |
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| CN105887559A (en) * | 2016-04-07 | 2016-08-24 | 中山市博海精细化工有限公司 | Novel water-based paint for environment-friendly glassine and preparation method of novel water-based paint |
| CN110424187A (en) * | 2019-06-24 | 2019-11-08 | 湖南和锐镭射科技有限公司 | Environment-friendly water-based back painting and preparation method thereof, high viscose performance transfer paper jam and resist blocking and that shift paper jam |
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Application publication date: 20150325 |