CN108250867A - A kind of aqueous silver color process paint and preparation method thereof - Google Patents

A kind of aqueous silver color process paint and preparation method thereof Download PDF

Info

Publication number
CN108250867A
CN108250867A CN201810010818.XA CN201810010818A CN108250867A CN 108250867 A CN108250867 A CN 108250867A CN 201810010818 A CN201810010818 A CN 201810010818A CN 108250867 A CN108250867 A CN 108250867A
Authority
CN
China
Prior art keywords
silver color
agent
color process
water
aqueous silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810010818.XA
Other languages
Chinese (zh)
Inventor
杨伟平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Dazhong Sanlian Technology Co ltd
Original Assignee
Guangdong Dazhong Sanlian Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Dazhong Sanlian Technology Co ltd filed Critical Guangdong Dazhong Sanlian Technology Co ltd
Priority to CN201810010818.XA priority Critical patent/CN108250867A/en
Publication of CN108250867A publication Critical patent/CN108250867A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of aqueous silver color process paint, it is characterised in that the raw material matched by following weight is made:Water-based acrylic resin 70 80%;Water 5 10%;Polycarbodiimide 1 2%;Dispersant 0.20 0.80%;Wetting agent 0.20 0.80%;Levelling agent 0.10 0.60%;Antifoaming agent 0.20 0.80%;Aqueous aluminum powder slurry 5 10%;Fungicide 0.10 0.50%;Thickener 0.50 3%;Coalescents 2 6%;PH adjusting agent 0.10 0.50%.The present invention also provides a kind of preparation methods of above-mentioned aqueous silver color process paint.The aqueous silver color process paint of the present invention pre-processes water-based acrylic resin as a result of polycarbodiimide, carboxylic acid reaction micro in water-based acrylic resin is fallen, so that the stability of the water paint added in after aqueous aluminum powder slurry is obviously improved, and do not have any harmful effect to the performance and storage characteristics of whole water paint;This aqueous silver color process paint can be dried at normal temperatures, be a kind of aqueous product having compared with high storage stability, can solve the problems, such as that product rises tank in the flatulence of storage process.

Description

A kind of aqueous silver color process paint and preparation method thereof
Technical field
The present invention relates to paint fields, and in particular to a kind of aqueous silver color process paint and preparation method thereof.
Background technology
In craftwork polychromy, golden silver color is liked deeply with the metal effect of its unique and beautiful always, big in the past Use solvent type nitro or acrylic compounds metallic paint more, it is easy because containing in solvent based product with the reinforcement of environmental consciousness Toxic organic solvent is fired, is increasingly used limitation.Government has promulgated a series of pressure of limitation solvent based coatings successively Standard, part municipal government shopping list clear stipulaties can only select environmentally friendly aqueous product, and water paint replaces molten The paces of dosage form coating have been getting faster.
So the release of water-based metal effect paint has great significance, at present because can not have in golden aqueous effect paint Cu-Zn alloy powder and using being produced to the highly stable Pearlied gold pigment of water and water-base resin, so difficulty is little.But silver color Pigment used in metal effect paint will usually use aluminium powder, and the activity of aluminium is higher, although raw material producer carries out coating to it In the case that processing, makes it avoid reacting with water, but water-base resin in formula contains a small amount of carboxylic acid, still have micro anti- It should occur, product is made easily to generate flatulence during storage and is risen tank phenomenon, product quality can be also influenced when serious and is imitated with construction Fruit.
Invention content
The technical problems to be solved by the invention are to provide a kind of aqueous silver color process paint and preparation method thereof, this aqueous Silver color process paint storage stability is high, solves the problems, such as that product rises tank in the flatulence of storage process.The technical solution of use is as follows:
A kind of aqueous silver color process paint, it is characterised in that the raw material matched by following weight is made:Water-based acrylic resin 70- 80%;Water 5-10%;Polycarbodiimide 1-2%;Dispersant 0.20-0.80%;Wetting agent 0.20-0.80%;Levelling agent 0.10- 0.60%;Antifoaming agent 0.20-0.80%;Aqueous aluminum powder starches 5-10%;Fungicide 0.10-0.50%;Thickener 0.50-3%;Film forming helps Agent 2-6%;PH adjusting agent 0.10-0.50%.
Above-mentioned water-based acrylic resin is film forming matter, provides paint film.
Diluent of the above-mentioned water as aqueous silver color process paint plays diluting effect.
Above-mentioned polycarbodiimide plays the role of reacting with the carboxyl in water-based acrylic resin as inorganic agent;Profit Water-based acrylic resin is pre-processed with polycarbodiimide, carboxylic acid reaction micro in resin is fallen.
It is preferred that above-mentioned dispersant is the polyacrylic hydrosol of the affinity groups containing pigment.Above-mentioned dispersant plays dispersion and makees With.
It is preferred that above-mentioned wetting agent is non-ionic polysiloxane surfactant.Above-mentioned wetting agent plays wetting and dispersing and makees With.
It is preferred that above-mentioned levelling agent is the copolymer of siloxanes and polyethers.Above-mentioned levelling agent plays levelling, can promote coating A smooth, smooth, uniform film is formed during drying and forming-film.
It is preferred that above-mentioned antifoaming agent is Siloxane-Oxyalkylene Copolymers solution.Above-mentioned antifoaming agent plays defoaming.
Above-mentioned aqueous aluminum powder slurry is metallic pigments, plays pigmentation.Aqueous aluminum powder slurry is also known as water aluminum-silver slurry, can be in market On buy.
It is preferred that above-mentioned fungicide is isothiazolinone.Above-mentioned fungicide plays sterilization and anticorrosion.
It is preferred that above-mentioned thickener is polyurethane-modified polyethers thickener.Above-mentioned thickener plays thickening power.
It is preferred that above-mentioned coalescents are the mixtures of dipropylene glycol methyl ether (DPM) and dipropylene (DPNB).It is more excellent It is 1 to select the weight ratio of dipropylene glycol methyl ether and dipropylene:(0.8-1.2).Even more preferably dipropylene glycol methyl ether and two The weight ratio of propandiol butyl ether is 1:1.This coalescents, which rise, helps water-based acrylic resin filming function.
It is preferred that above-mentioned pH adjusting agent is 2- amino-2-methyl propyl alcohol.This pH adjusting agent rises and stablizes for adjusting acid-base value System acts on.
The present invention also provides a kind of preparation methods of above-mentioned aqueous silver color process paint, it is characterised in that includes the following steps:
(1)Following raw materials are equipped with according to the weight percent of setting:Water-based acrylic resin 70-80%, water 5-10%, poly- carbonization two Imines 1-2%, dispersant 0.20-0.80%, wetting agent 0.20-0.80%, levelling agent 0.10-0.60%, antifoaming agent 0.20-0.80%, Aqueous aluminum powder slurry 5-10%, fungicide 0.10-0.50%, thickener 0.50-3%, coalescents 2-6%, pH adjusting agent 0.10- 0.50%;
(2)Water-based acrylic resin and water are added in stirring container, polycarbodiimide is added in while stirring, is stirred 24-48 hours are stood after uniformly, it is spare;
(3)By step(2)The spare material stood is added in a mixing bowl equipped with blender, then by dispersant, profit Humectant, levelling agent and antifoaming agent are added in a mixing bowl, are mixed slowly 5-10 minutes, after stirring evenly, when stirring by aqueous aluminium Slurry is added in a mixing bowl, and then moderate-speed mixer disperses 10-20 minutes, then by fungicide, thickener, coalescents and pH Conditioning agent is added in a mixing bowl, and the pH value for stirring evenly and adjusting mixture obtains aqueous silver color process paint to 8-9.
It is preferred that above-mentioned steps(3)In, the rotating speed of blender is 300~400 turns per minute when mixing slowly, during moderate-speed mixer The rotating speed of blender is 600~800 turns per minute.
Above-mentioned steps(3)In, after moderate-speed mixer disperses 10-20 minutes, paint film, eye can be prepared with 150 microns of thick broaching tools After eyeball observation is without apparent coarse grain, then will be in fungicide, thickener, coalescents and pH adjusting agent addition a mixing bowl.
The advantageous effect of the present invention against existing technologies is, as a result of polycarbodiimide to water-based acrylic resin It is pre-processed, carboxylic acid reaction micro in water-based acrylic resin is fallen so that add in the water paint after aqueous aluminum powder slurry Stability be obviously improved, and there is no any harmful effect to the performance and storage characteristics of whole water paint;It is this Aqueous silver color process paint can be dried at normal temperatures, be a kind of aqueous product having compared with high storage stability, can solve to produce Product rise tank problem in the flatulence of storage process.The aqueous silver color process paint of the present invention can be used for the techniques such as woodwork, ceramics, plastic cement The incrustation of product.
Specific embodiment
Embodiment 1
In the present embodiment, the preparation method of aqueous silver color process paint includes the following steps:
(1)Following raw materials are equipped with according to the weight percent of setting:Water-based acrylic resin 78%, water 8.8%, polycarbodiimide 1.5%th, dispersant 0.30%, wetting agent 0.30%, levelling agent 0.20%, antifoaming agent 0.50%, aqueous aluminum powder slurry 6%, fungicide 0.30% (It is isothiazolinone), thickener 1%, coalescents 3%(Wherein dipropylene glycol methyl ether 1.5%, dipropylene 1.5%)、 PH adjusting agent 0.10%(It is 2- amino-2-methyl propyl alcohol);
(2)Water-based acrylic resin and water are added in stirring container, polycarbodiimide is added in while stirring, is stirred 24 hours are stood after uniformly, it is spare;
(3)By step(2)The spare material stood is added in a mixing bowl equipped with blender, then by dispersant, profit Humectant, levelling agent and antifoaming agent are added in a mixing bowl, are mixed slowly 5 minutes, after stirring evenly, are starched aqueous aluminum powder when stirring It is added in a mixing bowl, then moderate-speed mixer disperses 10 minutes, then by fungicide, thickener, coalescents and pH adjusting agent It is added in a mixing bowl, the pH value for stirring evenly and adjusting mixture obtains aqueous silver color process paint to 8.
Above-mentioned steps(3), the rotating speed of blender is 300 turns per minute when mixing slowly, and blender turns during moderate-speed mixer Speed is 600 turns per minute.
Above-mentioned steps(3)In, moderate-speed mixer disperses after ten minutes, paint film can be prepared with 150 microns of thick broaching tools, and eyes are seen It examines without after apparent coarse grain, then fungicide, thickener, coalescents and pH adjusting agent is added in a mixing bowl.
Above-mentioned water-based acrylic resin uses the product of Ahmedabad richness company, model 3230D.
Above-mentioned polycarbodiimide uses the product of golden brother company.
Above-mentioned dispersant, levelling agent, wetting agent, antifoaming agent use the product of Di Gao companies of Germany.
Above-mentioned aqueous aluminum powder slurry is using the product of Jun Chi companies, model JCS220.
Above-mentioned fungicide uses the product of Sol company, model EGCT.
Above-mentioned thickener uses the product in Aksu.
Above-mentioned coalescents are using the 1 of the DPM and DPNB of Tao Shi:1 mixed liquor.
Above-mentioned pH adjusting agent uses the product of Tao Shi, model AMP-95.
Embodiment 2
In the present embodiment, the preparation method of aqueous silver color process paint includes the following steps:
(1)Following raw materials are equipped with according to the weight percent of setting:Water-based acrylic resin 75%, water 7%, polycarbodiimide 2%th, dispersant 0.50%, wetting agent 0.50%, levelling agent 0.40%, antifoaming agent 0.70%, aqueous aluminum powder slurry 8%, fungicide 0.50% (It is isothiazolinone), thickener 3%, coalescents 4%(Wherein dipropylene glycol methyl ether 2%, dipropylene 2%), pH tune Save agent 0.30%(It is 2- amino-2-methyl propyl alcohol);
(2)Water-based acrylic resin and water are added in stirring container, polycarbodiimide is added in while stirring, is stirred 36 hours are stood after uniformly, it is spare;
(3)By step(2)The spare material stood is added in a mixing bowl equipped with blender, then by dispersant, profit Humectant, levelling agent and antifoaming agent are added in a mixing bowl, are mixed slowly 7 minutes, after stirring evenly, are starched aqueous aluminum powder when stirring It is added in a mixing bowl, then moderate-speed mixer disperses 15 minutes, then by fungicide, thickener, coalescents and pH adjusting agent It is added in a mixing bowl, the pH value for stirring evenly and adjusting mixture obtains aqueous silver color process paint to 8.5.
Above-mentioned steps(3)In, the rotating speed of blender is 350 turns per minute when mixing slowly, blender during moderate-speed mixer Rotating speed is 700 turns per minute.
Above-mentioned steps(3)In, after moderate-speed mixer disperses 15 minutes, paint film can be prepared with 150 microns of thick broaching tools, eyes are seen It examines without after apparent coarse grain, then fungicide, thickener, coalescents and pH adjusting agent is added in a mixing bowl.
Above-mentioned water-based acrylic resin uses the product of Ahmedabad richness company, model 3230D.
Above-mentioned polycarbodiimide uses the product of golden brother company.
Above-mentioned dispersant, levelling agent, wetting agent, antifoaming agent use the product of Di Gao companies of Germany.
Above-mentioned aqueous aluminum powder slurry is using the product of Jun Chi companies, model JCS220.
Above-mentioned fungicide uses the product of Sol company, model EGCT.
Above-mentioned thickener uses the product in Aksu.
Above-mentioned coalescents are using the 1 of the DPM and DPNB of Tao Shi:1 mixed liquor.
Above-mentioned pH adjusting agent uses the product of Tao Shi, model AMP-95.
Embodiment 3
In the present embodiment, the preparation method of aqueous silver color process paint includes the following steps:
(1)Following raw materials are equipped with according to the weight percent of setting:Water-based acrylic resin 71%, water 5%, polycarbodiimide 1%th, dispersant 0.70%, wetting agent 0.70%, levelling agent 0.50%, antifoaming agent 0.20%, aqueous aluminum powder slurry 10%, fungicide 0.10% (It is isothiazolinone), thickener 2%, coalescents 6%(Wherein dipropylene glycol methyl ether 3%, dipropylene 3%), pH tune Save agent 0.50%(It is 2- amino-2-methyl propyl alcohol);
(2)Water-based acrylic resin and water are added in stirring container, polycarbodiimide is added in while stirring, is stirred 48 hours are stood after uniformly, it is spare;
(3)By step(2)The spare material stood is added in a mixing bowl equipped with blender, then by dispersant, profit Humectant, levelling agent and antifoaming agent are added in a mixing bowl, are mixed slowly 10 minutes, after stirring evenly, when stirring by aqueous aluminum powder Slurry is added in a mixing bowl, and then moderate-speed mixer disperses 20 minutes, then adjusts fungicide, thickener, coalescents and pH Agent is added in a mixing bowl, and the pH value for stirring evenly and adjusting mixture obtains aqueous silver color process paint to 9.
Above-mentioned steps(3)In, the rotating speed of blender is 400 turns per minute when mixing slowly, blender during moderate-speed mixer Rotating speed is 800 turns per minute.
Above-mentioned steps(3)In, moderate-speed mixer disperses after twenty minutes, paint film can be prepared with 150 microns of thick broaching tools, and eyes are seen It examines without after apparent coarse grain, then fungicide, thickener, coalescents and pH adjusting agent is added in a mixing bowl.
Above-mentioned water-based acrylic resin uses the product of Ahmedabad richness company, model 3230D.
Above-mentioned polycarbodiimide uses the product of golden brother company.
Above-mentioned dispersant, levelling agent, wetting agent, antifoaming agent use the product of Di Gao companies of Germany.
Above-mentioned aqueous aluminum powder slurry is using the product of Jun Chi companies, model JCS220.
Above-mentioned fungicide uses the product of Sol company, model EGCT.
Above-mentioned thickener uses the product in Aksu.
Above-mentioned coalescents are using the 1 of the DPM and DPNB of Tao Shi:1 mixed liquor.
Above-mentioned pH adjusting agent uses the product of Tao Shi, model AMP-95.
Existing water before storage stability and our company to the obtained aqueous silver color process paints of above-described embodiment 1-3 The storage stability of property silver color process paint is compared, and test result is as follows shown in table 1.
1 storage stability test result of table
Storage stability 50 DEG C store 1 month 50 DEG C store 3 months Naturally half a year is placed Naturally it places 1 year
Existing aqueous silver process paint sample There is a small amount of bubble to generate in tank Bubble is more, micro- to have the tank phenomenon that rises There is a small amount of bubble to generate in tank Bubble is more, there is the apparent tank phenomenon that rises
Embodiment 1 Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises
Embodiment 2 Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises
Embodiment 3 Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises Normally, bubble-free, without the tank phenomenon that rises
The storage stability that can be seen that the aqueous silver color process paint of embodiment 1-3 from more than test result is fine, can be normal The lower drying of temperature, is a kind of aqueous product having compared with high storage stability.

Claims (10)

1. a kind of aqueous silver color process paint, it is characterised in that the raw material matched by following weight is made:Water-based acrylic resin 70- 80%;Water 5-10%;Polycarbodiimide 1-2%;Dispersant 0.20-0.80%;Wetting agent 0.20-0.80%;Levelling agent 0.10- 0.60%;Antifoaming agent 0.20-0.80%;Aqueous aluminum powder starches 5-10%;Fungicide 0.10-0.50%;Thickener 0.50-3%;Film forming helps Agent 2-6%;PH adjusting agent 0.10-0.50%.
2. aqueous silver color process paint according to claim 1, it is characterised in that:The dispersant is affinity groups containing pigment Polyacrylic hydrosol.
3. aqueous silver color process paint according to claim 1, it is characterised in that:The wetting agent is non-ionic poly- silicon Oxygen alkane surfactant.
4. aqueous silver color process paint according to claim 1, it is characterised in that:The levelling agent is siloxanes and polyethers Copolymer.
5. aqueous silver color process paint according to claim 1, it is characterised in that:The antifoaming agent is polyether-modified poly- silica Alkane solution.
6. aqueous silver color process paint according to claim 1, it is characterised in that:The fungicide is isothiazolinone;Institute It is polyurethane-modified polyethers thickener to state thickener;The pH adjusting agent is 2- amino-2-methyl propyl alcohol.
7. aqueous silver color process paint according to claim 1, it is characterised in that:The coalescents are dipropylene glycol methyl ethers With the mixture of dipropylene;The weight ratio of the dipropylene glycol methyl ether and the dipropylene is 1:(0.8- 1.2)。
8. aqueous silver color process paint according to claim 7, it is characterised in that:The dipropylene glycol methyl ether and the dipropyl The weight ratio of glycol butyl ether is 1:1.
9. a kind of preparation method of aqueous silver color process paint, it is characterised in that include the following steps:
(1)Following raw materials are equipped with according to the weight percent of setting:Water-based acrylic resin 70-80%, water 5-10%, poly- carbonization two Imines 1-2%, dispersant 0.20-0.80%, wetting agent 0.20-0.80%, levelling agent 0.10-0.60%, antifoaming agent 0.20-0.80%, Aqueous aluminum powder slurry 5-10%, fungicide 0.10-0.50%, thickener 0.50-3%, coalescents 2-6%, pH adjusting agent 0.10- 0.50%;
(2)Water-based acrylic resin and water are added in stirring container, polycarbodiimide is added in while stirring, is stirred 24-48 hours are stood after uniformly, it is spare;
(3)By step(2)The spare material stood is added in a mixing bowl equipped with blender, then by dispersant, profit Humectant, levelling agent and antifoaming agent are added in a mixing bowl, are mixed slowly 5-10 minutes, after stirring evenly, when stirring by aqueous aluminium Slurry is added in a mixing bowl, and then moderate-speed mixer disperses 10-20 minutes, then by fungicide, thickener, coalescents and pH Conditioning agent is added in a mixing bowl, and the pH value for stirring evenly and adjusting mixture obtains aqueous silver color process paint to 8-9.
10. the preparation method of aqueous silver color process paint according to claim 9, it is characterised in that:
The step(3)In, the rotating speed of blender is 300~400 turns per minute when mixing slowly, blender during moderate-speed mixer Rotating speed is 600~800 turns per minute.
CN201810010818.XA 2018-01-05 2018-01-05 A kind of aqueous silver color process paint and preparation method thereof Pending CN108250867A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810010818.XA CN108250867A (en) 2018-01-05 2018-01-05 A kind of aqueous silver color process paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810010818.XA CN108250867A (en) 2018-01-05 2018-01-05 A kind of aqueous silver color process paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108250867A true CN108250867A (en) 2018-07-06

Family

ID=62725749

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810010818.XA Pending CN108250867A (en) 2018-01-05 2018-01-05 A kind of aqueous silver color process paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108250867A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109056003A (en) * 2018-08-23 2018-12-21 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 A kind of silver jeweleries and preparation method thereof
CN109111809A (en) * 2018-07-26 2019-01-01 深圳市莱莉雅环保科技有限公司 The single-component water-based plastic cement aluminium paint of scintilla, preparation process and spraying method
CN110028888A (en) * 2019-04-19 2019-07-19 上海福岛新材料科技有限公司 A kind of environment-friendly water-based metallic paint
CN117511308A (en) * 2023-11-07 2024-02-06 广东电安新材料科技有限公司 Corrosion-resistant high-conductivity coating and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0792908A1 (en) * 1996-02-29 1997-09-03 Nisshinbo Industries Inc. Aqueous coating composition
CN105315813A (en) * 2015-07-02 2016-02-10 江苏足迹涂料有限公司 Water-based automobile metal base coat and preparing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0792908A1 (en) * 1996-02-29 1997-09-03 Nisshinbo Industries Inc. Aqueous coating composition
CN105315813A (en) * 2015-07-02 2016-02-10 江苏足迹涂料有限公司 Water-based automobile metal base coat and preparing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
马建中等: "《皮革化学品》", 31 March 2008, 化学工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109111809A (en) * 2018-07-26 2019-01-01 深圳市莱莉雅环保科技有限公司 The single-component water-based plastic cement aluminium paint of scintilla, preparation process and spraying method
CN109056003A (en) * 2018-08-23 2018-12-21 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 A kind of silver jeweleries and preparation method thereof
CN110028888A (en) * 2019-04-19 2019-07-19 上海福岛新材料科技有限公司 A kind of environment-friendly water-based metallic paint
CN117511308A (en) * 2023-11-07 2024-02-06 广东电安新材料科技有限公司 Corrosion-resistant high-conductivity coating and preparation method and application thereof
CN117511308B (en) * 2023-11-07 2024-04-05 广东电安新材料科技有限公司 Corrosion-resistant high-conductivity coating and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN108250867A (en) A kind of aqueous silver color process paint and preparation method thereof
KR100564264B1 (en) Polyalkoxysiloxane compounds, preparation process thereof and coating compositions the same
CN105885690A (en) Water-borne acrylic resin anticorrosive coating and preparation method thereof
CN107108815A (en) Finely divided aqueous emulsion polymer and its be used for the purposes of hydrophobic coating
CN106047132B (en) Water-based paint
CN106675366A (en) Water-based double-ingredient environment-friendly middle coating primer and preparation method thereof
CN108587351A (en) A kind of automotive trim water transfer aqueous priming paint coating and preparation method thereof
CN110194926A (en) A kind of water paint and preparation method thereof
CN107353795A (en) A kind of water-based orange-peel paint of low VOC content
TW201410749A (en) Epoxy resins and silane aqueous co-dispersions and the uses thereof
CN108997887A (en) One kind containing the double-component aqueous corrosion-resistant epoxy paint of glass flake and its preparation, application method
CN107488375B (en) High-filling water-based transparent putty for woodware and preparation method thereof
CN106634467A (en) Rheological metal basecoat and preparation method thereof
CN109762443A (en) A kind of coating and its preparation method and application of water-based mono-component bottom surface unification
CN102363704A (en) Aqueous blocking agent and its preparation method
CN114045074A (en) Water-based pencil draw-coating matte varnish and preparation method thereof
CN109880496A (en) A kind of bumper quick-dry type coating and preparation method thereof
CN107446437A (en) Aqueous woodware paint and preparation method thereof
CN107955475A (en) A kind of aqueous one-component automotive trim paint and preparation method thereof
CN112812634A (en) Water-based vacuum cup baking paint and preparation method thereof
CN115141532B (en) Low-VOC safe and environment-friendly water-based paint and preparation method thereof
CN109608956A (en) A kind of water-based mono-component Diamond Search paint and preparation method thereof
CN102367358A (en) Waterborne single-component full-glossy white finish and preparation method thereof
CN114686069B (en) Polyacrylate resin modified waterborne epoxy emulsion and preparation method thereof
US4655961A (en) Foam inhibitors for aqueous dispersions and solutions of synthetic resins

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180706

RJ01 Rejection of invention patent application after publication