CN106243961A - Display screen processing aqueous peelable glue and preparation method thereof - Google Patents
Display screen processing aqueous peelable glue and preparation method thereof Download PDFInfo
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- CN106243961A CN106243961A CN201610717285.XA CN201610717285A CN106243961A CN 106243961 A CN106243961 A CN 106243961A CN 201610717285 A CN201610717285 A CN 201610717285A CN 106243961 A CN106243961 A CN 106243961A
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- display screen
- peelable glue
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of display screen processing aqueous peelable glue and preparation method thereof, the emulsion that this peelable glue is formed with water-soluble resin and deionized water, aqueous dispersion or aqueous solution are aqueous matrix, and add wetting agent wherein, releasing agent, thickening agent, coalescents, pH adjusting agent, sterilization antiseptic and defoamer are as auxiliary element, it is without organic solvent or the monomer that can corrode base material, and all can be from dry film forming below 85% humidity more than 5 DEG C, need not hot setting, it is applicable to by PMMA resin, PC resin, the display screen base material that PET resin or glass material etc. are formed, and this peelable glue storage stablize, solidification is convenient easily, safety and environmental protection is pollution-free, use process is easily peeled off.
Description
Technical field
The present invention relates to a kind of peelable glue and preparation method thereof, particularly relate to a kind of display screen processing aqueous peelable glue and
Its preparation method, belongs to adhesive and preparing technical field thereof.
Background technology
In manufacturing industry parts and some finished product in processing and transportation often because of dust, the globule, greasy dirt, scratch or
The radiation of ultraviolet etc. damage surface, and the display screen used on a lot of electronic equipments especially at present, with greater need for careful protection
Its surface, it is to avoid any damage occurs.To the protected mode that display screen is common be paste on its surface one layer low-viscosity can
Peel ply adds the temporary protective material in man-hour as display screen surface, when display screen be in need not protection when by strippable coating
Remove.The strippable coating used in the most common display screen course of processing is mostly heat curing-type peelable glue or UV-curing
Changing peelable glue, above two peelable glue can be good at protecting display screen in the display screen course of processing, but in reality
In production and application, due to the material of display screen or similar display screen workpiece be mostly by PMMA resin, PC resin, PET resin or
The substrate that glass material etc. are formed, when using above-mentioned peelable glue can due to peelable glue in the organic solvent that contains and substrate is produced
Raw bigger erosion, and it is the most all 140~160 DEG C when using heat curing-type peelable glue due to its solidification temperature especially, and place
Hardening time under high temperature is the most long (typically 8~15min), makes this type of peelable glue not be suitable for PMMA resin, PC tree
Fat, PET resin etc. are heated deformable material.The most above-mentioned traditional peelable glue all exist certain limit that it uses lack
Fall into.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, the invention provides a kind of display screen processing aqueous peelable
Glue and preparation method thereof, this peelable glue can film forming and base material will not be corroded at normal temperatures, environment friendly and pollution-free, peel off easily
Convenient, belong to display screen surface processing temporary protective coatings screen printing water glue.
The present invention is to solve that its technical problem be the technical scheme is that
Aqueous peelable glue is used in a kind of display screen processing, presses display screen processing aqueous peelable glue gross weight percentage including following
Each component than meter:
It is preferably:
Its further technical scheme is:
Described water-soluble resin is water soluble acrylic resin, soluble chloride ethylene-vinyl acetate resin, water-soluble poly
At least one in urethane resin, water-soluble poval resin and aqueous arabic gum, and above-mentioned water-soluble resin is with described
Deionized water is jointly presented in emulsion, aqueous dispersion or aqueous solution (solid content is 33~55wt.%).I.e. form water
Soluble acrylic emulsion, soluble chloride ethylene-vinyl acetate emulsion, soluble polyurethane aqueous dispersion, water-soluble polyethylene
Alcohol-water solution and water-soluble Arabic gum, and solid content is 33~55wt.%.Deionized water therein can also select pure water,
Other pure water such as distilled water.
Described thickening agent is alkali swelling type acrylic emulsion thickener, association type polyurethane thickener and aerosil
In at least one.Wherein containing carboxylic acid ion, the poly-ammonia of association type on the strand of alkali swelling type acrylic emulsion thickener
Contain hydrophilic group and hydrophobic group on the same molecular structure of ester thickener simultaneously, the particle diameter of aerosil be 20~
40nm。
Described wetting agent is at least one in sulfonate wetting agent and polysiloxane solution, and wherein sulfonate wetting agent is
Diisobutyl sodium naphthalene sulfonate, isopropyl naphthalene sulfonate or dodecyl sodium sulfate, described polysiloxane solution is poly dimethyl silicon
Oxygen alkane or Siloxane-Oxyalkylene Copolymers.
Described releasing agent be in polyether polyol releasing agent, polythene wax emulsion releasing agent and silicone release at least
A kind of.
Described coalescents is alcohol ester 12 (i.e. 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate), propylene glycol phenyl
At least one in ether (i.e. PPH), butyl glycol ether and propylene glycol monomethyl ether.
Described pH adjusting agent is ammonia, 2-amino-2-methyl-1-propanol (i.e. AMP-95), diethanolamine and triethanolamine
In at least one.
Described sterilization antiseptic is 1,2-benzisothiazole-3-ketone (i.e. BIT), MIT
(i.e. MIT), CMIT (i.e. CIT), Kathon (i.e. OIT) and
At least one in 2-methyl-4,5-propylidene-4-isothiazoline-3-ketone (i.e. MTI).
Described defoamer is at least one in mineral oil antifoam agent and organic silicon defoamer.
The invention also discloses the preparation method of a kind of above-mentioned display screen processing aqueous peelable glue, the method includes following
Step: (1) first by the proportioning weight portion of the display screen processing each component of aqueous peelable glue weigh water-soluble resin, wetting agent,
Releasing agent, thickening agent, coalescents, pH adjusting agent, sterilization antiseptic, defoamer and deionized water obtain each component raw material;(2)
Emulsion, aqueous dispersion or aqueous solution that water-soluble resin and deionized water are formed are added and feeding cylinder carries out stirring at low speed, so
After under stirring, other each component raw material are sequentially added into after carry out moderate-speed mixer 20~30min and obtain to mix homogeneously
Shallow milky thick liquid, obtains display screen processing aqueous peelable glue.
The method have the benefit that: this peelable glue is with water-soluble resin and the emulsion of deionized water formation, aqueous
Dispersion or aqueous solution are aqueous matrix, and add wherein wetting agent, releasing agent, thickening agent, coalescents, pH adjusting agent,
Sterilization antiseptic and defoamer are as auxiliary element, and it is without corroding organic solvent or the monomer of base material, and 5 DEG C with
All can be from dry film forming below upper 85% humidity, it is not necessary to hot setting, it is adaptable to by PMMA resin, PC resin, PET resin or glass
The display screen base material that glass material etc. are formed, and the storage of this peelable glue stablize, solidify and facilitate easy, safety and environmental protection without dirt
Dye, use process is easily peeled off.
Detailed description of the invention
Further illustrating the present invention below in conjunction with specific embodiment and comparative example, specific examples below is this
Invent preferably embodiment, but embodiments of the present invention are not limited by following embodiment, under being not limited to especially
State the model of each component raw material used in specific embodiment.
The selection of each component raw material used:
Water-soluble resin and deionized water: in embodiment 1, select soluble polyurethane aqueous dispersion, wherein water-soluble poly ammonia
Ester resin 35% (its solid content is 37.8wt.%), deionized water 57.5%;Embodiment 2 is selected soluble chloride ethyl vinyl acetate
Vinyl acetate emulsion, wherein soluble chloride ethylene-vinyl acetate resin 30% (its solid content is 33.1wt.%), deionized water
60.7%;In embodiment 3 select water-soluble acrylic emulsion, wherein water soluble acrylic resin 46% (its solid content is
50.0wt.%), deionized water 46%;Embodiment 4 is selected water-soluble poval aqueous solution, wherein water-soluble poval
Resin 42% (its solid content is 46.8wt.%), deionized water 47.75%;Embodiment 5 is selected water-soluble Arabic gum water-soluble
Liquid, wherein water-soluble Arabic gum 48% (its solid content is 53.3wt.%), deionized water 42%;Embodiment 6 selects water solublity
Acrylic emulsion, wherein water soluble acrylic resin 50% (its solid content is 54.6%), deionized water 41.5%.
Thickening agent: embodiment 1 selects association type polyurethane thickener;Embodiment 2 selects aerosil, and its particle diameter is
35nm;Embodiment 3 selects alkali swelling type acrylic emulsion thickener;Embodiment 4 selects association type polyurethane thickener;Embodiment
5 select the mixing that association type polyurethane thickener and alkali swelling type acrylic emulsion thickener are mixed to form in mass ratio for 1:3
Thickening agent;Embodiment 6 selects alkali swelling type acrylic emulsion thickener.
Wetting agent: embodiment 1~2 selects isopropyl naphthalene sulfonate;Embodiment 3~4 selects Siloxane-Oxyalkylene Copolymers;Real
Execute example 5 and select polydimethylsiloxane;Embodiment 6 selects diisobutyl sodium naphthalene sulfonate.
Releasing agent: embodiment 1~2 selects alcohol ester 12;Embodiment 3~4 selects PPH;Embodiment 5 selects PPH and second two
The mixing releasing agent that alcohol butyl ether is mixed to form by 2:1;Embodiment 6 selects butyl glycol ether and propylene glycol monomethyl ether to mix shape by 3:2
The mixing releasing agent become.
PH adjusting agent: embodiment 1,2 and 6 selects AMP-95;Embodiment 3 selects ammonia;Embodiment 4~5 selects diethanol
The mixing pH adjusting agent that amine and triethanolamine are mixed to form according to 2:1.
Sterilization antiseptic: embodiment 1 selects BIT;Embodiment 2 selects MIT;Embodiment 3 selects CIT;Embodiment 4 is selected
OIT;Embodiment 5 selects MTI;Embodiment selects the mixing sterilization antiseptic that MIT and MTI is mixed to form according to 3:2.
Defoamer: embodiment 1~3 selects mineral oil antifoam agent, can be selected for the mineral oil antifoam agent of this type routine model;
Embodiment 4~6 selects organic silicon defoamer, can be selected for the mineral oil antifoam agent of this type routine model.
Water-soluble resin, wetting agent, releasing agent, thickening is weighed respectively according to the formula consumption of embodiment 1~6 described in table 1
Agent, coalescents, pH adjusting agent, sterilization antiseptic, defoamer and deionized water obtain each component raw material;Then by water solublity tree
Emulsion, aqueous dispersion or aqueous solution that fat and deionized water are formed add and carry out stirring at low speed in feeding cylinder, then at stirring
Lower other each component raw material are sequentially added into after carry out moderate-speed mixer 20~30min and obtain shallow milky thickness to mix homogeneously
Liquid, obtains display screen processing aqueous peelable glue.
Table 1 embodiment 1~6 formula (unit: kg)
The display screen processing aqueous peelable glue that above-described embodiment 1~6 is prepared gained uses the mode of silk screen printing to be coated with
Overlaying on and solidify on base material, wherein base material selects PMMA resin and glass material herein, records aqueous peelable glue
Hardening time, solidification temperature, erosion degree and stripping complexity, result ginseng be shown in Table 2.
Table 2 embodiment 1~6 testing result
The foregoing is only the preferred embodiments of the present invention.It should be pointed out that, in the feelings without departing from the principle of the invention
Under condition, also can make some improvement and modification, be accordingly to be regarded as protection scope of the present invention.
Claims (8)
1. aqueous peelable glue is used in a display screen processing, it is characterised in that: include following by display screen processing aqueous peelable glue
Each component of total weight percent meter:
Wherein said water-soluble resin is water soluble acrylic resin, soluble chloride ethylene-vinyl acetate resin, water-soluble poly
At least one in urethane resin, water-soluble poval resin and aqueous arabic gum, and above-mentioned water-soluble resin is with described
Deionized water is jointly presented in emulsion, aqueous dispersion or aqueous solution;Described thickening agent is alkali swelling type propylene yogurt
At least one in liquid thickening agent, association type polyurethane thickener and aerosil.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described wetting agent is sulfonate
At least one in wetting agent and polysiloxane solution.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described releasing agent is that polyethers is many
At least one in unit's alcohol releasing agent, polythene wax emulsion releasing agent and silicone release.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described coalescents is alcohol ester
12, at least one in propylene glycol phenylate, butyl glycol ether and propylene glycol monomethyl ether.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described pH adjusting agent is ammonia
At least one in water, 2-amino-2-methyl-1-propanol, diethanolamine and triethanolamine.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described sterilization antiseptic is 1,
2-benzisothiazole-3-ketone, MIT, CMIT, 2-are the most pungent
At least one in base-4-isothiazoline-3-ketone and 2-methyl-4,5-propylidene-4-isothiazoline-3-ketone.
Display screen processing aqueous peelable glue the most according to claim 1, it is characterised in that: described defoamer is mineral oil
At least one in defoamer and organic silicon defoamer.
8. a display screen processing preparation method for aqueous peelable glue described in any claim in claim 1 to 7, its
It is characterised by: comprise the steps: that (1) first weighs water by the proportioning weight portion of the display screen processing each component of aqueous peelable glue
Soluble resin, wetting agent, releasing agent, thickening agent, coalescents, pH adjusting agent, sterilization antiseptic, defoamer and deionized water obtain
To each component raw material;(2) emulsion, aqueous dispersion or aqueous solution that water-soluble resin and deionized water are formed are added in feeding cylinder
Carry out stirring at low speed, after then other each component raw material being sequentially added under stirring, carry out moderate-speed mixer 20~30min
To mix homogeneously, obtain shallow milky thick liquid, obtain display screen processing aqueous peelable glue.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107189512A (en) * | 2017-06-19 | 2017-09-22 | 合肥市惠科精密模具有限公司 | Aqueous peelable glue is used in a kind of TFT LCD displays processing |
CN107201181A (en) * | 2017-06-14 | 2017-09-26 | 合肥市惠科精密模具有限公司 | Aqueous peelable glue is used in a kind of TFT LCD displays processing |
CN107474767A (en) * | 2017-10-18 | 2017-12-15 | 东莞市冠力胶业有限公司 | One kind is without aldehyde sheet material adhesive and preparation method thereof |
CN107828322A (en) * | 2017-11-13 | 2018-03-23 | 上海韦奇化工有限公司 | A kind of water-based Stripable paint and preparation method thereof |
CN108239496A (en) * | 2016-12-23 | 2018-07-03 | 张家港康得新光电材料有限公司 | Maleic anhydride of styrene prepares preparation method, aqueous peelable glue composition and the aqueous peelable glue of amic acid |
CN108411049A (en) * | 2018-04-10 | 2018-08-17 | 中国皮革和制鞋工业研究院(晋江)有限公司 | Negative oxygen ion filler and preparation method thereof |
CN114958118A (en) * | 2022-07-05 | 2022-08-30 | 浙江广印通新材料科技有限公司 | Knife coating release coating for PET film |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108239496A (en) * | 2016-12-23 | 2018-07-03 | 张家港康得新光电材料有限公司 | Maleic anhydride of styrene prepares preparation method, aqueous peelable glue composition and the aqueous peelable glue of amic acid |
CN107201181A (en) * | 2017-06-14 | 2017-09-26 | 合肥市惠科精密模具有限公司 | Aqueous peelable glue is used in a kind of TFT LCD displays processing |
CN107189512A (en) * | 2017-06-19 | 2017-09-22 | 合肥市惠科精密模具有限公司 | Aqueous peelable glue is used in a kind of TFT LCD displays processing |
CN107474767A (en) * | 2017-10-18 | 2017-12-15 | 东莞市冠力胶业有限公司 | One kind is without aldehyde sheet material adhesive and preparation method thereof |
CN107828322A (en) * | 2017-11-13 | 2018-03-23 | 上海韦奇化工有限公司 | A kind of water-based Stripable paint and preparation method thereof |
CN107828322B (en) * | 2017-11-13 | 2020-06-12 | 上海韦奇化工有限公司 | Water-based strippable coating and preparation method thereof |
CN108411049A (en) * | 2018-04-10 | 2018-08-17 | 中国皮革和制鞋工业研究院(晋江)有限公司 | Negative oxygen ion filler and preparation method thereof |
CN108411049B (en) * | 2018-04-10 | 2020-10-09 | 中国皮革和制鞋工业研究院(晋江)有限公司 | Negative oxygen ion filler and preparation method thereof |
CN114958118A (en) * | 2022-07-05 | 2022-08-30 | 浙江广印通新材料科技有限公司 | Knife coating release coating for PET film |
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