CN102367348A - Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof - Google Patents

Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof Download PDF

Info

Publication number
CN102367348A
CN102367348A CN2011101808553A CN201110180855A CN102367348A CN 102367348 A CN102367348 A CN 102367348A CN 2011101808553 A CN2011101808553 A CN 2011101808553A CN 201110180855 A CN201110180855 A CN 201110180855A CN 102367348 A CN102367348 A CN 102367348A
Authority
CN
China
Prior art keywords
water
reaction kettle
resin
coated
singly
Prior art date
Application number
CN2011101808553A
Other languages
Chinese (zh)
Inventor
陈智
段孔荣
Original Assignee
上海乘鹰新材料有限公司
上海维凯化学品有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 上海乘鹰新材料有限公司, 上海维凯化学品有限公司 filed Critical 上海乘鹰新材料有限公司
Priority to CN2011101808553A priority Critical patent/CN102367348A/en
Publication of CN102367348A publication Critical patent/CN102367348A/en

Links

Abstract

The invention relates to an aqueous single-coating matt transferring aluminum-plating paint and a preparation method thereof. The paint comprises the following components in parts by weight: 20-70 parts of aqueous resin, 10-70 parts of deionized water, 0.5-2 parts of delustering powder, 5-30 parts of cosolvent, 0-10 parts of pigment, 0-2 parts of pH value regulating agent, 0-0.5 part of wetting agent, 0-0.2 part of flatting agent and 0.05-0.2 part of defoaming agent. Compared with the prior art, the aqueous single-coating matt transferring aluminum-plating paint has the advantages of excellent delustering property, simple production process and the like, and is environmentally-friendly.

Description

A kind of water-based singly is coated with matt transferring aluminum-plating paint and preparation method thereof
Technical field
The present invention relates to a kind of synthesis technique of polyamide resin, especially relate to a kind of water-based and singly be coated with matt transferring aluminum-plating paint and preparation method thereof.
Background technology
At present; The mute light that the is used for the tobacco package printing at present paper of aluminizing all uses the two matt transferring aluminum-plating paints that are coated with of solvent-borne type in process of production; And coating process is for two being coated with is to dry rolling after the PET basement membrane has been coated with the first road coating earlier, unreels again after the rolling to be coated with the second road coating and to dry rolling more again.This technology exists following drawback: 1. pair be coated with technology and cause tediously long, the consuming time expense merit of operation, production efficiency low; 2. it is healthy and environment caused severe contamination that the use of a large amount of organic solvents damages producers on the one hand, causes production cost to increase substantially on the other hand; 3. coating the time is prone to and stings quality problems such as the delustring that the end causes is inhomogeneous, dark fringe because of two interlayers; 4. the more and more stricter VOC requirement of tobacco package industry becomes the development bottleneck of solvent matte transfer aluminium-plating coating.Therefore, it is very urgent to develop that a kind of environmental protection, extinction effect are excellent, the simple water-based of production technique singly is coated with matt transferring aluminum-plating paint.
Applicant's earlier application application number be a kind of single-coating type matt transferring aluminum-plating paint of patent of invention of 200910201063.2 and preparation method thereof; This coating comprises following component and weight part content: main resin 10-20, assisted resin 0-10, dissolution solvent 70-80, mute light powder 0.5-2, whitening powder 0.2-0.5, dispersing auxiliary 0-0.5, leveling auxiliary agent 0-0.5, skimmer 0-0.5, anti scuffing agent 0-0.5; After getting the raw materials ready 90% dissolution solvent, main resin, assisted resin, leveling auxiliary agent, anti scuffing agent, skimmer are placed the reaction kettle stirring reaction, mixing behind the solvent dispersion 10min of mute light powder of adding and whitening powder, residue 10%, stirring, filtration obtain product in another dispersion cylinder.Though the product printing performance has been improved in this patented claim part; But the solvent that is adopted, auxiliary agent etc. remain organic solvent; It is healthy and environment caused severe contamination that the use of a large amount of organic solvents damages producers on the one hand, causes production cost to increase substantially on the other hand.
Summary of the invention
The object of the invention is exactly to provide a kind of environmental protection, eliminate optical property excellence, the simple water-based of production technique singly to be coated with matt transferring aluminum-plating paint and preparation method thereof for the defective that overcomes above-mentioned prior art existence.
The object of the invention can be realized through following technical scheme: a kind of water-based singly is coated with matt transferring aluminum-plating paint, it is characterized in that, this coating comprises following component and weight part content:
Water-base resin 20~70;
Deionized water 10~70;
Flatting silica 0.5~2;
Solubility promoter 5~30;
Colorant 0~10;
PH value regulator 0~2;
Wetting agent 0~0.5;
Flow agent 0~0.2;
Skimmer 0.05~0.2.
Described coating comprises following component and weight part content:
Water-base resin 30~40;
Deionized water 60~70;
Flatting silica 1.5~2;
Solubility promoter 5~8;
Colorant 8~10;
PH value regulator 1.5~2;
Wetting agent 0.4~0.5;
Flow agent 0.1~0.2;
Skimmer 0.1~0.2.
Described coating comprises following component and weight part content:
Water-base resin 50~70;
Deionized water 50~60;
Flatting silica 0.5~1;
Solubility promoter 10~20;
Colorant 1~2;
PH value regulator 0.1~0.5;
Wetting agent 0.1~0.2;
Flow agent 0.05~0.08;
Skimmer 0.05~0.08.
It is characterized in that described water-base resin bag water-based is drawn together one or more in vinyl resin, urethane resin or the polyvinyl alcohol resin.
Described water-borne acrylic resin comprises that phenylpropyl alcohol is acrylic resin modified, in fluorine-silicon modified acrylic resin or the self-crosslinking acrylic resin one or more; Its weight-average molecular weight (Mw) scope is 10,000~140,000, and second-order transition temperature (Tg) scope is~10 ℃~120 ℃.
Described urethane resin comprises one or more in organic silicon modified polyurethane resin, epoxy modified polyurethane resin, the acrylic acid modified polyurethane resin, and softening point range is 100~250 ℃.
Described flatting silica is the silicon-dioxide of particle diameter 4~8 μ m, in the synthetic wax one or both.
Described solubility promoter is one or more in ethanol, Virahol, the Ucar 35 ethers; Described pH value regulator is selected from a kind of in dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol, the dimethylethanolamine; Described wetting agent is selected from a kind of in anionic wetting agent, the non-ionic wetting agent; Described flow agent is modified organic silicon or acrylic acid or the like; Described skimmer is selected from one or more in modified polyorganosiloxane, non-ionic interfacial agent or the modified silicone defoamer.
A kind of water-based singly is coated with the preparation method of matt transferring aluminum-plating paint, it is characterized in that, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part content:
Water-base resin 20~70;
Deionized water 10~70;
Flatting silica 0.5~2;
Solubility promoter 5~30;
Colorant 0~10;
PH value regulator 0~2;
Wetting agent 0~0.5;
Flow agent 0~0.2;
Skimmer 0.05~0.2;
(2) water-base resin and colorant are dropped in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) filtration obtains environment-friendly type aqueous transfer matt transferring aluminum-plating paint at last.
Compared with prior art, the mute light single coating transfer aluminum plating coating of water-based of the present invention has the following advantages:
(1) with water be main dispersing medium, volatile organic matter (VOCs) content is extremely low, has environmental protection and production cost advantage;
(2) coating process is simple, only need coating once just can reach the two extinction effects that are coated with matt transferring aluminum-plating paint of solvent-borne type, and has overcome solvent based coating and send out quality problems such as mist because of stinging dark fringe, form and aspect instability, the moisture absorption that the end occurs;
(3) stable, the excellent printing adaptability of color and luster;
(4) can adapt to the more and more stricter VOC requirement of tobacco package industry;
(5) through in trial production confirm directly to be used for to substitute the two matt transferring aluminum-plating paints that are coated with of existing solvent-borne type.
Embodiment
Below in conjunction with specific embodiment the present invention is elaborated.
Embodiment 1
A kind of water-based singly is coated with matt transferring aluminum-plating paint, and this coating is got the raw materials ready by following component and content (weight part):
The weight-average molecular weight Mw of waterborne polyurethane resin is 40,000, and softening temperature is 250 ℃;
(2) water-base resin, colorant are joined in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(5) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (6) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(7) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 2
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
The softening temperature of waterborne polyurethane resin is 180 ℃, and the glass transition temperature Tg of water-borne acrylic resin is 30 ℃, and weight-average molecular weight (Mw) is 140,000;
(2) water-base resin, colorant are added in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 3
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
The softening temperature of waterborne polyurethane resin is 150 ℃;
(2) water-base resin, colorant are added in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent successively, middling speed 700~800rpm stirs 10~20min, obtains mute light base-material;
(6) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (7) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(8) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 4
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
Silicon modification olefin(e) acid resin glass temperature (Tg) is 120 ℃, and self-crosslinking acrylic resin second-order transition temperature (Tg) is 30 ℃, and the softening temperature of aqueous polyurethane is 100 ℃;
(2) water-base resin is added in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 5
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
The acrylic resin modified weight-average molecular weight of phenylpropyl alcohol (Mw) is 40,000, and second-order transition temperature (Tg) is 100 ℃; The acrylic acid modified polyurethane resin softening point is 230 ℃;
(2) water-base resin is added in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min, obtains mute light base-material;
(6) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (7) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(8) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 6
A kind of high peeling environment-friendly type aqueous transfer coating, this aqueous transfer coating is a raw material by following component and content (weight part):
The weight-average molecular weight Mw of water soluble acrylic acid is 100,000, and glass transition temperature Tg is 110 ℃;
(2) water-base resin is added in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) detect the viscosity that above-mentioned steps obtains sample, filter at last and obtain environment-friendly type aqueous transfer matt transferring aluminum-plating paint.
Embodiment 7
A kind of water-based singly is coated with matt transferring aluminum-plating paint, and this coating is got the raw materials ready by following component and content (weight part):
The weight-average molecular weight Mw of water-borne acrylic resin is 10~130,000, and second-order transition temperature is 100 ℃~110 ℃;
(2) water-base resin and colorant are dropped in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) filtration obtains environment-friendly type aqueous transfer matt transferring aluminum-plating paint at last.
Embodiment 8
A kind of water-based singly is coated with matt transferring aluminum-plating paint, and this coating is got the raw materials ready by following component and content (weight part):
(2) water-base resin and colorant are dropped in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) filtration obtains environment-friendly type aqueous transfer matt transferring aluminum-plating paint at last.

Claims (9)

1. a water-based singly is coated with matt transferring aluminum-plating paint, it is characterized in that, this coating comprises following component and weight part content:
Water-base resin 20~70;
Deionized water 10~70;
Flatting silica 0.5~2;
Solubility promoter 5~30;
Colorant 0~10;
PH value regulator 0~2;
Wetting agent 0~0.5;
Flow agent 0~0.2;
Skimmer 0.05~0.2.
2. a kind of water-based according to claim 1 singly is coated with matt transferring aluminum-plating paint, it is characterized in that, described coating comprises following component and weight part content:
Water-base resin 30~40;
Deionized water 60~70;
Flatting silica 1.5~2;
Solubility promoter 5~8;
Colorant 8~10;
PH value regulator 1.5~2;
Wetting agent 0.4~0.5;
Flow agent 0.1~0.2;
Skimmer 0.1~0.2.
3. a kind of water-based according to claim 1 singly is coated with matt transferring aluminum-plating paint, it is characterized in that, described coating comprises following component and weight part content:
Water-base resin 50~70;
Deionized water 50~60;
Flatting silica 0.5~1;
Solubility promoter 10~20;
Colorant 1~2;
PH value regulator 0.1~0.5;
Wetting agent 0.1~0.2;
Flow agent 0.05~0.08;
Skimmer 0.05~0.08.
4. singly be coated with matt transferring aluminum-plating paint according to each described a kind of water-based in the claim 1~3, it is characterized in that, described water-base resin bag water-based is drawn together one or more in vinyl resin, urethane resin or the polyvinyl alcohol resin.
5. a kind of water-based according to claim 4 singly is coated with matt transferring aluminum-plating paint; It is characterized in that; Described water-borne acrylic resin comprises that phenylpropyl alcohol is acrylic resin modified, in fluorine-silicon modified acrylic resin or the self-crosslinking acrylic resin one or more; Its weight-average molecular weight (Mw) scope is 10,000~140,000, and second-order transition temperature (Tg) scope is~10 ℃~120 ℃.
6. a kind of water-based according to claim 4 singly is coated with matt transferring aluminum-plating paint; It is characterized in that; Described urethane resin comprises one or more in organic silicon modified polyurethane resin, epoxy modified polyurethane resin, the acrylic acid modified polyurethane resin, and softening point range is 100~250 ℃.
7. singly be coated with matt transferring aluminum-plating paint according to each described a kind of water-based in the claim 1~3, it is characterized in that, described flatting silica is the silicon-dioxide of particle diameter 4~8 μ m, in the synthetic wax one or both.
8. singly be coated with matt transferring aluminum-plating paint according to each described a kind of water-based in the claim 1~3, it is characterized in that, described solubility promoter is one or more in ethanol, Virahol, the Ucar 35 ethers; Described pH value regulator is selected from a kind of in dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol, the dimethylethanolamine; Described wetting agent is selected from a kind of in anionic wetting agent, the non-ionic wetting agent; Described flow agent is modified organic silicon or acrylic acid or the like; Described skimmer is selected from one or more in modified polyorganosiloxane, non-ionic interfacial agent or the modified silicone defoamer.
9. a water-based as claimed in claim 1 singly is coated with the preparation method of matt transferring aluminum-plating paint, it is characterized in that this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part content:
Water-base resin 20~70;
Deionized water 10~70;
Flatting silica 0.5~2;
Solubility promoter 5~30;
Colorant 0~10;
PH value regulator 0~2;
Wetting agent 0~0.5;
Flow agent 0~0.2;
Skimmer 0.05~0.2;
(2) water-base resin and colorant are dropped in the reaction kettle, low speed 300~500rpm stirs;
(3) solubility promoter and deionized water are mixed after, under condition of stirring, add 90% in reaction kettle, low speed 300~500rpm stirs 5~10min;
(4) in reaction kettle, add pH value regulator, the pH value that makes system is between 8.0~9.0;
(5) in reaction kettle, add wetting agent, flow agent successively, middling speed 700~800rpm stirs 10~20min;
(6) in reaction kettle, add skimmer, 1000~1200rpm stirred 20~30 minutes at a high speed, obtained mute light base-material;
(7) in another reaction kettle, add flatting silica, will remain 10% solubility promoter and deionized water mixed solution adding immersion 10min then, controlling rotating speed again is that 100~1200rpm disperses 10min;
The mute light base-material that (8) will before make joins in the reaction kettle, and the control rotating speed is 1000~1200rpm dispersed with stirring, 30~60min;
(9) filtration obtains environment-friendly type aqueous transfer matt transferring aluminum-plating paint at last.
CN2011101808553A 2011-06-29 2011-06-29 Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof CN102367348A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011101808553A CN102367348A (en) 2011-06-29 2011-06-29 Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011101808553A CN102367348A (en) 2011-06-29 2011-06-29 Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN102367348A true CN102367348A (en) 2012-03-07

Family

ID=45759943

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011101808553A CN102367348A (en) 2011-06-29 2011-06-29 Aqueous single-coating matt transferring aluminum-plating paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102367348A (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102719185A (en) * 2012-06-27 2012-10-10 安徽灵达化工科技有限公司 Benzene and homolog thereof-free waterborne polyurethane laser transfer coating and preparation method thereof
CN102732141A (en) * 2012-06-08 2012-10-17 广州立邦涂料有限公司 Water general paint for refurbished mosaic bottom
CN102864684A (en) * 2012-08-21 2013-01-09 湖南中烟工业有限责任公司 Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process
CN103436119A (en) * 2013-07-29 2013-12-11 重庆恒美涂料有限公司 Preparation method of water-base glass matte paint
CN103555180A (en) * 2013-11-19 2014-02-05 三友(天津)高分子技术有限公司 Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof
CN104497743A (en) * 2014-12-14 2015-04-08 安徽顺彤包装材料有限公司 Environment-friendly waterborne transfer coating
CN104830176A (en) * 2015-05-19 2015-08-12 广东可逸智膜科技有限公司 Water-based wiping-resistant matte coating film and preparation method thereof
CN105038554A (en) * 2015-08-04 2015-11-11 上海乘鹰新材料有限公司 Low-dry-measure strippable vacuum aluminizing waterborne transfer coating and preparation method thereof
CN105062347A (en) * 2015-07-16 2015-11-18 合肥市科天化工有限公司 Synthetic method for matte waterborne polyurethane resin composite emulsion
CN105462471A (en) * 2015-12-28 2016-04-06 上海乘鹰新材料有限公司 Self-matting water-based transfer aluminizing paint
CN105462323A (en) * 2016-01-11 2016-04-06 惠阳区施美克化工有限公司 Peelable chemical-erosion-resistant protective paint and preparation method and application thereof
CN105585881A (en) * 2016-03-18 2016-05-18 江苏金恒新型包装材料有限公司 Water-based matte laser transfer coating for preparing anti-counterfeit material through film transfer
CN105818559A (en) * 2016-03-18 2016-08-03 江苏金恒新型包装材料有限公司 Laser anti-counterfeiting material used for medicine packaging and processing technology thereof
CN106752822A (en) * 2016-12-13 2017-05-31 西安大天新材料有限公司 A kind of aqueous high-temperature-resistant matt transferring aluminum-plating paint and preparation method thereof
CN107266986A (en) * 2017-07-20 2017-10-20 江苏乘鹰新材料股份有限公司 A kind of cigarette bag radium-shine coating of aqueous transfer directly-plating and preparation method
CN107760152A (en) * 2017-09-30 2018-03-06 四会市启德信息咨询服务有限公司 A kind of wear-resisting environment protecting water-based paint of dumb light
CN108264806A (en) * 2017-12-30 2018-07-10 东莞市宏成转印材料有限公司 A kind of concave-convex effect water transfer printing film and preparation method thereof
CN109705711A (en) * 2018-12-19 2019-05-03 上海乘鹰新材料有限公司 A kind of light general color water paint and preparation method thereof
CN111087908A (en) * 2019-12-25 2020-05-01 天津米一科技有限公司 Special anticorrosive material for carbon steel replacing stainless steel and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402818A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly watersoluble tintage paint, preparation and uses thereof
CN101407656A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 Environment-friendly type moldable aqueous transfer coating, preparation and use thereof
CN101407654A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 High peeling environment-friendly type aqueous transfer coating and use thereof
CN101760091A (en) * 2009-12-14 2010-06-30 上海维凯化学品有限公司 Single-coating type matt transferring aluminum-plating paint and preparation method thereof
CN101760121A (en) * 2009-12-14 2010-06-30 上海维凯化学品有限公司 Temperature-resistance environmental-protection aqueous transfer coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402818A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly watersoluble tintage paint, preparation and uses thereof
CN101407656A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 Environment-friendly type moldable aqueous transfer coating, preparation and use thereof
CN101407654A (en) * 2008-11-14 2009-04-15 上海维凯化学品有限公司 High peeling environment-friendly type aqueous transfer coating and use thereof
CN101760091A (en) * 2009-12-14 2010-06-30 上海维凯化学品有限公司 Single-coating type matt transferring aluminum-plating paint and preparation method thereof
CN101760121A (en) * 2009-12-14 2010-06-30 上海维凯化学品有限公司 Temperature-resistance environmental-protection aqueous transfer coating and preparation method thereof

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732141A (en) * 2012-06-08 2012-10-17 广州立邦涂料有限公司 Water general paint for refurbished mosaic bottom
CN102719185A (en) * 2012-06-27 2012-10-10 安徽灵达化工科技有限公司 Benzene and homolog thereof-free waterborne polyurethane laser transfer coating and preparation method thereof
CN102719185B (en) * 2012-06-27 2015-02-11 安徽灵达化工科技有限公司 waterborne polyurethane laser transfer coating free of benzene and homolog and preparation method thereof
CN102864684A (en) * 2012-08-21 2013-01-09 湖南中烟工业有限责任公司 Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process
CN102864684B (en) * 2012-08-21 2015-03-11 湖南中烟工业有限责任公司 Preparation process of aqueous silvery vacuum aluminized paper and transfer coating used for preparation process
CN103436119A (en) * 2013-07-29 2013-12-11 重庆恒美涂料有限公司 Preparation method of water-base glass matte paint
CN103555180A (en) * 2013-11-19 2014-02-05 三友(天津)高分子技术有限公司 Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof
CN104497743A (en) * 2014-12-14 2015-04-08 安徽顺彤包装材料有限公司 Environment-friendly waterborne transfer coating
CN104830176A (en) * 2015-05-19 2015-08-12 广东可逸智膜科技有限公司 Water-based wiping-resistant matte coating film and preparation method thereof
CN105062347A (en) * 2015-07-16 2015-11-18 合肥市科天化工有限公司 Synthetic method for matte waterborne polyurethane resin composite emulsion
CN105038554A (en) * 2015-08-04 2015-11-11 上海乘鹰新材料有限公司 Low-dry-measure strippable vacuum aluminizing waterborne transfer coating and preparation method thereof
CN105462471A (en) * 2015-12-28 2016-04-06 上海乘鹰新材料有限公司 Self-matting water-based transfer aluminizing paint
CN105462323A (en) * 2016-01-11 2016-04-06 惠阳区施美克化工有限公司 Peelable chemical-erosion-resistant protective paint and preparation method and application thereof
CN105585881A (en) * 2016-03-18 2016-05-18 江苏金恒新型包装材料有限公司 Water-based matte laser transfer coating for preparing anti-counterfeit material through film transfer
CN105818559A (en) * 2016-03-18 2016-08-03 江苏金恒新型包装材料有限公司 Laser anti-counterfeiting material used for medicine packaging and processing technology thereof
CN106752822A (en) * 2016-12-13 2017-05-31 西安大天新材料有限公司 A kind of aqueous high-temperature-resistant matt transferring aluminum-plating paint and preparation method thereof
CN107266986A (en) * 2017-07-20 2017-10-20 江苏乘鹰新材料股份有限公司 A kind of cigarette bag radium-shine coating of aqueous transfer directly-plating and preparation method
CN107266986B (en) * 2017-07-20 2019-08-02 江苏乘鹰新材料股份有限公司 A kind of cigarette the packet radium-shine coating of aqueous transfer directly-plating and preparation method
CN107760152A (en) * 2017-09-30 2018-03-06 四会市启德信息咨询服务有限公司 A kind of wear-resisting environment protecting water-based paint of dumb light
CN108264806A (en) * 2017-12-30 2018-07-10 东莞市宏成转印材料有限公司 A kind of concave-convex effect water transfer printing film and preparation method thereof
CN108264806B (en) * 2017-12-30 2020-10-09 东莞市宏成转印材料有限公司 Concave-convex effect water transfer printing film and preparation method thereof
CN109705711A (en) * 2018-12-19 2019-05-03 上海乘鹰新材料有限公司 A kind of light general color water paint and preparation method thereof
CN111087908A (en) * 2019-12-25 2020-05-01 天津米一科技有限公司 Special anticorrosive material for carbon steel replacing stainless steel and preparation method thereof

Similar Documents

Publication Publication Date Title
CN103614026B (en) Aqueous woodenware matte clean finishing coat and its preparation method
CN101701128B (en) Water-based two-pack polyurethane preservative coating and preparation method thereof
TWI428403B (en) Pigment dispersants, their production process, and their use
CN100526362C (en) Water-soluble alcohol-acid resin solution and water-soluble alcohol-acid amino baking paint and preparing method
CN101709550B (en) Leather flatting coating composition and preparation method thereof
CN104962173B (en) A kind of epoxide terrace sealing wax and preparation method thereof
CN101747818B (en) Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof
CN103740205B (en) A kind of water-based is sprayed paint and preparation method thereof
CN101781496B (en) Composition of water-based silver powder coating
CN1618897A (en) Ink and its use
CN102702933B (en) Ultraviolet curing woodware colored paint coating and preparation method thereof
CN101104768B (en) Highlight water-based automobile paint
CN104164145A (en) Water-based baked industrial paint
CN103183985B (en) Water-based printing ink and application thereof
CN1847342A (en) Organosilicone resin emulsion composition and article having coating thereof
CN1446865A (en) Aquosity intaglio printing ink and its preparation method
CN103396699A (en) Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof
CN103709833B (en) Preparation method for polymer coated inorganic pigment paste for color modulation of production line
CN104263069B (en) A kind of aqueous thermosetting glass printing ink and preparation method thereof
US9238742B2 (en) Method of preparing UV-curable inkjet pigment ink for textile printing
CN101675127A (en) Method for preparing paints and inks using a resin coated pigment
CN105462410A (en) High dirt resistance exterior wall latex paint capable of degrading haze and production process thereof
CN102304307B (en) Gravure printing ink for poly(ethylene terephthalate) (PET) base material and preparation method for gravure printing ink
CN105349019A (en) Water-borne acrylic polyurethane primer-topcoat corrosion-resistant decorative coating containing double components and preparation method of coating
CN101768398A (en) Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20120307