CN104059576A - Single-component aqueous aluminized glass bead coating transfer glue and preparation method thereof - Google Patents
Single-component aqueous aluminized glass bead coating transfer glue and preparation method thereof Download PDFInfo
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- CN104059576A CN104059576A CN201410111800.0A CN201410111800A CN104059576A CN 104059576 A CN104059576 A CN 104059576A CN 201410111800 A CN201410111800 A CN 201410111800A CN 104059576 A CN104059576 A CN 104059576A
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Abstract
The invention discloses a single-component aqueous aluminized glass bead coating transfer glue and preparation method thereof. The transfer glue is prepared from a microgel copolymer emulsion of organosilicon modified acrylic acid and ester thereof, a wetting dispersant, a light-reflective pigment, a rheological thickening additive, an adhesion promoter, a defoaming agent, a film-coalescing aid, an aqueous crosslinking agent and deionized water. The transfer glue is prepared in a manner of mechanically stirring dispersion. According to the invention, water, instead of an organic solvent, is employed in the transfer glue. The transfer glue is free of any atmosphere pollution, reduces a fire hidden danger, improves a working environment, is safe and environmental-friendly, saves resources and reduces cost. The transfer glue has obviously technical and economical advantages of being good in transferring effect of an aluminized glass bead coating, being strong in reversely-regressive light-reflective capability, being good in water-washing fastness and being good in flexibility. Meanwhile, finish products of the single-component aqueous aluminized glass bead coating transfer glue is packaged in cans so that storage stability is good. A swelling defect and a blacking defect are avoided. The finish product is easy and convenient to use. A glue-coating roller and device tools are easy to clean through water.
Description
Technical field
The reflecting at night security warning material technology field the present invention relates to, is specially a kind of single-component water-based aluminum plating glass pearl coating transfer adhesive and preparation method thereof.
Background technology
Aluminum plating glass pearl coating has retro-reflectivity function to light source, in reflecting at night security warning Material Field, is widely used.This century in the recent decade, the traditional two component oiliness acrylicacidandesters class transfer adhesive of the many employings of production of reflective fabric material, coat on polyester chemical fibre cloth base material by machinery, after heating surface drying with another interface PET film substrate on the vacuum aluminum-coated granulated glass sphere coating that adheres to carry out pressure viscosity laminated, again the aluminum plating glass pearl coating on PET film substrate is adhered on polyester chemical fibre cloth base material through peeling off to shift, it is good that its finished product has aluminum plating glass pearl coating transfer effect, the reflective power of material is strong, the advantages such as washing fastness is good, but need on-the-spot allotment because two components two are canned, material period of storage is short, clout after used the same day easily solidifies the rotten waste that causes, upper glue roller and equipment tool clean trouble and the expense of taking a lot of work is expected time-consuming, in application, there is organic solvent loss, contaminate environment, waste resource, cost is high, be harmful to health, there is disaster hidden-trouble.
Summary of the invention
Technical problem solved by the invention is to provide a kind of single-component water-based aluminum plating glass pearl coating transfer adhesive and preparation method thereof, replace traditional two component oiliness aluminum plating glass pearl coating transfer adhesive, realize with water for organic solvent, to solve the problem proposing in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 50 parts-80 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.1 part-0.5 part of wetting dispersing agent, 1 part-15 parts, reflective colorant, 0.1 part-2 parts of rheology thickening auxiliary agents, 0.1 part-5 parts of adhesion promoters, 0.1 part-0.5 part of defoamer, 1 part-5 parts of film coalescence aid, 0.01 part-0.5 part of water cross-linking agent, 10 parts-40 parts of deionized waters.
As preferably, described organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, and solid content is that 45 ± 2%, PH is 7.5 ± 0.5, and viscosity is 2000 ± 200mpa.s, and Tg value is-10 ± 10 DEG C.
As preferably, described wetting dispersing agent is one or more in aliphatic polycarboxylic acid's salt, segmented copolymer and organic silicon solution, acetylenic diols ethoxy compound, polyether-modified organopolysiloxane, polyether polyester modification by copolymerization organopolysiloxane.
As preferably, described reflective colorant is one or more in 200-2000 order silicon dioxide coating type aluminium powder, 200-2000 order silicon dioxide coating type water aluminum-silver slurry, 200-2000 order mica titanium silvery white pearlescence, 200-2000 order water mica titanium silvery white pearlite slurry.
As preferably, described rheology thickening auxiliary agent is one or more in non-ionic type polyamine esters thickening material, association type acrylic thickener, the swelling association type acrylic thickener of alkali.
As preferably, described adhesion promoter is one or more in 3-glycidyl ether oxygen base oxypropyl trimethyl silane, epoxide modified dimethyl siloxane, the aminated acrylate copolymer of ethene.
As preferably, described defoamer is polyether modified siloxane class, modified organic silicon class, paraffin mineral oils, and alkoxyl group alkyne diol divides one or more in subclass, alkyne diol molecule defoamer.
As preferably, described film coalescence aid agent is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester, alcohol ester-12, one or more in propylene glycol monobutyl ether.
As preferably, described water cross-linking agent is to have bifunctional by one or more in amino, epoxy group(ing), hydroxy kind compound and aziridine and polymine.
A preparation method for single-component water-based aluminum plating glass pearl coating transfer adhesive, comprises the following steps:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after double-layer leaching net filters of the material after being uniformly mixed.
In sum, beneficial effect of the present invention:
The present invention has realized with water for organic solvent, without topsoil, reduce disaster hidden-trouble, improve work situation, safety, environmental protection, saving resource, reduce costs, the obvious technology economy advantage such as have that aluminum plating glass pearl coating transfer effect is good, the reflective power of material is strong, washing fastness is good, snappiness is good.Meanwhile, the prepared finished product of the single-component water-based aluminum plating glass pearl of the present invention coating transfer adhesive is one canned, excellent storage stability, and without " swollen listening ", without " blackening " disadvantage, just, upper glue roller and equipment tool water clean easily application operating cylinder.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 60 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.3 part of wetting dispersing agent, 5 parts, reflective colorant, 0.8 part of rheology thickening auxiliary agent, 1.5 parts of adhesion promoters, 0.1 part of defoamer, 1 part of film coalescence aid, 0.33 part of water cross-linking agent, 30.97 parts of deionized waters.
Wherein, organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content 45 ± 2%, and PH=7.5 ± 0.5, viscosity (3# rotor/30r/min/25 DEG C) 2000 ± 200mpa.s, Tg value (DEG C)-15; Wetting dispersing agent is made up of the acetylenic diols ethoxy compound of 0.2 part and the polyethers organopolysiloxane of 0.1 part; Reflective colorant is 1000 order silicon dioxide coating type aluminium powders; Rheology thickening auxiliary agent is made up of the non-ionic type polyamine esters thickening material of 0.5 part and the swelling association type acrylic thickener of alkali of 0.3 part; Adhesion promoter is made up of the epoxide modified dimethyl siloxane of 0.5 part and the aminated acrylate copolymer of ethene of 1 part; Defoamer is made up of the paraffin mineral oil defoaming agent of 0.05 part and the alkoxyl group alkyne diol molecule defoamer of 0.05 part; Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester; Water cross-linking agent is made up of the aziridine of 0.03 part and amino, epoxy group(ing), the hydroxy kind compd B 30S (Shanghai Mo Tian Chemical Co., Ltd. product) by having bifunctional of 0.3 part.
A kind of preparation method of single-component water-based aluminum plating glass pearl coating transfer adhesive is as follows:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after 100 order double-layer nylon net filtrations of the material after being uniformly mixed.
Wherein, the product technology performance of preparation is: solid content (%) 33; Viscosity (3# rotor/30r/min/25 DEG C) 3700mpa.s; PH=7.5; Washing fastness (60 DEG C of washing/2h/ dry, 50 circulations) light retro-reflectivity is greater than 200; Package stability (25 DEG C/60d) is without swollenly listening, without blackening phenomena.
Embodiment 2
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 75 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.3 part of wetting dispersing agent, 6 parts, reflective colorant, 0.6 part of rheology thickening auxiliary agent, 1.5 parts of adhesion promoters, 0.1 part of defoamer, 2 parts of film coalescence aid, 0.33 part of water cross-linking agent, 14.17 parts of deionized waters.
Wherein, organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content 45 ± 2%, and PH=7.5 ± 0.5, viscosity (3# rotor/30r/min25 DEG C) 2000 ± 200mpa.s, Tg value (DEG C)-15; Wetting dispersing agent is the acetylenic diols ethoxy compound of 0.2 part and the polyethers organopolysiloxane composition of 0.1 part; Reflective colorant is made up of the 1200 order silicon dioxide coating type aluminium powders of 0.3 part and the 800 order silicon dioxide coating type aluminium powders of 0.3 part; Rheology thickening auxiliary agent is made up of 0.4 part of non-ionic type polyamine esters thickening material and 0.2 part of swelling association type acrylic thickener of alkali; Adhesion promoter is made up of 0.5 part of epoxide modified dimethyl siloxane and 1 part of aminated acrylate copolymer of ethene; Defoamer is made up of 0.05 part of paraffin mineral oil defoaming agent and 0.05 part of alkoxyl group alkyne diol molecule defoamer; Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester; Water cross-linking agent is made up of 0.03 part of aziridine and 0.3 part of amino, epoxy group(ing), hydroxy kind compd B 30S (Shanghai Mo Tian Chemical Co., Ltd. product) with bifunctional.
A kind of preparation method of single-component water-based aluminum plating glass pearl coating transfer adhesive is as follows:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after 100 order double-layer nylon net filtrations of the material after being uniformly mixed.
Wherein, the product technology performance of preparation is: solid content (%) 41.75; Viscosity (3# rotor/30r DEG C/min/25 DEG C) 3800mpa.s; PH=7.5; Washing fastness (60 DEG C of washing/2h/ dry, 50 circulations) light retro-reflectivity is greater than 200; Package stability (25 DEG C/60d) is without swollenly listening, without blackening phenomena.
Embodiment 3
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 65 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.5 part of wetting dispersing agent, 8 parts, reflective colorant, 0.6 part of rheology thickening auxiliary agent, 1.5 parts of adhesion promoters, 0.1 part of defoamer, 1 part of film coalescence aid, 0.33 part of water cross-linking agent, 22.97 parts of deionized waters.
Wherein, organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content 45 ± 2%, and PH=7.5 ± 0.5, viscosity (3# rotor/30r/min/25 DEG C) 2000 ± 200mpa.s, Tg value (DEG C)-15; Wetting dispersing agent is made up of 0.4 part of aliphatic polycarboxylic acid's salt compounds and 0.1 part of polyethers organopolysiloxane; Reflective colorant is 1000 order mica titanium silvery white pearlescences; Rheology thickening auxiliary agent is made up of 0.4 part of non-ionic type polyamine esters thickening material and 0.2 part of swelling association type acrylic thickener of alkali; Adhesion promoter is made up of 0.5 part of epoxide modified dimethyl siloxane and 1 part of aminated acrylate copolymer of ethene; Defoamer is made up of 0.05 part of paraffin mineral oil defoaming agent and 0.05 part of alkoxyl group alkyne diol molecule defoamer; Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester; Water cross-linking agent is made up of 0.03 part of aziridine and 0.3 part of amino, epoxy group(ing), hydroxy kind compd B 30S (Shanghai Mo Tian Chemical Co., Ltd. product) with bifunctional.
A kind of preparation method of single-component water-based aluminum plating glass pearl coating transfer adhesive is as follows:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after 100 order double-layer nylon net filtrations of the material after being uniformly mixed.
Wherein, the product technology performance of preparation is: solid content (%) 38.25; Viscosity (3# rotor/30r DEG C/min/25 DEG C) 3800mpa.s; PH=7.5; Washing fastness (60 DEG C of washing/2h/ dry, 50 circulations) light retro-reflectivity is greater than 200; Package stability (25 DEG C/60d) is without swollenly listening, without blackening phenomena.
Embodiment 4
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 62 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.3 part of wetting dispersing agent, 7.5 parts, reflective colorant, 0.8 part of rheology thickening auxiliary agent, 1.5 parts of adhesion promoters, 0.1 part of defoamer, 1 part of film coalescence aid, 0.33 part of water cross-linking agent, 26.47 parts of deionized waters.
Wherein, organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content 45 ± 2%, and PH=7.5 ± 0.5, viscosity (3# rotor/30r/min/25 DEG C) 2000 ± 200mpa.s, Tg value (DEG C)-15; Wetting dispersing agent is made up of 0.2 part of acetylenic diols ethoxy compound and 0.1 part of polyethers organopolysiloxane; Reflective colorant is 1000 order silicon dioxide coating type water aluminum-silver slurries of solid content 65%; Rheology thickening auxiliary agent is made up of 0.5 part of non-ionic type polyamine esters thickening material and 0.3 part of swelling association type acrylic thickener of alkali; Adhesion promoter is by 0.5 part of epoxide modified dimethyl siloxane and 1 part of aminated acrylate copolymer of ethene; Defoamer is made up of 0.05 part of paraffin mineral oil defoaming agent and 0.05 part of alkoxyl group alkyne diol molecule defoamer; Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester; Water cross-linking agent is made up of 0.03 part of aziridine and 0.3 part of amino, epoxy group(ing), hydroxy kind compd B 30S (Shanghai Mo Tian Chemical Co., Ltd. product) with bifunctional.
A kind of preparation method of single-component water-based aluminum plating glass pearl coating transfer adhesive is as follows:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim.
(4) after dispersed with stirring completes, by the tinning after 100 order double-layer nylon net filtrations of the material after being uniformly mixed.
Wherein, the product technology performance of preparation is: solid content (%) 33.78; Viscosity (3# rotor/30r DEG C/min/25 DEG C) 3600mpa.s; PH=7.5; Washing fastness (60 DEG C of washing/2h/ dry, 50 circulations) light retro-reflectivity is greater than 200; Package stability (25 DEG C/60d) is without swollenly listening, without blackening phenomena.
Embodiment 5
A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive, comprise following weight part composition: 68 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.3 part of wetting dispersing agent, 10 parts, reflective colorant, 0.8 part of rheology thickening auxiliary agent, 1.5 parts of adhesion promoters, 0.1 part of defoamer, 1 part of film coalescence aid, 0.33 part of water cross-linking agent, 17.97 parts of deionized waters.
Wherein, organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content 45 ± 2%, and PH=7.5 ± 0.5, viscosity (3# rotor/30r/min/25 DEG C) 2000 ± 200pa.s, Tg value (DEG C)-15; Wetting dispersing agent is made up of 0.2 part of aliphatic polycarboxylic acid's salt compounds and 0.1 part of polyethers organopolysiloxane; The 800 order water mica titaniums silvery white pearlite slurries that reflective colorant is 50% by 5 parts of solid contents 1800 order water mica titaniums silvery white pearlite slurries and 5 parts of solid contents are 60% form; Rheology thickening auxiliary agent is made up of 0.5 part of non-ionic type polyamine esters thickening material and 0.3 part of swelling association type acrylic thickener of alkali; Adhesion promoter is made up of 0.5 part of epoxide modified dimethyl siloxane and 1 part of aminated acrylate copolymer of ethene; Defoamer is made up of 0.05 part of paraffin mineral oil defoaming agent and 0.05 part of alkoxyl group alkyne diol point subclass defoamer; Film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester; Water cross-linking agent is made up of 0.03 part of aziridine and 0.3 part of amino, epoxy group(ing), hydroxy kind compd B 30S (Shanghai Mo Tian Chemical Co., Ltd. product) with bifunctional.
A kind of preparation method of single-component water-based aluminum plating glass pearl coating transfer adhesive is as follows:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after 100 order double-layer nylon net filtrations of the material after being uniformly mixed.
Wherein, the product technology performance of preparation is: solid content (%) 37.10; Viscosity (3# rotor/30r DEG C/min/25 DEG C) 3500mpa.s; PH=7.5; Washing fastness (60 DEG C of washing/2h/ dry, 50 circulations) light retro-reflectivity is greater than 200; Package stability (25 DEG C/60d) is without swollenly listening, without blackening phenomena.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned example embodiment, and in the situation that not deviating from spirit of the present invention or essential characteristic, can realize the present invention with other specific form.Therefore, no matter from which point, all should regard embodiment as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, is therefore intended to all changes by justice and scope that are equal to important document that drop on claim to include in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but be not that each embodiment only wraps by a technical scheme independently, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should make specification sheets as a whole, and the technical scheme in each embodiment also can, through appropriately combined, form other embodiments that it will be appreciated by those skilled in the art that.
Claims (10)
1. a single-component water-based aluminum plating glass pearl coating transfer adhesive, it is characterized in that, comprise following weight part composition: 50 parts-80 parts of organosilicon-modified acrylic and ester class microgel co-polymer emulsions thereof, 0.1 part-0.5 part of wetting dispersing agent, 1 part-15 parts, reflective colorant, 0.1 part-2 parts of rheology thickening auxiliary agents, 0.1 part-5 parts of adhesion promoters, 0.1 part-0.5 part of defoamer, 1 part-5 parts of film coalescence aid, 0.01 part-0.5 part of water cross-linking agent, 10 parts-40 parts of deionized waters.
2. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described organosilicon-modified acrylic and ester class microgel co-polymer emulsion thereof are anionic, solid content is 45 ± 2%, pH value is 7.5 ± 0.5, viscosity is 2000 ± 200mpa.s, and Tg value is-10 ± 10 DEG C.
3. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described wetting dispersing agent is one or more in aliphatic polycarboxylic acid's salt, segmented copolymer and organic silicon solution, acetylenic diols ethoxy compound, polyether-modified organopolysiloxane, polyether polyester modification by copolymerization organopolysiloxane.
4. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described reflective colorant is one or more in 200-2000 order silicon dioxide coating type aluminium powder, 200-2000 order silicon dioxide coating type water aluminum-silver slurry, 200-2000 order mica titanium silvery white pearlescence, 200-2000 order water mica titanium silvery white pearlite slurry.
5. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described rheology thickening auxiliary agent is one or more in non-ionic type polyamine esters thickening material, association type acrylic thickener, the swelling association type acrylic thickener of alkali.
6. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described adhesion promoter is one or more in 3-glycidyl ether oxygen base oxypropyl trimethyl silane, epoxide modified dimethyl siloxane, the aminated acrylate copolymer of ethene.
7. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, it is characterized in that, described defoamer is polyether modified siloxane class, modified organic silicon class, paraffin mineral oils, and alkoxyl group alkyne diol divides one or more in subclass, alkyne diol molecule defoamer.
8. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, is characterized in that, described film coalescence aid agent is 2,2,4-trimethylammonium-1,3-pentanediol diisobutyl ester, alcohol ester-12, one or more in propylene glycol monobutyl ether.
9. the single-component water-based aluminum plating glass pearl of one according to claim 1 coating transfer adhesive, is characterized in that, described water cross-linking agent is to have bifunctional by one or more in amino, epoxy group(ing), hydroxy kind compound and aziridine and polymine.
10. a preparation method for the single-component water-based aluminum plating glass pearl coating transfer adhesive as described in as arbitrary in claim 1-9, comprises the following steps:
(1) ratio takes required material by weight;
(2) start stirrer, under 50-100r/min speed stirs, taken material is put into stainless steel stirred vessel successively;
(3), after feeding intake, stirrer, under 400-500r/min speed stirs, continues dispersed with stirring 20-30mim;
(4) after dispersed with stirring completes, by the tinning after double-layer leaching net filters of the material after being uniformly mixed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410111800.0A CN104059576B (en) | 2014-03-20 | 2014-03-20 | A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410111800.0A CN104059576B (en) | 2014-03-20 | 2014-03-20 | A kind of single-component water-based aluminum plating glass pearl coating transfer adhesive and preparation method thereof |
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| CN104059576B CN104059576B (en) | 2018-02-02 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163409A (en) * | 1996-04-21 | 1997-10-29 | 安徽省反光材料工业公司 | Material and technology for producing reflective film |
| WO1998045735A1 (en) * | 1997-04-04 | 1998-10-15 | Minnesota Mining And Manufacturing Company | Use of a crystalline bead bond layer in a retroreflective article |
| CN101407654A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | High peeling environment-friendly type aqueous transfer coating and use thereof |
| CN101698788A (en) * | 2009-09-22 | 2010-04-28 | 北京高盟化工有限公司 | Adhesive for light-reflecting particles and preparation method thereof |
-
2014
- 2014-03-20 CN CN201410111800.0A patent/CN104059576B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1163409A (en) * | 1996-04-21 | 1997-10-29 | 安徽省反光材料工业公司 | Material and technology for producing reflective film |
| WO1998045735A1 (en) * | 1997-04-04 | 1998-10-15 | Minnesota Mining And Manufacturing Company | Use of a crystalline bead bond layer in a retroreflective article |
| CN101407654A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | High peeling environment-friendly type aqueous transfer coating and use thereof |
| CN101698788A (en) * | 2009-09-22 | 2010-04-28 | 北京高盟化工有限公司 | Adhesive for light-reflecting particles and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 于范芹: ""反光材料的转移法加工技术"", 《印染》 * |
| 反光标志膜课题组: ""道路反光标志膜的研究"", 《公路交通科技》 * |
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