CN103788831A - Corrosion-proof ice-covering-proof coating - Google Patents
Corrosion-proof ice-covering-proof coating Download PDFInfo
- Publication number
- CN103788831A CN103788831A CN201410046117.3A CN201410046117A CN103788831A CN 103788831 A CN103788831 A CN 103788831A CN 201410046117 A CN201410046117 A CN 201410046117A CN 103788831 A CN103788831 A CN 103788831A
- Authority
- CN
- China
- Prior art keywords
- covering
- ice
- proof
- resin
- protection against
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to the field of corrosion-proof ice-covering-proof coatings, and particularly relates to a corrosion-proof ice-covering-proof coating. The corrosion-proof ice-covering-proof coating comprises the following components in percentage by weight: 15%-30% of epoxy resin, 10%-15% of fluoroolefin resin, 15%-40% of nanometer silicon oxide, 10%-20% of solidifying agents, 1%-5% of toughening resin, 5%-10% of titanium dioxide blending agents, 15%-30% of fluorinated acrylate modified polyurethane resin and 5%-15% of organic solvents, wherein each titanium dioxide blending agent comprises polyurethane, biuret, polyester J4, butyl alcohol, ethanol ethyl ester, petroleum type dimethyl benzene, titanium dioxide, fine particle calcium carbonate, talcum powder, sodium pentachlorophenate and tri-butyl alcohol, and the weight ratio of polyurethane to biuret to polyester J4 to butyl alcohol to ethanol ethyl ester to petroleum type dimethyl benzene to titanium dioxide to fine particle calcium carbonate to talcum powder to sodium pentachlorophenate to tri-butyl alcohol is (1.5-2.5):(1-2):(1.5-2):(1.5-2):(1-1.5):(2-2.5):(1.5-2):(1-2):(1-1.5):(0.1-0.3):(0.3-0.5). The corrosion-proof ice-covering-proof coating disclosed by the invention has good adhesive force, can meet the requirements for use conditions of an oil drill rod in a using process in a cold place, and has the advantages of acid resistance, alkali resistance, corrosion proofing and ice-covering proofing.
Description
Technical field
The present invention relates to the ice-covering-proof paint field of a kind of protection against corrosion, be specifically related to the ice-covering-proof coating of a kind of protection against corrosion.
Background technology
paint is that one can firmly cover body surface, plays the ice-covering-proof coating of a kind of protection against corrosion of chemical mixture of protection, decoration, mark and other special purposes.China's a kind of protection against corrosion ice-covering-proof more authoritative " coating process that a kind of protection against corrosion is ice-covering-proof " book of coating circle is definition like this: " the ice-covering-proof coating of a kind of protection against corrosion is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." belonging to organic chemical industry's macromolecular material, the film forming belongs to macromolecular compound type.According to the classification of current Chemicals of modern times, the ice-covering-proof coating of a kind of protection against corrosion belongs to fine chemical product.The modern ice-covering-proof coating of a kind of protection against corrosion is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.For the ice-covering-proof coating of a kind of protection against corrosion of beam hanger drilling rod, also there is no in the market the special ice-covering-proof coating of a kind of protection against corrosion, meet the applying working condition of beam hanger drilling rod, high temperature resistant, wear-resisting, shock-resistant, acid-fast alkali-proof also will meet ice-covering-proof.
Summary of the invention
in order to address the above problem, the present invention proposes the ice-covering-proof coating of a kind of protection against corrosion, can meet cold zone applying working condition, can acid-fast alkali-proof when use.
In order to reach foregoing invention problem, the present invention proposes following technical scheme:
the coating that a kind of protection against corrosion is ice-covering-proof, the ice-covering-proof coating of this kind of protection against corrosion comprises following component and % by weight content: epoxy resin 15-30%, fluoroolefin resin 10-15%, nano-silicon oxide compound 15-40%, solidifying agent 10-20%, toughened resin 1-5 % by weight, titanium dioxide mixture 5-10 % by weight, fluorinated acrylate modified polyurethane resin 15-30%, organic solvent 5-15%; Described titanium dioxide mixture is Polyurethane second, contracting two urine, polyester J
4, butanols, ethanol second fat, petroleum type dimethylbenzene, titanium dioxide, fine particle calcium carbonate, talcum powder, sodium pentachlorophenate and three butanols composition, their weight proportion is 1.5-2.5: 1-2: 1.5-2: 1.5-2: 1-1.5: 2-2.5: 1.5-2: 1-2: 1-1.5: 0.1-0.3: 0.3-0.5.
Described fluoroolefin resin comprises the one that is selected from poly-three fluoro ethyl propenes, tetrafluoroethylene, daiflon.
Described organic solvent is one or more in ester class, ketone and solvent of ether ester type; Described esters solvent is butylacetate or ethyl acetate; Described ketones solvent is acetone or methyl ethyl ketone; Described solvent of ether ester type is ethylene glycol ether acetate, 2-Butoxyethyl acetate, 1-Methoxy-2-propyl acetate or propandiol butyl ether acetic ester.
Described solidifying agent comprises the one being selected from resol, polyamide resin.
Described epoxy resin is bisphenol A epoxide resin, and it comprises the one being selected from E03, E06, E14, E44, E42 epoxy resin.
The coating material production course of processing that described a kind of protection against corrosion is ice-covering-proof, first epoxy resin, fluoroolefin resin, toughened resin, fluorinated acrylate modified polyurethane resin are rendered in container and stirred successively according to the ratio of formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce rotating speed and require to add nano-silicon oxide compound according to formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce again rotating speed and require to add titanium dioxide mixture according to formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce again rotating speed and require to add organic solvent according to formula, disperse 15-45min by the speed of 1500-3000r/min; After disperseing completely, on shredder, grind, note as requested the temperature 25-55 ℃ of the following and material outlet of the fineness 45 μ m of discharging; The solidifying agent that material after grinding completes is allocated certain proportioning in actual use according to the requirement of formula uses.
Advantage of the present invention is that sticking power is good, can meet the applying working condition of beam hanger drilling rod in the local use procedure of cold, acid-fast alkali-proof, and protection against corrosion, ice-covering-proof.
Embodiment
The present invention is further illustrated by following unrestriced embodiment, but need to understand described embodiment only in order to the present invention, but not in order to limit the scope of the invention.
Embodiment 1
Adopt following formula:
Table 1
| Material | Mass percent/% |
| Bisphenol A epoxide resin E14 | 20 |
| Teflon resin | 10 |
| Nano-silicon oxide compound | 24 |
| Polyamide resin | 10 |
| Toughened resin | 1 |
| Titanium dioxide mixture | 5 |
| Fluorinated acrylate modified polyurethane resin | 25 |
| Methyl ethyl ketone | 5 |
Coating ice-covering-proof a kind of protection against corrosion of prepared beam hanger drilling rod is adopted the constructional method of the routines such as brushing, obliterating, manual roller construction, air gun or airless spray gun spraying, electrostatic spraying, thermospray, roller coat or dip-coating be coated on beam hanger drilling rod, its performance is as shown in table 2.
Table 2
| Project | Requirement | Result |
| Condition in container | Before stirring/after stirring | Without lump/be uniform state |
| Application property | Brush two-layer | Accessible |
| Appearance of film | Splitting resistance | Flawless |
| Contrast ratio (white and light color) | Be greater than 95 | Meet the requirements |
| Artificial weathering ageing resistance | Non-foaming flawless, efflorescence≤1 grade, variable color≤2 grade of not peeling off of 1000h | Reach requirement |
| Acidproof | 10%H 2SO 4 | Unchanged |
| Alkaline-resisting | 10%NaOH | Unchanged |
| Ice-covering-proof | Under rime condition, keep 12 h | Without freezing |
Embodiment 2
Adopt following formula:
Table 3
| Material | Mass percent/% |
| Bisphenol A epoxide resin E03 | 15 |
| Poly-trifluoro ethylene-propylene resin | 12 |
| Nano-silicon oxide compound | 20 |
| Resol | 15 |
| Toughened resin | 3 |
| Titanium dioxide mixture | 10 |
| Fluorinated acrylate modified polyurethane resin | 15 |
| Ethyl acetate | 10 |
Coating ice-covering-proof a kind of protection against corrosion of prepared beam hanger drilling rod is adopted the constructional method of the routines such as brushing, obliterating, manual roller construction, air gun or airless spray gun spraying, electrostatic spraying, thermospray, roller coat or dip-coating be coated on beam hanger drilling rod, its performance is as shown in table 4.
Table 4
| Project | Requirement | Result |
| Condition in container | Before stirring/after stirring | Without lump/be uniform state |
| Application property | Brush two-layer | Accessible |
| Appearance of film | Splitting resistance | Flawless |
| Contrast ratio (white and light color) | Be greater than 95 | Meet the requirements |
| Artificial weathering ageing resistance | Non-foaming flawless, efflorescence≤1 grade, variable color≤2 grade of not peeling off of 1000h | Reach requirement |
| Acidproof | 10%H 2SO 4 | Unchanged |
| Alkaline-resisting | 10%NaOH | Unchanged |
| Ice-covering-proof | Under rime condition, keep 12 h | Without freezing |
Embodiment 3
Adopt following formula:
Table 5
| Material | Mass percent/% |
| Bisphenol A epoxide resin E42 | 20 |
| Daiflon | 10 |
| Nano-silicon oxide compound | 24 |
| Resol | 10 |
| Toughened resin | 1 |
| Titanium dioxide mixture | 5 |
| Fluorinated acrylate modified polyurethane resin | 25 |
| Ethylene glycol ether acetate | 5 |
Coating ice-covering-proof a kind of protection against corrosion of prepared beam hanger drilling rod is adopted the constructional method of the routines such as brushing, obliterating, manual roller construction, air gun or airless spray gun spraying, electrostatic spraying, thermospray, roller coat or dip-coating be coated on beam hanger drilling rod, its performance is as shown in table 6.
Table 6
| Project | Requirement | Result |
| Condition in container | Before stirring/after stirring | Without lump/be uniform state |
| Application property | Brush two-layer | Accessible |
| Appearance of film | Splitting resistance | Flawless |
| Contrast ratio (white and light color) | Be greater than 95 | Meet the requirements |
| Artificial weathering ageing resistance | Non-foaming flawless, efflorescence≤1 grade, variable color≤2 grade of not peeling off of 1000h | Reach requirement |
| Acidproof | 10%H 2SO 4 | Unchanged |
| Alkaline-resisting | 10%NaOH | Unchanged |
| Ice-covering-proof | Under rime condition, keep 12 h | Without freezing |
Claims (6)
1. the coating that protection against corrosion is ice-covering-proof, it is characterized in that the ice-covering-proof coating of this kind of protection against corrosion comprises following component and % by weight content: epoxy resin 15-30%, fluoroolefin resin 10-15%, nano-silicon oxide compound 15-40%, solidifying agent 10-20%, toughened resin 1-5 % by weight, titanium dioxide mixture 5-10 % by weight, fluorinated acrylate modified polyurethane resin 15-30%, organic solvent 5-15%; Described titanium dioxide mixture is Polyurethane second, contracting two urine, polyester J
4, butanols, ethanol second fat, petroleum type dimethylbenzene, titanium dioxide, fine particle calcium carbonate, talcum powder, sodium pentachlorophenate and three butanols composition, their weight proportion is 1.5-2.5: 1-2: 1.5-2: 1.5-2: 1-1.5: 2-2.5: 1.5-2: 1-2: 1-1.5: 0.1-0.3: 0.3-0.5.
2. the ice-covering-proof coating of a kind of protection against corrosion according to claim 1, is characterized in that described fluoroolefin resin comprises the one that is selected from poly-three fluoro ethyl propenes, tetrafluoroethylene, daiflon.
3. the ice-covering-proof coating of a kind of protection against corrosion according to claim 1, is characterized in that described organic solvent is one or more in ester class, ketone and solvent of ether ester type; Described esters solvent is butylacetate or ethyl acetate; Described ketones solvent is acetone or methyl ethyl ketone; Described solvent of ether ester type is ethylene glycol ether acetate, 2-Butoxyethyl acetate, 1-Methoxy-2-propyl acetate or propandiol butyl ether acetic ester.
4. the ice-covering-proof coating of a kind of protection against corrosion according to claim 1, is characterized in that described solidifying agent comprises the one being selected from resol, polyamide resin.
5. the ice-covering-proof coating of a kind of protection against corrosion according to claim 1, is characterized in that described epoxy resin is bisphenol A epoxide resin, and it comprises the one being selected from E03, E06, E14, E44, E42 epoxy resin.
6. the ice-covering-proof coating of a kind of protection against corrosion according to claim 1, it is characterized in that the described ice-covering-proof coating material production course of processing of a kind of protection against corrosion, first epoxy resin, fluoroolefin resin, toughened resin, fluorinated acrylate modified polyurethane resin are rendered in container and stirred successively according to the ratio of formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce rotating speed and require to add nano-silicon oxide compound according to formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce again rotating speed and require to add titanium dioxide mixture according to formula, disperse 5-20min by the speed of 1500-3000r/min; Suitably reduce again rotating speed and require to add organic solvent according to formula, disperse 15-45min by the speed of 1500-3000r/min; After disperseing completely, on shredder, grind, note as requested the temperature 25-55 ℃ of the following and material outlet of the fineness 45 μ m of discharging; The solidifying agent that material after grinding completes is allocated certain proportioning in actual use according to the requirement of formula uses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410046117.3A CN103788831A (en) | 2014-02-10 | 2014-02-10 | Corrosion-proof ice-covering-proof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410046117.3A CN103788831A (en) | 2014-02-10 | 2014-02-10 | Corrosion-proof ice-covering-proof coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103788831A true CN103788831A (en) | 2014-05-14 |
Family
ID=50664906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410046117.3A Pending CN103788831A (en) | 2014-02-10 | 2014-02-10 | Corrosion-proof ice-covering-proof coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103788831A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104610872A (en) * | 2015-01-28 | 2015-05-13 | 芜湖县双宝建材有限公司 | Water-tolerant and ageing-resistant waterborne polyurethane coating |
| CN105062168A (en) * | 2015-08-11 | 2015-11-18 | 国网山东省电力公司临沂供电公司 | Ice-over resistant coating for feeder cable |
| CN106590388A (en) * | 2016-12-15 | 2017-04-26 | 苏州富艾姆工业设备有限公司 | Strong-acid-resisting high-strength hanging beam and preparation method thereof |
| CN107573768A (en) * | 2017-10-18 | 2018-01-12 | 江苏建中能源科技有限公司 | A kind of polyurethane fluorine carbon anticorrosive paint formula and its preparation technology |
| CN113667374A (en) * | 2021-07-27 | 2021-11-19 | 宁夏星邦豹丰涂料科技有限公司 | Water-based epoxy thick-paste anticorrosive paint for petroleum steel pipes |
| US11459482B2 (en) | 2020-06-19 | 2022-10-04 | Pall Corporation | Icephobic coating and coated articles |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093727A (en) * | 1993-04-16 | 1994-10-19 | 保定市工艺建材厂 | High-bright enamel glaze coating |
| CN101230224A (en) * | 2008-02-27 | 2008-07-30 | 孟中 | Fluorosilicone rubber nano composite alloy three-proof paint and production method thereof |
| CN101270255A (en) * | 2007-03-21 | 2008-09-24 | 上海赛能石油管道特种涂料有限公司 | TC oil well pipe paint |
| CN103305112A (en) * | 2013-06-27 | 2013-09-18 | 浙江大学 | Environment-friendly coating with anti-icing function and preparation method thereof |
| CN103483890A (en) * | 2013-09-12 | 2014-01-01 | 西安交通大学 | Polymer ice-coating-preventing coating containing modified nano particles and preparing method thereof |
-
2014
- 2014-02-10 CN CN201410046117.3A patent/CN103788831A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093727A (en) * | 1993-04-16 | 1994-10-19 | 保定市工艺建材厂 | High-bright enamel glaze coating |
| CN101270255A (en) * | 2007-03-21 | 2008-09-24 | 上海赛能石油管道特种涂料有限公司 | TC oil well pipe paint |
| CN101230224A (en) * | 2008-02-27 | 2008-07-30 | 孟中 | Fluorosilicone rubber nano composite alloy three-proof paint and production method thereof |
| CN103305112A (en) * | 2013-06-27 | 2013-09-18 | 浙江大学 | Environment-friendly coating with anti-icing function and preparation method thereof |
| CN103483890A (en) * | 2013-09-12 | 2014-01-01 | 西安交通大学 | Polymer ice-coating-preventing coating containing modified nano particles and preparing method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104610872A (en) * | 2015-01-28 | 2015-05-13 | 芜湖县双宝建材有限公司 | Water-tolerant and ageing-resistant waterborne polyurethane coating |
| CN105062168A (en) * | 2015-08-11 | 2015-11-18 | 国网山东省电力公司临沂供电公司 | Ice-over resistant coating for feeder cable |
| CN106590388A (en) * | 2016-12-15 | 2017-04-26 | 苏州富艾姆工业设备有限公司 | Strong-acid-resisting high-strength hanging beam and preparation method thereof |
| CN107573768A (en) * | 2017-10-18 | 2018-01-12 | 江苏建中能源科技有限公司 | A kind of polyurethane fluorine carbon anticorrosive paint formula and its preparation technology |
| US11459482B2 (en) | 2020-06-19 | 2022-10-04 | Pall Corporation | Icephobic coating and coated articles |
| CN113667374A (en) * | 2021-07-27 | 2021-11-19 | 宁夏星邦豹丰涂料科技有限公司 | Water-based epoxy thick-paste anticorrosive paint for petroleum steel pipes |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103788831A (en) | Corrosion-proof ice-covering-proof coating | |
| CN102719162B (en) | Water-based artificial granite paint | |
| CN108949017A (en) | Aqueous high-temperature-resistant paint and preparation method thereof | |
| CN103666201A (en) | Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof | |
| CN106752272A (en) | A kind of aluminium section bar protective coating preparation adhesion promoter | |
| CN105295495A (en) | Water-based environmentally friendly wood putty and preparation method | |
| WO2022088114A1 (en) | Water-based paint special for glass substrates and preparation method therefor | |
| CN104263146A (en) | Water-soluble electroplating glazing oil and manufacturing method thereof | |
| CN104962179B (en) | It is a kind of suitable for priming paint of antitheft door and preparation method thereof | |
| CN100366686C (en) | Silicon fluoride super-amphiphobic non-stick coating material | |
| CN106947354A (en) | Aqueous acrylic modified two component epoxy paint for priming paint and top lacquer and preparation method thereof | |
| CN105694714A (en) | Medical sterilization siloxane coating and preparing method thereof | |
| CN105038489A (en) | Modified acrylic resin energy-conservation and environmental-friendly coating for product packing metal box | |
| CN108531066A (en) | A kind of preparation method and application of aqueous peelable film coating | |
| JP5981636B2 (en) | Zinc-based composite materials and use thereof | |
| CN108485412A (en) | It is a kind of to can be used for the wet on wet aqueous high temperature plain color paint and preparation method thereof for exempting from middle painting system | |
| CN103740271A (en) | Wear-resistant and impact-resistant coating | |
| CN107057532A (en) | A kind of graphene compound ethylene base ester anticorrosive paint and preparation method thereof | |
| CN111117331A (en) | Colorful water-based paint with fluorescent effect | |
| CN115260881A (en) | Low-temperature curing polyester type powder coating and preparation method thereof | |
| CN105602400B (en) | A kind of preparation method of environment-friendly water-based metal color steel tile coating coating | |
| WO2022088119A1 (en) | Water-based paint highly imitating aluminum composite panel, and preparation method for water-based paint | |
| CN104073078B (en) | A kind of water soluble amino acrylate resin coating and preparation method thereof | |
| CN106752273A (en) | A kind of aluminium section bar protective coating dedicated weather-proof agent and preparation method thereof | |
| CN113999607B (en) | Film-coated adhesive coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140514 |