CN105038474A - Modified acrylic resin energy conservation and environment protection coating for suspended ceiling print-coating plate - Google Patents
Modified acrylic resin energy conservation and environment protection coating for suspended ceiling print-coating plate Download PDFInfo
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Abstract
The invention provides a modified acrylic resin energy conservation and environment protection coating for a suspended ceiling print-coating plate. The coating adopts organic fluorine-silicon modified acrylic resin, and therefore the coating has the advantages that the excellent flame retardance and wear resistance property are achieved, the curing speed is high, the better mechanical property, aging resistance property and chemical corrosion resistance property are achieved, the adhesive force is high, the ductility is good, the high temperature resistance property is achieved, the service life is long, the processing technology is changed, roller coating processing is concentratedly completed on a plate blank of the suspended ceiling print-coating plate, the processing procedure is simplified, and a painting workshop does not need to be separately arranged.
Description
Technical field
The present invention relates to the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate.
Background technology
Acrylic resin is the resin be made up of acrylate and methacrylic ester and other olefinic type monomers copolymerization, compared with other synthetic macromolecule resins, acrylic resin has many outstanding advantages, as fast light, the weathering resistance of excellence, open air weather resistance of being exposed to the sun is strong, ultraviolet resistance irradiates and not easily decomposes and turn yellow, original gloss and color and luster can be kept for a long time, good heat resistance, the chemical such as good acid-and base-resisting, salt, grease and washing composition are had to stain and corrosive nature, fabulous snappiness and minimum pigment reactivity.Therefore, have a wide range of applications automobile, household electrical appliances, art metal furniture, coiled material industry, instrument, building, textiles, woodwork, papermaking and plastics etc. are industrial.
But the heat that the linear structure of acrylic resin causes sticks cold short, anti-after-tackiness and thermotolerance is not good etc. that shortcoming has a definite limitation to its range of application.The equal phase structure of acrylic resin makes its cold tolerance and resistance toheat be difficult to take into account, and as increased resistance to low temperature, then can lose resistance to elevated temperatures, vice versa, and thus common acrylic acid or the like coating and decorating material just inevitably exists above-mentioned shortcoming.
By with other monomers, resin copolymerization and modification, the various aspects of performance of coating can be changed, make the coating of multiple different performance and Application Areas.
Silicone resin has the performances such as excellent thermotolerance, weathering resistance, hydrophobicity performance and gloss retention, but silicone resin exists following shortcoming: can not normal temperature self-drying, and to the poor adhesive force of bottom, organic solvent resistance is poor, and price is more expensive.Therefore, by this two family macromolecules Material cladding together, preparing the novel material of both's excellent properties, is the problem of extremely people's attention at present.
At present, the following organosilicon modified crylic acid resin coating of domestic existence:
Chinese patent 201310464964.7, discloses a kind of organosilicon modified crylic acid resin frie retardant coating, and comprise A, B bis-component, component A comprises: organosilicon modified crylic acid resin 40 ~ 50 parts; 10 ~ 30 parts, the etherified aminoresin of pregnancy; BYK defoamer 0.1 ~ 1 part; Flow agent 0.1 ~ 1 part; Auxiliary rheological agents 0.1 ~ 1 part; Active silica 5 ~ 15 parts; Tinting pigment 10 ~ 20 parts; Rust-stabilising pigment 10 ~ 20 parts; Described B component is modified silane coupler 0.5 ~ 5 part.But its organosilicon modified crylic acid resin used is existing, this existing resin, and price is high, and the performances such as oleophobic, hydrophobic, resistant to chemical media are insuperior.
In addition, the application mode of existing acrylic resin paint adopts spray-coating mostly, such as Chinese patent CN201310607469.7, disclose a kind of thermosetting acrylic resin used for powder coating, this resin ester is equipped with the thermosetting powder coating(s) that unclassified stores is made, the film formed after spraying, has excellent weathering resistance, good flow leveling, excellent surface hardness and high-luster, weather resistance and decorate properties; Can be used for indoor or outdoors shape or material of construction.TGIC can be substituted to a certain extent, avoid the use of toxic substance.
But spraying is by spray gun or dish-style spraying gun, by means of pressure or centrifugal force, is dispersed into even and fine droplet, is applied over the coating process on coated article surface.Subject matter in spraying is the coating cloud of high dispersing and the solvent (i.e. volatile organic contaminant, VOCs) evaporated, and both contaminate environment, are unfavorable for HUMAN HEALTH, waste coating again, cause financial loss.Volatilization, the coating be diffused in air, then form volatile organic contaminant, be detrimental to health.At painting workshop, coating, as the main source of volatile organic contaminant, is easy to cause acute poisoning during volatile organic compounds excessive concentration in air in painting workshop, and the lighter there will be headache, dizziness, cough, Nausea and vomiting or is dead drunk liquor-saturated shape; Severe one there will be liver poisoning and even goes into a coma very soon, and what have also may be in peril of one's life.Treat for a long time, in the painting workshop of volatile organic compounds pollution, can chronic poisoning be caused, damage liver and neural system, cause general weakness, drowsiness, skin pruritus etc.What have also may cause endocrine disturbance, affects sexual function; Benzene and dimethylbenzene can also damage system, so that cause leukemia.
Summary of the invention
The object of the present invention is to provide the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate, described coating adopts organic fluorinated silicone modified acrylic resin, described coating is made to have excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by furred ceiling printing plate slab, simplify machining clearance, without the need to arranging painting workshop separately.
For achieving the above object, the technical solution used in the present invention is:
The acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 70 ~ 80 parts, hydroxypropylcellulose: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, diamino-cyclohexane: 10 ~ 15 parts, MBT: 3 ~ 8 parts, copper stearate: 5 ~ 15 parts, Sodium dodecylbenzene sulfonate: 1 ~ 5 part, pure aluminium silicate: 10 ~ 20 parts, polyester resin change properties of organic silicon oxygen alkane: 2 ~ 6 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 ~ 5 parts, zinc oxide: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, tertiary carbonic acid glycidyl ester: 30 ~ 40 parts, water: 80 ~ 90 parts.
Preferably, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 76 parts, hydroxypropylcellulose: 5 parts, aminoresin: 6 parts, diamino-cyclohexane: 12 parts, MBT: 4 parts, copper stearate: 14 parts, Sodium dodecylbenzene sulfonate: 3 parts, pure aluminium silicate: 18 parts, polyester resin change properties of organic silicon oxygen alkane: 5 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 parts, zinc oxide: 6 parts, diatomite: 7 parts, polyamide wax pulp: 8 parts, tertiary carbonic acid glycidyl ester: 35 parts, water: 90 parts.
Preferably, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 70 parts, hydroxypropylcellulose: 3 parts, aminoresin: 8 parts, diamino-cyclohexane: 13 parts, MBT: 3 parts, copper stearate: 5 parts, Sodium dodecylbenzene sulfonate: 5 parts, pure aluminium silicate: 15 parts, polyester resin change properties of organic silicon oxygen alkane: 2 parts, polyoxyethylene polyoxypropylene glyceryl ether: 3 parts, zinc oxide: 5 parts, diatomite: 4 parts, polyamide wax pulp: 8 parts, tertiary carbonic acid glycidyl ester: 30 parts, water: 85 parts.
Preferably, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 74 parts, hydroxypropylcellulose: 4 parts, aminoresin: 6 parts, diamino-cyclohexane: 12 parts, MBT: 4 parts, copper stearate: 10 parts, Sodium dodecylbenzene sulfonate: 3 parts, pure aluminium silicate: 13 parts, polyester resin change properties of organic silicon oxygen alkane: 4 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 parts, zinc oxide: 6 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, tertiary carbonic acid glycidyl ester: 30 parts, water: 80 parts.
Separately, the preparation of described organosilicon modified crylic acid resin, comprises the steps:
1) by the vinylformic acid that 1 ~ 5 quality is divided, the ethyl propenoate that 30 ~ 40 quality are divided, the butyl acrylate that 5 ~ 10 quality are divided, the Isooctyl acrylate monomer that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
2) the propenyl Trimethoxy silane 20 ~ 30 quality divided, the octamethylcyclotetrasiloxane that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided, the dodecyl sulphate that 0.5 ~ 2 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
3) reaction flask is got, add step 1) gained emulsion, after being heated to 80 ~ 85 DEG C, insulation 1 ~ 2h, then in described reaction flask, step 2 is dripped) gained emulsion, at the uniform velocity drip, dropwise in 1 ~ 1.5h, at 80 DEG C, insulation 2 ~ 3h, be cooled to room temperature, adjust ph, to neutral, filters to obtain described organosilicon modified crylic acid resin.
Separately having, step 1) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.
Again, step 2) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.
Further, it is characterized in that, described coating is coated to furred ceiling printing plate steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
Beneficial effect of the present invention is:
Described coating adopts organic fluorinated silicone modified acrylic resin, there is excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by furred ceiling printing plate slab, simplify machining clearance, without the need to arranging painting workshop separately.
In the furred ceiling printing plate slab stage namely by roller coat by paint spraying provided by the present invention in furred ceiling printing plate steel slab surface, form coating, directly can carry out following process, obtain shaping furred ceiling printing plate, even if baroque furred ceiling printing plate structure, also paint spraying is completed in the slab stage, without the need to follow-up application, to instead of in existing technique " be first processed into desired shape; and then spraying obtains moulding product " technique, coating and furred ceiling printing plate slab strong adhesion, can not crack because of complete processing or come off.Owing to being the roller coating technology replacement spraying coating process of the shaping quick-drying of roller coat, during application, the availability of coating can reach more than 90%, decrease the volatilization in air and waste, the VOCs that effective reduction causes coating volatilization to be formed because of spraying, VOCs quantity discharged≤420ppm in roller coat workshop, coating environment protecting is good.The furred ceiling printing plate goods that roller coat application completes are processed, the curved performance of furred ceiling printing plate T can reach 0T (after the finished product slab after roller coat 180 ° bending, completely seamlessly to close up, coating does not burst and comes off) or 1T (after slab twice 180 ° of bendings, outermost painting charge level does not come off, do not burst), ensure furred ceiling printing plate quality.
Described organosilicon modified crylic acid resin is prepared from by the mode of core-shell emulsion polymerization, obtain heterogeneous latex particle, after tackiness is shouldered when effectively can promote film formation at low temp performance, the high temperature of coating, and make coating have excellent package stability, after being coated in steel slab surface formation film, at high temperature can keep higher hardness, the wear resisting property of coating is greatly improved.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment does not limit the scope of the invention.
Table 1 is furred ceiling printing plate a kind of described in the embodiment of the present invention acrylic resin modified energy-saving and environment-friendly paint composition quality mark list.Table 2 prepares step 1 in organosilicon modified crylic acid resin for described in the embodiment of the present invention) and step 2) middle emulsion ingredient lists.Table 3 is furred ceiling printing plate acrylic resin modified energy-saving and environment-friendly paint performance perameter list a kind of described in the embodiment of the present invention.Table 4 is furred ceiling printing plate a kind of described in the embodiment of the present invention coating performance parameter list of acrylic resin modified energy-saving and environment-friendly paint roller coat after furred ceiling printing plate steel slab surface.
Described furred ceiling printing plate is as follows by acrylic resin modified energy-saving and environment-friendly paint compound method:
Each component is added in high speed dispersor, after stirring, high speed dispersion 30 ~ 60min, stirring, discharging, filtration, packaging, warehouse-in.
Wherein, described organosilicon modified crylic acid resin process for preparation is as follows:
1) by the vinylformic acid that 1 ~ 5 quality is divided, the ethyl propenoate that 30 ~ 40 quality are divided, the butyl acrylate that 5 ~ 10 quality are divided, the Isooctyl acrylate monomer that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
2) the propenyl Trimethoxy silane 20 ~ 30 quality divided, the octamethylcyclotetrasiloxane that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided, the dodecyl sulphate that 0.5 ~ 2 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
3) reaction flask is got, add step 1) gained emulsion, after being heated to 80 ~ 85 DEG C, insulation 1 ~ 2h, then in described reaction flask, step 2 is dripped) gained emulsion, at the uniform velocity drip, dropwise in 1 ~ 1.5h, at 80 DEG C, insulation 2 ~ 3h, be cooled to room temperature, adjust ph, to neutral, filters to obtain described organosilicon modified crylic acid resin.
Wherein, step 1) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.Step 2) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.
Table 1 (unit: part)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Organosilicon modified crylic acid resin | 70 | 75 | 80 | 78 | 73 |
| Hydroxypropylcellulose | 3 | 5 | 4 | 3 | 5 |
| Aminoresin | 8 | 10 | 7 | 5 | 6 |
| Diamino-cyclohexane | 13 | 10 | 12 | 15 | 11 |
| MBT | 3 | 8 | 7 | 6 | 5 |
| Copper stearate | 5 | 10 | 15 | 12 | 13 |
| Sodium dodecylbenzene sulfonate | 5 | 4 | 3 | 2 | 1 |
| Pure aluminium silicate | 15 | 10 | 18 | 20 | 13 |
| Polyester resin change properties of organic silicon oxygen alkane | 2 | 5 | 4 | 3 | 6 |
| Polyoxyethylene polyoxypropylene glyceryl ether | 3 | 2 | 5 | 4 | 3 |
| Zinc oxide | 5 | 8 | 7 | 6 | 5 |
| Diatomite | 4 | 7 | 5 | 8 | 6 |
| Polyamide wax pulp | 8 | 5 | 10 | 9 | 7 |
| Tertiary carbonic acid glycidyl ester | 30 | 35 | 40 | 38 | 32 |
| Water | 85 | 80 | 90 | 88 | 83 |
Table 2 (unit: quality is divided)
Table 3
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Tensile strength (MPa) | 30 | 25 | 15 | 20 | 28 |
| Elongation at break (%) | 8.5 | 6.7 | 5.5 | 7.5 | 8.0 |
| Shore hardness | 60 | 55 | 50 | 58 | 54 |
The acrylic resin modified energy-saving and environment-friendly paint of furred ceiling printing plate a kind of described in the embodiment of the present invention is coated in furred ceiling printing plate steel slab surface by roll coating model, at 200 DEG C after solidification, be cooled to room temperature, place 48 hours, measure slab top coat performance as shown in table 4.Wherein, the method of the mensuration paint film impact resistance that impact resistance testing method specifies with reference to standard GB/T/T1732-93, falls within the weight of fixed mass (1kg) maximum height (cm) that test plate (panel) does not cause paint film to destroy and represents paint film impact resistance.
Table 4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Impact resistance (cm) | 120 | 115 | 110 | 117 | 113 |
| Salt spray resistance duration (h) | 3100 | 2900 | 2950 | 3000 | 3050 |
| Artificial accelerated aging duration (h) | 3300 | 3250 | 3280 | 3100 | 3190 |
| Resistance toheat | 750 | 680 | 700 | 650 | 690 |
Adopt a kind of furred ceiling printing plate provided by the present invention furred ceiling printing plate obtained after acrylic resin modified energy-saving and environment-friendly paint application furred ceiling printing plate slab, the curved performance of T can reach 0T or 1T.Utilization efficiency of coatings is high, and every 30 kilograms of coating can application 1 ton of slab.Do not ftracture under 230 DEG C of high temperature, nondiscoloration, resistance of aging is strong, is placed on the not yellowing in 10 ~ 15 years of outdoor consecutive sunlight, nondiscoloration.Acidproof corrosion resistance is strong, the product that roller coat is good is put into 85 DEG C of water and boils that 2H is raw is heated to 100 DEG C more gradually, product without variable color, fall paint, bubble.After using the Nad solution soaking 24H of 5% at normal temperatures, product surface non-corroding, variable color and coating come off.Pure cotton cloth is dipped in full 95% alcohol to be wrapped on 500g counterweight, wipes examination 50 circulation with the stroke of speed (20mm) left and right of per minute 40-60 time at product surface, and nothing fades de-oiling.Detect according to the X method of drawing in U.S. ASTM the shaping furred ceiling printing plate goods being coated with coating provided by the present invention, can reach the 0=ASTM grade of ISO grade, notching edge is completely smooth, and what edge had not a particle of peels off.
It should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted.Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to the technical scheme of invention or equivalent replacement, and not depart from the scope of technical solution of the present invention, it all should be encompassed in right of the present invention.
Claims (8)
1. the acrylic resin modified energy-saving and environment-friendly paint of furred ceiling printing plate, is characterized in that, in described coating, each composition quality mark is as follows:
Organosilicon modified crylic acid resin: 70 ~ 80 parts, hydroxypropylcellulose: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, diamino-cyclohexane: 10 ~ 15 parts, MBT: 3 ~ 8 parts, copper stearate: 5 ~ 15 parts, Sodium dodecylbenzene sulfonate: 1 ~ 5 part, pure aluminium silicate: 10 ~ 20 parts, polyester resin change properties of organic silicon oxygen alkane: 2 ~ 6 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 ~ 5 parts, zinc oxide: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, tertiary carbonic acid glycidyl ester: 30 ~ 40 parts, water: 80 ~ 90 parts.
2. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 76 parts, hydroxypropylcellulose: 5 parts, aminoresin: 6 parts, diamino-cyclohexane: 12 parts, MBT: 4 parts, copper stearate: 14 parts, Sodium dodecylbenzene sulfonate: 3 parts, pure aluminium silicate: 18 parts, polyester resin change properties of organic silicon oxygen alkane: 5 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 parts, zinc oxide: 6 parts, diatomite: 7 parts, polyamide wax pulp: 8 parts, tertiary carbonic acid glycidyl ester: 35 parts, water: 90 parts.
3. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 70 parts, hydroxypropylcellulose: 3 parts, aminoresin: 8 parts, diamino-cyclohexane: 13 parts, MBT: 3 parts, copper stearate: 5 parts, Sodium dodecylbenzene sulfonate: 5 parts, pure aluminium silicate: 15 parts, polyester resin change properties of organic silicon oxygen alkane: 2 parts, polyoxyethylene polyoxypropylene glyceryl ether: 3 parts, zinc oxide: 5 parts, diatomite: 4 parts, polyamide wax pulp: 8 parts, tertiary carbonic acid glycidyl ester: 30 parts, water: 85 parts.
4. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: organosilicon modified crylic acid resin: 74 parts, hydroxypropylcellulose: 4 parts, aminoresin: 6 parts, diamino-cyclohexane: 12 parts, MBT: 4 parts, copper stearate: 10 parts, Sodium dodecylbenzene sulfonate: 3 parts, pure aluminium silicate: 13 parts, polyester resin change properties of organic silicon oxygen alkane: 4 parts, polyoxyethylene polyoxypropylene glyceryl ether: 2 parts, zinc oxide: 6 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, tertiary carbonic acid glycidyl ester: 30 parts, water: 80 parts.
5. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 1, it is characterized in that, the preparation of described organosilicon modified crylic acid resin, comprises the steps:
By the vinylformic acid that 1 ~ 5 quality is divided, the ethyl propenoate that 30 ~ 40 quality are divided, the butyl acrylate that 5 ~ 10 quality are divided, the Isooctyl acrylate monomer that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
The propenyl Trimethoxy silane that 20 ~ 30 quality are divided, the octamethylcyclotetrasiloxane that 10 ~ 15 quality are divided, the emulsifying agent that 1 ~ 3 quality is divided, the dodecyl sulphate that 0.5 ~ 2 quality is divided and the water that 40 ~ 50 quality are divided mixing, stir, pre-emulsification, obtains emulsion;
Get reaction flask, add step 1) gained emulsion, after being heated to 80 ~ 85 DEG C, insulation 1 ~ 2h, then in described reaction flask, step 2 is dripped) gained emulsion, at the uniform velocity drip, dropwise in 1 ~ 1.5h, at 80 DEG C, insulation 2 ~ 3h, be cooled to room temperature, adjust ph, to neutral, filters to obtain described organosilicon modified crylic acid resin.
6. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 5, it is characterized in that, step 1) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.
7. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to claim 5, it is characterized in that, step 2) described emulsifying agent is selected from one in oxyethyl group phenolic ether ammonium sulfate, polyoxyethylene nonylphenol ether, allyl ethers hydroxypropyl azochlorosulfonate acid sodium.
8. the acrylic resin modified energy-saving and environment-friendly paint of a kind of furred ceiling printing plate according to any one of claim 1 ~ 7, it is characterized in that, described coating is coated to furred ceiling printing plate steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
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| CN106223562A (en) * | 2016-08-30 | 2016-12-14 | 唐健发 | A kind of coating application method of body of wall |
| CN106221456A (en) * | 2016-08-30 | 2016-12-14 | 唐健发 | Inner wall of building anti-flaming dope and construction technology thereof |
| CN106349846A (en) * | 2016-08-30 | 2017-01-25 | 唐健发 | A coating construction process |
| CN109970905A (en) * | 2019-03-12 | 2019-07-05 | 煤科集团杭州环保研究院有限公司 | Integral ceiling veneer coating aqueous high molecular lotion and preparation method thereof |
| CN110591553A (en) * | 2019-09-29 | 2019-12-20 | 佛山市红树水性印涂材料有限公司 | Low-temperature-cured high-hardness wear-resistant water-based organic silicon coating and preparation method thereof |
| CN116515358A (en) * | 2023-04-28 | 2023-08-01 | 深圳市深赛尔股份有限公司 | Preparation method of modified aqueous aluminum rolling paint and aqueous aluminum rolling-aqueous printing paint |
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| CN109970905B (en) * | 2019-03-12 | 2021-07-13 | 中煤科工集团杭州研究院有限公司 | Water-based polymer emulsion for integrated ceiling finishing coating and preparation method thereof |
| CN110591553A (en) * | 2019-09-29 | 2019-12-20 | 佛山市红树水性印涂材料有限公司 | Low-temperature-cured high-hardness wear-resistant water-based organic silicon coating and preparation method thereof |
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