CN101735703A - Aqueous environment-friendly packaging steel drum paint and preparation method thereof - Google Patents
Aqueous environment-friendly packaging steel drum paint and preparation method thereof Download PDFInfo
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Abstract
The invention relates to an aqueous environment-friendly packaging steel drum paint, which is prepared by mixing the following compositions in part by weight: 20 to 70 parts of aqueous solution of acrylic resin with a solid content of 30 to 80 percent and/or aqueous solution of epoxy resin with the solid content of 30 to 80 percent, 4 to 10 parts of aqueous solution of amino resin with the solid content of 60 to 98 percent, 1 to 5 parts of organic amine, 1 to 50 parts of filling materials with the granularity of more than 2,000 meshes, 0.5 to 10 parts of color paste, 0.2 to 2 parts of wetting levelling agent, 0.2 to 2 parts of thickening agent, 0.1 to 0.8 part of antifoaming agent, 1 to 5 parts of adhesive force accelerant, 0.2 to 5 parts of catalyst, 0 to 30 parts of alcohol diluting solvent and/or 0 to 5 parts of non-toxic ether diluting solvent, and 20 to 50 parts of deionized water. The aqueous environment-friendly packaging steel drum paint has the advantages of wide application range, high rigidity, good flexibility, strong adhesive force and good anti-scraping and anti-collision properties and environmental protection; and meanwhile, the invention discloses a preparation method for the aqueous environment-friendly packaging steel drum paint.
Description
Technical field
The present invention relates to a kind of coating composition of organic high molecular compound, specifically, is a kind of aqueous environment-friendly packaging steel drum paint and preparation method thereof.
Background technology
Along with improving constantly of people's living standard, aqueous environment-friendly packaging steel drum paint has obtained using widely in the packing of product (as food, grain and oil, oil, chemical industry, pharmaceutical prod) of various industries, to improve internal and external anti-corrosive and the environment protection health and the decorative effect of product.The current packaging steel drum paint mainly is made up of oleoresin film forming matter and the color stuffing, the noxious solvent that contain heavy metal, film forming matter is generally formed by alkyd, vibrin or acrylic resin and amino resin crosslinked curing, and acrylic resin can be used widely with its better weather; Solvent is generally the virulent organic solvent of volatility, as Chinese patent CN101270258A.Mainly there is following shortcoming in the current packaging steel drum paint:
(1) can only be used to not have the outside surface application of pail packs such as the lower food of oil, chemical industry and the health requirements of environment protection health requirement, grain and oil, medicine mostly, just can not use an application in the bucket that the environment protection health requirement is arranged;
(2) hardness of paint film and toughness are difficult to take into account, and hardness is difficult to break through 2H, and toughness also is difficult to break through 1, and is easily crisp;
(3) the anti-scraping of paint film, collision performance are poor;
(4) the paint film solvent resistance is poor;
(5) the paint film heavy metal content is big, contains carcinogenic substance, and directly harm humans is healthy;
(6) solvent is toxic mostly, and volatilization is polluted air and infringement environment for human survival in air, and it is healthy that the harm people holds class;
(7) spraying application difficulty big (surface treatment is numerous and diverse, and operation is many, and recoatability is poor);
(8) surface is easy to generate pin hole, flake, smooth poor flatness;
(9) at the bottom of the cost performance, thereby make production cost high.
In a word, present casing steel barrel lacquer exists that little, the scratch resistant sidewipe collision poor performance of the scope of application, poisonous and harmful operating efficiency are low, the problem of not environmental protection.
Summary of the invention
One of purpose of the present invention is to provide a kind of aqueous environment-friendly packaging steel drum paint that is applicable to application in the high bucket of health requirements.
In order to realize above-mentioned purpose of the present invention, aqueous environment-friendly packaging steel drum paint of the present invention, mixed by each component of following weight part: solids content is that 30～80% water-borne acrylic resin solution and/or solids content are 20～70 parts of 30～80% aqueous epoxy resins solution, solids content is 4～10 parts of 60～98% water-compatible amino resin solution, 1～5 part of organic amine, 1～50 part of filler more than granularity 2000 orders, 0.5～10 part of mill base, 0.2～2 part of moistening flatting agent, 0.2～2 part of thickening material, 0.1～0.8 part of defoamer, 1～5 part of adhesion promoter, 0.2～5 part of catalyzer, 0～5 part of 0～30 part of alcohols diluting solvent and/or nontoxic ethers diluting solvent, 20～50 parts of deionized waters; Described catalyzer is one or more of Ammonia, alcohols, Phenylsulfonic acid class.
In technique scheme, described water-compatible amino resin solution is selected from one or both in half methyl-etherified aminoresin, the full methyl-etherified aminoresin.Described organic amine is selected from N, one or more in N dimethylethanolamine, trolamine, the triethylamine.Described adhesion promoter be selected from resin type, silicone-type and silicone based in one or more.Described filler is selected from one or more in titanium dioxide, aluminium triphosphate, glass micro mist, mica powder, fine particle calcium carbonate, the coarse whiting.Described mill base is selected from that titanium white, peptide cyanines orchid, peptide cyanines are green, in iron oxide red, iron oxide yellow, carbon black, permanent bordeaux etc. one or more grind and form or market finished product mill base.
As the preferred embodiment of technique scheme, described mill base, preparation as follows successively:
Step (1), deionized water, organic amine, dispersion agent, wetting agent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition;
Step (2), in proportion slowly add the pigment powder after, dispersion machine is raised speed to 1500～3000n/min, under this speed, stir 30～60min and make its thorough dispersion, underspeed to 1000～1500n/min, slowly add water-based thickener solution, make its solution granularity reach 50～100S (being coated with 4 glasss 23 ℃);
Step (3) is the scattered mill base of step (2), with the sand mill sand milling to fineness less than 10um, filter then.
Described pigment powder is selected from that titanium white, peptide cyanines orchid, peptide cyanines are green, in the iron oxide red, iron oxide yellow, carbon black, permanent bordeaux one or more.
Another object of the present invention is to provide a kind of preparation method of aqueous environment-friendly packaging steel drum paint, comprise the following steps:
Step (1), deionized water, diluting solvent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition, reduce to normal temperature;
Step (2), adding organic amine, the dispersion machine speed-raising is to 600～1200n/min, under this speed, stir 5～10min, after slowly adding water-borne acrylic resin solution and/or aqueous epoxy resins solution and water-compatible amino resin solution dispersion 15～25min, raise speed to 2000n/min redispersion 30～45min;
Step (3) is reduced to 1200～1500n/min with dispersion machine, slowly adds filler and mill base, and various auxiliary agents stir 50～70min, get product.
Compared with prior art, the invention has the beneficial effects as follows:
1) Du Te anticorrosion, weather-proof mechanism: this product is a multipolymer with resins such as acrylic acid, epoxy, Polyurethane, organosilicons, oil-soluble resin is scattered in the water, form thermodynamic stable system, take into account oxidized form and connect skill together with the composite of self-emulsifying type resin, it is well balanced that water-base epoxy is obtained.Preferred ion stabilized type self-emulsifying of new generation " nuclear～shell " structure water-base resin adopts ultra-fine or nano level color stuffing and mill base nonpoisonous and tasteless, heavy metal free.Under the wet film state, can repeat construction, cheap, the hardness of paint film height of formation, strong adhesion, water-fast, salt tolerant, alkaline-resisting, acidproof, anti-solvent, anti-collision, scrape resistant, toxicological harmless and weather-proof good corrosion-resistanting decoration effect.
2) design of Xian Jin technical recipe, science: it is one unique formula and technology that this product absorbs the elite of domestic and international water, oiliness coating varnish, poly-cross-linking type, oil-in-water type three, the employing self-emulsifying of science is main, and taking into account crosslinked, response type is the design of assisting.Selected nano grade inorganic, nontoxic color stuffing.
3) Zhuo Yue Environmental Safety: this product adopts inorganic poisonous material; rationally utilize nano material; select the inorganic aqueous organic waterborne polymeric of part for use; adopting self-emulsification aqueous resin, is thinner with water, no benzene, no aldehyde, heavy metal free material in the lacquer liquid; so nonpoisonous and tasteless, pollution-free, no three wastes; do not fire not quick-friedly, guaranteed environment protection and security against fire, ensured that laborer's is healthy.
4) tough and tensile paint film property excellence: the paint film that this product forms, have hardness height, damage resistant, strong adhesion, salt spray resistance, salt water resistance, acid and alkali-resistance, water boiling resistance, oil resistant, ultraviolet light, ageing-resistant, anti-low temperature, moisture-proof heat, anti-solvent, sweat proof liquid, scrape resistant, do not fire not quick-fried, reusable on old paint film (water-based, oiliness) surface, can not cause the paint film damage, superpower paint film flexibility etc.The general paint film life-span can reach 8～10 years.
5) Synergistic and energy-saving reduces cost: this product is thinner with water; simple to operate; save traditional lacquer solvent dilution, reduce the dilution cost, this product utilization rate 100%; can improve work efficiency more than 3 times; 8～12 square metres of every kg coating areas, unit painting cost are domestic minimum, can significantly reduce enterprise in labour protection; security against fire, and the investment cost of environment protection aspect.
6) extensive applicability: this product belongs to medium-to-high grade aqueous environment-friendly packaging steel drum paint, because mechanism uniqueness, design science, technology advanced person, excellent performance is widely used in the food, makeup, grain and oil, oil, chemical industry, medicine, household electrical appliance, house ornamentation, hardware component of various metal bases, the surfaces externally and internally application of quoting water pot, automobile and motorcycle tank.
Embodiment
Further the present invention is illustrated below in conjunction with case study on implementation.
Embodiment 1
Prescription: water-borne acrylic resin solution (solids content 50%) 40 weight parts, water-compatible amino resin solution (BASF 066 aminoresin, solids content 80%) 5 weight parts, N, N dimethylethanolamine 1.5 weight parts, titanium dioxide slurry (BASF 121) 8 weight parts, the blue slurry of peptide cyanines (permanent safe 5302) 4 weight parts, moistening flatting agent (BYK346) 0.5 weight part, thickening material (hydrophobically-modified alkali swelling type thickening material H-400) 0.3 weight part, defoamer (extra large river F-111) 0.5 weight part, adhesion promoter (DH-F6021) 1 weight part, catalyzer (the sharp catalyzer D of Beijing Jin Hui) 0.5 weight part, ethanol 10 weight parts, propylene glycol monomethyl ether 2 weight parts, deionized water 27.2 weight parts.
The preparation method: deionized water, ethanol and propylene glycol monomethyl ether are added the lacquer cylinder in proportion, and the operation dispersion machine allows it fully stir evenly at the stirring at low speed state; Add N, N dimethylethanolamine, dispersion machine raise speed to 1000n/min, stir 8min under this speed, slowly add after water-borne acrylic resin solution and water-compatible amino resin solution disperses 20min, raise speed to the above redispersion 30min of 2000n/min; Dispersion machine is reduced to 1400n/min, slowly add filler and mill base, moistening flatting agent, thickening material, defoamer, adhesion promoter, catalyzer, stirring 60min get product.
Water-borne acrylic resin solution can make with method, reversed emulsion polymerization or the graft polymerization method of general synthetic macromolecule, also can some hydrophilic acrylic monomer or contain q.s (for example more than 50%) wetting ability acrylic monomer and acrylate and other monomeric mixtures, with water is that solvent carries out polymerization, directly make the aqueous solution of acrylic resin, the prescription of used water-borne acrylic resin solution sees the following form in the present embodiment.
Table 1: the prescription of the used water-borne acrylic resin solution of present embodiment
| The monomer title | Each monomeric weight percent (%) |
| Methyl methacrylate | ??40.8 |
| Butyl acrylate | ??40.8 |
| Hydroxyethyl methylacrylate | ??10 |
| Vinylformic acid | ??8.4 |
Embodiment 2
Prescription: aqueous epoxy resins solution (the sharp E60 of Beijing Jin Hui, solids content 70%) 50 weight parts, water-compatible amino resin solution (three wooden 5747 aminoresin, solids content 98%) 5 weight parts, N, N dimethylethanolamine 1.5 weight parts, glass micro mist 5 weight parts, rutile titanium white powder (BASF 121) 2 weight parts, permanent bordeaux (a product RY01) 6 weight parts, moistening flatting agent (BYK346) 0.5 weight part, thickening material (hydrophobically-modified alkali swelling type thickening material H-400) 0.3 weight part, defoamer (extra large river F-111) 0.5 weight part, adhesion promoter (DH-F6021) 1 weight part, catalyzer (the sharp catalyzer D1 of Beijing Jin Hui) 0.5 weight part, ethanol 10 weight parts, deionized water 17.7 weight parts.
The preparation method: deionized water, ethanol and propylene glycol monomethyl ether are added the lacquer cylinder in proportion, and the operation dispersion machine allows it fully stir evenly at the stirring at low speed state, reduces to normal temperature; Add trolamine, dispersion machine raises speed to 1200n/min, stirs 5min under this speed, slowly adds after aqueous epoxy resins solution and water-compatible amino resin solution disperses 15min, raises speed to the above redispersion 25min of 2000n/min; Dispersion machine is reduced to 1500n/min, slowly adds filler and mill base, moistening flatting agent, thickening material, defoamer, adhesion promoter, catalyzer, product.
Embodiment 3
Prescription: water-borne acrylic resin solution (solids content 70%) 35 weight parts, aqueous epoxy resins solution (the sharp E60 of Beijing Jin Hui, solids content 60%) 10 weight parts, water-compatible amino resin solution (BASF 066 aminoresin, solids content 100%) 6 weight parts, N, N dimethylethanolamine 1 weight part, trolamine 1 weight part, mill base 5 weight parts, rutile titanium white powder (climbing titanium 128) 10 weight parts, moistening flatting agent (BYK346) 0.5 weight part, thickening material (hydrophobically-modified alkali swelling type thickening material TR-935) 0.5 weight part, defoamer (BEK-760) 0.5 weight part, adhesion promoter (DH-F6021) 1 weight part, catalyzer (the sharp catalyzer D of Beijing Jin Hui) 0.5 weight part, ethanol 10 weight parts, deionized water 26 weight parts.
In the present embodiment, used mill base is preparation as follows successively:
Step (1), deionized water, organic amine, dispersion agent, wetting agent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition;
Step (2), in proportion slowly add ferric oxide red powder after, dispersion machine is raised speed to 2000n/min, under this speed, stir 40min and make its thorough dispersion, underspeed to 1200n/min, slowly add water-based thickener solution, make its solution granularity reach 50～100S (being coated with 4 glasss 23 ℃);
Step (3) is the scattered mill base of step (2), with the sand mill sand milling to fineness less than 10um, filter then.
The preparation method: deionized water and ethanol are added the lacquer cylinder in proportion, and the operation dispersion machine allows it fully stir evenly at the stirring at low speed state, reduces to normal temperature; Add organic amine, dispersion machine raises speed to 600n/min, stirs 10min under this speed, slowly adds after water-borne acrylic resin solution, aqueous epoxy resins solution and water-compatible amino resin solution disperses 25min, raises speed to the above redispersion 35min of 2000n/min; Dispersion machine is reduced to 1500n/min, slowly add filler and mill base, moistening flatting agent, thickening material, defoamer, adhesion promoter, catalyzer stir 60min, get product.
Embodiment 4
Prescription: water-borne acrylic resin solution (solids content 50%) 35 weight parts, aqueous epoxy resins solution (the sharp E60 of Beijing Jin Hui, solids content 60%) 15 weight parts, water-compatible amino resin solution (BASF 066 aminoresin, solids content 100%) 5 weight parts, trolamine 1 weight part, aluminium triphosphate 5 weight parts, mica powder 5 weight parts, mill base 3 weight parts, moistening flatting agent (BYK346) 0.5 weight part, thickening material (hydrophobically-modified alkali swelling type thickening material TR-935) 0.5 weight part, defoamer (BEK-760) 0.5 weight part, adhesion promoter (DH-F6021) 1 weight part, catalyzer (the sharp catalyzer D1 of Beijing Jin Hui) 0.5 weight part, ethanol 8 weight parts, deionized water 20 weight parts.
In the present embodiment, used mill base is preparation as follows successively:
Step (1), deionized water, organic amine, dispersion agent, wetting agent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition;
Step (2), in proportion slowly add carbon powder after, dispersion machine is raised speed to 3000n/min, under this speed, stir 30min and make its thorough dispersion, underspeed to 1500n/min, slowly add water-based thickener solution, make its solution granularity reach 50～100S;
Step (3) is the scattered mill base of step (2), with the sand mill sand milling to fineness less than 10um, filter then.
The preparation method is identical with embodiment 1.
The aqueous environment-friendly packaging steel drum paint that embodiment 1～4 is made was diluted to granularity 30 seconds after (23 ℃ are coated with 4 glasss) with tap water, respectively spray proof on cold-rolled steel sheet, aluminum magnesium alloy, stainless steel, plain metal base material.
Its technical feature detects index:
| Project | Index |
| Outward appearance | Smooth smooth |
| Viscosity (23 ± 1 ℃ of .S) | ??100～120 |
| Fineness (micron) | ??≤15 |
| Dry | Surface drying (25 ℃ of 15min); Baking (100～150 ℃ of 0.5h) |
| Gloss (%) | ??≥85 |
| Hardness (pencil) | ??≥3H |
| Sticking power (cross-hatching) | ??≤1 |
| Snappiness (bending) mm | ??≤1 |
| Surging force (positive and negative) cm | ??50 |
| Water-fast (25 ± 1 ℃ of .1000h) | No change |
| Salt tolerant acid (HCl5%) 24h | No change |
| Alkaline-resisting water (NaOH 2%200h) | No change |
| Salt water resistance (NaCl5%.200h) | No change |
| Salt spray resistance (NaCl5%.200h) | No change |
| Oil resistant (93# gasoline, 28# machine oil, brake solution) 48h | No change |
| Ethanol-tolerant 95%24h | No change |
| Anti-scratch 3000 times | No change |
Claims (8)
1. aqueous environment-friendly packaging steel drum paint is characterized in that: mixed by each component of following weight part: solids content is that 30～80% water-borne acrylic resin solution and/or solids content are 20～70 parts of 30～80% aqueous epoxy resins solution, solids content is 4～10 parts of 60～98% water-compatible amino resin solution, 1～5 part of organic amine, 1～50 part of filler more than granularity 2000 orders, 0.5～10 part of mill base, 0.2～2 part of moistening flatting agent, 0.2～2 part of thickening material, 0.1～0.8 part of defoamer, 1～5 part of adhesion promoter, 0.2～5 part of catalyzer, 0～5 part of 0～30 part of alcohols diluting solvent and/or nontoxic ethers diluting solvent, 20～50 parts of deionized waters; Described catalyzer is one or more of Ammonia, alcohols, Phenylsulfonic acid class.
2. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described water-compatible amino resin solution is selected from one or both in half methyl-etherified aminoresin, the full methyl-etherified aminoresin.
3. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described organic amine is selected from N, one or more in N dimethylethanolamine, trolamine, the triethylamine.
4. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described adhesion promoter be selected from resin type, silicone-type and silicone based in one or more.
5. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described filler is selected from one or more in titanium dioxide, aluminium triphosphate, glass micro mist, mica powder, fine particle calcium carbonate, the coarse whiting.
6. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described mill base is selected from that titanium white, peptide cyanines orchid, peptide cyanines are green, in iron oxide red, iron oxide yellow, carbon black, permanent bordeaux etc. one or more grind and form or market finished product mill base.
7. aqueous environment-friendly packaging steel drum paint according to claim 1 is characterized in that: described mill base is preparation as follows successively:
Step (1), deionized water, organic amine, dispersion agent, wetting agent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition;
Step (2), in proportion slowly add the pigment powder after, dispersion machine is raised speed to 1500～3000n/min, under this speed, stir 30～60min and make its thorough dispersion, underspeed to 1000～1500n/min, slowly add water-based thickener solution, make its solution granularity reach 50～100S (being coated with 4 glasss 23 ℃);
Step (3) is the scattered mill base of step (2), with the sand mill sand milling to fineness less than 10um, filter then.
8. as the preparation method of the described aqueous environment-friendly packaging steel drum paint of claim 1～7, it is characterized in that comprising the following steps:
Step (1), deionized water, diluting solvent are added the lacquer cylinder in proportion, the operation dispersion machine makes its mixing under the stirring at low speed condition;
Step (2), adding organic amine, the dispersion machine speed-raising is to 600～1200n/min, under this speed, stir 5～10min, after slowly adding water-borne acrylic resin solution and/or aqueous epoxy resins solution and water-compatible amino resin solution dispersion 15～25min, raise speed to the above redispersion 25～35min of 2000n/min;
Step (3) is reduced to 1200～1500n/min with dispersion machine, slowly adds filler and pigment slurry, and various auxiliary agents stir 50～70min, get product.
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| CN101987936A (en) * | 2010-12-09 | 2011-03-23 | 上海电动工具研究所 | Single-component water-soluble insulated enamel paint and preparation method thereof |
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| CN104109449B (en) * | 2014-07-28 | 2017-01-04 | 西安经建油漆股份有限公司 | A kind of aqueous food container inner wall paint and preparation method thereof |
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| CN107118670A (en) * | 2017-06-27 | 2017-09-01 | 六安三创建筑材料有限公司 | A kind of interior wall environment friendly emulsion paint and preparation method thereof |
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| CN108017964A (en) * | 2017-12-13 | 2018-05-11 | 青岛益群环保新材料有限公司 | A kind of cold spray steel drum paint of water-based oil rub resistance |
| CN108219615A (en) * | 2018-01-15 | 2018-06-29 | 安徽龙谷商贸有限公司 | A kind of novel aqueous acrylic paint |
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| CN109021733A (en) * | 2018-06-06 | 2018-12-18 | 徐昊 | A kind of aqueous, environmental protective automobile coating and preparation method thereof |
| CN109280460A (en) * | 2018-09-17 | 2019-01-29 | 浙江鑫翔环保科技有限公司 | A kind of the environment-friendly epoxy water-based industrial paint and its preparation process of heavy anti-corrosion antirust |
| CN109836966A (en) * | 2018-12-28 | 2019-06-04 | 惠州市凯辉化工有限公司 | A kind of aqueous automobile interior trim nylon glass material paint special and preparation method thereof |
| CN110591513A (en) * | 2019-10-11 | 2019-12-20 | 重庆华辉涂料有限公司 | High-water-resistant heat-resistant environment-friendly coating for packaging barrel and preparation method thereof |
| CN111484784A (en) * | 2020-06-17 | 2020-08-04 | 山东省博兴县华丰新型材料有限公司 | Durable color-coated steel coil and preparation method thereof |
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| CN112226121B (en) * | 2020-09-10 | 2021-12-17 | 重庆华辉涂料有限公司 | High-gloss water-based varnish and preparation method thereof |
| WO2022088115A1 (en) * | 2020-10-30 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Water-based paint specially for stainless steel substrate and preparation method therefor |
| WO2022088141A1 (en) * | 2020-10-31 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Water-based paint for small hardware, preparation method therefor and use thereof |
| CN115340788A (en) * | 2021-09-26 | 2022-11-15 | 温岭市彩源颜料有限公司 | Water paint universal color paste and use method thereof |
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Application publication date: 20100616 |