CN101338107B - Water-soluble wickerwork paint and preparation thereof - Google Patents
Water-soluble wickerwork paint and preparation thereof Download PDFInfo
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- CN101338107B CN101338107B CN200810147313A CN200810147313A CN101338107B CN 101338107 B CN101338107 B CN 101338107B CN 200810147313 A CN200810147313 A CN 200810147313A CN 200810147313 A CN200810147313 A CN 200810147313A CN 101338107 B CN101338107 B CN 101338107B
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- water
- acid sodium
- ammonium salt
- deionized water
- dipropylene glycol
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- 239000003973 paint Substances 0.000 title abstract description 17
- 238000002360 preparation method Methods 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 69
- 239000004816 latex Substances 0.000 claims abstract description 25
- 229920000126 latex Polymers 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- -1 waterborne drier Substances 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 18
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000080 wetting agent Substances 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 22
- 229910052708 sodium Inorganic materials 0.000 claims description 34
- 239000011734 sodium Substances 0.000 claims description 34
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 23
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 238000009954 braiding Methods 0.000 claims description 17
- 239000000839 emulsion Substances 0.000 claims description 17
- 230000008719 thickening Effects 0.000 claims description 17
- 229920000180 alkyd Polymers 0.000 claims description 16
- 239000004922 lacquer Substances 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 15
- 150000003863 ammonium salts Chemical class 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 11
- OAZJUWGXQIQPJO-GRHBHMESSA-N [Na].C(\C=C/C(=O)O)(=O)O.CC(C)=C.CC(C)=C Chemical compound [Na].C(\C=C/C(=O)O)(=O)O.CC(C)=C.CC(C)=C OAZJUWGXQIQPJO-GRHBHMESSA-N 0.000 claims description 11
- 150000007942 carboxylates Chemical class 0.000 claims description 11
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 11
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 235000015424 sodium Nutrition 0.000 claims description 8
- 239000001488 sodium phosphate Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 8
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 8
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 7
- 239000004408 titanium dioxide Substances 0.000 claims 6
- 238000001035 drying Methods 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002562 thickening agent Substances 0.000 abstract 2
- 235000010215 titanium dioxide Nutrition 0.000 abstract 2
- 230000006866 deterioration Effects 0.000 abstract 1
- 238000004880 explosion Methods 0.000 abstract 1
- 230000005923 long-lasting effect Effects 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 8
- 239000001038 titanium pigment Substances 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000007704 transition Effects 0.000 description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 208000031737 Tissue Adhesions Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- MHWRYTCHHJGQFQ-UHFFFAOYSA-N prop-2-enoic acid hydrate Chemical compound O.OC(=O)C=C MHWRYTCHHJGQFQ-UHFFFAOYSA-N 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses wicker water-based paint which comprises deionized water, propanediol, dispersant, foam killer, wetting agent, titanium white powder (rutile type), waterborne self-crosslinked acrylic acid latex, dipropylene glycol ether, alcohol acid latex, waterborne drier, preservative and thickener. The deionized water and propanediol are added into a material preparation pot to be stirred at low speed; the dispersant, the foam killer and the wetting agent are subsequently added in to be evenly mixed; the titanium white powder (rutile type) is added in to be dispersed at high speed to form even paint paste; the paint paste is ground and thrown into a mixer, stirred and mixed at low speed; the waterborne self-crosslinked acrylic acid latex, the dipropylene glycol ether, the alcohol acid latex, waterborne drier and preservative are added in to be stirred and thickened by the thickener with the deionized water added in. The Liubian water-based paint has the advantages of excellent gloss retention, long-lasting color, quick drying speed, high lustrousness, strong adhesion force to wickers, good water resistance, even paint film, good paint liquid stability, no flame, no explosion, no harm, no deterioration when being stored at low temperature, wide scope of application, and applicability in the coating of all wicker woven crafts.
Description
One, technical field:
The invention belongs to a kind of water-based wicker plaiting article lacquer and preparation method thereof.
Two, background technology:
China is maximum in the world wicker plaiting article base, and according to relevant statistics of export numeral, the outlet of willow-plaited process article was above 2.5 hundred million dollars in 2006; The coating that uses of willow-plaited process article more than 95% was to be master's solvent based coating with alkyd, nitro etc. in the past; Their VOC content is higher, and in construction process, needs organic solvent diluting, not only atmospheric environment is produced greatly and pollutes; And have a strong impact on constructing operation personnel's physical and mental health, increased the disaster hidden-trouble of willow-plaited process article factories.The water-miscible paint that with water is diluted composition has no irritating odor, and does not contain objectionable impuritiess such as benzene,toluene,xylene, ethylbenzene, stores and do not exist when using the dangerous hidden danger of blast and fire, is a kind of environmentally friendly coating.
Water-miscible paint on the market is single acrylic latex type now, is mainly used in the application of building inside and outside wall, and part is used for the water-based wicker plaiting article; And bigger owing to its particle diameter with the water-based wicker plaiting article lacquer of single water soluble acrylic acid water emulsion preparation, film-forming properties is poor, must add a certain amount of furtherance film; Just can form successive films; The compactness of filming that forms like this is poor, and gloss is low, and the steam transmitance is high; Especially show relatively poor on gloss of film and the water tolerance, so on gloss and water tolerance, exist tangible gap with comparing with the solvent-thinned paint of class with the water-based wicker plaiting article lacquer of water emulsion type base-material preparation.Latex has different second-order transition temperature (Tg) on the other hand; After selecting the high latex film forming of second-order transition temperature for use, good hardness, tissue adhesion; But the latex normal temperature film forming that second-order transition temperature is high need add more a large amount of furtherance films; It is slower to volatilize, and the initial stage hardness of paint film and various resistance rise slower, are unfavorable for requiring quick-drying coating.Select the low latex of second-order transition temperature for use, difference of hardness, resistance to blocking is poor, but the required furtherance film of normal temperature film forming amount is few, and volatilization is fast, and initial stage hardness is set up very fast, but is unfavorable for anti-stick coat.No matter second-order transition temperature is a film forming matter with the single aqueous acrylic latex mainly just, all exists gloss low, poor water resistance, the problem that cost is high.
Three, summary of the invention
The object of the invention is exactly to solve the problems referred to above that exist in the prior art, provide after a kind of application paint film do soon, smooth, even, glossiness is high, the water-based wicker plaiting article of water-tolerant lacquer and preparation method thereof.
For realizing the object of the invention; Technical scheme of the present invention is: a kind of water-based wicker plaiting article lacquer; It is processed by following proportioning raw materials, counts by weight percentage: the water-borne Self-Crosslinked Acrylic latex of the wetting agent of the dispersion agent of the deionized water of 8-15%, the Ucar 35 of 1-2%, 0.5-1.5%, the skimmer of 0.1-0.5%, 0.5-1.5%, the white titanium pigment (rutile-type) of 15-25%, 45-65%, the dipropylene glycol of 1-5%, the alkyd emulsion of 3-8%, the water-based siccative of 0.2-0.6%, the sanitas of 0.05-0.1% and the thickening material of 0.3-0.6%; Described dispersion agent is a kind of in the ammonium salt, polyfunctional group polymkeric substance alkoxyl group ammonium salt, vinylbenzene cis-butenedioic anhydride butanols half carboxylate, PEMULEN TR2 of condenses, Diisobutylene maleic acid sodium, polyacrylic acid sodium salt, poly carboxylic acid sodium, the acrylate copolymer of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate; Perhaps a kind of in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium, polyacrylic acid sodium salt and the poly carboxylic acid sodium, a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the ammonium salt of acrylate copolymer and the polyfunctional group polymkeric substance alkoxyl group ammonium salt, a kind of mixture in the PEMULEN TR2; The perhaps ammonium salt of a kind of and acrylate copolymer in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium, polyacrylic acid sodium salt and the poly carboxylic acid sodium, a kind of mixture in the polyfunctional group polymkeric substance alkoxyl group ammonium salt; Perhaps a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium, polyacrylic acid sodium salt, the poly carboxylic acid sodium, a kind of mixture in the PEMULEN TR2; Perhaps a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the ammonium salt of acrylate copolymer, the polyfunctional group polymkeric substance alkoxyl group ammonium salt, a kind of mixture in the PEMULEN TR2; Described skimmer is a tributyl phosphate, emulsification methyl-silicone oil, polymethylphenyl siloxane fluid, modified natural fatty cpd, modified dimethyl polysiloxane solution, one or more mixtures in the polyether-modified ZGK 5.
A kind of making method of above-mentioned said water-based wicker plaiting article lacquer, it may further comprise the steps:
1, with deionized water, the Ucar 35 of 2/3-3/4, add in the pot of getting the raw materials ready according to formula ratio, mix with the lower velocity of 400-600rpm;
2, according to formula ratio, add dispersion agent, skimmer and wetting agent successively, after mixing, add pigment again: white titanium pigment (rutile-type), more than 20 minutes, form even mill base with 1200rpm speed high speed dispersion, there is not obvious dry mash piece;
3, the mill base that stirs is ground, to fineness≤30um;
4, will grind qualified mill base and squeeze into to transfer and convert in the jar, and open stirring, low speed mixing is even, slowly adds the water-borne Self-Crosslinked Acrylic latex of formula ratio successively, dipropylene glycol, and alkyd emulsion and water-based siccative and sanitas stir more than at least 15 minutes; The deionized water that adds 1/4-1/3 in the thickening material of formula ratio is transferred rare, is joined thickening in the mixture then at normal temperatures, to temperature be 25 ℃, the viscosity under the condition of 3#12rpm is 5500-6000mpa.
Because the present invention has adopted such scheme, the composite gloss retention of water-borne Self-Crosslinked Acrylic latex and alkyd emulsion with excellence, color is lasting; Fast drying, glossiness is high, to the strong adhesion of wicker; Water-tolerant; Paint film is even, and lacquer liquid good stability does not fire, not quick-fried, nuisanceless, low tempertaure storage never degenerates.The adding of high effective additives, the application property that can obtain to suit.Applied widely, can be used for the application of various wicker basketry article.The cost of material is low, is suitable for exporting the use of willow-plaited process article fully.
In a word; The utlity model has following characteristic: 1, be dispersion medium with water; Do not contain phthalate, halogenated hydrocarbon; Harmful materials such as gylcol ether, benzene,toluene,xylene, ethylbenzene meet the technical requirements of environmental labelling product, and the feature of environmental protection requirement of exported product.2, paint film water-tolerant can form crosslinked filming through oxidation drying, soaks not come off in 48 hours.3, mechanical and physical performance is good, and glossiness is high, and white paint reaches (60 °) more than 85%, and strong adhesion, wicker products collide with, swipe, and paint film does not come off.4, fast drying, 20 minutes surface dryings were done something in disregard of obstacles in 2 hours.5, do not fire, not quick-fried, nuisanceless, low tempertaure storage never degenerates.6, be suitable for the application of the basket work of various Various Seasonal harvestings, paint film is smooth, and evenly, smooth, the area of application is big.
Four, embodiment:
Below in conjunction with specific embodiment the present invention is done further description:
Embodiment 1, present embodiment are processed by following proportioning raw materials, count by weight percentage: 8% deionized water, 1.5% Ucar 35,0.8% tripoly phosphate sodium STPP, 0.3% tributyl phosphate, 1.0% wetting agent, 20% white titanium pigment (rutile-type), 58.4% water-based are handed over acrylic latex, 4% dipropylene glycol, 5% alkyd emulsion, 0.4% water-based siccative, 0.1% sanitas and 0.5% thickening material from joining.
Its making method may further comprise the steps:
1, with deionized water, the Ucar 35 of 2/3-3/4, adds in the pot of getting the raw materials ready, carry out stirring at low speed with the speed of 400-600rpm and mix according to formula ratio.
2, according to formula ratio, add dispersion agent successively: tripoly phosphate sodium STPP, skimmer: tributyl phosphate and wetting agent, after mixing; Add pigment again: white titanium pigment (rutile-type); More than 20 minutes, form even mill base with 1200rpm speed high speed dispersion, do not have obvious dry mash piece;
3, the mill base that stirs is ground, to fineness≤30um;
4, will grind qualified mill base and squeeze into to transfer and convert in the jar, and open stirring, low speed mixing is even; The water-borne Self-Crosslinked Acrylic latex that slowly adds formula ratio successively, dipropylene glycol, alkyd emulsion and water-based siccative and sanitas; Stir more than at least 15 minutes, survey initial viscosity; The deionized water that adds 1/4-1/3 in the thickening material of formula ratio is transferred rare, is joined thickening in the mixture at normal temperatures according to initial viscosity then, to temperature be 25 ℃, the viscosity under the condition of 3#12rpm is 5500-6000mpa.
5, check its viscosity to meet the requirements, spraying or dip-coating wicker checking dryness, hardness, surface effect meet the requirements, surfacing, no significant defect, notice packing.
Embodiment 2, present embodiment are processed by following proportioning raw materials, count by weight percentage: 8.95% deionized water, 1% Ucar 35,0.5% poly carboxylic acid sodium, 0.2% polyether-modified ZGK 5,0.5% wetting agent, 15% white titanium pigment (rutile-type), 65% water-based are handed over acrylic latex, 5% dipropylene glycol, 3% alkyd emulsion, 0.2% water-based siccative, 0.05% sanitas and 0.6% thickening material from joining.
The dispersion agent that its making method remove to add is 0.5% poly carboxylic acid sodium, and skimmer is that remaining is with embodiment 1 outside 0.2% the polyether-modified ZGK 5.
Embodiment 3, present embodiment are processed by following proportioning raw materials, count by weight percentage: the ammonium salt of 10.95% deionized water, 2% Ucar 35,0.25% poly carboxylic acid sodium, 0.25% acrylate copolymer, 0.2% polyether-modified ZGK 5,0.5% wetting agent, 25% white titanium pigment (rutile-type), 55% water-based are handed over acrylic latex, 2% dipropylene glycol, 3% alkyd emulsion, 0.2% water-based siccative, 0.05% sanitas and 0.6% thickening material from joining.
The dispersion agent that its making method remove to add is the ammonium salt of 0.25% poly carboxylic acid sodium, 0.25% acrylate copolymer, and skimmer is that remaining is with embodiment 1 outside 0.2% the polyether-modified ZGK 5.
Embodiment 4, present embodiment are processed by following proportioning raw materials, count by weight percentage: the ammonium salt of 12.88% deionized water, 1.35% Ucar 35,1.5% acrylate copolymer, 0.5% polyether-modified ZGK 5,0.5% wetting agent, 23.55% white titanium pigment (rutile-type), 50% water-based are handed over acrylic latex, 3% dipropylene glycol, 6% alkyd emulsion, 0.32% water-based siccative, 0.1% sanitas and 0.3% thickening material from joining.
The dispersion agent that its making method remove to add is the ammonium salt of 1.5% acrylate copolymer, and skimmer is that remaining is with embodiment 1 outside the 0.5% polyether-modified ZGK 5.
Instance 5, present embodiment are processed by following proportioning raw materials, count by weight percentage: 15% deionized water, 1.65% Ucar 35,0.6% Diisobutylene maleic acid sodium, 0.6% PEMULEN TR2,0.48% vinylbenzene cis-butenedioic anhydride butanols half carboxylate, 0.05% emulsification methyl-silicone oil, 0.05% polymethylphenyl siloxane fluid, 1.5% wetting agent, 25% white titanium pigment (rutile-type), 45% water-based are handed over acrylic latex, 1% dipropylene glycol, 8% alkyd emulsion, 0.6% water-based siccative, 0.07% sanitas and 0.4% thickening material from joining.
The dispersion agent that its making method remove to add is 0.6% Diisobutylene maleic acid sodium, 0.6% PEMULEN TR2 and 0.48% vinylbenzene cis-butenedioic anhydride butanols half carboxylate; Skimmer is that remaining is with embodiment 1 outside the polymethylphenyl siloxane fluid of 0.05% emulsification methyl-silicone oil and 0.05%.
Claims (8)
1. a water-based wicker plaiting article is coated with lacquer; It is characterized in that: it is processed by following proportioning raw materials, counts by weight percentage: the water-borne Self-Crosslinked Acrylic latex of the wetting agent of the dispersion agent of the deionized water of 8-15%, the Ucar 35 of 1-2%, 0.5-1.5%, the skimmer of 0.1-0.5%, 0.5-1.5%, the Rutile type Titanium Dioxide of 15-25%, 45-65%, the dipropylene glycol of 1-5%, the alkyd emulsion of 3-8%, the water-based siccative of 0.2-0.6%, the sanitas of 0.05-0.1% and the thickening material of 0.3-0.6%; Described dispersion agent is a kind of in the ammonium salt, polyfunctional group polymkeric substance alkoxyl group ammonium salt, vinylbenzene cis-butenedioic anhydride butanols half carboxylate, PEMULEN TR2 of condenses, Diisobutylene maleic acid sodium, poly carboxylic acid sodium, the acrylate copolymer of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate; Perhaps a kind of in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium and the poly carboxylic acid sodium, a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the ammonium salt of acrylate copolymer and the polyfunctional group polymkeric substance alkoxyl group ammonium salt, a kind of mixture in the PEMULEN TR2; The perhaps ammonium salt of a kind of and acrylate copolymer in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium and the poly carboxylic acid sodium, a kind of mixture in the polyfunctional group polymkeric substance alkoxyl group ammonium salt; Perhaps a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the condenses of tripoly phosphate sodium STPP, trisodium phosphate, sodium sulfonate, Diisobutylene maleic acid sodium, the poly carboxylic acid sodium, a kind of mixture in the PEMULEN TR2; Perhaps a kind of and vinylbenzene cis-butenedioic anhydride butanols half carboxylate in the ammonium salt of acrylate copolymer, the polyfunctional group polymkeric substance alkoxyl group ammonium salt, a kind of mixture in the PEMULEN TR2; Described skimmer is a tributyl phosphate, emulsification methyl-silicone oil, polymethylphenyl siloxane fluid, modified natural fatty cpd, modified dimethyl polysiloxane solution, one or more mixtures in the polyether-modified ZGK 5.
2. water-based wicker plaiting article lacquer according to claim 1; It is characterized in that: it is processed by following proportioning raw materials, counts by weight percentage: 8% deionized water, 1.5% Ucar 35,0.8% tripoly phosphate sodium STPP, 0.3% tributyl phosphate, 1.0% wetting agent, 20% Rutile type Titanium Dioxide, 58.4% water-based are handed over acrylic latex, 4% dipropylene glycol, 5% alkyd emulsion, 0.4% water-based siccative, 0.1% sanitas and 0.5% thickening material from joining.
3. water-based wicker plaiting article lacquer according to claim 1; It is characterized in that: it is processed by following proportioning raw materials, counts by weight percentage: 15% deionized water, 1.65% Ucar 35,0.6% Diisobutylene maleic acid sodium, 0.6% PEMULEN TR2,0.48% vinylbenzene cis-butenedioic anhydride butanols half carboxylate, 0.05% emulsification methyl-silicone oil, 0.05% polymethylphenyl siloxane fluid, 1.5% wetting agent, 25% Rutile type Titanium Dioxide, 45% water-based are handed over acrylic latex, 1% dipropylene glycol, 8% alkyd emulsion, 0.6% water-based siccative, 0.07% sanitas and 0.4% thickening material from joining.
4. water-based wicker plaiting article lacquer according to claim 1, it is characterized in that: described skimmer is polyether-modified ZGK 5.
5. according to claim 1 or 4 described water-based wicker plaiting articles lacquer, it is characterized in that: described dispersion agent be a kind of in the ammonium salt of poly carboxylic acid sodium, acrylate copolymer or two kinds according to 1: the mixture of 1-4.
6. water-based wicker plaiting article lacquer according to claim 5; It is characterized in that: it is processed by following proportioning raw materials, counts by weight percentage: 8.95% deionized water, 1% Ucar 35,0.5% poly carboxylic acid sodium, 0.2% polyether-modified ZGK 5,0.5% wetting agent, 15% Rutile type Titanium Dioxide, 65% water-based are handed over acrylic latex, 5% dipropylene glycol, 3% alkyd emulsion, 0.2% water-based siccative, 0.05% sanitas and 0.6% thickening material from joining.
7. water-based wicker plaiting article lacquer according to claim 5; It is characterized in that: it is processed by following proportioning raw materials, counts by weight percentage: the ammonium salt of 10.95% deionized water, 2% Ucar 35,0.25% poly carboxylic acid sodium, 0.25% acrylate copolymer, 0.2% polyether-modified ZGK 5,0.5% wetting agent, 25% Rutile type Titanium Dioxide, 55% water-based are handed over acrylic latex, 2% dipropylene glycol, 3% alkyd emulsion, 0.2% water-based siccative, 0.05% sanitas and 0.6% thickening material from joining.
8. the making method of water-based wicker plaiting article lacquer, it is characterized in that: it may further comprise the steps: formula ratio is according to described formula ratio wherein among the claim 1-7,
(1), the deionized water with 2/3-3/4, Ucar 35, add in the pot of getting the raw materials ready according to formula ratio, mix with the speed of 400-600rpm;
(2), according to formula ratio, add dispersion agent, skimmer and wetting agent successively, after mixing, add pigment again: Rutile type Titanium Dioxide, more than 20 minutes, form even mill base with 1200rpm speed high speed dispersion, do not have obvious dry mash piece;
(3), the mill base that stirs is ground, to fineness≤30um;
(4), will grind qualified mill base and squeeze into to transfer and convert in the jar, open stirring, low speed mixing is even, slowly adds the water-borne Self-Crosslinked Acrylic latex of formula ratio successively, dipropylene glycol, alkyd emulsion and water-based siccative and sanitas stir more than at least 15 minutes; The deionized water that adds 1/4-1/3 in the thickening material of formula ratio is transferred rare, is joined thickening in the mixture then at normal temperatures, to temperature be 25 ℃, the viscosity under the condition of 3#12rpm is 5500-6000mpa.
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| CN200810147313A CN101338107B (en) | 2008-08-07 | 2008-08-07 | Water-soluble wickerwork paint and preparation thereof |
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| CN200810147313A CN101338107B (en) | 2008-08-07 | 2008-08-07 | Water-soluble wickerwork paint and preparation thereof |
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| CN101338107B true CN101338107B (en) | 2012-09-19 |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102127279B (en) * | 2011-01-19 | 2012-09-05 | 深圳云之彩美术工艺用品有限公司 | Preparation technologies of decorative material and decorative scene |
| CN104031536B (en) * | 2014-05-26 | 2016-06-29 | 阜南腾强工艺品有限公司 | A kind of wicker plaiting article paint |
| CN104449095A (en) * | 2014-09-25 | 2015-03-25 | 阜南县猛发工艺品有限公司 | Oil paint special for wickerwork |
| CN104449094A (en) * | 2014-09-25 | 2015-03-25 | 阜南县永盛工艺品有限公司 | Wicker coating |
| CN104449129A (en) * | 2014-09-25 | 2015-03-25 | 阜南县猛发工艺品有限公司 | Pigmented paint for wickerwork |
| CN105017827A (en) * | 2015-07-20 | 2015-11-04 | 孙晨 | Wicker product and aqueous paint for wicker furniture |
| CN105017911A (en) * | 2015-07-20 | 2015-11-04 | 孙晨 | Environmentally friendly willow woven product water-based paint |
| CN105969015B (en) * | 2016-07-22 | 2018-09-21 | 阜南县永盛工艺品有限公司 | A kind of wicker products high-quality water paint |
| CN106065246A (en) * | 2016-07-22 | 2016-11-02 | 阜南县金威工艺品有限公司 | A kind of wicker plaiting article water paint |
| CN106221472A (en) * | 2016-07-29 | 2016-12-14 | 安徽昌发实业有限公司 | A kind of high-quality water paint for wicker products |
| CN106433362A (en) * | 2016-09-22 | 2017-02-22 | 安徽三和工艺品有限公司 | Wickerwork coating |
| CN106893434A (en) * | 2017-02-16 | 2017-06-27 | 河北晨阳工贸集团有限公司 | Aqueous, environmental protective wicker products varnish and preparation method thereof |
| CN107216732A (en) * | 2017-06-03 | 2017-09-29 | 阜南县猛发工艺品有限公司 | A kind of willow-plaited process product paint |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1872920A (en) * | 2005-05-31 | 2006-12-06 | 玉门石油管理局 | Super weather resisting elastic water proofing paint, and producing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1872920A (en) * | 2005-05-31 | 2006-12-06 | 玉门石油管理局 | Super weather resisting elastic water proofing paint, and producing method |
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