CN106221472A - A kind of high-quality water paint for wicker products - Google Patents
A kind of high-quality water paint for wicker products Download PDFInfo
- Publication number
- CN106221472A CN106221472A CN201610614398.7A CN201610614398A CN106221472A CN 106221472 A CN106221472 A CN 106221472A CN 201610614398 A CN201610614398 A CN 201610614398A CN 106221472 A CN106221472 A CN 106221472A
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- parts
- kaolin
- water
- rotating speed
- stirring
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high-quality water paint for wicker products, be made up of following material: butyl acrylate, 2 methyl methacrylates, ethyl methacrylate, modified kaolin, tetraethyl orthosilicate, paraffin oil, propylene glycol methyl ether acetate, soybean lecithin, hydroxypropyl methyl cellulose, polyoxyethylene polyoxypropylene tetramethylolmethane ether, titanate coupling agent, water.The water paint adhesive force that the present invention prepares is strong, and dispersive property is good, water-fast, corrosion resistant performance strong, has good filming performance, the most easy to crack, and is practically free of volatile solvent, and during use, safety is high.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of high-quality water paint for wicker products.
Background technology
Wicker plaiting article industry is the most prosperous now, and wicker products can utilize the materials such as discarded straw, both can avoid waste,
Can improve again the economic worth of straw, wicker products mostly is practical object, often uses, in wicker plaiting article with Body contact
After completing, paint to be carried out processes increases aesthetic measure and the decay resistance of wicker products, but present paint
Containing a lot of volatile solvents, health can be damaged.Water paint replaces organic solvent due to use water, so in film forming
Time volatilize is all water, also would not bring any injury to human body.Pursue although water paint is people and develops
Direction, but present water paint generally also exists the problem of the poor-performing such as resistance to water, wearability, hinders it and further pushes away
Wide development.
Summary of the invention
In order to solve the problems referred to above, the invention provides a kind of high-quality water paint for wicker products.
The present invention is achieved through the following technical solutions:
A kind of high-quality water paint for wicker products, is made up of the material of following weight portion:
20 ~ 25 parts of butyl acrylate, 10 ~ 15 parts of 2-methyl methacrylates, 20 ~ 25 parts of ethyl methacrylate, 6 ~ 8 parts of modifications
Kaolin, 4 ~ 7 parts of tetraethyl orthosilicates, 1 ~ 2 part of paraffin oil, 0.5 ~ 0.8 part of propylene glycol methyl ether acetate, 0.6 ~ 1 part of Semen sojae atricolor ovum
Phospholipid, 0.8 ~ 1.5 part of hydroxypropyl methyl cellulose, 0.6 ~ 1 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, 0.5 ~ 1 part of metatitanic acid
Ester coupling agent, 40 ~ 50 parts of water；Described modified kaolin is made up of the material of following weight portion: 30 ~ 40 parts of Kaolin, 6 ~ 8 parts receive
Rice titanium dioxide, 2 ~ 4 parts of sodium pyrophosphates, 0.5 ~ 1 part of wood vinegar, 0.5 ~ 1 part of Azedarachin, 3 ~ 5 parts of dimethyl carbonate.
Further, the preparation method of described modified kaolin comprises the steps:
(1) Kaolin is put in the phosphoric acid solution that mass fraction is 5 ~ 7% and take out after immersion treatment 1 ~ 2h, then put it into matter
Measure immersion treatment 1 ~ 2h in the salpeter solution that mark is 6 ~ 8%, rinse well with clear water standby after taking-up；
(2) Kaolin after step (1) being processed puts into calcining 3 ~ 5h under conditions of temperature is 780 ~ 830 DEG C, uses nitrogen after taking-up
Gas quickly cooling is to after room temperature, then puts it into calcining 2 ~ 3h under conditions of temperature is 960 ~ 1020 DEG C, naturally cools to room after taking-up
Temperature is standby；
(3) after the distilled water of sodium pyrophosphate, wood vinegar, Azedarachin and dimethyl carbonate with its gross mass 3 ~ 4 times being mixed jointly,
After stirring with the rotating speed of 800 ~ 900 revs/min, uniformly spray on the Kaolin after step (2) processes, then by kaolinite
Soil is dried that to be not more than 10% to water content standby；
(4) after the Kaolin of step (3) gained being pulverized 1000 mesh, then with nano titanium oxide mixing and stirring, to obtain final product
Modified kaolin.
The preparation method of a kind of high-quality water paint for wicker products, comprises the steps:
(1) after butyl acrylate, 2-methyl methacrylate, ethyl methacrylate and water being mixed jointly, with 400 ~ 430
Rev/min rotating speed stirring 15 ~ 20min after, then modified kaolin and tetraethyl orthosilicate are added, improve rotating speed to 490 ~
520 revs/min, and solution temperature is heated to 42 ~ 45 DEG C, stir 30 ~ 40min；
(2) paraffin oil, propylene glycol methyl ether acetate and soybean lecithin are joined in the solution of step (1) gained, with 600 ~
The rotating speed of 640 revs/min is standby after stirring 20 ~ 25min；
(3) finally hydroxypropyl methyl cellulose, polyoxyethylene polyoxypropylene tetramethylolmethane ether, titanate coupling agent are added jointly
In the solution of step (2) gained, after stirring with the rotating speed of 300 ~ 330 revs/min.
There is advantages that the present invention with acrylate as primary raw material, compounding with the addition of changes wherein
Property Kaolin and tetraethyl orthosilicate, these two kinds of compositions can well and acrylic ester polymerization be filled up in polymer molecule
In space, enhance its wearability, resistance to water and Corrosion Protection；The interpolation of propylene glycol methyl ether acetate and soybean lecithin carries
High overall dispersibility and mobility；Final under the mating reaction of each composition, the water paint adhesive force that the present invention prepares is strong,
Dispersive property is good, and water-fast, corrosion resistant performance is strong, has good filming performance, the most easy to crack, and is practically free of volatile solvent,
During use, safety is high.
Detailed description of the invention
Embodiment 1
A kind of high-quality water paint for wicker products, is made up of the material of following weight portion:
22 parts of butyl acrylate, 12 parts of 2-methyl methacrylates, 20 parts of ethyl methacrylate, 6 parts of modified kaolins, 5 parts
Tetraethyl orthosilicate, 1 part of paraffin oil, 0.5 part of propylene glycol methyl ether acetate, 0.6 part of soybean lecithin, 0.8 part of hydroxypropyl methyl
Cellulose, 0.8 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, 0.7 part of titanate coupling agent, 43 parts of water；Described modified kaolinite
Soil is made up of the material of following weight portion: 33 parts of Kaolin, 6 parts of nano titanium oxides, 2 parts of sodium pyrophosphates, 0.7 part of wood vinegar,
0.6 part of Azedarachin, 3.5 parts of dimethyl carbonate.
Further, the preparation method of described modified kaolin comprises the steps:
(1) Kaolin is put in the phosphoric acid solution that mass fraction is 7% and take out after immersion treatment 1.2h, then put it into quality
Mark be 8% salpeter solution in immersion treatment 1.5h, rinse well standby after taking-up with clear water；
(2) Kaolin after step (1) being processed puts into calcining 5h under conditions of temperature is 810 DEG C, uses nitrogen quickly cooling after taking-up
To room temperature, then put it into calcining 2h under conditions of temperature is 1000 DEG C, naturally cool to room temperature after taking-up standby；
(3) after the distilled water of sodium pyrophosphate, wood vinegar, Azedarachin and dimethyl carbonate with its gross mass 3 times being mixed jointly, with
After the rotating speed of 840 revs/min stirs, uniformly spray on the Kaolin after step (2) processes, then Kaolin is dried
It is not more than 10% standby to water content；
(4) after the Kaolin of step (3) gained being pulverized 1000 mesh, then with nano titanium oxide mixing and stirring, to obtain final product
Modified kaolin.
The preparation method of a kind of high-quality water paint for wicker products, comprises the steps:
(1) after butyl acrylate, 2-methyl methacrylate, ethyl methacrylate and water being mixed jointly, with 420 revs/min
After the rotating speed stirring 20min of clock, then modified kaolin and tetraethyl orthosilicate are added, improve rotating speed to 500 revs/min, and
Solution temperature is heated to 45 DEG C, stirs 36min；
(2) paraffin oil, propylene glycol methyl ether acetate and soybean lecithin are joined in the solution of step (1) gained, with 620
Rev/min rotating speed stirring 25min after standby；
(3) finally hydroxypropyl methyl cellulose, polyoxyethylene polyoxypropylene tetramethylolmethane ether, titanate coupling agent are added jointly
In the solution of step (2) gained, after stirring with the rotating speed of 300 revs/min.
Comparative example 1
Kaolin compared with Example 1, is not modified processing by this comparative example 1, and method step in addition is the most identical.
Comparative example 2
Compared with Example 1, the ethyl methacrylate of the weight portions such as use replaces modified kaolin to this comparative example 2, removes
In addition method step is the most identical.
Comparative example 3
Compared with Example 1, the modified kaolin of the weight portions such as use replaces ethyl methacrylate to this comparative example 3, removes
In addition method step is the most identical.
Matched group
Existing wicker products water paint.
In order to contrast effect of the present invention, the water paint preparing above-mentioned five kinds of modes carries out performance test, its correction data
As shown in the table:
| Embodiment 1 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Matched group | |
| Hardness of paint film (shoreD) | 67±1 | 64±2 | 60±2 | 61±2 | 59±2 |
| Adhesive force (ISO grade) | 5B | 4B | 3B | 3B | 3B |
| Resistance to water (50d) | Unchanged | Loss of gloss, light discolouration | Light discolouration, loss of gloss, foaming | Variable color, loss of gloss, wrinkling | Variable color, loss of gloss, bubble, come off |
Above-mentioned test is all followed relevant criterion and is carried out.
As can be seen from the above table, the water paint hardness of present invention preparation, adhesive force, water resistance all have well lifting,
And between the ethyl methacrylate of interpolation and modified kaolin composition, there is the most collaborative facilitation.
Claims (3)
1. the high-quality water paint for wicker products, it is characterised in that be made up of the material of following weight portion:
20 ~ 25 parts of butyl acrylate, 10 ~ 15 parts of 2-methyl methacrylates, 20 ~ 25 parts of ethyl methacrylate, 6 ~ 8 parts of modifications
Kaolin, 4 ~ 7 parts of tetraethyl orthosilicates, 1 ~ 2 part of paraffin oil, 0.5 ~ 0.8 part of propylene glycol methyl ether acetate, 0.6 ~ 1 part of Semen sojae atricolor ovum
Phospholipid, 0.8 ~ 1.5 part of hydroxypropyl methyl cellulose, 0.6 ~ 1 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, 0.5 ~ 1 part of metatitanic acid
Ester coupling agent, 40 ~ 50 parts of water；Described modified kaolin is made up of the material of following weight portion: 30 ~ 40 parts of Kaolin, 6 ~ 8 parts receive
Rice titanium dioxide, 2 ~ 4 parts of sodium pyrophosphates, 0.5 ~ 1 part of wood vinegar, 0.5 ~ 1 part of Azedarachin, 3 ~ 5 parts of dimethyl carbonate.
A kind of high-quality water paint for wicker products the most according to claim 1, it is characterised in that described modified high
The preparation method of ridge soil comprises the steps:
(1) Kaolin is put in the phosphoric acid solution that mass fraction is 5 ~ 7% and take out after immersion treatment 1 ~ 2h, then put it into matter
Measure immersion treatment 1 ~ 2h in the salpeter solution that mark is 6 ~ 8%, rinse well with clear water standby after taking-up；
(2) Kaolin after step (1) being processed puts into calcining 3 ~ 5h under conditions of temperature is 780 ~ 830 DEG C, uses nitrogen after taking-up
Gas quickly cooling is to after room temperature, then puts it into calcining 2 ~ 3h under conditions of temperature is 960 ~ 1020 DEG C, naturally cools to room after taking-up
Temperature is standby；
(3) after the distilled water of sodium pyrophosphate, wood vinegar, Azedarachin and dimethyl carbonate with its gross mass 3 ~ 4 times being mixed jointly,
After stirring with the rotating speed of 800 ~ 900 revs/min, uniformly spray on the Kaolin after step (2) processes, then by kaolinite
Soil is dried that to be not more than 10% to water content standby；
(4) after the Kaolin of step (3) gained being pulverized 1000 mesh, then with nano titanium oxide mixing and stirring, to obtain final product
Modified kaolin.
A kind of high-quality water paint for wicker products the most according to claim 1, it is characterised in that its preparation method
Comprise the steps:
(1) after butyl acrylate, 2-methyl methacrylate, ethyl methacrylate and water being mixed jointly, with 400 ~ 430
Rev/min rotating speed stirring 15 ~ 20min after, then modified kaolin and tetraethyl orthosilicate are added, improve rotating speed to 490 ~
520 revs/min, and solution temperature is heated to 42 ~ 45 DEG C, stir 30 ~ 40min；
(2) paraffin oil, propylene glycol methyl ether acetate and soybean lecithin are joined in the solution of step (1) gained, with 600 ~
The rotating speed of 640 revs/min is standby after stirring 20 ~ 25min；
(3) finally hydroxypropyl methyl cellulose, polyoxyethylene polyoxypropylene tetramethylolmethane ether, titanate coupling agent are added jointly
In the solution of step (2) gained, after stirring with the rotating speed of 300 ~ 330 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614398.7A CN106221472A (en) | 2016-07-29 | 2016-07-29 | A kind of high-quality water paint for wicker products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614398.7A CN106221472A (en) | 2016-07-29 | 2016-07-29 | A kind of high-quality water paint for wicker products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221472A true CN106221472A (en) | 2016-12-14 |
Family
ID=57535461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610614398.7A Pending CN106221472A (en) | 2016-07-29 | 2016-07-29 | A kind of high-quality water paint for wicker products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221472A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629662A (en) * | 2017-10-11 | 2018-01-26 | 阜南县大自然工艺品有限公司 | A kind of environment-friendly water-based paint for wicker products |
| CN112680285A (en) * | 2020-12-29 | 2021-04-20 | 上海塞寇文化传播有限公司 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338107A (en) * | 2008-08-07 | 2009-01-07 | 刘善江 | Water-soluble wickerwork paint and preparation thereof |
| CN105331214A (en) * | 2015-10-31 | 2016-02-17 | 阜南县黄岗镇工艺柳编厂 | Anti-corrosion paint for wickerwork made of purple willow |
-
2016
- 2016-07-29 CN CN201610614398.7A patent/CN106221472A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338107A (en) * | 2008-08-07 | 2009-01-07 | 刘善江 | Water-soluble wickerwork paint and preparation thereof |
| CN105331214A (en) * | 2015-10-31 | 2016-02-17 | 阜南县黄岗镇工艺柳编厂 | Anti-corrosion paint for wickerwork made of purple willow |
Non-Patent Citations (3)
| Title |
|---|
| 刘德峥等: "《精细化工生产技术第二版》", 30 September 2011 * |
| 唐春红主编: "《天然防腐剂与抗氧化剂》", 31 May 2010 * |
| 张巧玲等: "《化工工艺学》", 31 July 2015 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629662A (en) * | 2017-10-11 | 2018-01-26 | 阜南县大自然工艺品有限公司 | A kind of environment-friendly water-based paint for wicker products |
| CN112680285A (en) * | 2020-12-29 | 2021-04-20 | 上海塞寇文化传播有限公司 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
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| PB01 | Publication | ||
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Application publication date: 20161214 |