CN112680285A - Preparation method of environment-friendly cleaning agent with strong decontamination effect - Google Patents
Preparation method of environment-friendly cleaning agent with strong decontamination effect Download PDFInfo
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- CN112680285A CN112680285A CN202011593139.3A CN202011593139A CN112680285A CN 112680285 A CN112680285 A CN 112680285A CN 202011593139 A CN202011593139 A CN 202011593139A CN 112680285 A CN112680285 A CN 112680285A
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Abstract
The invention discloses a preparation method of a powerful decontamination environment-friendly cleaning agent, belonging to the technical field of cleaning agent preparation, and comprising the following steps: (1) preparing an enhanced additive, (2) weighing raw materials, and (3) mixing the raw materials to prepare the enhanced additive. The invention discloses a preparation method of a strong decontamination environment-friendly cleaning agent, which has the advantages of simple process, reasonable matching of all steps, easy commercial popularization and application, safety, environmental protection, strong decontamination performance, high use stability and the like.
Description
Technical Field
The invention belongs to the technical field of detergent preparation, and particularly relates to a preparation method of a strong decontamination environment-friendly detergent.
Background
With the development of economic society and industry, detergents for washing clothes or cleaning appliances or cleaning furniture emerge like bamboo shoots in the spring after rain, different types of detergents have different performances, and the performances of the detergents directly influence the washing effect and the use quality of the appliances and further influence the service life and the performances of the appliances, so that the search for detergents with excellent performances is particularly important for ensuring the use quality of the appliances.
At present, the application range of the cleaning agent is gradually expanding, and the cleaning agent is used for cleaning various greasy dirt, stains and grease such as plastic, optical glass lenses, metal products (copper, iron, aluminum, steel and alloy) and the like in the industrial industry, such as surface stretching oil, cutting oil, antirust oil, lubricating oil and stamping oil. At the present stage, in order to ensure the safety of people and equipment, the detergent is widely applied in the fields of electric appliances, instruments, distribution boxes and the like, and in order to meet the cleaning requirements of different fields on the detergent, people put forward higher requirements on the detergent, so that the detergent is required to have better decontamination capability, and is also required to be environment-friendly, antibacterial and high in cleaning effect and efficiency.
The traditional cleaning agent in the prior art has poor integral decontamination capability and unobvious cleaning effect, can not effectively remove some bacteria, can increase the oxidation and corrosion effects on the cleaned surface, has serious corrosivity, and has certain harmfulness to the environment and human bodies.
Therefore, there is a need in the art to develop an environmentally friendly detergent product that provides enhanced soil removal.
Disclosure of Invention
The invention aims to provide a preparation method of a powerful decontamination environment-friendly cleaning agent.
The technical purpose of the invention is realized by the following technical scheme:
a preparation method of an environment-friendly detergent with strong decontamination comprises the following steps:
(1) preparing a reinforcing additive:
a. mixing kaolin and nano titanium dioxide together, carrying out ball milling treatment for 1-2 h, and taking out to obtain mixed powder for later use;
b. b, placing the mixed powder obtained in the operation a into a calcining furnace for high-temperature calcining treatment for 40-45 min, and taking out for later use after the high-temperature calcining treatment is completed;
c. mixing sodium alginate, sodium pyrophosphate and deionized water together, stirring uniformly, adding alkyl glycoside, and continuously stirring uniformly to obtain a mixed solution for later use;
d. c, atomizing and spraying the mixed solution obtained in the operation c on the mixed powder treated in the operation b, uniformly stirring, and drying to constant weight to obtain an enhanced additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight: 4-7 parts of an antibacterial agent, 6-10 parts of the reinforcing additive prepared in the step (1), 3-6 parts of an emulsifier, 20-25 parts of a solvent and 10-15 parts of deionized water;
(3) mixing and preparing raw materials:
putting the antibacterial agent weighed in the step (2), the reinforcing additive prepared in the step (1), the emulsifier, the solvent and deionized water into a stirring tank together according to the corresponding weight parts, uniformly stirring at a high speed and taking out.
Further, in the step (1), the kaolin and the nano titanium dioxide are mixed together at a corresponding weight ratio of 6-8: 1.
further, the temperature in the calcining furnace is controlled to be 800-860 ℃ during the high-temperature calcining treatment in the operation b of the step (1).
Further, in the step (1), the sodium alginate, the sodium pyrophosphate and the deionized water are mixed together in a corresponding weight ratio of 3-5: 2-4: 10-15; the addition amount of the alkyl glycoside is 30-40% of the total mass of the sodium alginate.
Further, the weight ratio of the mixed liquid and the mixed powder in the operation d of the step (1) is 0.6-0.7: 1.
further, the antibacterial agent in the step (2) is at least one of imidazole, thiazole and quaternary ammonium salt antibacterial agents.
Further, the emulsifier in the step (2) is at least one of alkylphenol ethoxylate, lauryl alcohol ethoxylate and fatty amine ethoxylate.
Further, the solvent in the step (2) is at least one of ethanol, ethylene glycol and isopropanol.
Further, the stirring speed in the high-speed stirring treatment in the step (3) is 1800-2000 rpm.
Compared with the prior art, the invention has the following advantages:
the invention discloses a preparation method of a powerful decontamination environment-friendly cleaning agent, which is simple in process, reasonable in matching of all steps and easy for commercial popularization and application. The cleaning agent finally prepared by the method has the advantages of safety, environmental protection, harmlessness, strong decontamination performance, high use stability and the like, and has great market competitiveness.
Detailed Description
Example 1
A preparation method of an environment-friendly detergent with strong decontamination comprises the following steps:
(1) preparing a reinforcing additive:
a. mixing kaolin and nano titanium dioxide together, carrying out ball milling treatment for 1h, and taking out to obtain mixed powder for later use;
b. b, placing the mixed powder obtained in the operation a into a calcining furnace for high-temperature calcining treatment for 40min, and taking out for later use after the high-temperature calcining treatment is finished;
c. mixing sodium alginate, sodium pyrophosphate and deionized water together, stirring uniformly, adding alkyl glycoside, and continuously stirring uniformly to obtain a mixed solution for later use;
d. c, atomizing and spraying the mixed solution obtained in the operation c on the mixed powder treated in the operation b, uniformly stirring, and drying to constant weight to obtain an enhanced additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight: 4 parts of an antibacterial agent, 6 parts of the reinforcing additive prepared in the step (1), 3 parts of an emulsifier, 20 parts of a solvent and 10 parts of deionized water;
(3) mixing and preparing raw materials:
putting the antibacterial agent weighed in the step (2), the reinforcing additive prepared in the step (1), the emulsifier, the solvent and deionized water into a stirring tank together according to the corresponding weight parts, uniformly stirring at a high speed and taking out.
When the kaolin and the nano titanium dioxide in the operation a in the step (1) are mixed together, the corresponding weight ratio is 6: 1.
the high-temperature calcination treatment in operation b of step (1) is carried out while controlling the temperature in the calciner to 800 ℃.
In the step (1), the sodium alginate, the sodium pyrophosphate and the deionized water in the operation c are mixed together in a corresponding weight ratio of 3: 2: 10; the addition amount of the alkyl glycoside is 30 percent of the total mass of the sodium alginate.
The weight ratio of the mixed liquid and the mixed powder in the operation d in the step (1) is 0.6: 1.
the antibacterial agent in the step (2) is an imidazole antibacterial agent.
And (3) the emulsifier in the step (2) is alkylphenol polyoxyethylene.
The solvent in the step (2) is ethanol.
The stirring speed in the high-speed stirring treatment in step (3) was 1800 rpm.
Example 2
A preparation method of an environment-friendly detergent with strong decontamination comprises the following steps:
(1) preparing a reinforcing additive:
a. mixing kaolin and nano titanium dioxide together, carrying out ball milling treatment for 1.5h, and taking out to obtain mixed powder for later use;
b. b, placing the mixed powder obtained in the operation a into a calcining furnace for high-temperature calcining treatment for 43min, and taking out for later use after the high-temperature calcining treatment is finished;
c. mixing sodium alginate, sodium pyrophosphate and deionized water together, stirring uniformly, adding alkyl glycoside, and continuously stirring uniformly to obtain a mixed solution for later use;
d. c, atomizing and spraying the mixed solution obtained in the operation c on the mixed powder treated in the operation b, uniformly stirring, and drying to constant weight to obtain an enhanced additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight: 6 parts of an antibacterial agent, 8 parts of the reinforcing additive prepared in the step (1), 5 parts of an emulsifier, 23 parts of a solvent and 12 parts of deionized water;
(3) mixing and preparing raw materials:
putting the antibacterial agent weighed in the step (2), the reinforcing additive prepared in the step (1), the emulsifier, the solvent and deionized water into a stirring tank together according to the corresponding weight parts, uniformly stirring at a high speed and taking out.
When the kaolin and the nano titanium dioxide in the operation a in the step (1) are mixed together, the corresponding weight ratio is 7: 1.
the high temperature calcination treatment in operation b of step (1) is carried out while controlling the temperature in the calciner to be 830 ℃.
In the step (1), the sodium alginate, the sodium pyrophosphate and the deionized water in the operation c are mixed together in a corresponding weight ratio of 4: 3: 12; the addition amount of the alkyl glycoside is 35 percent of the total mass of the sodium alginate.
The weight ratio of the mixed liquid and the mixed powder in the operation d in the step (1) is 0.65: 1.
the antibacterial agent in the step (2) is thiazole antibacterial agent.
And (3) the emulsifier in the step (2) is polyoxyethylene lauryl ether.
The solvent in the step (2) is ethylene glycol.
The stirring speed in the high-speed stirring treatment in step (3) was 1900 rpm.
Example 3
A preparation method of an environment-friendly detergent with strong decontamination comprises the following steps:
(1) preparing a reinforcing additive:
a. mixing kaolin and nano titanium dioxide together, carrying out ball milling treatment for 2 hours, and taking out to obtain mixed powder for later use;
b. b, placing the mixed powder obtained in the operation a into a calcining furnace for high-temperature calcining treatment for 45min, and taking out for later use after the high-temperature calcining treatment is finished;
c. mixing sodium alginate, sodium pyrophosphate and deionized water together, stirring uniformly, adding alkyl glycoside, and continuously stirring uniformly to obtain a mixed solution for later use;
d. c, atomizing and spraying the mixed solution obtained in the operation c on the mixed powder treated in the operation b, uniformly stirring, and drying to constant weight to obtain an enhanced additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight: 7 parts of an antibacterial agent, 10 parts of the reinforcing additive prepared in the step (1), 6 parts of an emulsifier, 25 parts of a solvent and 15 parts of deionized water;
(3) mixing and preparing raw materials:
putting the antibacterial agent weighed in the step (2), the reinforcing additive prepared in the step (1), the emulsifier, the solvent and deionized water into a stirring tank together according to the corresponding weight parts, uniformly stirring at a high speed and taking out.
When the kaolin and the nano titanium dioxide in the operation a in the step (1) are mixed together, the corresponding weight ratio is 8: 1.
the high temperature calcination treatment in the operation b of the step (1) is carried out while controlling the temperature in the calciner to 860 ℃.
In the step (1), the sodium alginate, the sodium pyrophosphate and the deionized water in the operation c are mixed together in a corresponding weight ratio of 5: 4: 15; the addition amount of the alkyl glycoside is 40 percent of the total mass of the sodium alginate.
The weight ratio of the mixed liquid and the mixed powder in the operation d in the step (1) is 0.7: 1.
the antibacterial agent in the step (2) is a quaternary ammonium salt antibacterial agent.
The emulsifier in the step (2) is fatty amine polyoxyethylene ether.
The solvent in the step (2) is isopropanol.
The stirring speed in the high-speed stirring treatment in step (3) was 2000 rpm.
Comparative example 1
This comparative example 1 is different from example 2 only in that the use of nano titania in operation a is omitted in the preparation of the reinforcing additive in step (1), except that the other steps of the method are the same.
Comparative example 2
This comparative example 2 is different from example 2 only in that the preparation of the mixed solution and the subsequent use in the step (1) of preparing the reinforcing additive are omitted except that the steps of the method are the same.
Comparative example 3
This comparative example 3 is different from example 2 only in that in the weighing of the raw materials in the step (2), the reinforcing additive component prepared in the step (1) is replaced with an equal part by mass of ordinary kaolin, except that the other steps of the method are the same.
In order to compare the effects of the invention, the performance tests of the cleaning agents prepared in the above example 2 and comparative examples 1 to 3 were performed, and the specific comparative data are shown in the following table 1:
TABLE 1
Note: the surface tension described in table 1 above is a surface tension test experiment, specifically: according to JISK 3362: the torus method of 1998: determined corresponding to ISO 304; the cleaning removal rate adopts a cleaning experiment, and specifically comprises the following steps: a 2.5-inch magnetic disk glass substrate was polished using a commercially available colloidal silica slurry (average particle size about 30nm) as an abrasive and a polishing cloth, and then dried with nitrogen gas to prepare a contaminated substrate, 1,000 parts of a cleaning agent corresponding to each group was taken out of a glass beaker, the prepared contaminated substrate was immersed, cleaned at 30 ℃ for 5 minutes in an ultrasonic cleaner (200kHz), taken out of the substrate after cleaning, rinsed sufficiently with ultrapure water, and dried with nitrogen gas, and the removal rate was calculated using a differential interference microscope (manufactured by Nikon corporation, OPTIPHOT-2, magnification 400 times) to evaluate the cleaning property of the substrate surface; the antibacterial rate of staphylococcus and the antibacterial rate of escherichia coli are determined by referring to GB15981-1995, Q/02GZS001 detection method and standard to detect the antibacterial performance (calculated by colony number) of the cleaning agent.
As can be seen from the above table 1, the cleaning agent prepared by the method of the invention has strong antibacterial and cleaning capabilities, is safe, environment-friendly, green and harmless, and has great popularization and practical values.
Claims (9)
1. The preparation method of the powerful decontamination environment-friendly cleaning agent is characterized by comprising the following steps:
(1) preparing a reinforcing additive:
a. mixing kaolin and nano titanium dioxide together, carrying out ball milling treatment for 1-2 h, and taking out to obtain mixed powder for later use;
b. b, placing the mixed powder obtained in the operation a into a calcining furnace for high-temperature calcining treatment for 40-45 min, and taking out for later use after the high-temperature calcining treatment is completed;
c. mixing sodium alginate, sodium pyrophosphate and deionized water together, stirring uniformly, adding alkyl glycoside, and continuously stirring uniformly to obtain a mixed solution for later use;
d. c, atomizing and spraying the mixed solution obtained in the operation c on the mixed powder treated in the operation b, uniformly stirring, and drying to constant weight to obtain an enhanced additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight: 4-7 parts of an antibacterial agent, 6-10 parts of the reinforcing additive prepared in the step (1), 3-6 parts of an emulsifier, 20-25 parts of a solvent and 10-15 parts of deionized water;
(3) mixing and preparing raw materials:
putting the antibacterial agent weighed in the step (2), the reinforcing additive prepared in the step (1), the emulsifier, the solvent and deionized water into a stirring tank together according to the corresponding weight parts, uniformly stirring at a high speed and taking out.
2. The preparation method of the powerful decontamination environment-friendly detergent as claimed in claim 1, wherein the kaolin clay and the nano titanium dioxide in the operation a of the step (1) are mixed together at a weight ratio of 6-8: 1.
3. the method for preparing the strong decontamination environmental protection detergent according to claim 1, wherein the temperature in the calcining furnace is controlled to be 800-860 ℃ during the high temperature calcining treatment in the operation b of the step (1).
4. The preparation method of the powerful decontamination environment-friendly detergent as claimed in claim 1, wherein the weight ratio of the sodium alginate, the sodium pyrophosphate and the deionized water in the step (1) operation c is 3-5: 2-4: 10-15; the addition amount of the alkyl glycoside is 30-40% of the total mass of the sodium alginate.
5. The method for preparing the strong decontamination environment-friendly cleaning agent according to claim 1, wherein the weight ratio of the mixed solution to the mixed powder in the operation d of the step (1) is 0.6-0.7: 1.
6. the method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the antibacterial agent in the step (2) is at least one of imidazole, thiazole and quaternary ammonium salt antibacterial agents.
7. The method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the emulsifier in the step (2) is at least one of alkylphenol ethoxylate, lauryl alcohol ethoxylate and fatty amine ethoxylate.
8. The method for preparing the environmental-friendly detergent with strong detergency as claimed in claim 1, wherein the solvent in step (2) is at least one of ethanol, ethylene glycol and isopropanol.
9. The method for preparing the strong decontamination environmental protection detergent according to claim 1, wherein the stirring speed during the high-speed stirring treatment in the step (3) is 1800-2000 rpm.
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Patent Citations (7)
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|---|---|---|---|---|
| CN105969015A (en) * | 2016-07-22 | 2016-09-28 | 阜南县永盛工艺品有限公司 | High-quality water-based paint for wicker products |
| CN106221472A (en) * | 2016-07-29 | 2016-12-14 | 安徽昌发实业有限公司 | A kind of high-quality water paint for wicker products |
| CN111704962A (en) * | 2017-11-12 | 2020-09-25 | 湖南七纬科技有限公司 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
| CN108047496A (en) * | 2017-12-14 | 2018-05-18 | 全椒县三安塑业有限公司 | A kind of filler for being used to promote plastic strength |
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Application publication date: 20210420 |