CN111704962A - Preparation method of environment-friendly cleaning agent with strong decontamination effect - Google Patents
Preparation method of environment-friendly cleaning agent with strong decontamination effect Download PDFInfo
- Publication number
- CN111704962A CN111704962A CN202010196744.0A CN202010196744A CN111704962A CN 111704962 A CN111704962 A CN 111704962A CN 202010196744 A CN202010196744 A CN 202010196744A CN 111704962 A CN111704962 A CN 111704962A
- Authority
- CN
- China
- Prior art keywords
- parts
- solvent
- friendly
- hours
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 34
- 238000005202 decontamination Methods 0.000 title claims abstract description 30
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 230000000694 effects Effects 0.000 title description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 24
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 14
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- SBKRBXBQFDKYSO-UHFFFAOYSA-N (3-tert-butyl-4-hydroxy-5-methylphenyl) propanoate Chemical compound CCC(=O)OC1=CC(C)=C(O)C(C(C)(C)C)=C1 SBKRBXBQFDKYSO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 10
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000010992 reflux Methods 0.000 claims abstract description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 7
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- XFLNVMPCPRLYBE-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;tetrahydrate Chemical compound O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XFLNVMPCPRLYBE-UHFFFAOYSA-J 0.000 claims abstract description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 42
- 238000002390 rotary evaporation Methods 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 16
- 239000003599 detergent Substances 0.000 claims description 15
- 238000001291 vacuum drying Methods 0.000 claims description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- -1 dibenzyl diphenol Chemical compound 0.000 claims description 12
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 5
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 5
- VUQPJRPDRDVQMN-UHFFFAOYSA-N 1-chlorooctadecane Chemical compound CCCCCCCCCCCCCCCCCCCl VUQPJRPDRDVQMN-UHFFFAOYSA-N 0.000 claims description 4
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 4
- HNTGIJLWHDPAFN-UHFFFAOYSA-N 1-bromohexadecane Chemical compound CCCCCCCCCCCCCCCCBr HNTGIJLWHDPAFN-UHFFFAOYSA-N 0.000 claims description 3
- WSULSMOGMLRGKU-UHFFFAOYSA-N 1-bromooctadecane Chemical compound CCCCCCCCCCCCCCCCCCBr WSULSMOGMLRGKU-UHFFFAOYSA-N 0.000 claims description 3
- CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 claims description 3
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 claims description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 21
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 231100000719 pollutant Toxicity 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 238000001035 drying Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/22—Electronic devices, e.g. PCBs or semiconductors
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a preparation method of a strong decontamination environment-friendly cleaning agent, which is prepared from the following raw materials in parts by weight: 40-50 parts of antibacterial surfactant, 10-20 parts of water, 3-7 parts of emulsifier and 20-30 parts of solvent; the preparation method of the antibacterial surfactant comprises the following steps: 1) dissolving triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in a solvent, then adding epichlorohydrin and a catalyst into the solvent, and stirring the mixture to react for 6 to 8 hours at a temperature of between 70 and 80 ℃; 2) dissolving the product prepared in the step 1) in tetrahydrofuran, adding ethylene diamine tetraacetic acid tetrasodium and long-chain halogenated alkane, and refluxing and stirring for 4-6 hours at 40-50 ℃. The powerful decontamination environment-friendly cleaning agent disclosed by the invention has the advantages of wider application range and higher cleaning efficiency, can effectively remove various pollutants remained on the surfaces of various materials or products, ensures the uniformity of cleaning, does not pollute the environment, and is green and environment-friendly.
Description
The invention relates to a divisional application of a Chinese patent 'a powerful decontamination environment-friendly cleaning agent', the application date is 11, 12 and 2017, and the application number is 201711110629.1.
Technical Field
The invention relates to the technical field of cleaning agents, in particular to a powerful decontamination environment-friendly cleaning agent.
Background
With the development of economic society and industry, detergents for washing clothes or cleaning appliances or cleaning furniture emerge like bamboo shoots in the spring after rain, different types of detergents have different performances, and the performances of the detergents directly influence the washing effect and the use quality of the appliances and further influence the service life and the performances of the appliances, so that the search for detergents with excellent performances is particularly important for ensuring the use quality of the appliances.
At present, the application range of the cleaning agent is gradually expanding, and the cleaning agent is used for cleaning various greasy dirt, stains and grease such as plastic, optical glass lenses, metal products (copper, iron, aluminum, steel and alloy) and the like in the industrial industry, such as surface stretching oil, cutting oil, antirust oil, lubricating oil and stamping oil. At the present stage, in order to ensure the safety of people and equipment, the detergent is widely applied in the fields of electric appliances, instruments, distribution boxes and the like, and in order to meet the cleaning requirements of different fields on the detergent, people put forward higher requirements on the detergent, so that the detergent is required to have better decontamination capability, and is also required to be environment-friendly, antibacterial and high in cleaning effect and efficiency.
The traditional cleaning agent in the prior art has poor integral decontamination capability and unobvious cleaning effect, can not effectively remove some bacteria, can increase the oxidation and corrosion effects on the cleaned surface, has serious corrosivity, and has certain harmfulness to the environment and human bodies.
Therefore, the development of a powerful decontamination environment-friendly cleaning agent is imperative.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides the powerful decontamination environment-friendly cleaning agent which has the advantages of easily available raw materials, low price, wider application range, higher cleaning efficiency, capability of effectively removing various pollutants remained on the surfaces of various materials or products and ensuring the uniformity of cleaning, no pollution to the environment and environmental protection compared with the cleaning agent disclosed in the prior art.
In order to achieve the aim, the invention adopts the technical scheme that the strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 40-50 parts of antibacterial surfactant, 10-20 parts of water, 3-7 parts of emulsifier and 20-30 parts of solvent;
wherein the solvent is selected from one or more of ethanol, ethylene glycol, isopropanol and propylene glycol;
the emulsifier is one or more selected from dibenzyl diphenol polyoxypropylene polyoxyethylene ether, alkylphenol polyoxyethylene ether, lauryl alcohol polyoxyethylene ether, fatty amine polyoxyethylene ether, stearic acid polyoxyethylene ester and phenethyl phenol polyoxyethylene ether formaldehyde condensate;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in a solvent, adding epoxy chloropropane and a catalyst, stirring and reacting at 70-80 ℃ for 6-8 hours, performing rotary evaporation, washing with ethyl acetate for 5-8 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 40-50 ℃ to dry for 8-10 hours;
2) dissolving the product prepared in the step 1) in tetrahydrofuran, adding ethylene diamine tetraacetic acid tetrasodium and long-chain halogenated alkane into the tetrahydrofuran, refluxing and stirring the mixture for 4 to 6 hours at the temperature of between 40 and 50 ℃, performing rotary evaporation, washing the mixture for 5 to 8 times by using ethyl acetate, performing rotary evaporation again, and finally putting the mixture into a vacuum drying oven at the temperature of between 40 and 50 ℃ to dry the mixture for 8 to 10 hours;
wherein, the weight ratio of the triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate, the solvent, the epichlorohydrin and the catalyst in the step 1) is (6-7): (35-40) 2: 5;
the solvent is selected from one or more of methyl isobutyl ketone, methyl n-butyl ether, acetonitrile and dichloromethane;
the catalyst is selected from one or more of benzyltriethylammonium chloride, benzyldimethylamine, triethylamine, potassium carbonate and sodium hydroxide;
in the step 2), the mass ratio of the product prepared in the step 1), tetrahydrofuran, ethylene diamine tetraacetic acid tetrasodium salt and long-chain halogenated alkane is 1: (3-5):1: (1-1.2);
the long-chain halogenated alkane is selected from one or more of chlorooctadecane, chlorohexadecane, bromooctadecane and bromohexadecane;
adopt the produced beneficial effect of above-mentioned technical scheme to lie in:
(1) compared with the cleaning agent in the prior art, the strong decontamination environment-friendly cleaning agent greatly improves the cleaning and decontaminating capability and has better cleaning effect; the cleaning time is short, the cleaning efficiency is high, various pollutants remained on the surfaces of various materials or products can be effectively removed, and the uniformity of cleaning is ensured.
(2) The strong decontamination environment-friendly cleaning agent has the advantages of easily available raw materials, low price and high performance-price ratio.
(3) The quaternary ammonium salt structure is also arranged in the molecular structure of the strong decontamination environment-friendly cleaning agent, so that the cleaning agent has better antibacterial performance on the premise of not additionally adding an antibacterial agent.
(4) The solvent used by the strong decontamination environment-friendly cleaning agent is alcohol, has the effects of disinfection and sterilization, does not contain other toxic and harmful substances or solvents, has no pollution to the environment, and has no harm to the health of human bodies.
(5) The antibacterial surfactant serving as the main component of the powerful decontamination environment-friendly cleaning agent has oxidation resistance and antistatic performance, contains a plurality of carboxylate structures, and can perform a complexing effect on some metal dirt, so that the cleaning agent is wide in application range and is particularly suitable for cleaning electronic materials and products.
Detailed Description
In order to make the technical solutions of the present invention better understood and make the above features, objects, and advantages of the present invention more comprehensible, the present invention is further described with reference to the following examples. The examples are intended to illustrate the invention only and are not intended to limit the scope of the invention.
The raw material used in the following examples of the present invention was obtained from Shanghai spring Xin import & export trade company, Inc.
Example 1
The strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 40 parts of antibacterial surfactant, 10 parts of water, 3 parts of emulsifier dibenzyl diphenol polyoxypropylene polyoxyethylene ether and 20 parts of solvent ethanol;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving 600g of triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate into 3500g of methyl isobutyl ketone, then adding 200g of epoxy chloropropane and 500g of benzyltriethylammonium chloride serving as a catalyst into the mixture, stirring the mixture at 70 ℃ for reaction for 6 hours, carrying out rotary evaporation, washing the mixture for 5 times by using ethyl acetate, carrying out rotary evaporation again, and finally putting the mixture into a vacuum drying oven at 40 ℃ for drying for 8 hours;
2) dissolving 100g of the product prepared in the step 1) in 300g of tetrahydrofuran, adding 100g of ethylene diamine tetraacetic acid tetrasodium and 100g of chlorooctadecane, refluxing and stirring for 4 hours at 40 ℃, washing for 5 times by ethyl acetate through rotary evaporation, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 40 ℃ for drying for 8 hours.
Example 2
The strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 45 parts of antibacterial surfactant, 12 parts of water, 4 parts of emulsifier alkylphenol polyoxyethylene and 23 parts of solvent ethylene glycol;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving 620g of triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate into 3600g of methyl n-butyl ether, then adding 200g of epichlorohydrin and 500g of catalyst benzyldimethylamine, stirring and reacting for 7 hours at 74 ℃, carrying out rotary evaporation, washing for 6 times by using ethyl acetate, carrying out rotary evaporation again, and finally putting the product into a vacuum drying oven at 45 ℃ to dry for 9 hours;
2) dissolving 100g of the product prepared in the step 1) in 400g of tetrahydrofuran, adding 100g of ethylenediaminetetraacetic acid tetrasodium salt and 110g of bromooctadecane, refluxing and stirring at 45 ℃ for 5 hours, performing rotary evaporation, washing with ethyl acetate for 6 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 45 ℃ for drying for 9 hours.
Example 3
The strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 45 parts of antibacterial surfactant, 15 parts of water, 5 parts of emulsifier fatty amine polyoxyethylene ether and 25 parts of solvent isopropanol;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving 650g of triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in 3800g of acetonitrile solvent, then adding 200g of epichlorohydrin and 500g of triethylamine catalyst, stirring and reacting for 8 hours at 76 ℃, performing rotary evaporation, washing for 8 times by using ethyl acetate, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 48 ℃ to dry for 10 hours;
2) dissolving 100g of the product prepared in the step 1) in 450g of tetrahydrofuran, adding 100g of ethylenediaminetetraacetic acid tetrasodium salt and 115g of chlorohexadecane, refluxing and stirring at 48 ℃ for 5.6 hours, performing rotary evaporation, washing with ethyl acetate for 8 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 49 ℃ for drying for 9.5 hours.
Example 4
The strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 48 parts of antibacterial surfactant, 18 parts of water, 7 parts of emulsifier phenethyl phenol polyoxyethylene ether formaldehyde condensate and 28 parts of solvent propylene glycol;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving 670g of triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in 3900g of solvent dichloromethane, then adding 200g of epoxy chloropropane and 500g of catalyst potassium carbonate, stirring and reacting for 7 hours at 78 ℃, performing rotary evaporation, washing for 7 times by using ethyl acetate, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 50 ℃ to dry for 10 hours;
2) dissolving 100g of the product prepared in the step 1) in 480g of tetrahydrofuran, adding 100g of ethylene diamine tetraacetic acid tetrasodium and 120g of chlorooctadecane, refluxing and stirring at 50 ℃ for 6 hours, performing rotary evaporation, washing with ethyl acetate for 7 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 50 ℃ for drying for 9 hours;
example 5
The strong decontamination environment-friendly cleaning agent is prepared from the following raw materials in parts by weight: 50 parts of antibacterial surfactant, 20 parts of water, 7 parts of emulsifier polyoxyethylene stearate and 30 parts of solvent ethylene glycol;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving 700g of triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in 4000g of methyl isobutyl ketone solvent, adding 200g of epoxy chloropropane and 500g of benzyltriethylammonium chloride catalyst, stirring and reacting for 8 hours at 80 ℃, performing rotary evaporation, washing for 8 times by using ethyl acetate, performing rotary evaporation again, and finally putting the mixture into a vacuum drying oven at 50 ℃ to dry for 10 hours;
2) dissolving 100g of the product prepared in the step 1) in 500g of tetrahydrofuran, adding 100g of ethylenediaminetetraacetic acid tetrasodium salt and 120g of bromohexadecane, refluxing and stirring at 50 ℃ for 6 hours, performing rotary evaporation, washing with ethyl acetate for 8 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 50 ℃ for drying for 10 hours;
comparative example
Conventional commercial cationic surfactant based cleaners.
Product performance testing of the above examples and comparative examples:
(1) surface tension test: according to JIS K3362: the torus method of 1998: determined in accordance with ISO 304.
(2) Cleaning property test: a 2.5-inch magnetic disk glass substrate was polished using a commercially available colloidal silica slurry (average particle size of about 30nm) as a polishing agent and a polishing cloth, and then blown dry with nitrogen gas to prepare a contaminated substrate. The contaminated substrate thus prepared was immersed in 1,000 parts of the test cleaning agent in a glass beaker, and cleaned in an ultrasonic cleaner (200kHz) at 30 ℃ for 5 minutes. After cleaning, the substrate was taken out, sufficiently rinsed with ultrapure water, blown dry with nitrogen gas, and the removal rate was calculated by using a differential interference microscope (optiphoto-2, 400 × magnification, manufactured by Nikon corporation) to evaluate the cleaning property of the substrate surface.
(3) Corrosion of metal: 100 parts of the cleaning agent for testing was taken out from a polypropylene container, and a test piece (made of SUS304, 5 cm. times.2.5 m in size and 0.1cm in thickness) made of stainless steel was immersed in the cleaning agent. After the vessel was sealed and left to stand in a room at a temperature of 23 ℃ for 3 days, the iron ion content (ppm) eluted from the solution was analyzed by a high frequency Inductively Coupled Plasma (ICP) emission spectrometer (Varian 730-ES, manufactured by VARIAN) to evaluate the corrosion of the detergent to metals.
(4) Rinsing property: the weight (g) of the 2.5-inch glass substrate for a magnetic disk used in the test was measured to the decimal 5 th position in advance, 1L of a cleaning agent for test was added to a 1L beaker, the temperature was adjusted to 25 ℃ in a constant-temperature water tank, the glass substrate whose weight was measured was completely immersed in the water, the substrate was quickly taken out after 30 seconds of immersion, immersed in 1L of ultrapure water for 5 seconds, and then suspended at 25 ℃ for about 30 minutes to be naturally dried. The weight of the substrate after drying was measured, and the rinsing property (mg) was calculated and evaluated by the following formula. Rinsing property (mg) ═ substrate weight after test (g) -substrate weight before test (g)]×10-3
(5) The antibacterial performance (calculated by colony count) of the cleaning agent is tested by referring to GB15981-1995, Q/02GZS001 test method and standard; the test results are shown in Table 1.
TABLE 1 Properties of samples of examples and comparative examples
| Item | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Comparative example |
| Surface tension (mN/m) | ≤25 | ≤25 | ≤22 | ≤24 | ≤20 | ≤60 |
| Cleaning removal rate (%) | 95 | 93 | 94 | 97 | 99 | 80 |
| Corrosion of metals (ppm) | 0.027 | 0.026 | 0.024 | 0.022 | 0.020 | 0.35 |
| Rinsing property (mg) | 0.008 | 0.008 | 0.007 | 0.006 | 0.007 | 0.05 |
| Antibacterial ratio of Escherichia coli (%) | 100 | ≥99.9 | 100 | ≥99.9 | 100 | ≥90 |
| Antibacterial ratio (%) of Staphylococcus | ≥99.8 | 100 | ≥99.9 | 100 | ≥99.9 | ≥90 |
From the above table, it can be seen that the powerful decontamination environment-friendly cleaning agent disclosed by the embodiment of the invention has better surface activity and cleaning efficiency, and also has excellent antibacterial property and less corrosivity to metals.
The foregoing is merely a preferred embodiment of the invention and is not intended to limit the invention in any manner; those of ordinary skill in the art can readily practice the present invention as described herein; however, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention; meanwhile, any changes, modifications, and evolutions of the equivalent changes of the above embodiments according to the actual techniques of the present invention are still within the protection scope of the technical solution of the present invention.
Claims (8)
1. The preparation method of the powerful decontamination environment-friendly cleaning agent is characterized by being prepared from the following raw materials in parts by weight: 40-50 parts of antibacterial surfactant, 10-20 parts of water, 3-7 parts of emulsifier and 20-30 parts of solvent;
the preparation method of the antibacterial surfactant comprises the following steps:
1) dissolving triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate in a solvent, adding epoxy chloropropane and a catalyst, stirring and reacting at 70-80 ℃ for 6-8 hours, performing rotary evaporation, washing with ethyl acetate for 5-8 times, performing rotary evaporation again, and finally putting the product into a vacuum drying oven at 40-50 ℃ to dry for 8-10 hours;
2) dissolving the product prepared in the step 1) in tetrahydrofuran, adding ethylene diamine tetraacetic acid tetrasodium and long-chain halogenated alkane into the tetrahydrofuran, refluxing and stirring the mixture for 4 to 6 hours at the temperature of between 40 and 50 ℃, performing rotary evaporation, washing the mixture for 5 to 8 times by using ethyl acetate, performing rotary evaporation again, and finally putting the mixture into a vacuum drying oven at the temperature of between 40 and 50 ℃ to dry the mixture for 8 to 10 hours.
2. The method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the solvent is one or more selected from ethanol, ethylene glycol, isopropanol and propylene glycol.
3. The method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the emulsifier is one or more selected from dibenzyl diphenol polyoxypropylene polyoxyethylene ether, alkylphenol polyoxyethylene ether, lauryl alcohol polyoxyethylene ether, fatty amine polyoxyethylene ether, stearic acid polyoxyethylene ester and phenethyl phenol polyoxyethylene ether formaldehyde condensate.
4. The method for preparing the environmental-friendly strong decontamination detergent according to claim 1, wherein the weight ratio of the triethylene glycol ether-bis (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate to the solvent to the epichlorohydrin in the step 1) is (6-7): (35-40):2:5.
5. The method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the solvent is one or more selected from methyl isobutyl ketone, methyl n-butyl ether, acetonitrile and dichloromethane.
6. The method for preparing the environmental-friendly detergent with strong decontamination capability according to claim 1, wherein the catalyst is selected from one or more of benzyltriethylammonium chloride, benzyldimethylamine, triethylamine, potassium carbonate and sodium hydroxide.
7. The method for preparing the strong decontamination environment-friendly detergent as claimed in claim 1, wherein the mass ratio of the product prepared in the step 1) in the step 2) to the tetrahydrofuran, the tetrasodium ethylenediamine tetraacetate and the long-chain halogenated alkane is 1: (3-5):1: (1-1.2).
8. The method for preparing the strong decontamination environmental protection cleanser according to claim 1, wherein the long-chain halogenated alkane is one or more selected from the group consisting of chlorooctadecane, chlorohexadecane, bromooctadecane and bromohexadecane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010196744.0A CN111704962A (en) | 2017-11-12 | 2017-11-12 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711110629.1A CN107881020B (en) | 2017-11-12 | 2017-11-12 | Strong decontamination environment-friendly cleaning agent |
| CN202010196744.0A CN111704962A (en) | 2017-11-12 | 2017-11-12 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711110629.1A Division CN107881020B (en) | 2017-11-12 | 2017-11-12 | Strong decontamination environment-friendly cleaning agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111704962A true CN111704962A (en) | 2020-09-25 |
Family
ID=61780334
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010196744.0A Withdrawn CN111704962A (en) | 2017-11-12 | 2017-11-12 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
| CN201711110629.1A Active CN107881020B (en) | 2017-11-12 | 2017-11-12 | Strong decontamination environment-friendly cleaning agent |
| CN202010196754.4A Withdrawn CN111704966A (en) | 2017-11-12 | 2017-11-12 | Preparation method and application of antibacterial surfactant |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711110629.1A Active CN107881020B (en) | 2017-11-12 | 2017-11-12 | Strong decontamination environment-friendly cleaning agent |
| CN202010196754.4A Withdrawn CN111704966A (en) | 2017-11-12 | 2017-11-12 | Preparation method and application of antibacterial surfactant |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN111704962A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680285A (en) * | 2020-12-29 | 2021-04-20 | 上海塞寇文化传播有限公司 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114107998A (en) * | 2021-12-06 | 2022-03-01 | 佛山市顺德区正泽精细化工有限公司 | Environment-friendly cleaning degreaser |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035733A1 (en) * | 2001-09-27 | 2003-05-01 | Cytec Technology Corp. | Process for improving the shelf life of a hindered phenol antioxidant |
| US20050065182A1 (en) * | 2003-09-23 | 2005-03-24 | Papazoglou Elisabeth S. | Method and compositions for chronic wound care |
| CN102051273A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Carpet cleaner |
| CN104059789A (en) * | 2014-06-30 | 2014-09-24 | 李兆源 | Strong decontamination cleaner |
| CN104830572A (en) * | 2015-03-13 | 2015-08-12 | 周华庆 | Leather cleaning agent |
| CN105623865A (en) * | 2014-10-31 | 2016-06-01 | 张媛媛 | Brightener for household electrical appliance |
| CN106977687A (en) * | 2017-04-27 | 2017-07-25 | 久盛地板有限公司 | Environment-protecting polyurethane antibacterial adhesive and preparation method thereof |
| CN107118852A (en) * | 2017-06-16 | 2017-09-01 | 苏州锐耐洁电子科技新材料有限公司 | A kind of cleaning agent of strong dirt-removing |
| CN107129881A (en) * | 2017-06-12 | 2017-09-05 | 苏州锐耐洁电子科技新材料有限公司 | A kind of restraining and sterilizing bacteria high-performance environment-friendly cleaning agent |
-
2017
- 2017-11-12 CN CN202010196744.0A patent/CN111704962A/en not_active Withdrawn
- 2017-11-12 CN CN201711110629.1A patent/CN107881020B/en active Active
- 2017-11-12 CN CN202010196754.4A patent/CN111704966A/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003035733A1 (en) * | 2001-09-27 | 2003-05-01 | Cytec Technology Corp. | Process for improving the shelf life of a hindered phenol antioxidant |
| US20050065182A1 (en) * | 2003-09-23 | 2005-03-24 | Papazoglou Elisabeth S. | Method and compositions for chronic wound care |
| CN102051273A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Carpet cleaner |
| CN104059789A (en) * | 2014-06-30 | 2014-09-24 | 李兆源 | Strong decontamination cleaner |
| CN105623865A (en) * | 2014-10-31 | 2016-06-01 | 张媛媛 | Brightener for household electrical appliance |
| CN104830572A (en) * | 2015-03-13 | 2015-08-12 | 周华庆 | Leather cleaning agent |
| CN106977687A (en) * | 2017-04-27 | 2017-07-25 | 久盛地板有限公司 | Environment-protecting polyurethane antibacterial adhesive and preparation method thereof |
| CN107129881A (en) * | 2017-06-12 | 2017-09-05 | 苏州锐耐洁电子科技新材料有限公司 | A kind of restraining and sterilizing bacteria high-performance environment-friendly cleaning agent |
| CN107118852A (en) * | 2017-06-16 | 2017-09-01 | 苏州锐耐洁电子科技新材料有限公司 | A kind of cleaning agent of strong dirt-removing |
Non-Patent Citations (1)
| Title |
|---|
| 刘祥: "乙二胺四乙酸合成双子型阳离子表面活性剂", 《上海化工》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112680285A (en) * | 2020-12-29 | 2021-04-20 | 上海塞寇文化传播有限公司 | Preparation method of environment-friendly cleaning agent with strong decontamination effect |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111704966A (en) | 2020-09-25 |
| CN107881020B (en) | 2020-05-01 |
| CN107881020A (en) | 2018-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109628947B (en) | Environment-friendly neutral cleaning agent and preparation method and application thereof | |
| US6048831A (en) | Surfactant composition | |
| CN107881020B (en) | Strong decontamination environment-friendly cleaning agent | |
| US8685912B2 (en) | Detergent for metal | |
| CN101684558A (en) | Water-base cleaning agent composition for cleaning metal parts | |
| EP1295935A1 (en) | Detergent composition | |
| CN1316497A (en) | Water-base composite detergent for metallic parts | |
| CN108277101B (en) | Efficient cleaning agent for electronic products | |
| CN109370797B (en) | Neutral cleaning agent for mobile phone cover plate glass | |
| CN108559650B (en) | Antibacterial glass cleaning agent and preparation method and application thereof | |
| JP2960387B2 (en) | Alkaline cleaning composition for steel sheets | |
| CN109735397B (en) | Wax and particle removing cleaning agent for L ED sapphire substrate, preparation method, application and cleaning method | |
| JP7320839B2 (en) | How to use rinse agent and rinse agent | |
| EP3416999A1 (en) | Alkoxylated phenol derivatives | |
| CN110565104A (en) | Environment-friendly spray cleaning agent and preparation method thereof | |
| CN111349944A (en) | Tensile oil cleaning agent and preparation method thereof | |
| EP3719104B1 (en) | Surfactant and detergent containing surfactant | |
| CN114561252A (en) | Low-residue efficient cleaning agent and preparation method thereof | |
| CN108350394A (en) | aqueous formulation with good storage capacity | |
| US5965509A (en) | Aqueous based solvent free cleaner compositions containing a blend of polyoxyalkylene block copolymers and fatty alcohols oxyethylate moieties | |
| JP2010275362A (en) | Detergent composition for fiber | |
| US5958859A (en) | Aqueous based solvent free cleaner compositions containing a blend of polyoxyalkylene block copolymers | |
| CN118240626A (en) | Silicon wafer cleaning additive and silicon wafer cleaning method | |
| KR100357709B1 (en) | multifunctional cleaning agent | |
| CN108456595A (en) | A kind of cleaning agent for electronic material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20200925 |