CN108219615A - A kind of novel aqueous acrylic paint - Google Patents
A kind of novel aqueous acrylic paint Download PDFInfo
- Publication number
- CN108219615A CN108219615A CN201810037163.5A CN201810037163A CN108219615A CN 108219615 A CN108219615 A CN 108219615A CN 201810037163 A CN201810037163 A CN 201810037163A CN 108219615 A CN108219615 A CN 108219615A
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- novel aqueous
- acrylic paint
- aqueous acrylic
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of novel aqueous acrylic paints, include the raw material of following parts by weight, 40~45 parts of acrylic resin, 12~15 parts of Amino resin, 8~10 parts of inositol hexaphosphate, 0.8~1 part of initiator, 10~12 parts of talcum powder, 0.3~0.5 part of dispersant, 0.2~0.5 part of antifoaming agent, 20~25 parts of deionized water, 15~20 parts of absolute ethyl alcohol, 3~5 parts of kaolin, 0.7~1.5 part of pigment.Novel acrylic paint has good water resistance, resistance to salt water, resistance to petroleum product, chemical reagent resistance and heat resistance made from present invention process formula；Therefore novel acrylic paint performance is better than conventional acrylic paint in the market, conducive to popularization.
Description
Technical field
The present invention relates to paint technology field, specially a kind of novel aqueous acrylic paint.
Background technology
At present, acrylic paint in the market mainly has two kinds, and one kind is solvent-type acrylic paint, it is by acrylic acid tree
Fat, extender pigment, auxiliary agent, organic solvent etc. are formulated, which is widely used in the paint of metal material, wood furniture.Separately
One kind is water soluble acrylic acid paint, it be by the auxiliary agents such as acrylic acid or acrylic acid ester emulsion, extender pigment, antifoaming agent, levelling agent and
Water etc. is formulated, which is commonly used in the brushing of external and internal wall.Solvent-type acrylic paint and water soluble acrylic acid paint respectively have excellent
Shortcoming, solvent-type acrylic paint paint film is bright, hard, has good guarantor's color, a Gloss Retention, water resistance and adhesive force is good,
And can be prolonged constant, paint film fast drying, heat-resist, weather resistance is good, has preferable outdoor durable, can be in relatively low temperature
Under the conditions of apply, the shortcomings that paint, can be damaged to human body and environment containing a large amount of organic solvent in paint.
Organic solvent is free of in water soluble acrylic acid paint so this is a kind of environment-friendly type paint, but existing water paint is still
There are the defects of corrosion resistant performance is poor, environmental-protecting performance is poor, water resistance and fire line are bad.
Invention content
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of novel aqueous acrylic paint, current third is solved
The problem of olefin(e) acid paint corrosion resistant performance is poor, environmental-protecting performance is poor, water resistance and fire line are bad.
(2) technical solution
To achieve the above object, the present invention provides following technical solution：A kind of novel aqueous acrylic paint, including following
The raw material of parts by weight：40~45 parts of acrylic resin, 8~10 parts of inositol hexaphosphate, draws at 12~15 parts of Amino resin
Send out 0.8~1 part of agent, 10~12 parts of talcum powder, 0.3~0.5 part of dispersant, 0.2~0.5 part of antifoaming agent, deionized water 20~25
Part, 15~20 parts of absolute ethyl alcohol, 3~5 parts of kaolin, 0.7~1.5 part of pigment.
Preferably, 3~5 parts of blanc fixe is also added into above-mentioned novel aqueous acrylic paint dispensing.
Preferably, the granularity of the blanc fixe is 700~800 mesh.
Preferably, the granularity of the talcum powder is 1200~1300 mesh.
Preferably, the initiator is specially one in benzoyl, peroxy dicarbonate and cumyl peroxide
Kind is several.
Preferably, the pigment is specially one or more of red lead, Xin Luo Huangs and aluminium silver powder.
Preferably, the dispersant is specially the addition product of fatty acid ethylene oxide, polyethylene glycol type polyalcohol and poly- second
The one or more of alkene imine derivative.
Preferably, the antifoaming agent is specially one or more of octanol, dimethicone and ST-50.
Preferably, 5~8 parts of fire retardant is also added into above-mentioned novel aqueous acrylic paint dispensing.
Preferably, the fire retardant is specially one kind in tetrabromobisphenol A, hexabromocyclododecane and decabromodiphenyl ether
It is or several.
(3) advantageous effect
The present invention provides a kind of novel aqueous acrylic paints, have following advantageous effect：
Due to adding inositol hexaphosphate, talcum powder, kaolin and precipitated sulfur in conventional acrylic paint formulation
Sour barium and fire retardant, so as to make novel acrylic paint obtained with good water resistance, resistance to salt water, resistance to petroleum product
Property, chemical reagent resistance and heat resistance；Therefore novel acrylic paint performance is painted better than conventional acrylic in the market,
Conducive to popularization.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work
Example, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of novel aqueous acrylic paint includes the raw material of following parts by weight：40 parts of acrylic resin, methyl-etherified amino
12 parts of resin, 8 parts of inositol hexaphosphate, 0.8 part of initiator, 10 parts of talcum powder, 0.3 part of dispersant, 0.2 part of antifoaming agent, go from
Sub- 20 parts of water, 15 parts of absolute ethyl alcohol, 3 parts of kaolin, 0.7 part of pigment.
Be also added into above-mentioned novel aqueous acrylic paint dispensing 3 parts blanc fixe and 5 parts of fire retardant；
And the granularity of the blanc fixe is 700 mesh, fire retardant is specially tetrabromobisphenol A.
The granularity of the talcum powder is 1200 mesh；The initiator is specially benzoyl；The pigment is specially red lead；Institute
State the addition product that dispersant is specially fatty acid ethylene oxide；The antifoaming agent is specially octanol.
Embodiment 2
A kind of novel aqueous acrylic paint includes the raw material of following parts by weight：43 parts of acrylic resin, methyl-etherified amino
13 parts of resin, 9 parts of inositol hexaphosphate, 0.9 part of initiator, 11 parts of talcum powder, 0.4 part of dispersant, 0.35 part of antifoaming agent, go from
Sub- 22.5 parts of water, 17.5 parts of absolute ethyl alcohol, 4 parts of kaolin, 1.1 parts of pigment.
Be also added into above-mentioned novel aqueous acrylic paint dispensing 4 parts blanc fixe and 6.5 parts fire-retardant
Agent；And the granularity of the blanc fixe is 750 mesh, fire retardant be specially hexabromocyclododecane with.
The granularity of the talcum powder is 1250 mesh；The initiator is specially peroxy dicarbonate；The pigment is specific
Wei Xin Luo are yellow；The dispersant is specially polyethylene glycol type polyalcohol；The antifoaming agent is specially dimethicone.
Embodiment 3
A kind of novel aqueous acrylic paint includes the raw material of following parts by weight：45 parts of acrylic resin, methyl-etherified amino
5 parts of resin, 10 parts of inositol hexaphosphate, 1 part of initiator, 12 parts of talcum powder, 0.5 part of dispersant, 0.5 part of antifoaming agent, deionization
25 parts of water, 20 parts of absolute ethyl alcohol, 5 parts of kaolin, 1.5 parts of pigment.
Be also added into above-mentioned novel aqueous acrylic paint dispensing 5 parts blanc fixe and 8 parts of fire retardant；
And the granularity of the blanc fixe is 800 mesh, fire retardant is specially decabromodiphenyl ether.
The granularity of the talcum powder is 1300 mesh；The initiator is specially cumyl peroxide；The pigment is specific
For aluminium silver powder；The dispersant is specially polyethylenimine derivates；The antifoaming agent is specially ST-50.
Performance test analysis：
Water resistance：Water resistance refers to the measurement of the damage capability of resist coating film water.It is under the defined conditions, to incite somebody to action that it, which is tested,
Film test plate (panel) impregnates in water, observes it whether there is phenomena such as whitening, loss of gloss, blistering, come off.And the difficulty or ease journey of reinstatement state
Degree.This service life that will directly affect film.Its detection method can be by GB/T 1733《Paint film water resistance measuring method》Middle regulation
It carries out.
Resistance to salt water：Property resistance to salt water refers to resistivity of the film to salt water contamination.It can be judged with salt water resistant test
The barrier propterty of film product.Its detection method can be by GB/T 1763-89《The agents measuring method of paint film salt water resistance》Or
GB16834-89《The measure of marine paint resistance to salt water》Middle regulation carries out.
Resistance to petroleum product：Resistance to petroleum product refers to resist coating film petroleum product (i.e. gasoline, lubricating oil and solvent etc.)
Damage capability measurement.Its detection method can be by GB/T 1734-93《Paint film petrol-resistance measuring method》Or HG/T 3343《Paint
Film oil resistivity measuring method》Middle regulation carries out.
Chemical reagent resistance：Chemical reagent resistance refers to the energy that resist coating film acid, alkali and salt and other chemicals destroy
Power.Its detection method can be by GB/T 1763《Paint film chemical reagent resistance assay method》With GB/T 9274-88《Paint and varnish
The measure of resistant to liquid medium》And GB/T 9265《The measure of building coating coating alkali resistance》Middle regulation carries out.
Heat resistance：Heat resistance refers to that film can keep the resistance to non-destructive ability of original performance at a high temperature of certain.Its
Detection method can be by GB 1735-79《Paint film Heat-tolerance Determination method》Middle regulation carries out.
The paint as made from any one of embodiment 1-3 formulas is tested for the property, test result is as follows table institute
Show：
As can be seen from the above table, novel acrylic paint made from the formula is with good water resistance, resistance to salt water, resistance to
Petroleum product, chemical reagent resistance and heat resistance；Therefore novel acrylic paint performance is better than common third in the market
Olefin(e) acid paints, conducive to popularization.
Inositol hexaphosphate and its salt can be one layer very thin in metal surface formation, and again fine and close organic phosphating coat,
The electrode potential for making the inert metal surfaces such as the electrode potential of metal surface and platinum, gold is close, so as to slow down corrosion of metal.It grinds
Study carefully and show that inositol hexaphosphate is excellent corrosion inhibiter of the metals such as copper, tin, aluminium and aluminium alloy, zinc, steel in aqueous solution, inositol six
Phosphate is that a kind of chelant acts on extremely strong metal cheating agents, the significant corrosion inhibiter of corrosion protection result, and inositol hexaphosphate can
The corrosion-resistant additive of the toxicity such as substitute and chromate, therefore be added into acrylic paint to reach and prevent well
Corrosive effect, and asepsis environment-protecting, conducive to popularization.
Kaolin has matter soft, and is easily dispersed in water, with good plasticity and high viscosity and excellent antiacid
Dissolubility and fire resistance；Due to talcum powder strong adsorption, easily high degree of dispersion, therefore can prevent paint from precipitating in the oil, again
It can make suspending agent, talcum powder can also adjust gloss, while talcum stable chemical performance, and strong covering power can prevent paint
Layer aging ruptures and improves weatherproof ability；
Therefore suitable kaolin and talcum powder are added in paint formulation, the antiacid molten of paint entirety can be greatly enhanced
Property, fire resistance and it is anti-aging rupture and weathering resistance characteristic.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any this practical relationship or sequence.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Non-exclusive inclusion, so that process, method, article or equipment including a series of elements not only will including those
Element, but also including other elements that are not explicitly listed or further include as this process, method, article or equipment
Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of novel aqueous acrylic paint, which is characterized in that include the raw material of following parts by weight：Acrylic resin 40~45
Part, 12~15 parts of Amino resin, 8~10 parts of inositol hexaphosphate, 0.8~1 part of initiator, 10~12 parts of talcum powder,
0.3~0.5 part of dispersant, 0.2~0.5 part of antifoaming agent, 20~25 parts of deionized water, 15~20 parts of absolute ethyl alcohol, kaolin 3~
5 parts, 0.7~1.5 part of pigment.
2. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：In above-mentioned novel aqueous propylene
3~5 parts of blanc fixe is also added into sour paint formulation.
3. a kind of novel aqueous acrylic paint according to claim 2, it is characterised in that：The grain of the blanc fixe
It spends for 700~800 mesh.
4. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：The granularity of the talcum powder is
1200~1300 mesh.
5. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：The initiator is specially benzene
One or more of formyl, peroxy dicarbonate and cumyl peroxide.
6. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：The pigment is specially red
One or more of red, Xin Luo Huangs and aluminium silver powder.
7. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：The dispersant is specially fat
The one or more of the addition product of fat acid ethylene oxide, polyethylene glycol type polyalcohol and polyethylenimine derivates.
8. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：The antifoaming agent is specially pungent
One or more of alcohol, dimethicone and ST-50.
9. a kind of novel aqueous acrylic paint according to claim 1, it is characterised in that：In above-mentioned novel aqueous propylene
5~8 parts of fire retardant is also added into sour paint formulation.
10. a kind of novel aqueous acrylic paint according to claim 9, it is characterised in that：The fire retardant is specially
One or more of tetrabromobisphenol A, hexabromocyclododecane and decabromodiphenyl ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810037163.5A CN108219615A (en) | 2018-01-15 | 2018-01-15 | A kind of novel aqueous acrylic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810037163.5A CN108219615A (en) | 2018-01-15 | 2018-01-15 | A kind of novel aqueous acrylic paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108219615A true CN108219615A (en) | 2018-06-29 |
Family
ID=62640359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810037163.5A Pending CN108219615A (en) | 2018-01-15 | 2018-01-15 | A kind of novel aqueous acrylic paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN108219615A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054541A (en) * | 2018-07-30 | 2018-12-21 | 界首市鑫全龙粮食机械购销有限公司 | A kind of rice harvester surface protective coating |
| CN111378336A (en) * | 2020-03-24 | 2020-07-07 | 安徽登王化工有限公司 | Water-based metallic paint and preparation method thereof |
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| CN101698771A (en) * | 2009-09-24 | 2010-04-28 | 中国海洋石油总公司 | Water-based primer-topcoat braking paint and preparation method thereof |
| CN101735703A (en) * | 2009-12-15 | 2010-06-16 | 重庆斯耐博涂料有限公司 | Aqueous environment-friendly packaging steel drum paint and preparation method thereof |
| CN103173082A (en) * | 2013-03-07 | 2013-06-26 | 宁波三力新材料有限公司 | Water-based metal coating |
| CN103725146A (en) * | 2014-01-20 | 2014-04-16 | 天津市新丽华色材有限责任公司 | Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed |
| CN106554706A (en) * | 2016-11-29 | 2017-04-05 | 天津市瑞宝绿色纳米涂料有限公司 | A kind of waterborne epoxy modified acrylic resin aluminium paint of use oiliness aluminum paste |
| CN107043580A (en) * | 2017-06-29 | 2017-08-15 | 合肥达户电线电缆科技有限公司 | A kind of video monitoring equipment support antirust paint and preparation method thereof |
-
2018
- 2018-01-15 CN CN201810037163.5A patent/CN108219615A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698771A (en) * | 2009-09-24 | 2010-04-28 | 中国海洋石油总公司 | Water-based primer-topcoat braking paint and preparation method thereof |
| CN101735703A (en) * | 2009-12-15 | 2010-06-16 | 重庆斯耐博涂料有限公司 | Aqueous environment-friendly packaging steel drum paint and preparation method thereof |
| CN103173082A (en) * | 2013-03-07 | 2013-06-26 | 宁波三力新材料有限公司 | Water-based metal coating |
| CN103725146A (en) * | 2014-01-20 | 2014-04-16 | 天津市新丽华色材有限责任公司 | Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed |
| CN106554706A (en) * | 2016-11-29 | 2017-04-05 | 天津市瑞宝绿色纳米涂料有限公司 | A kind of waterborne epoxy modified acrylic resin aluminium paint of use oiliness aluminum paste |
| CN107043580A (en) * | 2017-06-29 | 2017-08-15 | 合肥达户电线电缆科技有限公司 | A kind of video monitoring equipment support antirust paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054541A (en) * | 2018-07-30 | 2018-12-21 | 界首市鑫全龙粮食机械购销有限公司 | A kind of rice harvester surface protective coating |
| CN111378336A (en) * | 2020-03-24 | 2020-07-07 | 安徽登王化工有限公司 | Water-based metallic paint and preparation method thereof |
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Application publication date: 20180629 |
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