CN106554706A - A kind of waterborne epoxy modified acrylic resin aluminium paint of use oiliness aluminum paste - Google Patents
A kind of waterborne epoxy modified acrylic resin aluminium paint of use oiliness aluminum paste Download PDFInfo
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- CN106554706A CN106554706A CN201611074639.XA CN201611074639A CN106554706A CN 106554706 A CN106554706 A CN 106554706A CN 201611074639 A CN201611074639 A CN 201611074639A CN 106554706 A CN106554706 A CN 106554706A
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- acrylic resin
- modified acrylic
- epoxy modified
- waterborne epoxy
- aluminium paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to a kind of waterborne epoxy modified acrylic resin aluminium paint of use oiliness aluminum paste, the aluminium paint is prepared from by the raw material of following percentage by weight：Waterborne epoxy modified acrylic resin 30 70%, deionized water 10 30%, wetting agent 0.5 1%, pH adjusting agent 2 6%, thickener 0.5 1%, cosolvent 5 8%, amino resins 3 6%, oiliness aluminum paste 5 6%, the percentage by weight sum of the raw material is 100%；Described cosolvent is the composition of ethylene glycol monobutyl ether and isopropanol.The waterborne epoxy modified acrylic resin aluminium paint that the present invention is prepared, it is cheap, possess outstanding market competition more power, storage stability more than 6 months, and excellent performance, soaking-resistant, resistance to neutral salt spray, artificial ageing resistance, VOC emission amount is less than 60g/L.Film-forming temperature is low, save energy.
Description
Technical field
The present invention relates to water aluminum powder paint technical field, more particularly to a kind of use oiliness aluminum paste is waterborne epoxy modified
Acrylic resin aluminium paint and preparation method thereof.
Background technology
Metallic aluminium is active tellurium, and Yi Yushui, soda acid react, therefore are applied to water-base resin system
When, it is necessary to through special surface treatment.At present, on market water aluminum-silver slurry preparation method, substantially add corrosion inhibitor,
Chromic acid or its salt deactivation method.Inorganic matter coated with silica method, inorganic organic matter double-coating or hydridization cladding process.These methods
An aluminium and water segregation are intended to undoubtedly.But existing water aluminum-silver slurry in the market is because technological requirement is very rigorous, natural
For, price is generally higher, is more than 3 times of oiliness aluminium paint, and production technology is unskillful, causes product extremely unstable
Fixed, not exclusively, either storage or the presence in water-based system in the form of aluminum paste all can be with water for the parcel of aluminium powder
Contact, causes to react Al+H2O→Al(OH)3+H2↑ generation, affect coating quality and performance, cause damage to client.
The content of the invention
Stability and Cost Problems in order to solve aluminum paste and water-based system of the invention, there is provided a kind of to use oiliness aluminium
Epoxy modified acrylic resin aluminium paint of silver paste and preparation method thereof.
The present invention is adopted the following technical scheme that：
A kind of waterborne epoxy modified acrylic resin aluminium paint, the aluminium paint are prepared by the raw material of following percentage by weight
Form：
Waterborne epoxy modified acrylic resin 30-70%, deionized water 10-30%, wetting agent 0.5-1%, pH adjusting agent
2-6%, thickener 0.5-1%, cosolvent 5-8%, amino resins 3-6%, oiliness aluminum paste 5-6%, the weight of the raw material
Percentage sum is 100%；Described cosolvent is the composition of ethylene glycol monobutyl ether and isopropanol.
Preferably, the percentage by weight of the raw material is：Waterborne epoxy modified acrylic resin 50%, deionized water
27.9%th, wetting agent 0.8%, pH adjusting agent 3%, thickener 0.8%, cosolvent 8%, amino resins 4.5%, oiliness aluminum paste
5%.
Described waterborne epoxy modified acrylic resin is provided by Changzhou Guang Shu Chemical Industry Science Co., Ltd, model
GS-355 or GS-330.
Described wetting agent is ammonium polyacrylate salt, polycarboxylic acids ammonium salt, polycarboxylate sodium, polyethers phosphate, modified polyether
In one or more combination.Preferably, TEGO Dispers 655 of the described wetting agent for TEGO companies.
Described pH adjusting agent be AMP-95, N, in N- dimethylethanolamines, triethanolamine one or more
Combination.
Described thickener is polyurethane associative thickener, alkali swelling type thickener, in organobentonite thickener
One or more combination.
Described cosolvent is the mass ratio 1 of ethylene glycol monobutyl ether and isopropanol:3 composition.
Described amino resins is part Amino resin, full Amino resin, in high imino group resin
One or two.
Described oiliness aluminum paste is the kind generally sold in market, typically also a small amount of high boiling organic solvent.
Present invention also offers the preparation method of above-mentioned waterborne epoxy modified acrylic resin aluminium paint, including following step
Suddenly：
2/3 isopropanol is put in container, is stirred with 200r/min, be subsequently adding oiliness aluminum paste, stir 2-3min,
30min is stood, upper strata mixed liquor is isolated, 1/3 isopropanol is added again, is stirred, it is standby；Obtain mixture A；
Amino resins is well mixed with ethylene glycol monobutyl ether standby.Obtain mixture B；
Waterborne epoxy modified acrylic resin is added in paint mixing tank, condition of the low whipping speed for 200-300r/min
Under, pH adjusting agent is added, after stirring 2-3min, wetting agent is added, is stirred 2-3min, add deionized water, stir 10-20min；
Mixture A is added in paint mixing tank, with the mixing speed of 200-300r/min, 20-30min is stirred, afterwards slowly
Mixture B is added, is continued stirring 10-20min, thickener is slowly added in paint mixing tank, finally continue stirring 10-20min, mistake
Filter, packaging, gets product.
The waterborne epoxy modified acrylic resin aluminium paint of the present invention, select first be cheap, production technology
Jing very ripe oiliness aluminum paste, oiliness aluminum paste form aluminum paste shape using (water insoluble) dissolving of high boiling organic solvent
State, completely isolated water and air.It is just more stable in the form of supply of material, water prescription using front, first with isopropanol oiliness aluminium
Silver paste dissolves, and the mineral oil in oiliness aluminum paste and high-flash aromatics are simply extracted, upper strata mixed liquor is isolated, so
After add a kind of wetting agent, be a kind of modified polyether containing high pigment affinity groups, by TEGO provide, model TEGO
Dispers 655, in fact, being a kind of polymer for having package action to aluminium powder, structural formula is：
It is by styrene oxide, polyethers and the esterification of the polymer with phosphoric acid root architecture is formed, and phosphate radical ionizes out H+,
Polymer is made in acidity, so as to react with aluminium, the metal complex of complexity is formed on the surface of aluminium, in the form of passivation layer
Water in isolation aluminium and coating system, so that coating maintains storage stability.
Waterborne epoxy modified acrylic resin (GS-355 or GS-330) the collection water-borne acrylic resin that the present invention is adopted is excellent
Different cohesiveness, weatherability, film forming protect the excellent tack of light colour retention and aqueous epoxy resins, anticorrosive property, chemically-resistant
The advantages of moral character, heat endurance, is a kind of very high resin of combination property, can meet wanting for client in all its bearings
Ask.
The present invention is had the advantage that：
The waterborne epoxy modified acrylic resin aluminium paint that the present invention is prepared, it is cheap, possess outstanding market competing
Strive power, storage stability more than 6 months, and excellent performance, soaking-resistant, resistance to neutral salt spray, artificial ageing resistance, VOC emission amount
Less than 60g/L.Film-forming temperature is low, save energy.
Specific embodiment
With reference to specific embodiment, the invention will be further described, but does not limit protection scope of the present invention.
Embodiment 1
A kind of preparation method of waterborne epoxy modified acrylic resin aluminium paint, comprises the steps：
Waterborne epoxy modified acrylic resin (GS-355 of Changzhou Guang Shu Chemical Industry Science Co., Ltd) 10kg is weighed, is modified
Polyethers wetting agent (TEGO Dispers 655) 0.16kg, deionized water 5.58kg, N, N- dimethylethanolamine 0.6kg, isopropyl
Alcohol 1.2kg, ethylene glycol monobutyl ether 0.4kg, oiliness aluminum paste 1kg, high imino group resin (the special special type chemical industry 325 of cyanogen) 0.9kg, gather
Urethane type thickener (Hai Mingsi. De Qian Specialty Chemicals company 299) 0.16kg.
First 0.8kg isopropanols are put in container, are stirred with 200r/min, is subsequently adding 1kg oiliness aluminum pastes, stirred
2min, stands 30min, isolates upper strata mixed liquor, adds 0.4kg isopropanols again, stirs, standby；Obtain final product mixture
A；0.9kg amino resins is well mixed with 0.4kg ethylene glycol monobutyl ethers standby, obtains final product mixture B；
10kg waterborne epoxy modified acrylic resins are added in paint mixing tank, condition of the low whipping speed for 300r/min
Under, add 0.6kg N, N- dimethylethanolamines after stirring 3min, to add 0.16kg wetting agents, stir 3min, add 5.58kg
Deionized water, stirs 20min.
The mixture A being stirred is added in paint mixing tank, with the mixing speed of 200r/min, 20min is stirred, afterwards slowly
Mixture B is added, is continued stirring 10min, 0.16kg thickeners is slowly added in paint mixing tank, finally continue stirring 20min, mistake
Filter, packaging, gets product.
Waterborne epoxy modified acrylic resin aluminium paint prepared by embodiment 1, it is cheap, possess outstanding market
Competitiveness, storage stability more than 6 months, and excellent performance, 0 grade of adhesive force, resistance to 50kg impacts, hardness 3H, resistance to MEK are wiped
More than 100 times, soaking-resistant, resistance to neutral salt spray reach more than 700h, and more than artificial ageing resistance 500h, VOC emission amount are not enough
60g/L.Film-forming temperature is low, save energy.
Claims (10)
1. a kind of waterborne epoxy modified acrylic resin aluminium paint, it is characterised in that：The aluminium paint is by following percentage by weight
Raw material be prepared from：Waterborne epoxy modified acrylic resin 30-70%, deionized water 10-30%, wetting agent 0.5-1%, pH
Conditioning agent 2-6%, thickener 0.5-1%, cosolvent 5-8%, amino resins 3-6%, oiliness aluminum paste 5-6%, the raw material
Percentage by weight sum be 100%；Described cosolvent is the composition of ethylene glycol monobutyl ether and isopropanol.
2. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1, it is characterised in that：The raw material
Percentage by weight is：Waterborne epoxy modified acrylic resin 50%, deionized water 27.9%, wetting agent 0.8%, pH adjusting agent
3%th, thickener 0.8%, cosolvent 8%, amino resins 4.5%, oiliness aluminum paste 5%.
3. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
Waterborne epoxy modified acrylic resin is by the offer of Changzhou Guang Shu Chemical Industry Science Co., Ltd, model GS-355 or GS-330.
4. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
Wetting agent is ammonium polyacrylate salt, polycarboxylic acids ammonium salt, polycarboxylate sodium, polyethers phosphate, one or two in modified polyether
Combination above.
5. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 4, it is characterised in that：Described wetting
TEGO Dispers 655 of the agent for TEGO companies.
6. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
PH adjusting agent be AMP-95, N, one or more the combination in N- dimethylethanolamines, triethanolamine.
7. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
Thickener is polyurethane associative thickener, alkali swelling type thickener, one or more in organobentonite thickener
Combination.
8. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
Cosolvent is the mass ratio 1 of ethylene glycol monobutyl ether and isopropanol:3 composition.
9. a kind of waterborne epoxy modified acrylic resin aluminium paint according to claim 1 or claim 2, it is characterised in that：Described
Amino resins is part Amino resin, full Amino resin, one or two in high imino group resin.
10. the preparation method of waterborne epoxy modified acrylic resin aluminium paint described in any one of claim 1-9, its feature exist
In：Comprise the steps：
2/3 isopropanol is put in container, is stirred with 200r/min, be subsequently adding oiliness aluminum paste, stir 2-3min, stood
30min, isolates upper strata mixed liquor, adds 1/3 isopropanol again, stirs, standby；Obtain mixture A；
Amino resins is well mixed with ethylene glycol monobutyl ether standby.Obtain mixture B；
Waterborne epoxy modified acrylic resin is added in paint mixing tank, under conditions of low whipping speed is 200-300r/min, plus
Enter pH adjusting agent, after stirring 2-3min, add wetting agent, stir 2-3min, add deionized water, stir 10-20min；
Mixture A is added in paint mixing tank, with the mixing speed of 200-300r/min, 20-30min is stirred, after be slowly added to
Mixture B, continues stirring 10-20min, thickener is slowly added in paint mixing tank, finally continues stirring 10-20min, filters,
Packaging, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611074639.XA CN106554706B (en) | 2016-11-29 | 2016-11-29 | A kind of waterborne epoxy modified acrylic resin aluminium paint using oiliness aluminum paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611074639.XA CN106554706B (en) | 2016-11-29 | 2016-11-29 | A kind of waterborne epoxy modified acrylic resin aluminium paint using oiliness aluminum paste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106554706A true CN106554706A (en) | 2017-04-05 |
| CN106554706B CN106554706B (en) | 2019-07-16 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033750A (en) * | 2017-05-17 | 2017-08-11 | 河北晨阳工贸集团有限公司 | A kind of groove pipe fitting watersoluble baking dip painting and preparation method thereof |
| CN108219615A (en) * | 2018-01-15 | 2018-06-29 | 安徽龙谷商贸有限公司 | A kind of novel aqueous acrylic paint |
| CN112375443A (en) * | 2020-11-16 | 2021-02-19 | 北京红狮科技发展有限公司 | Water-based aluminum powder baking paint and preparation method thereof |
| CN115181461A (en) * | 2022-06-24 | 2022-10-14 | 擎天材料科技有限公司 | High-gloss water-based paint and preparation method and application thereof |
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| CN102212313A (en) * | 2010-04-01 | 2011-10-12 | 闵玉清 | Silver paste coating on curtain |
| US20120208020A1 (en) * | 2011-02-10 | 2012-08-16 | E.I. Du Pont De Nemours And Company | Coalescing agent for waterborne coatings |
| CN103289012A (en) * | 2013-06-24 | 2013-09-11 | 上海诺恰化工有限公司 | Preparation method of water-borne coating additive for oily aluminum paste and water-borne coating prepared from water-borne coating auxiliary |
| CN104789082A (en) * | 2015-04-28 | 2015-07-22 | 廊坊立邦涂料有限公司 | High-temperature-resistant amino baking varnish and preparation method thereof |
| CN104962135A (en) * | 2015-06-12 | 2015-10-07 | 广州擎天材料科技有限公司 | Waterborne aluminum paste for decorative waterborne metallic shining coating and soaking production process thereof |
-
2016
- 2016-11-29 CN CN201611074639.XA patent/CN106554706B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212313A (en) * | 2010-04-01 | 2011-10-12 | 闵玉清 | Silver paste coating on curtain |
| US20120208020A1 (en) * | 2011-02-10 | 2012-08-16 | E.I. Du Pont De Nemours And Company | Coalescing agent for waterborne coatings |
| CN103289012A (en) * | 2013-06-24 | 2013-09-11 | 上海诺恰化工有限公司 | Preparation method of water-borne coating additive for oily aluminum paste and water-borne coating prepared from water-borne coating auxiliary |
| CN104789082A (en) * | 2015-04-28 | 2015-07-22 | 廊坊立邦涂料有限公司 | High-temperature-resistant amino baking varnish and preparation method thereof |
| CN104962135A (en) * | 2015-06-12 | 2015-10-07 | 广州擎天材料科技有限公司 | Waterborne aluminum paste for decorative waterborne metallic shining coating and soaking production process thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033750A (en) * | 2017-05-17 | 2017-08-11 | 河北晨阳工贸集团有限公司 | A kind of groove pipe fitting watersoluble baking dip painting and preparation method thereof |
| CN108219615A (en) * | 2018-01-15 | 2018-06-29 | 安徽龙谷商贸有限公司 | A kind of novel aqueous acrylic paint |
| CN112375443A (en) * | 2020-11-16 | 2021-02-19 | 北京红狮科技发展有限公司 | Water-based aluminum powder baking paint and preparation method thereof |
| CN115181461A (en) * | 2022-06-24 | 2022-10-14 | 擎天材料科技有限公司 | High-gloss water-based paint and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN106554706B (en) | 2019-07-16 |
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