CN106318143A - Wooden transfer power paint for aluminium profile - Google Patents
Wooden transfer power paint for aluminium profile Download PDFInfo
- Publication number
- CN106318143A CN106318143A CN201610716173.2A CN201610716173A CN106318143A CN 106318143 A CN106318143 A CN 106318143A CN 201610716173 A CN201610716173 A CN 201610716173A CN 106318143 A CN106318143 A CN 106318143A
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- CN
- China
- Prior art keywords
- wood grain
- section bar
- powdery paints
- aluminium section
- transfer printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/032—Powdery paints characterised by a special effect of the produced film, e.g. wrinkle, pearlescence, matt finish
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides wooden transfer power paint for aluminium profile, prepared from, by weight percentage, 50- 58% of unsaturated polyester resin; 3.8%-4.4% of TGIC; 24. 4%- 38.1% of precipitated barium sulphate; 0.8-1.2% of flatting agent; 0.5-1.5% of transferring printing auxiliaries; 0.2-0.4% of benzoin; 6.6-10.1% of painting. 1%. The high-definition and paper-tearing wood grain powder paint for aluminium profile is especially suitable for thermal-printing technology for aluminium profile, capable of obtaining excellent flatting property, meanwhile, the painting is easy to tear, strong in water resistance and has high definition without affecting the film hardness.
Description
Technical field
The present invention relates to technical field of coatings, particularly a kind of aluminium section bar transfer printing wood grain powdery paints.
Background technology
Powdery paints is a kind of novel without solvent 100% solid powdery coating, have solvent-free, pollution-free, can
Recovery, environmental protection, the saving energy and resource, reduce labor intensity and film mechanical strength high, thus at coating industry
Status rises increasingly.While focusing on powder coating safeguard function, people's requirement ornamental to powdery paints the most gradually carries
High.Aluminium section bar transfer printing wood grain powdery paints is a kind of novel to have a high ornamental powdery paints kind, the most extensively
It is applied to the aspects such as building doors and windows, furniture and office appliance, and application the most constantly expands, wide market.
Powdery paints transfer technique be first by transfer printing wood grain powder paint on aluminium section bar, after film-forming, stick
After woodgrained paper, by transfer technique, being transferred on film by the pattern of woodgrained paper, wood grain effect is clear, true to nature.But present stage is general
The frauds such as paper-tear picture difficulty, transfer figure stricture of vagina is smudgy clear degree and water-resistance property of coating difference easily occur during wooden supporter stricture of vagina powder transfer
Disease, thus limit the fast development of transfer printing wood grain powdery paints.
Summary of the invention
For solving above-mentioned technical problem, the invention provides a kind of aluminium section bar transfer printing wood grain powdery paints, it include with
Lower components by weight percent raw material:
It is adsorbed in modified alta-mud it is preferred that described transfer auxiliary agent is organo silane coupling agent according to 20wt%.
It is preferred that described organo silane coupling agent is VTES, amino silicane coupling agent and epoxy radicals
One in silane coupler and several.
It is preferred that the preparation method of described transfer auxiliary agent is pretreated filler method, specifically include following steps:
A, according to formula as below prepare silane coupler solution:
Silane coupler 40%,
Alcohol 52%,
Water 8%；
B and modified alta-mud premixing: modified alta-mud is put into solid blender, silane coupler solution according to
Modified alta-mud weight ratio is the amount of 1:2, is sprayed directly on modified alta-mud and stirs 10-30min, be allowed to fully dispersed all
After even, dry 2 hours under the conditions of 120 DEG C, prepare the transfer auxiliary agent that silane coupled agent content is 20wt%.
It is preferred that the preparation method of described transfer auxiliary agent is directly joining method, specifically include following steps:
Silane coupler divide 3-5 time the mode added directly be sprayed onto on the modified alta-mud putting into solid blender,
Add every time after, stir 5min, after all adding, stir 20-30min, silane coupler consumption according to modified alta-mud weight
Amount ratio is 1:5.
It is preferred that described alcohol is the one in methanol, ethanol and isopropanol.
It is preferred that described modified alta-mud is organobentonite or sodio modified alta-mud.
It is preferred that described saturated terminal carboxyl polyester resin acid number is 30-38mgKOH/g.
It is preferred that described levelling agent is acrylate copolymer.
Present invention also offers a kind of aluminium section bar transfer printing wood grain powdery paints, its preparation method comprises the following steps:
1) premixing: following raw material is put into the most together in compounding jar and carry out premixing:
2) melt extrude: carry out melt extruding by double screw extruder by the raw material after premixing, tabletting, broken,
Wherein extruder I district stabilizes to 105-115 DEG C, and II district temperature is 110-120 DEG C；
Pulverize and sieve: by ACM mill, the sheet stock after broken is carried out stage reduction, and wherein powder diameter is 20-85 micron,
Carrying out screening by rotary screen again and obtain powder coating product, screen cloth used by described rotary screen is 180 mesh.
The method have the advantages that
The aluminium section bar fine definition that the present invention provides, strong resistance to water, the wood grain powdery paints of easy paper-tear picture are particularly well-suited to
Aluminium section bar Thermal-printing Technology, can have easy paper-tear picture, strong resistance to water and the spy of fine definition while obtaining fabulous levelling
Point, does not affect hardness of film simultaneously.
Certainly, the arbitrary product implementing the present invention it is not absolutely required to reach all the above advantage simultaneously.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the present invention is clearly and completely described, it is clear that institute
The embodiment described is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention,
All other embodiments that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into this
The scope of bright protection.
Embodiment 1
It is prepared according to the following steps the wood grain powdery paints of aluminium section bar fine definition, strong resistance to water, easy paper-tear picture:
1, preparation transfer auxiliary agent
(1) according to formula as below preparation silane coupler solution:
Amino silicane coupling agent 40%
Ethanol 52%
Water 8%
(2) with modified alta-mud premixing: organobentonite is put into solid blender, and amino silicane coupling agent solution is pressed
According to being the amount of 1:2 with organobentonite weight ratio, it is sprayed directly on organobentonite and stirs 10-30min, being allowed to fully divide
Dissipate uniformly, then dry under the conditions of 120 DEG C about 2 hours, prepare the transfer auxiliary agent that silane coupled agent content is 20wt%；
Wherein amino silicane coupling agent uses the product of Dow corning companyOFS-6011；Have
Machine bentonite uses product B S-1A of Zhejiang Fenghong New Material Co., Ltd.；
2, the wood grain powdery paints of aluminium section bar fine definition, strong resistance to water, easy paper-tear picture is prepared:
(1) premixing: following raw material is put into together according to following percentage by weight and carries out premixing in compounding jar；
Wherein saturated polyester uses the product SJ4E of Anhui Shenjian New Material Co., Ltd., and blanc fixe uses expensive
State China adds the product W-44HB of fine mining industry company limited, and levelling agent uses the PV88 of Germany's moral letter profit chemistry；
(2) melt extrude: carry out melt extruding by double screw extruder by the raw material after premixing, tabletting, broken,
Wherein extruder I district stabilizes to 105-115 DEG C, and II district temperature is 110-120 DEG C；
(3) pulverize and sieve: by ACM mill, the sheet stock after broken is carried out stage reduction, and wherein powder diameter is that 20-85 is micro-
Rice, then carry out screening acquisition powder coating product by rotary screen, screen cloth used by described rotary screen is 180 mesh；
Prepared powdery paints is tested by relevant criterion, meets National Standard of the People's Republic of China's " aluminium alloy
Architectural shape Part IV: powder spray section bar " requirement of (GB5237.4-2008).
Embodiment 2
It is prepared according to the following steps the wood grain powdery paints of aluminium section bar fine definition, strong resistance to water, easy paper-tear picture:
1, preparation transfer auxiliary agent
Silane coupler divide 3-5 time the mode added directly be sprayed onto on the organobentonite putting into solid blender,
Add every time after, stir 5min, after all adding, stir 20-30min, silane coupler consumption according to organobentonite weight
Amount ratio is 1:5；
Wherein amino silicane coupling agent uses the product of Dow corning companyOFS-6011；
Organobentonite uses product B S-1A of Zhejiang Fenghong New Material Co., Ltd.；
2, the wood grain powdery paints of aluminium section bar fine definition, strong resistance to water, easy paper-tear picture is prepared:
(1) premixing: following raw material is put into together according to following percentage by weight and carries out premixing in compounding jar；
Wherein saturated polyester uses the product SJ4E of Anhui Shenjian New Material Co., Ltd., and blanc fixe uses expensive
State China adds the product W-44HB of fine mining industry company limited, and levelling agent uses the PV88 of Germany's moral letter profit chemistry；
(2) melt extrude: carry out melt extruding by double screw extruder by the raw material after premixing, tabletting, broken,
Wherein extruder I district stabilizes to 105-115 DEG C, and II district temperature is 110-120 DEG C；
(3) pulverize and sieve: by ACM mill, the sheet stock after broken is carried out stage reduction, and wherein powder diameter is that 20-85 is micro-
Rice, then carry out screening acquisition powder coating product by rotary screen, screen cloth used by described rotary screen is 180 mesh；
Prepared powdery paints is tested by relevant criterion, meets National Standard of the People's Republic of China's " aluminium alloy
Architectural shape Part IV: powder spray section bar " requirement of (GB5237.4-2008).
Embodiment 3
The preparation process of the present embodiment is with embodiment 2, and except for the difference that bentonite used by transfer auxiliary agent is sodio bentone
Soil, wherein sodio modified alta-mud uses the sodio modified alta-mud of Industrial City, Xinyang bentonite factory of Tontru；
Embodiment 4
The preparation process of the present embodiment is with embodiment 1, and except for the difference that transfer auxiliary agent is VTES coupling
Agent is adsorbed in organobentonite by 20%wt, and wherein VTES coupling agent uses the easy Hue in Qufu work
The A-151 of company limited；
Embodiment 5
The preparation process of the present embodiment is with embodiment 1, and except for the difference that transfer auxiliary agent is that epoxy silane coupling is by 20%
Wt is adsorbed in organobentonite；Wherein epoxy silane coupling uses Dow corning ProductsOFS-6040；
Embodiment 6
The preparation process of the present embodiment is with embodiment 1, and except for the difference that transfer auxiliary dosage is 0.05%wt；
Embodiment 7
The preparation process of the present embodiment is with embodiment 1, and except for the difference that transfer auxiliary dosage is 0.15%wt；
Embodiment 8
The preparation process of the present embodiment is with embodiment 1, and except for the difference that preparing transfer alcohol used by auxiliary agent is methanol；
Embodiment 9
The preparation process of the present embodiment is with embodiment 1, and except for the difference that preparing transfer alcohol used by auxiliary agent is isopropanol；
Comparative example
The preparation process of the present embodiment, with embodiment 1, is except for the difference that not added with transfer auxiliary agent of the present invention.
Aluminium section bar fine definition, strong resistance to water, the spraying coating process of wood grain powdery paints of easy paper-tear picture comprise the following steps:
(1) powdery paints uses high pressure electrostatic painting method to spray to aluminium shape surface；
(2) toast 10min under the conditions of workpiece being put into 200 DEG C, be allowed to be fully cured；
(3) after workpiece cools down, with special thermal transfer glue even spread on a test piece, then wood grain is turned
Printing paper covers and wiping is smooth；
(4) baking 15min under 160 DEG C of baking conditions put into by the workpiece after processing；
(5) after cooling, transfer paper of tearing, obtain wood grain powdery paints film；
The test various performance indications of film, test result is as shown in Table 1；
The various performance indications of test above-described embodiment gained film, test result is as shown in table 1；
Table 1
Levelling is PCI grade, 1-10 level, and numerical value is the biggest, and flow leveling is the most excellent, and numerical value is the least, and levelling is the poorest；
Hardness is detected by GB/T6739-2006 standard；
Impact is detected by GB/T1732-1993 standard；
Resistance to water detects according to GB/T1733-1933 standard；Test result is 1-5 level, and numerical value is the least, water resistance
The most excellent, numerical value is the biggest, and resistance to water is the poorest；
Paper-tear picture performance test, point 1-5 level
1 grade: easily paper-tear picture, film clean noresidue paper scrap；
2 grades: easily paper-tear picture, film has and slightly remains paper scrap；
3 grades: easily paper-tear picture, film has and remains paper scrap in a large number；
4 grades: difficult paper-tear picture, film has and remains paper scrap in a large number；
5 grades: transfer paper can not be torn substantially；
Definition performance test, point 1-5 level
1 grade: clear patterns, true to nature, pattern boundaries is clearly demarcated；
2 grades: clear patterns, true to nature, partial pattern obscurity boundary；
3 grades: clear patterns, major part pattern boundaries obscures；
4 grades: dim design, pattern boundaries is the most smudgy；
5 grades: dim design, pattern non-boundary；
By above testing result, aluminium section bar fine definition prepared by the inventive method, strong resistance to water, easy paper-tear picture
Wood grain powdery paints be particularly well-suited to aluminium section bar Thermal-printing Technology, can have while obtaining fabulous levelling easy paper-tear picture,
Strong resistance to water and the feature of fine definition, do not affect hardness of film simultaneously.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.Preferred embodiment is the most detailed
Describe all of details, be also not intended to the detailed description of the invention that this invention is only described.Obviously, according to the content of this specification,
Can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is to preferably explain the present invention
Principle and actual application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and four corner thereof and equivalent.
Claims (10)
1. an aluminium section bar transfer printing wood grain powdery paints, it is characterised in that include following components by weight percent raw material:
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that described transfer auxiliary agent is for having
Machine silane coupling agent is adsorbed in modified alta-mud according to 20wt%.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 2, described organo silane coupling agent is vinyl
One in triethoxysilane, amino silicane coupling agent and epoxy silane coupling and several.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that the system of described transfer auxiliary agent
Preparation Method is pretreated filler method, specifically includes following steps:
A, according to formula as below prepare silane coupler solution:
Silane coupler 40%,
Alcohol 52%,
Water 8%；
B and modified alta-mud premixing: modified alta-mud is put into solid blender, silane coupler solution according to modification
Bentonite weight ratio is the amount of 1:2, is sprayed directly on modified alta-mud and stirs 10-30min, be allowed to fully dispersed uniformly
After, dry 2 hours under the conditions of 120 DEG C, prepare the transfer auxiliary agent that silane coupled agent content is 20wt%.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that the system of described transfer auxiliary agent
Preparation Method is directly joining method, specifically includes following steps:
Silane coupler divide 3-5 time the mode added directly be sprayed onto on the modified alta-mud putting into solid blender, every time
After addition, stir 5min, after all adding, stir 20-30min, silane coupler consumption according to modified alta-mud weight ratio
For 1:5.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 4, it is characterised in that described alcohol is methanol, second
One in alcohol and isopropanol.
7. according to the transfer printing wood grain powdery paints of the aluminium section bar described in claim 4 or 5, it is characterised in that described bentone
Soil is organobentonite or sodio modified alta-mud.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that described saturated terminal carboxyl polyester
Resinous acid value is 30-38mgKOH/g.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that described levelling agent is acrylic acid
Ester copolymer.
Aluminium section bar transfer printing wood grain powdery paints the most according to claim 1, it is characterised in that its preparation method include with
Lower step:
1) premixing: following raw material is put into the most together in compounding jar and carry out premixing:
2) melt extrude: carry out melt extruding by double screw extruder by the raw material after premixing, tabletting, broken, wherein
Extruder I district stabilizes to 105-115 DEG C, and II district temperature is 110-120 DEG C；
Pulverize and sieve: by ACM mill, the sheet stock after broken is carried out stage reduction, and wherein powder diameter is 20-85 micron, then leads to
Crossing rotary screen and carry out screening acquisition powder coating product, screen cloth used by described rotary screen is 180 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716173.2A CN106318143B (en) | 2016-08-24 | 2016-08-24 | A kind of aluminum profile transfer printing wood grain powdery paints |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716173.2A CN106318143B (en) | 2016-08-24 | 2016-08-24 | A kind of aluminum profile transfer printing wood grain powdery paints |
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| Publication Number | Publication Date |
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| CN106318143A true CN106318143A (en) | 2017-01-11 |
| CN106318143B CN106318143B (en) | 2019-04-12 |
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| CN201610716173.2A Active CN106318143B (en) | 2016-08-24 | 2016-08-24 | A kind of aluminum profile transfer printing wood grain powdery paints |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102535A (en) * | 2017-12-29 | 2018-06-01 | 安徽鑫发铝业有限公司 | A kind of transfer printing wood grain aluminium section bar |
| CN108250916A (en) * | 2017-12-29 | 2018-07-06 | 安徽鑫发铝业有限公司 | A kind of aluminum section for automobile process of surface treatment |
| CN108250915A (en) * | 2017-12-29 | 2018-07-06 | 安徽鑫发铝业有限公司 | A kind of heat-and corrosion-resistant aluminium alloy transfer printing wood grain section bar |
| CN108822703A (en) * | 2018-07-23 | 2018-11-16 | 廊坊市开元盛琳粉末涂料有限公司 | Powdery paints and preparation method thereof for the processing of thermal transfer metallic substrate surface |
| CN110305576A (en) * | 2019-07-15 | 2019-10-08 | 江西睿智环保科技有限公司 | With anti-graffiti high definition transfer printing wood grain powdery paints, Preparation method and use |
| CN111205731A (en) * | 2020-02-14 | 2020-05-29 | 广东涂亿科技有限公司 | High-toughness bending-delaying powder coating and preparation method thereof |
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| CN105367765A (en) * | 2015-12-07 | 2016-03-02 | 浙江传化天松新材料有限公司 | Polyester resin used for TGIC curing high-toughness thermal transfer printing powder paints, and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102535A (en) * | 2017-12-29 | 2018-06-01 | 安徽鑫发铝业有限公司 | A kind of transfer printing wood grain aluminium section bar |
| CN108250916A (en) * | 2017-12-29 | 2018-07-06 | 安徽鑫发铝业有限公司 | A kind of aluminum section for automobile process of surface treatment |
| CN108250915A (en) * | 2017-12-29 | 2018-07-06 | 安徽鑫发铝业有限公司 | A kind of heat-and corrosion-resistant aluminium alloy transfer printing wood grain section bar |
| CN108822703A (en) * | 2018-07-23 | 2018-11-16 | 廊坊市开元盛琳粉末涂料有限公司 | Powdery paints and preparation method thereof for the processing of thermal transfer metallic substrate surface |
| CN110305576A (en) * | 2019-07-15 | 2019-10-08 | 江西睿智环保科技有限公司 | With anti-graffiti high definition transfer printing wood grain powdery paints, Preparation method and use |
| CN111205731A (en) * | 2020-02-14 | 2020-05-29 | 广东涂亿科技有限公司 | High-toughness bending-delaying powder coating and preparation method thereof |
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|---|---|
| CN106318143B (en) | 2019-04-12 |
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