CN104497808A - Powder coating for MDF transfer printing and application method of powder coating - Google Patents

Powder coating for MDF transfer printing and application method of powder coating Download PDF

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Publication number
CN104497808A
CN104497808A CN201410850592.6A CN201410850592A CN104497808A CN 104497808 A CN104497808 A CN 104497808A CN 201410850592 A CN201410850592 A CN 201410850592A CN 104497808 A CN104497808 A CN 104497808A
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CN
China
Prior art keywords
transfer printing
powder coating
mdf
agent
transfer
Prior art date
Application number
CN201410850592.6A
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Chinese (zh)
Inventor
张剑
朱明林
李国威
张芳芳
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山东朗法博粉末涂装科技有限公司
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Priority to CN201410850592.6A priority Critical patent/CN104497808A/en
Publication of CN104497808A publication Critical patent/CN104497808A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention relates to powder coating and particularly relates to powder coating for MDF transfer printing and an application method of the powder coating. The powder coating is prepared from the following raw materials in percentage by weight: 53-90% of resin, 0-6.7% of a curing agent, 0.1-0.5% of a curing accelerant, 3-25% of auxiliaries, 5-30% of filler and 0.8-25% of pigment. After the powder coating is used for transfer printing, the texture is clear, the penetration is deep, the third dimension is strong, the transfer printing paper can be easily uncovered, the thermal transfer printing product is durable in use, and the patterns are not dropped, cracked or faded; moreover, the thermal transfer printing only achieves a surface decoration effect without changing the characteristics of the original glossiness, the wear resistance, the weather resistance, the acid and alkali resistance, and the like of the product. The invention also provides an application method of the powder coating.

Description

MDF transfer printing powder coating and application method thereof
Technical field
The present invention relates to a kind of powder coating, be specifically related to a kind of MDF transfer printing powder coating and application method thereof.
Background technology
Powder coating, is often referred to as boiled oil paint, is the product of a kind of environmental protection close friend, can provide more multi items and Geng Duo color.As the solvent-free decoration of one and protective material, powder coating is with its clean environment firendly and the advantage such as to reduce costs and be widely used in every field.Along with the development of society; people constantly propose higher requirement to the decoration of powder coating and protection effect; the assortment pursued are more and more rich and varied; though natural timber and building stones are best finishing material; but for the problem such as protection of the environment and use cost, make the use of these natural materialss be subject to a definite limitation.
Along with the application of the artificial medium density fiberboard of MDF in furniture industry, make again the powder coating be applied on MDF become a professional branch, along with the appearance of transfer technique, make again MDF proprietary powder coatings more rich and varied.At present at aluminium section bar furnishing fields, develop new powder kind-thermal transfer type powder coating Thermal-printing Technology and powder technology combined, still there is no corresponding MDF Low Temperature Thermal transfer printing powder coating, and also to there is after transfer printing the problems such as paper-tear picture difficulty in the at present hot transfer printing of powder coating.
Summary of the invention
For the deficiencies in the prior art, the object of this invention is to provide a kind of MDF transfer printing powder coating, clean mark after transfer printing, infiltration is dark, stereoscopic sensation is strong, transfer paper can be thrown off easily, and hot transfer product is durable in use, and pattern can not come off, chaps and fade; The present invention provides its application method simultaneously.
MDF transfer printing powder coating of the present invention, be made up of the raw material of following weight percentage:
Wherein,
Resin is the mixture of vibrin or vibrin and epoxy resin; Wherein, the mixture of vibrin and epoxy resin is preferably the mass ratio of vibrin and epoxy resin is 1:1.Resin preferably has the resin of good durability and levelling property.Vibrin preferred polyester resin 2441 or vibrin 6055, epoxy resin preferred epoxy DER6615, Dow Chemical provides.
Solidifying agent is isocyanuric acid three-glycidyl ester, preferred consolidation agent TGIC, and Anshan Runde Fine Chemicals Co., Ltd. provides; Curing catalyst is the mixture of polyester promotor or polyester promotor and very low temperature Epoxy curing accelerators, the preferred TE-230 of polyester promotor, and the auspicious Trade Co., Ltd. in Jiade, Qingdao provides; The preferred JT-6015A of very low temperature Epoxy curing accelerators, Shanghai Jingtian New Materials Technology Co., Ltd. provides.Curing catalyst is selected according to the type of selected resin, and when vibrin selected by resin, curing catalyst selects TE-230; When the mixture of vibrin and epoxy resin selected by resin, curing catalyst selects the mixture of TE-230 and JT-6015A, and both mass ratioes are preferably 1:1.
Auxiliary agent comprises flow agent, defoamer, air release agent, transfer printing wax powder, transfer printing promotor and optical brightener.
Wherein, flow agent is esters of acrylic acid flow agent, preferred GLP588, and Ningbo South-sea Chemical Co., Ltd. provides; Defoamer is st-yrax, and Ningbo South-sea Chemical Co., Ltd. provides; Air release agent is modified polyethylene wax, preferred CERAFLOUR 961, and German Byk Chemie GmbH provides; Optical brightener is butyl acrylate-methyl ester copolymer, preferred N701, and this new chemical materials company limited is come in Hubei to be provided.
Transfer printing wax powder is transfer printing wax T-407, and Shanghai Suo Shi Chemical Co., Ltd. provides; Transfer printing promotor is transfer printing promotor T-170, and Shanghai Suo Shi Chemical Co., Ltd. provides.
Auxiliary agent preferably also comprises sand streak agent and organobentonite; Wherein, sand streak agent is sand streak agent 815, and this new chemical materials company limited is come in Hubei to be provided; Organobentonite is organobentonite auxiliary rheological agents, and Qing Hong auxiliary chemicals factory of Linan City provides.
Filler is process white, and Zibo Hong Fang brake material factory provides; Pigment is one or more in white pigment, red pigment or black pigment, and pigment Guangzhou Sheng Qi macromolecular material Science and Technology Ltd. provides.The color of MDF transfer printing powder coating color of the present invention also mainly imitative trees, pigment therefore used is white pigment (in titanium dioxide, anatase titanium dioxide and rutile-type are all used), red pigment (iron oxide red, molybdenum red, organic red etc.), black pigment (carbon black) mainly.
The application method of described MDF transfer printing powder coating, first, by MDF transfer printing powder paint on MDF artificial board substrate, be heating and curing formation coating, then wraps up transfer paper, carries out hot transfer printing.
Ink at a set temperature on heat-transferring printing paper is by heat sublimation, multicolor patterns once one-tenth figure can be made, namely the clearly demarcated pattern of color is formed after sublimating, and powder coating coat inside 30-50 μm can be penetrated into, obtain surface decoration effect true to nature, it should be noted that when carrying out transfer printing on this kind of transfer printing powder coating basis, paper-tear picture process is without any difficulty especially.
The thickness of powder paint coating is 60-90 μm; The product that transfer paper preferred Foshan City Cai De finishing material company limited provides.
Solidification adopts medium-wave infrared solidification, and medium-wave infrared condition of cure is: solidify 5-15min at 130-150 DEG C; Heat is transferred as and adopts dull and stereotyped heat transfer machine transfer printing, and transfer printing condition is: transfer printing 2-4min at 160-200 DEG C.
Powder coating of the present invention is applicable to the hot transfer printing use of MDF, is by adjustment composition of raw materials, adds auxiliary agent and make it to be applicable to hot transfer printing.
In formula, resin is the part that accounting example is the highest, and in the present invention, resin adopts the mixture of vibrin or vibrin and epoxy resin, adds solidifying agent TGIC and meets the service requirements of MDF powder coating.
MDF transfer printing powder coating preparation method of the present invention is as follows:
According to formula weighing → mix → extrude (temperature in each district of screw rod controls at 100-120 DEG C) → pulverize → grinding → cross screen sizing → finished product.
Compared with prior art, the present invention has following beneficial effect:
(1) MDF transfer printing powder coating of the present invention, in order to the clear of texture and stereoscopic sensation are strong, select T-170 transfer printing promotor and T407 transfer printing wax powder, to control the directional migration of hot transfer ink in transfer process, improve the texture definition of transfer powder, and transfer paper can tear off easily, reach intact transferring effect.
(2) MDF transfer printing powder coating of the present invention is after transfer printing, clean mark, and infiltration is dark, and stereoscopic sensation is strong, and transfer paper can be thrown off easily, coordinates the measured transfer paper of printing quality and transfer printing process of controlling well, the image after transfer printing can be made to reach lifelike effect.
(3) the present invention provides application method simultaneously, and after MDF surface spraying powder coating of the present invention, then carry out hot transfer printing after adopting corresponding transfer paper to wrap up, the hot transfer product obtained is durable in use, and pattern can not come off, chaps and fade.And hot transfer printing just plays surface decoration effect, the characteristics such as the original glossiness of product, wear resistance, weathering resistance, resistance to acids and bases can not be changed because of hot transfer printing.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
The all raw materials used in embodiment, except specified otherwise, are commercial.
MDF transfer printing powder coating preparation method described in the embodiment of the present invention is as follows:
According to formula weighing → mix → extrude (screw rod Heating Zone Temperature controls at 110 DEG C) → pulverize → grinding → cross screen sizing → finished product.
Embodiment 1
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 130 DEG C, and set time is 15min; Coat-thickness is 70 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 190 DEG C, and heat-up time is 3min;
(3) Workpiece inspection warehouse-in.
Embodiment 2
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 160 DEG C, and set time is 5min; Coat-thickness is 90 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 195 DEG C, and heat-up time is 2.8min;
(3) Workpiece inspection warehouse-in.
Embodiment 3
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 150 DEG C, and set time is 10min; Coat-thickness is 80 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 200 DEG C, and heat-up time is 2.5min;
(3) Workpiece inspection warehouse-in.
Embodiment 4
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 140 DEG C, and set time is 12min; Coat-thickness is 90 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 180 DEG C, and heat-up time is 3.2min;
(3) Workpiece inspection warehouse-in.
Embodiment 5
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 135 DEG C, and set time is 13min; Coat-thickness is 85 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 160 DEG C, and heat-up time is 4min;
(3) Workpiece inspection warehouse-in.
Embodiment 6
MDF transfer printing powder coating described in the present embodiment, be made up of the raw material of following weight percentage:
Its application method is:
(1) carry out electrostatic powder coating to the MDF through surface pretreatment, solidification treatment obtains thermoset coatings; Curing mode adopts medium-wave infrared pulsed irradiation to be heating and curing, and solidification value is 150 DEG C, and set time is 8min; Coat-thickness is 60 μm;
(2) at the heat-transferring printing paper of above-mentioned coatingsurface parcel coupling, dull and stereotyped heat transfer machine carries out transfer printing, and Heating temperature is 175 DEG C, and heat-up time is 2.9min;
(3) Workpiece inspection warehouse-in.
Test embodiment 1-6 transferring effect respectively, test result is in table 1.
Table 1 embodiment 1-6 test result

Claims (10)

1. a MDF transfer printing powder coating, is characterized in that: be made up of the raw material of following weight percentage:
2. MDF transfer printing powder coating according to claim 1, is characterized in that: resin is the mixture of vibrin or vibrin and epoxy resin.
3. MDF transfer printing powder coating according to claim 1, is characterized in that: solidifying agent is isocyanuric acid three-glycidyl ester; Curing catalyst is the mixture of polyester promotor or polyester promotor and very low temperature Epoxy curing accelerators.
4. MDF transfer printing powder coating according to claim 1, is characterized in that: auxiliary agent comprises flow agent, defoamer, air release agent, transfer printing wax powder, transfer printing promotor and optical brightener.
5. MDF transfer printing powder coating according to claim 4, is characterized in that: flow agent is esters of acrylic acid flow agent; Defoamer is st-yrax; Air release agent is modified polyethylene wax; Optical brightener is butyl acrylate-methyl ester copolymer.
6. MDF transfer printing powder coating according to claim 4, is characterized in that: transfer printing wax powder is transfer printing wax T-407; Transfer printing promotor is transfer printing promotor T-170.
7. MDF transfer printing powder coating according to claim 4, is characterized in that: auxiliary agent also comprises sand streak agent and organobentonite; Wherein, sand streak agent is sand streak agent 815; Organobentonite is organobentonite auxiliary rheological agents.
8. MDF transfer printing powder coating according to claim 1, is characterized in that: filler is process white; Pigment is one or more in white pigment, red pigment or black pigment.
9. an application method for the arbitrary described MDF transfer printing powder coating of claim 1-8, is characterized in that: first, by MDF transfer printing powder paint on MDF artificial board substrate, then is cured it, then wraps up transfer paper, carry out hot transfer printing.
10. the application method of MDF transfer printing powder coating according to claim 9, is characterized in that: solidification adopts medium-wave infrared solidification, and medium-wave infrared condition of cure is: solidify 5-15min at 130-150 DEG C; Heat is transferred as and adopts dull and stereotyped heat transfer machine transfer printing, and transfer printing condition is: transfer printing 2-4min at 160-200 DEG C.
CN201410850592.6A 2014-12-31 2014-12-31 Powder coating for MDF transfer printing and application method of powder coating CN104497808A (en)

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105926355A (en) * 2016-05-09 2016-09-07 廊坊市亚龙粉末涂料制造有限公司 Heat transfer printing paint and preparing method thereof
CN106221507A (en) * 2016-08-31 2016-12-14 苏州翰晨商贸有限公司 A kind of high temperature resistant grit powder coating
CN106318143A (en) * 2016-08-24 2017-01-11 六安科瑞达新型材料有限公司 Wooden transfer power paint for aluminium profile
CN106366857A (en) * 2016-08-31 2017-02-01 苏州翰晨商贸有限公司 Abrasion-resistant and high-temperature-resistant sand grain powder coating
CN106833257A (en) * 2016-12-15 2017-06-13 福建万安化工科技有限公司 A kind of powdery paints of imitative snowflake line
CN107057522A (en) * 2017-03-24 2017-08-18 苏州翠南电子科技有限公司 A kind of electronic device decorative appearance coating
CN107325693A (en) * 2017-05-26 2017-11-07 张家港市五湖新材料技术开发有限公司 A kind of powder spray sand streak paint
CN107418395A (en) * 2017-09-15 2017-12-01 立邦涂料(天津)有限公司 A kind of transparent polyester type powdery paints, preparation method and applications
CN107652860A (en) * 2017-10-31 2018-02-02 山东瑞丰高分子材料股份有限公司 Medium-density plate cured powder paint and preparation method thereof
CN106497356B (en) * 2016-11-11 2018-04-10 黄石市永渤工贸有限公司 A kind of tung oil embossment transfer printing wood grain coating and its preparation method and application
CN108485349A (en) * 2018-04-03 2018-09-04 广东睿智环保科技有限责任公司 A kind of preparation formula of flame retardant type transfer coating
CN108795252A (en) * 2018-06-19 2018-11-13 广东睿智环保科技有限责任公司 A kind of preparation formula of antibacterial transfer powdery paints
CN108822699A (en) * 2018-05-17 2018-11-16 广东涂亿科技有限公司 A kind of weatherability luminous powder coating material and its preparation method and application, workpiece
CN110272677A (en) * 2019-07-17 2019-09-24 中国科学院过程工程研究所 A kind of thermal transfer powdery paints and its preparation method and application
CN110396356A (en) * 2019-07-26 2019-11-01 中山市鸿朗装饰材料有限公司 A kind of dumb light thermal transfer powdery paints
CN110408302A (en) * 2019-07-05 2019-11-05 浙江聚华材料科技股份有限公司 A kind of preparation method of powdery paints
CN110527412A (en) * 2019-10-22 2019-12-03 广西南宁维一防腐科技有限公司 A kind of solidification thermal transfer powder of environmental protection and preparation method thereof

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105926355B (en) * 2016-05-09 2019-01-04 廊坊市亚龙三惠科技股份有限公司 A kind of thermal transfer coating and preparation method thereof
CN105926355A (en) * 2016-05-09 2016-09-07 廊坊市亚龙粉末涂料制造有限公司 Heat transfer printing paint and preparing method thereof
CN106318143A (en) * 2016-08-24 2017-01-11 六安科瑞达新型材料有限公司 Wooden transfer power paint for aluminium profile
CN106221507A (en) * 2016-08-31 2016-12-14 苏州翰晨商贸有限公司 A kind of high temperature resistant grit powder coating
CN106366857A (en) * 2016-08-31 2017-02-01 苏州翰晨商贸有限公司 Abrasion-resistant and high-temperature-resistant sand grain powder coating
CN106497356B (en) * 2016-11-11 2018-04-10 黄石市永渤工贸有限公司 A kind of tung oil embossment transfer printing wood grain coating and its preparation method and application
CN106833257B (en) * 2016-12-15 2019-05-14 福建万安化工科技有限公司 A kind of powdery paints of imitative snowflake line
CN106833257A (en) * 2016-12-15 2017-06-13 福建万安化工科技有限公司 A kind of powdery paints of imitative snowflake line
CN107057522A (en) * 2017-03-24 2017-08-18 苏州翠南电子科技有限公司 A kind of electronic device decorative appearance coating
CN107325693A (en) * 2017-05-26 2017-11-07 张家港市五湖新材料技术开发有限公司 A kind of powder spray sand streak paint
CN107418395A (en) * 2017-09-15 2017-12-01 立邦涂料(天津)有限公司 A kind of transparent polyester type powdery paints, preparation method and applications
CN107652860A (en) * 2017-10-31 2018-02-02 山东瑞丰高分子材料股份有限公司 Medium-density plate cured powder paint and preparation method thereof
CN108485349A (en) * 2018-04-03 2018-09-04 广东睿智环保科技有限责任公司 A kind of preparation formula of flame retardant type transfer coating
CN108822699A (en) * 2018-05-17 2018-11-16 广东涂亿科技有限公司 A kind of weatherability luminous powder coating material and its preparation method and application, workpiece
CN108795252A (en) * 2018-06-19 2018-11-13 广东睿智环保科技有限责任公司 A kind of preparation formula of antibacterial transfer powdery paints
CN110408302A (en) * 2019-07-05 2019-11-05 浙江聚华材料科技股份有限公司 A kind of preparation method of powdery paints
CN110272677A (en) * 2019-07-17 2019-09-24 中国科学院过程工程研究所 A kind of thermal transfer powdery paints and its preparation method and application
CN110272677B (en) * 2019-07-17 2020-08-11 中国科学院过程工程研究所 Thermal transfer printing powder coating and preparation method and application thereof
CN110396356A (en) * 2019-07-26 2019-11-01 中山市鸿朗装饰材料有限公司 A kind of dumb light thermal transfer powdery paints
CN110527412A (en) * 2019-10-22 2019-12-03 广西南宁维一防腐科技有限公司 A kind of solidification thermal transfer powder of environmental protection and preparation method thereof

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