CN107325693A - A kind of powder spray sand streak paint - Google Patents

A kind of powder spray sand streak paint Download PDF

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Publication number
CN107325693A
CN107325693A CN201710387030.6A CN201710387030A CN107325693A CN 107325693 A CN107325693 A CN 107325693A CN 201710387030 A CN201710387030 A CN 201710387030A CN 107325693 A CN107325693 A CN 107325693A
Authority
CN
China
Prior art keywords
sand streak
powder spray
paint
agent
spray sand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710387030.6A
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Chinese (zh)
Inventor
陆磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City
Original Assignee
Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City filed Critical Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City
Priority to CN201710387030.6A priority Critical patent/CN107325693A/en
Publication of CN107325693A publication Critical patent/CN107325693A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of powder spray field, and in particular to a kind of powder spray sand streak paint, includes following component according to weight fraction:Polyester resin 45 60, curing agent 79, floride-free sand streak agent 0.5 1.5, no silicon levelling agent 46, titanium dioxide 10 20, adhesion promoter 5 10, barium sulfate 10 18, bentonite 0.1 0.7, growth agent 0.05 0.5.A kind of powder spray sand streak paint of the present invention, pass through each component in adjustment system, the each component used has abandoned the auxiliary agent of the low-surface-energy such as fluorine-containing and siliceous completely, the surface for adding cured film in allowed limits can, when occurring mass defect on sand streak surface and needing to return spray recoating, the combination on sand streak surface for being conducive to sand streak paint and having been cured.

Description

A kind of powder spray sand streak paint
Technical field
The present invention relates to a kind of powder spray field, and in particular to a kind of powder spray sand streak paint.
Background technology
Sand streak paint is exactly not have the gloss commonly painted after spraying, and touches up with frosted texture, provides various for furniture The painting effect of change, but when using frosted paint, in order that paint filler may be uniformly dispersed in paint, generally require to use Substantial amounts of solvent, auxiliary agent, these solvents and auxiliary agent contain substantial amounts of VOC (VOC), and pollution environment, infringement Painter is healthy, inflammable and explosive, waste petroleum resources, to the preparation of frosted paint and greatly inconvenient and potential using bringing Harm.
Aluminium shape surface has good barrier propterty and decoration performance after powder spray, by the development of decades, Spraying aluminum profile technique is gradually improved, and is also improved constantly while spraying yield rate.Generally, if strictly controlling pre-treatment And spraying coating process, the generation of defective work can be controlled to greatest extent.But due to raw and auxiliary material, extrusion billet, spraying equipment, life The factor such as environment and employee's sense of responsibility of production, aluminium section bar powder spray one-pass finished qualification rate is extremely difficult to 100%, wherein most Defect needs reparation of doing over again.
It has been observed that when sand streak surface occur mass defect need return spray recoating when, it some times happens that return sprayed coating with it is previous There is delamination between road sand streak coating.
The content of the invention
In order to solve when sand streak surface occur mass defect need return spray recoating when, return sprayed coating sand streak coating together with preceding Between the problem of there is delamination, the invention discloses a kind of powder spray sand streak paint, with good adhesive force is good and phase Capacitive, when mass defect, which occurs, in sand streak surface needs to return spray recoating, completely eliminates and returns sprayed coating sand streak coating together with preceding Between delamination.
To realize the purpose of the present invention, the present invention is adopted the following technical scheme that:
A kind of powder spray sand streak paint, includes following component according to weight fraction:
Specifically, above-mentioned polyester resin is saturated carboxyl polyester resin.Saturated carboxyl polyester resin is selected from great Bo Xindas The saturated carboxyl polyester resin of the H60 models of factory, its acid number is 60mgKOH/g.
Specifically, above-mentioned curing agent is triglycidyl isocyanurate.
Specifically, above-mentioned floride-free sand streak agent is sand streak agent 811.
Specifically, above-mentioned is GLP503 or GLP603 without silicon levelling agent.By that from without silicon levelling agent, on the one hand can subtract Shrinkage cavity in few system solidification process, on the other hand can not influence the original adhesive force of sand streak paint, moreover it is possible to ensure in sand streak table There is good adhesion when mass defect needs to return spray recoating in face.
Specifically, above-mentioned adhesion promoter is HF-1.On the one hand adhesive force of the sand streak paint to base material can be improved, together When, when occurring mass defect on sand streak surface and needing to return spray recoating, it can also be ensured that sand streak paint is to the sand streak surface that has been cured Keep good adhesive force.
Specifically, above-mentioned growth agent is growth agent EDF.The carried charge of powder particle when can effectively improve spraying, so that Powder in raising.In addition, leaking away the electric charge of workpiece surface in time when dusting, so as to overcome electrostatic screening effect, make workpiece Inner surface is easy to upper powder.
Specifically, above-mentioned barium sulfate is 2500-3000 mesh blanc fixes., can be with titanium from the barium sulfate of high mesh number White powder coordinates, to adjust the texture of sand streak paint film.
The device have the advantages that:
(1) a kind of powder spray sand streak paint of the invention, with the addition of adhesion promoter, on the one hand can improve sand streak paint To the adhesive force of base material, meanwhile, occur on sand streak surface mass defect need return spray recoating when, it can also be ensured that sand streak paint is to Cured sand streak surface keeps good adhesive force.
(2) a kind of powder spray sand streak paint of the invention, by each component in adjustment system, each component used is complete The auxiliary agent of the low-surface-energy such as fluorine-containing and siliceous has been abandoned, the surface energy of cured film has been added in allowed limits, in sand streak table When there is mass defect and needs to return spray recoating in face, the combination on sand streak surface for being conducive to sand streak paint and having been cured.
(3) the sand streak paint adhesive force for preparing of the present invention compared with it is strong, paint film is plentiful, hardness is high, spraying using simple, sand streak easily into Type and uniform, heavy metal free, environmental protection, security performance are higher.
Embodiment
Presently in connection with embodiment, the present invention is further detailed explanation.
Embodiment 1
A kind of powder spray sand streak paint, includes following component according to weight fraction:
Saturated carboxyl polyester resin 52, triglycidyl isocyanurate 8, sand streak agent 811 1.4, GLP5034, titanium dioxide 10, HF-1 6,3000 mesh barium sulfate 18, bentonite 0.4, growth agent EDF0.2.
A kind of preparation method of powder spray sand streak paint, comprises the following steps:
(1) various raw material are measured according to above-mentioned formula rate, imports and mixing 8-10 is carried out in convertible automatic mixing machine Minute;
(2) material melts mixed are extruded using double screw extruder, the extrusion temperature control of screw rod regional At 100 ± 4 DEG C;
(3) material of extrusion is depressed into the thin slice that thickness is not more than 1mm with format roll, and crushed with disintegrating machine;
(4) broken material is ground with flour mill;
(5) dry, cross 80-100 mesh sieves, produce powder spray sand streak paint powder.
Embodiment 2-5, substantially the same manner as Example 1, difference is table 1;Comparative example 1-3, with the basic phase of embodiment 5 Together, difference is table 1.
Table 1:
Embodiment 1-5 and comparative example 1-3 a kind of powder spray sand streak paint paint film property test such as table 2:
Table 2:
Spray recoating embodiment and contrast are returned in a kind of embodiment 1-5 and comparative example 1-3 powder spray sand streak paint paint film Example identical paint film, performance test such as table 3:
Table 3:
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.

Claims (8)

1. a kind of powder spray sand streak paint, it is characterised in that include following component according to weight fraction:
2. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The polyester resin is poly- for saturation carboxyl Ester resin.
3. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The curing agent is that isocyanuric acid three contracts Water glyceride.
4. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The floride-free sand streak agent is sand streak agent 811。
5. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:It is described without silicon levelling agent be GLP503 or GLP603。
6. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The adhesion promoter is HF-1.
7. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The growth agent is growth agent EDF.
8. a kind of powder spray sand streak paint as claimed in claim 1, it is characterised in that:The barium sulfate is 2500-3000 mesh Blanc fixe.
CN201710387030.6A 2017-05-26 2017-05-26 A kind of powder spray sand streak paint Pending CN107325693A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710387030.6A CN107325693A (en) 2017-05-26 2017-05-26 A kind of powder spray sand streak paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710387030.6A CN107325693A (en) 2017-05-26 2017-05-26 A kind of powder spray sand streak paint

Publications (1)

Publication Number Publication Date
CN107325693A true CN107325693A (en) 2017-11-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710387030.6A Pending CN107325693A (en) 2017-05-26 2017-05-26 A kind of powder spray sand streak paint

Country Status (1)

Country Link
CN (1) CN107325693A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111253838A (en) * 2020-02-17 2020-06-09 安徽华辉塑业科技股份有限公司 Powder coating with good wear resistance and impact resistance and preparation method thereof
CN112207228A (en) * 2020-10-15 2021-01-12 湖南塑源特科技有限公司 Environment-friendly type molding sand spraying agent for precision casting and preparation method thereof
CN113265191A (en) * 2021-05-08 2021-08-17 江苏耀坤液压股份有限公司 Powder spraying process
CN116875155A (en) * 2023-08-01 2023-10-13 湖北来斯涂塑新材料有限公司 Preparation method and application of fluorine-free texture additive for powder coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277067A (en) * 2011-05-24 2011-12-14 上海元方涂料有限公司 Thermosetting weather-resistant low-temperature solidifying powder
CN103483988A (en) * 2013-08-26 2014-01-01 广州擎天材料科技有限公司 Boiling-endurable sand-ripple powder paint for coating corners of aluminum section and preparation method thereof
CN104497808A (en) * 2014-12-31 2015-04-08 山东朗法博粉末涂装科技有限公司 Powder coating for MDF transfer printing and application method of powder coating
CN105907270A (en) * 2016-06-25 2016-08-31 张莘蔓 Environment-friendly sand-streak polyester weather-resistant powder paint
CN106010152A (en) * 2016-06-27 2016-10-12 广西平果宝信涂料有限公司 Sand-texture polyester type weather-resistant powder paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277067A (en) * 2011-05-24 2011-12-14 上海元方涂料有限公司 Thermosetting weather-resistant low-temperature solidifying powder
CN103483988A (en) * 2013-08-26 2014-01-01 广州擎天材料科技有限公司 Boiling-endurable sand-ripple powder paint for coating corners of aluminum section and preparation method thereof
CN104497808A (en) * 2014-12-31 2015-04-08 山东朗法博粉末涂装科技有限公司 Powder coating for MDF transfer printing and application method of powder coating
CN105907270A (en) * 2016-06-25 2016-08-31 张莘蔓 Environment-friendly sand-streak polyester weather-resistant powder paint
CN106010152A (en) * 2016-06-27 2016-10-12 广西平果宝信涂料有限公司 Sand-texture polyester type weather-resistant powder paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111253838A (en) * 2020-02-17 2020-06-09 安徽华辉塑业科技股份有限公司 Powder coating with good wear resistance and impact resistance and preparation method thereof
CN112207228A (en) * 2020-10-15 2021-01-12 湖南塑源特科技有限公司 Environment-friendly type molding sand spraying agent for precision casting and preparation method thereof
CN113265191A (en) * 2021-05-08 2021-08-17 江苏耀坤液压股份有限公司 Powder spraying process
CN116875155A (en) * 2023-08-01 2023-10-13 湖北来斯涂塑新材料有限公司 Preparation method and application of fluorine-free texture additive for powder coating

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Application publication date: 20171107

RJ01 Rejection of invention patent application after publication