CN106543872A - A kind of water-proof climate resisting powdery paints and preparation method thereof - Google Patents
A kind of water-proof climate resisting powdery paints and preparation method thereof Download PDFInfo
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- CN106543872A CN106543872A CN201611120816.3A CN201611120816A CN106543872A CN 106543872 A CN106543872 A CN 106543872A CN 201611120816 A CN201611120816 A CN 201611120816A CN 106543872 A CN106543872 A CN 106543872A
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- powdery paints
- water
- proof climate
- climate resisting
- powder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of water-proof climate resisting powdery paints, is prepared from the following raw materials in parts by weight:Drying oil alkyd resin 42 55, Polyamide-Polyamsne-Epichlorohydrin resin 16 23, distearyl dimethylammonium Strese Hofmann's hectorite. 2.5 3.8, sericite in powder 79, azodiisobutyronitrile 12, sodium lignin sulfonate 23, trimethylhexamethylenediamine 13, coumarone indene resin 12, organic silicone quaternary ammonium salt 0.1 1, compounded mix 58;Invention also provides the preparation method of the water-proof climate resisting powdery paints; the water-proof climate resisting powdery paints that the present invention is provided; transparency is high; good dispersion; the powdery paints of the present invention is with its excellent waterproof, weatherability and high-decoration; can be used for the durable protective decoration industries such as shop equipment facility, aluminium alloy curtain wall, television transmitting tower coating, it is also possible to be widely used in the building material fields such as bridge, door and window, enclosure wall, domestic mark color material.
Description
Technical field
The present invention relates to a kind of paint field, more particularly to a kind of water-proof climate resisting powdery paints and preparation method thereof.
Background technology
Powdery paints by polymer, pigment and additive constitute it is a kind of new, without solvent, pure solid powdery
Coating;With without solvent, pollution-free, save energy and resource, reduce labor intensity high with coating machinery intensity the features such as.Powder
Last coating due to not discharging VOC thus utilization rate is higher, in past 10 years, powdery paints in the world
Development speed quickly, annual average rate of increase is 8%-15%.But, also there is coating with metal-like in current powdery paints
Clear with reference to the effect not as paint, the thermal diffusivity of powdery paints is not good enough, the defect such as water-proof climate resisting poor performance.
The content of the invention
It is an object of the invention to the above-mentioned deficiency in the presence of overcoming prior art, there is provided a kind of water-proof climate resisting powder is applied
Material and preparation method thereof.The water-proof climate resisting powdery paints transparency is high, good dispersion, with excellent waterproof, weatherability and height
It is ornamental.
In order to realize foregoing invention purpose, the invention provides technical scheme below:
A kind of water-proof climate resisting powdery paints, is prepared from the following raw materials in parts by weight:
Drying oil alkyd resin 42-55, Polyamide-Polyamsne-Epichlorohydrin resin 16-23, distearyl dimethylammonium lithium cover de-
Stone 2.5-3.8, sericite in powder 7-9, azodiisobutyronitrile 1-2, sodium lignin sulfonate 2-3, trimethylhexamethylenediamine 1-3,
Coumarone indene resin 1-2, organic silicone quaternary ammonium salt 0.1-1, compounded mix 5-8;
Described compounded mix is made up of the raw material of following weight parts:
Stalactitum 15-21, active hargil 12-16, precipitated calcium carbonate 4-9, Zinc Oxide 2-4, carboxymethyl cellulose 1-2;
By above-mentioned Stalactitum, active hargil, precipitated calcium carbonate mixing, 1-3 hours are calcined at 700-800 DEG C, is discharged cold
But ball milling mixing is carried out in sending into ball mill afterwards, add Zinc Oxide and carboxymethyl cellulose, continue ball milling 1-2 hours, cross 80-
100 mesh sieves, obtain final product the compounded mix.
Another object of the present invention is to provide the preparation method of above-mentioned water-proof climate resisting powdery paints, comprise the following steps:
By above-mentioned each raw material mixing in addition to sericite in powder, high-speed mixer, 1200-1600 rev/min of stirring are sent into
Dispersion 2-6 minutes, extruder is sent into, melting extrusion is subsequently placed in grinder, adds sericite in powder, at 1500-2000 rev/min
Lower speed lapping, after 80-100 mesh sieves, obtains final product the water-proof climate resisting powdery paints.
Compared with prior art, beneficial effects of the present invention:
The water-proof climate resisting powdery paints that the present invention is provided, transparency are high, good dispersion, and the powdery paints of the present invention is excellent with which
Different waterproof, weatherability and high-decoration, can be used for shop equipment facility, aluminium alloy curtain wall, television transmitting tower coating etc. durable
Protective and decorative industry, it is also possible to be widely used in the building material fields such as bridge, door and window, enclosure wall, domestic mark color material.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood
Scope for above-mentioned theme of the invention is only limitted to below example, and all technologies realized based on present invention belong to this
The scope of invention.
Embodiment 1
A kind of water-proof climate resisting powdery paints, is prepared from the following raw materials in parts by weight:
Drying oil alkyd resin 49, Polyamide-Polyamsne-Epichlorohydrin resin 18, distearyl dimethylammonium Strese Hofmann's hectorite. 3.5,
Sericite in powder 8, azodiisobutyronitrile 1, sodium lignin sulfonate 2, trimethylhexamethylenediamine 2, coumarone indene resin 1, organosilicon
Ketone quaternary ammonium salt 0.6, compounded mix 7;
Described compounded mix is made up of the raw material of following weight parts:
Stalactitum 18, active hargil 14, precipitated calcium carbonate 7, Zinc Oxide 3, carboxymethyl cellulose 1;
By above-mentioned Stalactitum, active hargil, precipitated calcium carbonate mixing, calcine 2 hours at 800 DEG C, send after discharging cooling
Ball milling mixing is carried out in entering ball mill, Zinc Oxide and carboxymethyl cellulose is added, continues ball milling 1 hour, cross 100 mesh sieves, i.e.,
Obtain the compounded mix.
The preparation method of above-mentioned water-proof climate resisting powdery paints, comprises the following steps:
By above-mentioned each raw material mixing in addition to sericite in powder, high-speed mixer, 1400 revs/min of dispersed with stirring 5 are sent into
Minute, extruder is sent into, melting extrusion is subsequently placed in grinder, adds sericite in powder, in 1700 revs/min of lower speed lappings, then
90 mesh sieves are crossed, the water-proof climate resisting powdery paints is obtained final product.
Water-proof climate resisting powdery paints prepared by above-described embodiment 1 is sprayed at through pretreatment using the method for electrostatic spraying
Substrate of steel plate on, test film performance, test result is as follows, film adhesive (IS02409):1 grade, film impact strength
(GB/T1732-93):》60kg/cm, film resist bending:《2mm.
Claims (2)
1. a kind of water-proof climate resisting powdery paints, it is characterised in that be prepared from the following raw materials in parts by weight:
Drying oil alkyd resin 42-55, Polyamide-Polyamsne-Epichlorohydrin resin 16-23, distearyl dimethylammonium Strese Hofmann's hectorite.
2.5-3.8, sericite in powder 7-9, azodiisobutyronitrile 1-2, sodium lignin sulfonate 2-3, trimethylhexamethylenediamine 1-3, Gu
The grand resin 1-2 of horse, organic silicone quaternary ammonium salt 0.1-1, compounded mix 5-8;
Described compounded mix is made up of the raw material of following weight parts:
Stalactitum 15-21, active hargil 12-16, precipitated calcium carbonate 4-9, Zinc Oxide 2-4, carboxymethyl cellulose 1-2;
By above-mentioned Stalactitum, active hargil, precipitated calcium carbonate mixing, 1-3 hours are calcined at 700-800 DEG C, after discharging cooling
Ball milling mixing is carried out in sending into ball mill, Zinc Oxide and carboxymethyl cellulose is added, continues ball milling 1-2 hours, cross 80-100
Mesh sieve, obtains final product the compounded mix.
2. the preparation method of water-proof climate resisting powdery paints according to claim 1, it is characterised in that comprise the following steps:
By each raw material mixing in addition to sericite in powder, high-speed mixer, 1200-1600 rev/min of dispersed with stirring 2-6 point are sent into
Clock, sends into extruder, and melting extrusion is subsequently placed in grinder, adds sericite in powder, ground under 1500-2000 rev/min at a high speed
Mill, after 80-100 mesh sieves, obtains final product the water-proof climate resisting powdery paints.
Priority Applications (1)
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CN201611120816.3A CN106543872A (en) | 2016-12-07 | 2016-12-07 | A kind of water-proof climate resisting powdery paints and preparation method thereof |
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CN201611120816.3A CN106543872A (en) | 2016-12-07 | 2016-12-07 | A kind of water-proof climate resisting powdery paints and preparation method thereof |
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CN106543872A true CN106543872A (en) | 2017-03-29 |
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CN201611120816.3A Pending CN106543872A (en) | 2016-12-07 | 2016-12-07 | A kind of water-proof climate resisting powdery paints and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107384159A (en) * | 2017-08-03 | 2017-11-24 | 安徽真信涂料有限公司 | A kind of water-proof climate resisting composite powder coatings and preparation method thereof |
CN109320698A (en) * | 2018-08-27 | 2019-02-12 | 河北晨阳工贸集团有限公司 | A kind of aqueous coumarone indene resin modified alkyd resin and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103382354A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Anticorrosive and antibacterial novolac epoxy resin powdery paint |
CN103483989A (en) * | 2013-09-03 | 2014-01-01 | 安徽精一机械设备有限公司 | Water-boiling-resistant powder paint |
CN103497627A (en) * | 2013-09-03 | 2014-01-08 | 蚌埠德美过滤技术有限公司 | Thermo-set hammer-tone art powdery paint |
-
2016
- 2016-12-07 CN CN201611120816.3A patent/CN106543872A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103382354A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Anticorrosive and antibacterial novolac epoxy resin powdery paint |
CN103483989A (en) * | 2013-09-03 | 2014-01-01 | 安徽精一机械设备有限公司 | Water-boiling-resistant powder paint |
CN103497627A (en) * | 2013-09-03 | 2014-01-08 | 蚌埠德美过滤技术有限公司 | Thermo-set hammer-tone art powdery paint |
Non-Patent Citations (2)
Title |
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李子冬: "《胶黏剂助剂 第二版》", 30 June 2009, 化学工业出版社 * |
王大全: "《精细化工生产流程图解》", 28 February 1999, 化学工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107384159A (en) * | 2017-08-03 | 2017-11-24 | 安徽真信涂料有限公司 | A kind of water-proof climate resisting composite powder coatings and preparation method thereof |
CN109320698A (en) * | 2018-08-27 | 2019-02-12 | 河北晨阳工贸集团有限公司 | A kind of aqueous coumarone indene resin modified alkyd resin and preparation method thereof |
CN109320698B (en) * | 2018-08-27 | 2022-10-25 | 河北晨阳工贸集团有限公司 | Waterborne coumarone resin modified alkyd resin and preparation method thereof |
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