CN108485349A - A kind of preparation formula of flame retardant type transfer coating - Google Patents
A kind of preparation formula of flame retardant type transfer coating Download PDFInfo
- Publication number
- CN108485349A CN108485349A CN201810303680.2A CN201810303680A CN108485349A CN 108485349 A CN108485349 A CN 108485349A CN 201810303680 A CN201810303680 A CN 201810303680A CN 108485349 A CN108485349 A CN 108485349A
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- CN
- China
- Prior art keywords
- flame retardant
- preparation formula
- type transfer
- transfer coating
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to the preparation formula that a kind of flame retardant type transfers coating, raw material includes：Polyester resin, curing agent, auxiliary agent and fire retardant and color stuffing.The technical solution is suitable for being sprayed on furniture, and household electrical appliances can effectively prevent flame ignition, prevent propagation of flame.
Description
Technical field
The present invention relates to the preparation formulas that a kind of flame retardant type transfers coating.
Background technology
Powdery paints is a kind of environment-friendly type coating for existing with solid state powder kenel, storing and constructing, and solid content is up to
100%.Powdery paints is solvent-free in coating process, unlike the liquid coatings such as solvent-home and water-iome paint needs are dispersed in
In organic solvent or water, and it is dispersed in air and constructs.In general, the composition of coating includes following several classes：Tree
Fat, curing agent, auxiliary agent, color stuffing etc..Preparation process is to be pre-mixed above-mentioned material, then by melting extrusion, and after cooling down
It crushes, is then classified, screens, to which powdery paints finished product be prepared.It has many advantages：1, it is solvent-free, it can reduce pair
Environmental pollution；2, coating process is simple, efficient and loss is few；3, film performance is excellent；Functionalization powdery paints is that powder applies
Expect development an important directions, such as fire-retardant transfer powdery paints, it have it is cheap, construction technology is simple, in household electrical appliances, family
The fields such as tool, building materials have broad application prospects.
With the fast development of economic society, Wood consumption constantly increases, the excessive felling of forest, serious to destroy ecology
Balance.It is strided forward with industrialized, demand of the mankind to living environment is promoted, and to ecological, environmental protective, the people realize enhancing, and country
Pay much attention to.In furniture, house ornamentation, household electrical appliances, gradually there are MDF planks in the industries such as building materials, with " modeling " Dai Mu, in recent years, even more
The new concept of full aluminium household is gradually presented in each scene of living with " aluminium " Dai Mu.
Invention content
Present invention aims at providing one kind being sprayed on furniture, household electrical appliances can effectively prevent flame ignition, prevent flame climing
A kind of preparation formula of flame retardant type transfer coating prolonged.
The technical scheme is that：A kind of preparation formula of flame retardant type transfer coating, raw material include：Polyester resin,
Curing agent, auxiliary agent and fire retardant and color stuffing.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the raw material percentage by weight in formula
It is respectively than composition：Polyester resin 55.8%, curing agent 4.2%, auxiliary agent 4~5%, fire proofing 10%, color stuffing be 26~
28%.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the curing agent is isocyanuric acid three
Ethylene oxidic ester TGIC.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the auxiliary agent includes levelling agent, rests in peace
Perfume, wetting agent, smoke suppressant.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the polyester resin, isocyanuric acid three
The mass fraction of ethylene oxidic ester TGIC is 99%.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the mass fraction of the levelling agent is
60%, the styrax, wetting agent, smoke suppressant mass fraction be 99%.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the raw material percentage by weight in formula
It is respectively than composition：Polyester resin 55.8%, isocyanuric acid three-glycidyl ester TGIC 4.2%, levelling agent 1%, styrax
0.3%, wetting agent 0.5%, smoke suppressant 2%, fire retardant 10%, color stuffing 26.2%.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the fire retardant is organic fire-retardant
Or the inorganic combustion inhibitor of the inorganic combustion inhibitor or uncoated processing by cladding processing.
Preferably, the preparation formula of above-mentioned a kind of flame retardant type transfer coating, wherein the inorganic combustion inhibitor is hydroxide
The mixture of aluminium and ammonium polyphosphate.
Beneficial effects of the present invention are as follows：The technical solution is kneaded using extrusion equipment and is squeezed by adding fire-retardant based material
Go out to make powder transfer coating, is coated in substrate surface using the mode of electrostatic spraying, after forming a film in the curing process, utilizes
The pattern of needs is transferred to coating by heat sublimation principle, and having prevents flame ignition, prevents the using effect of propagation of flame.
Description of the drawings
Fig. 1：DSC tests the solidification process figure of fire-type powdery paints.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is this hair
Bright a part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not having
There is the every other embodiment obtained under the premise of making creative work, shall fall within the protection scope of the present invention.
A kind of preparation formula of flame retardant type transfer coating, raw material include：Polyester resin, curing agent, auxiliary agent and fire retardant,
And color stuffing.
Specifically, the raw material in formula forms by weight percentage is respectively：Polyester resin 55.8%, curing agent 4.2%,
Auxiliary agent 4~5%, fire proofing 10%, color stuffing are 26~28%.
Wherein, the curing agent is isocyanuric acid three-glycidyl ester TGIC；The auxiliary agent include levelling agent, styrax,
Wetting agent, smoke suppressant.
In addition, the mass fraction of the polyester resin, isocyanuric acid three-glycidyl ester TGIC is 99%；The levelling
The mass fraction of agent be 60%, the styrax, wetting agent, smoke suppressant mass fraction be 99%.
The technical solution makes powder by adding fire-retardant based material, using extrusion equipment mixing extrusion and transfers coating, can
Substrate surface is coated in the way of electrostatic spraying, after forming a film in the curing process, using heat sublimation principle by the figure of needs
Case is transferred to coating, and having prevents flame ignition, prevents the using effect of propagation of flame.
【Embodiment 1】
Raw material in formula forms by weight percentage：Polyester resin 55.8%, isocyanuric acid three-glycidyl
Ester TGIC 4.2%, levelling agent 1%, styrax 0.3%, wetting agent 0.5%, smoke suppressant 2%, organic fire-retardant 10%, face is filled out
Material 26.2%.
【Embodiment 2】
Raw material in formula forms by weight percentage：Polyester resin 55.8%, isocyanuric acid three-glycidyl
Ester TGIC 4.2%, levelling agent 1%, styrax 0.3%, wetting agent 0.5%, smoke suppressant 2%, the inorganic resistance of uncoated processing
Fire agent 10%, color stuffing 26.2%.
More specifically, the wherein described inorganic combustion inhibitor is aluminium hydroxide and the mixture of ammonium polyphosphate.
【Embodiment 3】
Raw material in formula forms by weight percentage：Polyester resin 55.8%, isocyanuric acid three-glycidyl
Ester TGIC 4.2%, levelling agent 1%, styrax 0.3%, wetting agent 0.5%, smoke suppressant 2%, by the inorganic resistance of cladding processing
Fire agent 10%, color stuffing 26.2%.
【Experiment test】
The technology mode transferred by vacuum, utilizes the principle of ink heat sublimation：By embodiment 1, embodiment 2, embodiment 3
The powdery paints of preparation sprays to workpiece surface respectively by high pressure electrostatic painting mode, by powdery paints made of 3 formulas,
220 DEG C of X10min (material temperature) are carried out again, and cooling is taken out after coating is fully cured；Select appropriate pattern (such as：Teak,
Cherry, gold is as wood etc.) transfer paper or transfer film, be posted on transfer paper or transfer film are smooth on the workpiece sprayed,
High temperature gummed tape is put on, vacuum has been taken out, after being put into baking transfer in heating furnace (165 DEG C -185 DEG C, toast 10 minutes), waits for workpiece
It is cooling, remove the transfer paper used and high temperature membrane, the transfer of clear patterns is on coating.
The comparison of embodiment 1-3 transfer performance is as follows：
By the analysis to transferring result, different types of fire retardant has very big influence, Ying Xuan to transfer paper-tear picture
It selects and does not do cladding processing, inorganic fire retardant is preferred.
And to embodiment 2, its solidification process is measured using DSC, it is specific as shown in Figure 1.
About quantitative measurement：
The coating that is prepared of control Examples 1 to 3 in identical film thickness range, test its coating gloss, impact strength,
The convex, adhesive force of cup, test result is as follows shown in table：
| Formula | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Film thickness | 60-80um | 60-80um | 60-80um |
| 60 ° of glossiness | 58-60% | 62-65% | 69-72% |
| Impact strength 50inch.lbs | ok | ok | ok |
| Cup is convex | 4.3mm | 5.5mm | 5.3mm |
| 1 millimeter of Crosshatch adhesion | 0 grade | 0 grade | 0 grade |
| Gel time (200 DEG C) | 234s | 198s | 176s |
| Oblique flow length (180 DEG C) | 74mm | 64mm | 58mm |
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that：Its according to
So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into
Row equivalent replacement；And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (9)
1. a kind of preparation formula of flame retardant type transfer coating, raw material include：Polyester resin, curing agent, auxiliary agent and fire retardant, with
And color stuffing.
2. a kind of preparation formula of flame retardant type transfer coating according to claim 1, which is characterized in that the raw material in formula
Forming by weight percentage is respectively：Polyester resin 55.8%, curing agent 4.2%, auxiliary agent 4~5%, fire proofing 10%, face
Filler is 26~28%.
3. a kind of preparation formula of flame retardant type transfer coating according to claim 1 or 2, which is characterized in that the solidification
Agent is isocyanuric acid three-glycidyl ester TGIC.
4. a kind of preparation formula of flame retardant type transfer coating according to claim 1 or 2, which is characterized in that the auxiliary agent
Including levelling agent, styrax, wetting agent, smoke suppressant.
5. a kind of preparation formula of flame retardant type transfer coating according to claim 3, which is characterized in that the polyester tree
Fat, isocyanuric acid three-glycidyl ester TGIC mass fraction be 99%.
6. a kind of preparation formula of flame retardant type transfer coating according to claim 3, which is characterized in that the levelling agent
Mass fraction is 60%, the styrax, wetting agent, smoke suppressant mass fraction be 99%.
7. a kind of preparation formula of flame retardant type transfer coating according to claim 1 or 2, which is characterized in that in formula
Raw material forms by weight percentage：Polyester resin 55.8%, isocyanuric acid three-glycidyl ester TGIC 4.2%, levelling
Agent 1%, styrax 0.3%, wetting agent 0.5%, smoke suppressant 2%, fire retardant 10%, color stuffing 26.2%.
8. a kind of preparation formula of flame retardant type transfer coating according to claim 7, which is characterized in that the fire retardant is
Organic fire-retardant or inorganic combustion inhibitor or halogenated flame retardant.
9. a kind of preparation formula of flame retardant type transfer coating according to claim 8, which is characterized in that described inorganic fire-retarded
Agent is aluminium hydroxide and the mixture of ammonium polyphosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810303680.2A CN108485349A (en) | 2018-04-03 | 2018-04-03 | A kind of preparation formula of flame retardant type transfer coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810303680.2A CN108485349A (en) | 2018-04-03 | 2018-04-03 | A kind of preparation formula of flame retardant type transfer coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108485349A true CN108485349A (en) | 2018-09-04 |
Family
ID=63314754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810303680.2A Pending CN108485349A (en) | 2018-04-03 | 2018-04-03 | A kind of preparation formula of flame retardant type transfer coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108485349A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114437613A (en) * | 2021-12-27 | 2022-05-06 | 张家港市华辰塑粉有限公司 | Flame-retardant powder coating and preparation method thereof |
| CN117285851A (en) * | 2023-11-24 | 2023-12-26 | 广东睿智环保科技股份有限公司 | Transfer powder coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747830A (en) * | 2008-12-08 | 2010-06-23 | 李新春 | Outdoor and indoor transfer powder |
| CN103265874A (en) * | 2013-05-23 | 2013-08-28 | 浙江超浪新材料有限公司 | High-toughness powder coating specially used for security door |
| CN104231872A (en) * | 2013-06-24 | 2014-12-24 | 江苏长松科技发展有限公司 | Anti-adhesion powder coating for wooden transfer |
| CN104497808A (en) * | 2014-12-31 | 2015-04-08 | 山东朗法博粉末涂装科技有限公司 | Powder coating for MDF transfer printing and application method of powder coating |
-
2018
- 2018-04-03 CN CN201810303680.2A patent/CN108485349A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747830A (en) * | 2008-12-08 | 2010-06-23 | 李新春 | Outdoor and indoor transfer powder |
| CN103265874A (en) * | 2013-05-23 | 2013-08-28 | 浙江超浪新材料有限公司 | High-toughness powder coating specially used for security door |
| CN104231872A (en) * | 2013-06-24 | 2014-12-24 | 江苏长松科技发展有限公司 | Anti-adhesion powder coating for wooden transfer |
| CN104497808A (en) * | 2014-12-31 | 2015-04-08 | 山东朗法博粉末涂装科技有限公司 | Powder coating for MDF transfer printing and application method of powder coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114437613A (en) * | 2021-12-27 | 2022-05-06 | 张家港市华辰塑粉有限公司 | Flame-retardant powder coating and preparation method thereof |
| CN117285851A (en) * | 2023-11-24 | 2023-12-26 | 广东睿智环保科技股份有限公司 | Transfer powder coating and preparation method thereof |
| CN117285851B (en) * | 2023-11-24 | 2024-03-08 | 广东睿智环保科技股份有限公司 | Transfer powder coating and preparation method thereof |
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Application publication date: 20180904 |
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| RJ01 | Rejection of invention patent application after publication |