CN106543883A - A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof - Google Patents
A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof Download PDFInfo
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- CN106543883A CN106543883A CN201611048063.XA CN201611048063A CN106543883A CN 106543883 A CN106543883 A CN 106543883A CN 201611048063 A CN201611048063 A CN 201611048063A CN 106543883 A CN106543883 A CN 106543883A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
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Abstract
The present invention discloses a kind of sprayable aqueous fire-proof coating being applied on glass, it is made up of the material of following parts by weight proportioning, including 20 28 parts of urethane acrylate, 18 28 parts of modified epoxy, 17 25 parts of dipentaerythritol acrylate, 8 19 parts of ethoxyquin trimethylolpropane trimethacrylate, 17 13 parts of hydroxy-cyclohexyl benzyl ketone, 7 11 parts of ethyl acetate, 11 17 parts of titanium dioxide, 12 20 parts of amino resins, 58 parts of charcoal blacks, 26 parts of wetting dispersing agent, 35 parts of silicone oil, 47 parts of styrene, 24 parts of alcohol ether cosolvent, 24 parts of initiator, 35 parts of 13 parts of hexanediol and azodiisobutyronitrile；A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof has environmental protection, low cost and sprays convenient advantage.
Description
Technical field
Present invention relates particularly to a kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof.
Background technology
Acrylic resin is referred to as with the copolymer that the monomers such as acrylate, methacrylate are main Material synthesis, with
Which is that the coating of film forming binder is referred to as acrylic resin paint.Such coating have color it is shallow, protect color, protect light, it is weather-proof, corrosion-resistant and
The advantages of anti-pollution, it is widely used to automobile, aircraft, machinery, electronics, furniture, building, leather finish, papermaking, printing and dyeing, wood
The covering with paint of material processing, industrial plastic and article of everyday use.Divide from coating dosage form, mainly have solvent based coating, water paint, high solid
Component coating and powdery paints.Compared with traditional solvent based coating, water soluble paint have price it is low, using safety, save
One of the advantages of resource and the energy, reduction environmental pollution and public hazards, thus become Main way of current coatings industry development.
But there is the shortcomings of resistance to elevated temperatures is poor, and paint film adhesion is low, fire line is bad in conventional water soluble coating.
The content of the invention
The technical problem to be solved in the present invention is to provide and is applied to glass with environmental protection, low cost and the simple one kind of spraying
On sprayable aqueous fire-proof coating and preparation method thereof.
To solve the above problems, the present invention is adopted the following technical scheme that：
A kind of sprayable aqueous fire-proof coating being applied on glass, is made up of the material of following parts by weight proportioning, including poly-
Urethane acrylate 20-28 part, modified epoxy 18-28 parts, dipentaerythritol acrylate 17-25 parts, ethoxyquin three
Hydroxymethyl-propane triacrylate 8-19 parts, 1- hydroxy-cyciohexyls-benzyl ketone 7-13 parts, ethyl acetate 7-11 parts, titanium dioxide
11-17 parts, amino resins 12-20 parts, charcoal blacks 5-8 parts, wetting dispersing agent 2-6 parts, silicone oil 3-5 parts, styrene 4-7 parts,
Alcohol ether cosolvent 2-4 parts, initiator 2-4 parts, hexanediol 1-3 parts and azodiisobutyronitrile 3-5 parts.
Further, a kind of sprayable aqueous fire-proof coating being applied on glass is by following parts by weight proportioning
Material is made, including 28 parts of urethane acrylate, 18 parts of modified epoxy, 17 parts of dipentaerythritol acrylate, second
8 parts of trimethylolpropane trimethacrylate of oxidation, 1- hydroxy-cyciohexyls -7 parts of benzyl ketone, 7 parts of ethyl acetate, titanium dioxide 11
Part, 12 parts of amino resins, 5 parts of charcoal blacks, 2 parts of wetting dispersing agent, 3 parts of silicone oil, 4 parts of styrene, 2 parts of alcohol ether cosolvent, draw
Send out 3 parts of 2 parts of agent, 1 part of hexanediol and azodiisobutyronitrile.
Further, a kind of sprayable aqueous fire-proof coating being applied on glass is by following parts by weight proportioning
Material is made, including 20 parts of urethane acrylate, 28 parts of modified epoxy, 25 parts of dipentaerythritol acrylate, second
19 parts of trimethylolpropane trimethacrylate of oxidation, 1- hydroxy-cyciohexyls -13 parts of benzyl ketone, 11 parts of ethyl acetate, titanium dioxide
17 parts, 20 parts of amino resins, 8 parts of charcoal blacks, 6 parts of wetting dispersing agent, 5 parts of silicone oil, 7 parts of styrene, 4 parts of alcohol ether cosolvent,
5 parts of 4 parts of initiator, 3 parts of hexanediol and azodiisobutyronitrile.
Further, a kind of sprayable aqueous fire-proof coating being applied on glass is by following parts by weight proportioning
Material is made, including 24 parts of urethane acrylate, 22 parts of modified epoxy, 21 parts of dipentaerythritol acrylate, second
13 parts of trimethylolpropane trimethacrylate of oxidation, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, 9 parts of ethyl acetate, titanium dioxide
14 parts, 16 parts of amino resins, 7 parts of charcoal blacks, 4 parts of wetting dispersing agent, 4 parts of silicone oil, 5 parts of styrene, 3 parts of alcohol ether cosolvent,
4 parts of 3 parts of initiator, 2 parts of hexanediol and azodiisobutyronitrile.
The invention solves the problems that another technical problem be that a kind of sprayable aqueous fire-proof coating being applied on glass is provided
Preparation method, comprise the following steps：
1) modified epoxy 18-28 parts are taken and amino resins 12-20 parts are put in smelting furnace, melt which by high-temperature heating,
Prepared glue, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take urethane acrylate 20-28 parts, dipentaerythritol acrylate 17-25 parts, ethoxyquin trimethylolpropane
Triacrylate 8-19 parts, 1- hydroxy-cyciohexyls-benzyl ketone 7-13 parts and ethyl acetate 7-11 parts are poured in container, and rise
To 100 degrees Celsius, insulation makes which react 30 minutes to temperature, and mixed solution is obtained, standby；
4）Take hexanediol 1-3 parts and be added to step 3）In, it is dehydrated by hexanediol reaction, sticky solution is obtained, it is standby；
5）Treat step 4）Obtained solution reaction is finished, and adds titanium dioxide 11-17 parts and charcoal blacks 5-8 parts, by blender
It is slowly stirred uniformly, then heats to 160 degrees Celsius, standing and reacting 2 hours is standby；
6）By step 5）Obtained solution is added to step 2）In the glue for diluting, and at the uniform velocity stirred by blender so that
Dilution glue is uniform with material mixing, standby；
7）By step 6）The material being mixed to get is warmed up to 110 degrees Celsius again, and adds wetting dispersing agent 2-6 parts, silicone oil 3-5
Part, styrene 4-7 parts, alcohol ether cosolvent 2-4 parts and initiator 2-4 parts so that above-mentioned material and step 6）Solution mixing it is equal
It is even, and insulation reaction 40 minutes, it is standby；
8）By step 7）The material obtained after reaction is placed where being placed in depletion of YANG light irradiation, stands cooling, standby；
9）Take azodiisobutyronitrile 3-5 parts and be added to step 8）In the material obtained after cooling.Coating is obtained final product after stirring, so
After be placed in be dried ventilation where preserve, you can.
The invention has the beneficial effects as follows：Made by material with environment protecting obtain it is a kind of be applied on glass can
Spraying aqueous fire-proof coating, which not only makes simply, and the cost of material is low, and prepared coating also has the convenient fire prevention of spraying when in use
The good advantage of effect.
Specific embodiment
Embodiment 1：
A kind of sprayable aqueous fire-proof coating being applied on glass, is made up of the material of following parts by weight proportioning, including poly-
28 parts of urethane acrylate, 18 parts of modified epoxy, 17 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane
8 parts of triacrylate, 1- hydroxy-cyciohexyls -7 parts of benzyl ketone, 7 parts of ethyl acetate, 11 parts of titanium dioxide, 12 parts of amino resins,
5 parts of charcoal blacks, 2 parts of wetting dispersing agent, 3 parts of silicone oil, 4 parts of styrene, 2 parts of alcohol ether cosolvent, 2 parts of initiator, 1 part of hexanediol
With 3 parts of azodiisobutyronitrile.
A kind of preparation method of the sprayable aqueous fire-proof coating being applied on glass, comprises the following steps：
1) take 18 parts of modified epoxy and 12 parts of amino resins are put in smelting furnace, melt which by high-temperature heating, glue is obtained
Liquid, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 28 parts of urethane acrylate, 17 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane tris propylene
7 parts of 8 parts of acid esters, 1- hydroxy-cyciohexyls -7 parts of benzyl ketone and ethyl acetate are poured in container, and are warming up to 100 degrees Celsius, are protected
Temperature makes which react 30 minutes, and mixed solution is obtained, standby；
4）Take 1 part of hexanediol and be added to step 3）In, it is dehydrated by hexanediol reaction, sticky solution is obtained, it is standby；
5）Treat step 4）Obtained solution reaction is finished, and is added 5 parts of 11 parts of titanium dioxide and charcoal blacks, is slowly stirred by blender
Mix uniform, then heat to 160 degrees Celsius, standing and reacting 2 hours is standby；
6）By step 5）Obtained solution is added to step 2）In the glue for diluting, and at the uniform velocity stirred by blender so that
Dilution glue is uniform with material mixing, standby；
7）By step 6）The material being mixed to get is warmed up to 110 degrees Celsius again, and add 2 parts of wetting dispersing agent, 3 parts of silicone oil,
2 parts of 4 parts of styrene, 2 parts of alcohol ether cosolvent and initiator so that above-mentioned material and step 6）Solution mix homogeneously, and be incubated
Reaction 40 minutes, it is standby；
8）By step 7）The material obtained after reaction is placed where being placed in depletion of YANG light irradiation, stands cooling, standby；
9）Take 3 parts of azodiisobutyronitrile and be added to step 8）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in where being dried ventilation and preserves, you can.
Embodiment 2：
A kind of sprayable aqueous fire-proof coating being applied on glass, is made up of the material of following parts by weight proportioning, including poly-
20 parts of urethane acrylate, 28 parts of modified epoxy, 25 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane
19 parts of triacrylate, 1- hydroxy-cyciohexyls -13 parts of benzyl ketone, 11 parts of ethyl acetate, 17 parts of titanium dioxide, amino resins 20
Part, 8 parts of charcoal blacks, 6 parts of wetting dispersing agent, 5 parts of silicone oil, 7 parts of styrene, 4 parts of alcohol ether cosolvent, 4 parts of initiator, hexanediol
3 parts and 5 parts of azodiisobutyronitrile.
A kind of preparation method of the sprayable aqueous fire-proof coating being applied on glass, comprises the following steps：
1) take 28 parts of modified epoxy and 20 parts of amino resins are put in smelting furnace, melt which by high-temperature heating, glue is obtained
Liquid, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 20 parts of urethane acrylate, 25 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane tris propylene
11 parts of 19 parts of acid esters, 1- hydroxy-cyciohexyls -13 parts of benzyl ketone and ethyl acetate are poured in container, and it is Celsius to be warming up to 100
Degree, insulation make which react 30 minutes, and mixed solution is obtained, standby；
4）Take 3 parts of hexanediol and be added to step 3）In, it is dehydrated by hexanediol reaction, sticky solution is obtained, it is standby；
5）Treat step 4）Obtained solution reaction is finished, and is added 8 parts of 17 parts of titanium dioxide and charcoal blacks, is slowly stirred by blender
Mix uniform, then heat to 160 degrees Celsius, standing and reacting 2 hours is standby；
6）By step 5）Obtained solution is added to step 2）In the glue for diluting, and at the uniform velocity stirred by blender so that
Dilution glue is uniform with material mixing, standby；
7）By step 6）The material being mixed to get is warmed up to 110 degrees Celsius again, and add 6 parts of wetting dispersing agent, 5 parts of silicone oil,
4 parts of 7 parts of styrene, 4 parts of alcohol ether cosolvent and initiator so that above-mentioned material and step 6）Solution mix homogeneously, and be incubated
Reaction 40 minutes, it is standby；
8）By step 7）The material obtained after reaction is placed where being placed in depletion of YANG light irradiation, stands cooling, standby；
9）Take 5 parts of azodiisobutyronitrile and be added to step 8）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in where being dried ventilation and preserves, you can.
Embodiment 3：
A kind of sprayable aqueous fire-proof coating being applied on glass, is made up of the material of following parts by weight proportioning, including poly-
24 parts of urethane acrylate, 22 parts of modified epoxy, 21 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane
13 parts of triacrylate, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, 9 parts of ethyl acetate, 14 parts of titanium dioxide, amino resins 16
Part, 7 parts of charcoal blacks, 4 parts of wetting dispersing agent, 4 parts of silicone oil, 5 parts of styrene, 3 parts of alcohol ether cosolvent, 3 parts of initiator, hexanediol
2 parts and 4 parts of azodiisobutyronitrile.
A kind of preparation method of the sprayable aqueous fire-proof coating being applied on glass, comprises the following steps：
1) take 22 parts of modified epoxy and 16 parts of amino resins are put in smelting furnace, melt which by high-temperature heating, glue is obtained
Liquid, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take 24 parts of urethane acrylate, 21 parts of dipentaerythritol acrylate, ethoxyquin trimethylolpropane tris propylene
9 parts of 13 parts of acid esters, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone and ethyl acetate are poured in container, and are warming up to 100 degrees Celsius,
Insulation makes which react 30 minutes, and mixed solution is obtained, standby；
4）Take 2 parts of hexanediol and be added to step 3）In, it is dehydrated by hexanediol reaction, sticky solution is obtained, it is standby；
5）Treat step 4）Obtained solution reaction is finished, and adds 14 parts of titanium dioxide and charcoal blacks 5-8 parts, slow by blender
Stir, then heat to 160 degrees Celsius, standing and reacting 2 hours is standby；
6）By step 5）Obtained solution is added to step 2）In the glue for diluting, and at the uniform velocity stirred by blender so that
Dilution glue is uniform with material mixing, standby；
7）By step 6）The material being mixed to get is warmed up to 110 degrees Celsius again, and add 4 parts of wetting dispersing agent, 4 parts of silicone oil,
3 parts of 5 parts of styrene, 3 parts of alcohol ether cosolvent and initiator so that above-mentioned material and step 6）Solution mix homogeneously, and be incubated
Reaction 40 minutes, it is standby；
8）By step 7）The material obtained after reaction is placed where being placed in depletion of YANG light irradiation, stands cooling, standby；
9）Take 4 parts of azodiisobutyronitrile and be added to step 8）In the material obtained after cooling.Coating is obtained final product after stirring, then
It is placed in where being dried ventilation and preserves, you can.
Experimental example：
Experimental subject：150 blocks of glass, are divided into 3 groups according to experimental technique, per group of 50 blocks of glass.
Experimental technique and time：, by spraying common paint vehicle, matched group 2 is by existing Lacquer finish paint vehicle, real for matched group 1
A kind of sprayable aqueous fire-proof coating being applied on glass using the present invention is tested group, experimental period is 3 months, records number of times
For 3 times, floor situation is recorded.
Criterion：
Surface is smooth：After coating, glass surface is smooth, glossy；
Rough surface：Coating for a period of time after, glass surface occur split cruelly, depainting etc.；
Rat：Glass surface enamelled coating is raised, and with splitting cruelly and depainting situation；
Three groups of floors carry out first month effect and compare, and the results are shown in Table 1.
Test through first month, three groups of situations have notable difference.
Three groups of floors carry out second month effect and compare, and the results are shown in Table 2.
Test through second month, three groups of situations have highly significant sex differernce.
Three groups of floors carry out three month effect and compare, and the results are shown in Table 3.
Tested through three months, three groups of situations have highly significant sex differernce.
From above experimental result, a kind of effect of sprayable aqueous fire-proof coating being applied on glass of the present invention
It is best.
The invention has the beneficial effects as follows：Made by material with environment protecting obtain it is a kind of be applied on glass can
Spraying aqueous fire-proof coating, which not only makes simply, and the cost of material is low, and prepared coating also has the convenient fire prevention of spraying when in use
The good advantage of effect.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, should all cover within the scope of the present invention.
Claims (5)
1. a kind of sprayable aqueous fire-proof coating being applied on glass, it is characterised in that：By the material of following parts by weight proportioning
Material is made, including urethane acrylate 20-28 parts, modified epoxy 18-28 parts, dipentaerythritol acrylate 17-
25 parts, ethoxyquin trimethylolpropane trimethacrylate 8-19 parts, 1- hydroxy-cyciohexyls-benzyl ketone 7-13 parts, ethyl acetate
7-11 parts, titanium dioxide 11-17 parts, amino resins 12-20 parts, charcoal blacks 5-8 parts, wetting dispersing agent 2-6 parts, silicone oil 3-5 parts,
Styrene 4-7 parts, alcohol ether cosolvent 2-4 parts, initiator 2-4 parts, hexanediol 1-3 parts and azodiisobutyronitrile 3-5 parts.
2. a kind of sprayable aqueous fire-proof coating being applied on glass as claimed in claim 1, it is characterised in that：By following
The material of parts by weight proportioning is made, including 28 parts of urethane acrylate, 18 parts of modified epoxy, dipentaerythritol 6 third
17 parts of olefin(e) acid ester, 8 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -7 parts of benzyl ketone, ethyl acetate
7 parts, 11 parts of titanium dioxide, 12 parts of amino resins, 5 parts of charcoal blacks, 2 parts of wetting dispersing agent, 3 parts of silicone oil, 4 parts of styrene, alcohol ether
3 parts of 2 parts of cosolvent, 2 parts of initiator, 1 part of hexanediol and azodiisobutyronitrile.
3. a kind of sprayable aqueous fire-proof coating being applied on glass as claimed in claim 2, it is characterised in that：By following
The material of parts by weight proportioning is made, including 20 parts of urethane acrylate, 28 parts of modified epoxy, dipentaerythritol 6 third
25 parts of olefin(e) acid ester, 19 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -13 parts of benzyl ketone, acetic acid second
11 parts of ester, 17 parts of titanium dioxide, 20 parts of amino resins, 8 parts of charcoal blacks, 6 parts of wetting dispersing agent, 5 parts of silicone oil, 7 parts of styrene, alcohol
5 parts of 4 parts of ether cosolvent, 4 parts of initiator, 3 parts of hexanediol and azodiisobutyronitrile.
4. a kind of sprayable aqueous fire-proof coating being applied on glass as claimed in claim 3, it is characterised in that：By following
The material of parts by weight proportioning is made, including 24 parts of urethane acrylate, 22 parts of modified epoxy, dipentaerythritol 6 third
21 parts of olefin(e) acid ester, 13 parts of ethoxyquin trimethylolpropane trimethacrylate, 1- hydroxy-cyciohexyls -10 parts of benzyl ketone, acetic acid second
9 parts of ester, 14 parts of titanium dioxide, 16 parts of amino resins, 7 parts of charcoal blacks, 4 parts of wetting dispersing agent, 4 parts of silicone oil, 5 parts of styrene, alcohol
4 parts of 3 parts of ether cosolvent, 3 parts of initiator, 2 parts of hexanediol and azodiisobutyronitrile.
5. a kind of preparation method of the sprayable aqueous fire-proof coating being applied on glass as claimed in claim 1, its feature
It is：Comprise the following steps：
1) modified epoxy 18-28 parts are taken and amino resins 12-20 parts are put in smelting furnace, melt which by high-temperature heating,
Prepared glue, it is standby；
2）By step 1）Obtained glue and water in proportion 1:2 addition mixing, make glue thinning, standby；
3）Take urethane acrylate 20-28 parts, dipentaerythritol acrylate 17-25 parts, ethoxyquin trimethylolpropane
Triacrylate 8-19 parts, 1- hydroxy-cyciohexyls-benzyl ketone 7-13 parts and ethyl acetate 7-11 parts are poured in container, and rise
To 100 degrees Celsius, insulation makes which react 30 minutes to temperature, and mixed solution is obtained, standby；
4）Take hexanediol 1-3 parts and be added to step 3）In, it is dehydrated by hexanediol reaction, sticky solution is obtained, it is standby；
5）Treat step 4）Obtained solution reaction is finished, and adds titanium dioxide 11-17 parts and charcoal blacks 5-8 parts, by blender
It is slowly stirred uniformly, then heats to 160 degrees Celsius, standing and reacting 2 hours is standby；
6）By step 5）Obtained solution is added to step 2）In the glue for diluting, and at the uniform velocity stirred by blender so that
Dilution glue is uniform with material mixing, standby；
7）By step 6）The material being mixed to get is warmed up to 110 degrees Celsius again, and adds wetting dispersing agent 2-6 parts, silicone oil 3-5
Part, styrene 4-7 parts, alcohol ether cosolvent 2-4 parts and initiator 2-4 parts so that above-mentioned material and step 6）Solution mixing it is equal
It is even, and insulation reaction 40 minutes, it is standby；
8）By step 7）The material obtained after reaction is placed where being placed in depletion of YANG light irradiation, stands cooling, standby；
9）Take azodiisobutyronitrile 3-5 parts and be added to step 8）In the material obtained after cooling, coating is obtained final product after stirring, so
After be placed in be dried ventilation where preserve, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611048063.XA CN106543883A (en) | 2016-11-25 | 2016-11-25 | A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611048063.XA CN106543883A (en) | 2016-11-25 | 2016-11-25 | A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106543883A true CN106543883A (en) | 2017-03-29 |
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| CN201611048063.XA Pending CN106543883A (en) | 2016-11-25 | 2016-11-25 | A kind of sprayable aqueous fire-proof coating being applied on glass and preparation method thereof |
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| CN (1) | CN106543883A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337571A (en) * | 2018-09-30 | 2019-02-15 | 江苏耀兴安全玻璃有限公司 | A kind of glass fireproof coating and preparation method thereof |
| CN113502124A (en) * | 2021-07-22 | 2021-10-15 | 宋华杰 | Heat-insulating flame-retardant coating and preparation method thereof |
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| CN105111886A (en) * | 2015-08-28 | 2015-12-02 | 中国科学院合肥物质科学研究院 | Water-based epoxy multifunctional steel structure paint and preparation method thereof |
| CN105713487A (en) * | 2016-05-01 | 2016-06-29 | 深圳市中科宏业科技有限公司 | Water-based epoxy anticorrosive paint and preparation method thereof |
| CN105733414A (en) * | 2014-12-10 | 2016-07-06 | 田建频 | Anti-corrosive baking paint |
| CN105838182A (en) * | 2016-03-24 | 2016-08-10 | 浙江新迪在龙涂料科技有限公司 | Spray-coatable aqueous UV coating applied on glass and preparation method thereof |
| CN105907281A (en) * | 2016-06-28 | 2016-08-31 | 成都育芽科技有限公司 | Fireproof flame-retardant energy-saving building paint |
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| CN105733414A (en) * | 2014-12-10 | 2016-07-06 | 田建频 | Anti-corrosive baking paint |
| CN105111886A (en) * | 2015-08-28 | 2015-12-02 | 中国科学院合肥物质科学研究院 | Water-based epoxy multifunctional steel structure paint and preparation method thereof |
| CN105838182A (en) * | 2016-03-24 | 2016-08-10 | 浙江新迪在龙涂料科技有限公司 | Spray-coatable aqueous UV coating applied on glass and preparation method thereof |
| CN105713487A (en) * | 2016-05-01 | 2016-06-29 | 深圳市中科宏业科技有限公司 | Water-based epoxy anticorrosive paint and preparation method thereof |
| CN105907281A (en) * | 2016-06-28 | 2016-08-31 | 成都育芽科技有限公司 | Fireproof flame-retardant energy-saving building paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337571A (en) * | 2018-09-30 | 2019-02-15 | 江苏耀兴安全玻璃有限公司 | A kind of glass fireproof coating and preparation method thereof |
| CN113502124A (en) * | 2021-07-22 | 2021-10-15 | 宋华杰 | Heat-insulating flame-retardant coating and preparation method thereof |
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Application publication date: 20170329 |