CN105713133A - Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid - Google Patents
Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid Download PDFInfo
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- CN105713133A CN105713133A CN201610111806.7A CN201610111806A CN105713133A CN 105713133 A CN105713133 A CN 105713133A CN 201610111806 A CN201610111806 A CN 201610111806A CN 105713133 A CN105713133 A CN 105713133A
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- dispersion liquid
- resin dispersion
- aqueous woodware
- woodware paint
- propylene glycol
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
Abstract
The invention discloses resin dispersing liquid for water-borne wood paint and a preparation method of the resin dispersing liquid. The resin dispersing liquid is prepared from 20-39 parts of methyl methacrylate, 10-20 parts of styrene, 15-25 parts of butyl acrylate, 5-25 parts of hydroxyethyl methylacrylate, 1-5 parts of acrylic acid, 1-8 parts of initiator, 1-15 parts of solvent and 1-20 parts of solvent gasoline. The water-borne wood paint prepared from the resin dispersing liquid has the advantages of being free of odor, toxin and harm, high in hardness and adhesion and the like, and has wide application prospects.
Description
Technical field
The invention belongs to furniture lacquer technical field, be specifically related to a kind of aqueous woodware paint resin dispersion liquid and preparation method thereof and application.
Background technology
Along with the pressure of environmental protection policy, the continuous lifting of consumer's environmental consciousness, provinces and cities especially in all parts of the country have put into effect VOC emission limit standard, encourage furniture enterprise to use non-solvent coating, bring opportunity to the development of the environmental protection coating materials such as water paint.Although traditional coating is still in occupation of the bigger market share, but water paint is pollution-free industry, is the direction of paint class future development, and the water paint leading enterprise in domestic native country emerges.The development of water paint and the shared market share are undisputable facts increasing year by year, and have the trend of speed-raising.Some enterprises have appreciated that the market potential that water paint is wide, research and develop one after another, march, expand water paint market.
Although water paint is superior traditional paint on environmental-protecting performance, but in physical property, water paint product exists that construction is difficult, not water-fast, easily take off the defect such as skin, poor, the difference of hardness of richness.Paint owing to having the features such as hardness is strong, paint film richness is high, construction is tolerant, remain first-selected coating during many people's decorations.Only the defect in physical property is solved, even beyond tradition paint, and consumer just can more actively select to use water paint.Only catering to consumer on environmental-protecting performance, cannot meet consumer on construction technology, decorative effect, the market of water paint is still difficult to open.This needs water paint manufacturing enterprise to do technological innovation in water paint performance.
Although water-borne wood coating be it have been recognized that environment-friendly type coating, but water paint there is also many problems in prior art, as low in hardness, poor adhesive force, chance water easily whiten, the physical and chemical performance of film is poor, expensive etc., therefore, the combination property of water paint also has bigger gap compared with solvent based coating.The basic reason that there is bigger gap is in that do not have suitable water-base resin liquid.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of hardness height, adhesive force is good, meet the aqueous woodware paint resin liquid that water does not whiten, film comprehensive physical performance is good, cost performance is not high.
The present invention also to solve the technical problem that the preparation method being to provide above-mentioned aqueous woodware paint resin dispersion liquid.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
A kind of aqueous woodware paint resin dispersion liquid, it is to be prepared by the component including following volume parts:
Preferred as the present invention, described initiator is peroxide initiator.
Wherein, described peroxide initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Benzene potassium acid ester.
Preferred as the present invention, described solvent is alcohol ether solvent.
Wherein, described alcohol ether solvent is Propylene glycol n-propyl ether, propylene glycol diisopropyl ether, propylene glycol n-butyl ether, dipropylene.
Preferred as the present invention, the boiling range of described industrial naptha is 120 DEG C～200 DEG C, and after using this industrial naptha, the aqueous resin preparing gained dissipates easily, and obtained resin liquid water dispersible is good.
The preparation method of aqueous woodware paint resin dispersion liquid, comprises the steps:
(1) it is (1～15) by solvent and industrial naptha according to volume ratio: (1～20) adds in reactor, is warming up to 120～140 DEG C；
(2) it is (20～39) by methyl methacrylate, styrene, butyl acrylate, hydroxyethyl methylacrylate, acrylic acid, initiator according to volume ratio: (10～20): (15～25): (5～25): (1～5): (1～8) mix homogeneously, it being progressively added drop-wise in reactor, time for adding is 3～5h again；
(3) at 120～140 DEG C, it is incubated 1～2h after completion of dropwise addition, the temperature in reactor is down to 100～130 DEG C；
(4) adding ammonia, stirring neutralizes, and adds water by resin dispersion, and making the solid content of material in reactor is 40～45%, cooling down to 30～40 DEG C；
(5) filter, namely obtain aqueous woodware paint resin dispersion liquid.
Wherein, described solvent is the compositions of one or more the alcohol ethers in Propylene glycol n-propyl ether, propylene glycol diisopropyl ether, propylene glycol n-butyl ether, dipropylene；The boiling range of described industrial naptha is 120 DEG C～200 DEG C；Described initiator is the compositions of one or more in special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Benzene potassium acid ester.
The aqueous woodware paint resin dispersion liquid that the preparation method of above-mentioned aqueous woodware paint resin dispersion liquid prepares.
The application in preparation Waterborne wood paint of the above-mentioned aqueous woodware paint resin dispersion liquid.
Beneficial effect: the present invention has the advantage that relative to prior art
Aqueous woodware paint resin dispersion liquid and preparation method thereof prepared by the present invention is simple, low in the pollution of the environment, utilizes aqueous woodware paint hardness prepared by this aqueous woodware paint resin dispersion liquid high, and hardness can reach more than 1H, and adhesive force is good, and dried water of meeting does not whiten, and construction is easily.
Accompanying drawing explanation
The performance detection data of high rigidity aqueous woodware paint prepared by Fig. 1 present invention.
Detailed description of the invention
According to following embodiment, it is possible to be more fully understood that the present invention.But, as it will be easily appreciated by one skilled in the art that the content described by embodiment is merely to illustrate the present invention, and should without the present invention described in detail in restriction claims.
Embodiment 1: prepare acrylic resin dispersion liquid:
(1) resin formula (by volume mark meter):
(2) preparation method:
By Propylene glycol n-propyl ether and industrial naptha (boiling range 120 DEG C) according to above-mentioned volume ratio for adding in reactor, it is warming up to 140 DEG C；By methyl methacrylate, styrene, butyl acrylate, hydroxyethyl methylacrylate, acrylic acid, special hexyl peroxidating trimethylace tonitric ester is according to above-mentioned volume ratio mix homogeneously, then it is progressively added drop-wise in reactor, and time for adding is 4h；At 120 DEG C, it is incubated 1～2h after completion of dropwise addition, the temperature in reactor is down to 100 DEG C；Adding ammonia, stirring neutralizes, and adds water, and making the solid content of material in reactor is 40～45%；Cold filtration, namely obtains aqueous woodware paint resin dispersion liquid (acrylic resin dispersion liquid).
Embodiment 2: prepare acrylic resin dispersion liquid:
(1) resin formula (by volume mark meter):
(2) preparation method:
By propylene glycol diisopropyl ether and industrial naptha (boiling range 150 DEG C) according to above-mentioned volume ratio for adding in reactor, it is warming up to 140 DEG C；By methyl methacrylate, styrene, butyl acrylate, hydroxyethyl methylacrylate, acrylic acid, tert-butylperoxy caprylate is according to above-mentioned volume ratio mix homogeneously, then it is progressively added drop-wise in reactor, and time for adding is 3h；At 120 DEG C, it is incubated 1～2h after completion of dropwise addition, the temperature in reactor is down to 100 DEG C；Adding ammonia, stirring neutralizes, and adds water, and making the solid content of material in reactor is 40～45%；Cold filtration, namely obtains aqueous woodware paint resin dispersion liquid (acrylic resin dispersion liquid).
Embodiment 3: prepare acrylic resin dispersion liquid:
(1) resin formula (by volume mark meter):
(2) preparation method:
By propylene glycol n-butyl ether and industrial naptha (boiling range 200 DEG C) according to above-mentioned volume ratio for adding in reactor, it is warming up to 140 DEG C；By methyl methacrylate, styrene, butyl acrylate, hydroxyethyl methylacrylate, acrylic acid, tert-butylperoxy Benzene potassium acid ester is according to above-mentioned volume ratio mix homogeneously, then it is progressively added drop-wise in reactor, and time for adding is 3h；At 120 DEG C, it is incubated 1～2h after completion of dropwise addition, the temperature in reactor is down to 100 DEG C；Adding ammonia, stirring neutralizes, and adds water, and making the solid content of material in reactor is 40～45%；Cold filtration, namely obtains aqueous woodware paint resin dispersion liquid (acrylic resin dispersion liquid).
Embodiment 4: prepare aqueous woodware paint:
Being added in agitator by acrylic resin dispersion liquid, 800～1000rpm stirs, Propylene glycol n-propyl ether, BYK-018, BYK-342,FX600, P-240, water are sequentially added in agitator, and adjustment viscosity is 30～200s, obtains first component；During construction, the ratio that the cross-linking agent that first component forms with polyurethane is 4～8:1 by volume is mixed, stand, filter, obtain aqueous woodware paint.
Embodiment 5: prepare aqueous woodware paint:
Being added in agitator by acrylic resin dispersion liquid, 800～1000rpm stirs, propylene glycol diisopropyl ether, BYK-024, BYK-346,FX600, P-240, water are sequentially added in agitator, and adjustment viscosity is 30～200s, obtains first component；During construction, the ratio that the component B cross-linking agent that first component forms with polyurethane is 4～8:1 by volume is mixed, stand, filter, obtain aqueous woodware paint.
Embodiment 6: prepare aqueous woodware paint:
Being added in agitator by acrylic resin dispersion liquid, 800～1000rpm stirs, propylene glycol n-butyl ether, BYK-28, BYK-346,FX600, P-240, water are sequentially added in agitator, and adjustment viscosity is 30～200s, obtains first component；During construction, the ratio that the component B cross-linking agent that first component forms with polyurethane is 4～8:1 by volume is mixed, stand, filter, obtain aqueous woodware paint.
The examining report utilizing aqueous woodware paint prepared by said method is shown in Fig. 1, it can be seen that utilize the hardness of aqueous woodware paint prepared by said method to reach H level, is significantly larger than water paint national standard B level.Other indexs also all meet or exceed water paint national standard, have reached the national standard of solvent-borne type furniture lacquer.It is fully able to the needs of satisfied current wood furniture application, is the ideal product substituting solvent-borne type furniture lacquer.
Claims (8)
1. an aqueous woodware paint resin dispersion liquid, it is characterised in that it is to be prepared by the component including following volume parts:
2. aqueous woodware paint dispersion liquid according to claim 1, it is characterized in that, described initiator is one or more the peroxide initiator compositionss in special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Benzene potassium acid ester.
3. aqueous woodware paint resin dispersion liquid according to claim 1, it is characterised in that described solvent is the compositions of one or more the alcohol ether solvents in Propylene glycol n-propyl ether, propylene glycol diisopropyl ether, propylene glycol n-butyl ether, dipropylene.
4. aqueous woodware paint resin dispersion liquid according to claim 1, it is characterised in that the boiling range of described industrial naptha is 120 DEG C～200 DEG C.
5. the preparation method of aqueous woodware paint resin dispersion liquid described in Claims 1 to 4, it is characterised in that comprise the steps:
(1) it is (1～15) by solvent and industrial naptha according to volume ratio: (1～20) adds in reactor, is warming up to 100～140 DEG C；
(2) it is (20～39) by methyl methacrylate, styrene, butyl acrylate, hydroxyethyl methylacrylate, acrylic acid, initiator according to volume ratio: (10～20): (15～25): (5～25): (1～5): (1～8) mix homogeneously, it being progressively added drop-wise in reactor, time for adding is 3～5h again；
(3) at 120～130 DEG C, it is incubated 1～2h after completion of dropwise addition, the temperature in reactor is down to 80～100 DEG C；
(4) adding ammonia, stirring neutralizes, and adds after water makes reactant scatter, cools, make material in reactor temperature be down to 30～40 DEG C；
(5) filter, namely obtain aqueous woodware paint resin dispersion liquid.
6. the preparation method of aqueous woodware paint resin dispersion liquid according to claim 5, it is characterized in that, described solvent is propylene glycol kind solvent is the compositions of one or more in Propylene glycol n-propyl ether, propylene glycol diisopropyl ether, propylene glycol n-butyl ether, dipropylene；The boiling range of described industrial naptha is 120 DEG C～200 DEG C；Described initiator is the compositions of one or more in special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Benzene potassium acid ester.
7. the aqueous woodware paint resin dispersion liquid that the preparation method of the aqueous woodware paint resin dispersion liquid described in claim 5,6 prepares.
8. the application in preparation Waterborne wood paint of the aqueous woodware paint resin dispersion liquid described in any one of claim 1,2,3,4,5,7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111806.7A CN105713133A (en) | 2016-02-29 | 2016-02-29 | Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111806.7A CN105713133A (en) | 2016-02-29 | 2016-02-29 | Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid |
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| CN105713133A true CN105713133A (en) | 2016-06-29 |
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| CN201610111806.7A Pending CN105713133A (en) | 2016-02-29 | 2016-02-29 | Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337488A (en) * | 2018-07-04 | 2019-02-15 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
| CN109354959A (en) * | 2018-07-04 | 2019-02-19 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint and preparation method thereof |
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| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN101974184A (en) * | 2010-09-29 | 2011-02-16 | 苏州凯康化工科技有限公司 | Water-based acrylic emulsion and preparation method and application thereof |
| CN103525233A (en) * | 2012-07-04 | 2014-01-22 | 长春市三化实业有限责任公司 | Water-based automobile finish and preparation method thereof |
-
2016
- 2016-02-29 CN CN201610111806.7A patent/CN105713133A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN101974184A (en) * | 2010-09-29 | 2011-02-16 | 苏州凯康化工科技有限公司 | Water-based acrylic emulsion and preparation method and application thereof |
| CN103525233A (en) * | 2012-07-04 | 2014-01-22 | 长春市三化实业有限责任公司 | Water-based automobile finish and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337488A (en) * | 2018-07-04 | 2019-02-15 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
| CN109354959A (en) * | 2018-07-04 | 2019-02-19 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint and preparation method thereof |
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Application publication date: 20160629 |
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