CN109337488A - A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof - Google Patents
A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof Download PDFInfo
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- CN109337488A CN109337488A CN201811564837.3A CN201811564837A CN109337488A CN 109337488 A CN109337488 A CN 109337488A CN 201811564837 A CN201811564837 A CN 201811564837A CN 109337488 A CN109337488 A CN 109337488A
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- dispersion liquid
- resin dispersion
- metallic paint
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- propylene glycol
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous double-component metallic paint resin dispersion liquid, each component including following volumes number: 20 ~ 39 parts of methyl methacrylate；10 ~ 20 parts of styrene；15 ~ 25 parts of Isooctyl acrylate monomer；5 ~ 25 parts of hydroxyethyl methacrylate；1 ~ 5 part of acrylic acid；1 ~ 8 part of initiator；1 ~ 15 part of solvent；1 ~ 20 part of industrial naptha.And the aqueous double-component metallic paint resin dispersion liquid and preparation method thereof is provided, there is the beneficial effect that finished product stability is good, production cost is low.
Description
Technical field
The invention belongs to water paint technical fields, and in particular to a kind of aqueous dual-component metallic paint resin dispersion liquid and its
Preparation method.
Background technique
Metallic paint is called metal flash paint, added with fine metal powder (such as aluminium powder, copper powder) in its paint base,
After light is mapped on metal powder, and it is reflected through air film.Therefore, it appears that as metal is glittering.
This metal flash paint gives a kind of pleasant, brisk, novel feeling of people, changes the shapes and sizes of metal powder, so that it may
Control the shining of metallic coating film；In the outside of metallic paint, usually also protected added with one layer of varnish.Metallic paint is general
Have aqueous and two kinds of solvent type, with the pressure of environmental protection policy, the continuous promotion of consumer's environmental consciousness is especially in all parts of the country to save
City has put into effect VOC emission limit standard, encourages furniture enterprise to use non-solvent coating, to the development of the environmental protection coating materials such as water paint
Bring opportunity.
The most important application field of metallic paint is automobile industry.The outer surface of automobile of metallic paint is coated, can not only be allowed
Metal plate part surface after coating seems more glittering moving, and under a different angle, due to the refraction of light, can allow vehicle
Color, even profile can be all varied.Allow vehicle appearance and modeling to seem richer, more interesting, this be why " metallic paint "
More and more universal one of the reason of meeting.
Although the water paint feature of environmental protection is preferable, metal powder is unstable in water and air, and chemical reaction often occurs and becomes
Matter, therefore its surface needs to carry out specially treated, cause it is expensive for the metal powder in water paint, using being restricted,
Current metallic paint is mainly based on solvent type.
Therefore, new technology is needed to improve the deficiencies in the prior art.
Summary of the invention
Goal of the invention: the purpose of the present invention is: it is good, raw to provide a kind of finished product stability for the shortcomings that overcoming above-mentioned technology
Produce aqueous double-component metallic paint resin dispersion liquid and preparation method thereof at low cost.
Technical solution: a kind of aqueous double-component metallic paint resin dispersion liquid, each component including following volumes number:
20 ~ 39 parts of methyl methacrylate
10 ~ 20 parts of styrene
15 ~ 25 parts of Isooctyl acrylate monomer
5 ~ 25 parts of hydroxyethyl methacrylate
1 ~ 5 part of acrylic acid
1 ~ 8 part of initiator
1 ~ 15 part of solvent
1 ~ 20 part of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy
Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) be (1 ~ 15) according to volume ratio by solvent and industrial naptha: (1 ~ 20) is added in reaction kettle, is warming up to 100 ~ 140
℃；(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
Be (20 ~ 39): (10 ~ 20): (15 ~ 25): (5 ~ 25): (1 ~ 5) according to volume ratio: (1 ~ 8) is uniformly mixed, then it is gradually added drop-wise to
In reaction kettle, time for adding is 3 ~ 5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl mistake
Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters
Object.
The invention has the beneficial effects that: a kind of aqueous double-component metallic paint resin dispersion liquid provided by the invention,
Each component including following volumes number: 20 ~ 39 parts of methyl methacrylate；10 ~ 20 parts of styrene；Isooctyl acrylate monomer 15 ~
25 parts；5 ~ 25 parts of hydroxyethyl methacrylate；1 ~ 5 part of acrylic acid；1 ~ 8 part of initiator；1 ~ 15 part of solvent；Industrial naptha 1 ~ 20
Part.And the aqueous double-component metallic paint resin dispersion liquid and preparation method thereof is provided, have that finished product stability is good, production cost is low
Beneficial effect.
Specific embodiment
Technical scheme is described further below.
A kind of aqueous double-component metallic paint resin dispersion liquid, each component including following volumes number:
20 ~ 39 parts of methyl methacrylate
10 ~ 20 parts of styrene
15 ~ 25 parts of Isooctyl acrylate monomer
5 ~ 25 parts of hydroxyethyl methacrylate
1 ~ 5 part of acrylic acid
1 ~ 8 part of initiator
1 ~ 15 part of solvent
1 ~ 20 part of industrial naptha
The initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene
The composition of one or more of potassium acid esters.
The solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, one in dipropylene
Kind or several compositions.
The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) be (1 ~ 15) according to volume ratio by solvent and industrial naptha: (1 ~ 20) is added in reaction kettle, is warming up to 100 ~ 140
℃；(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
Be (20 ~ 39): (10 ~ 20): (15 ~ 25): (5 ~ 25): (1 ~ 5) according to volume ratio: (1 ~ 8) is uniformly mixed, then it is gradually added drop-wise to
In reaction kettle, time for adding is 3 ~ 5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl mistake
Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters
Object.
Embodiment 1: the aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number
Point:
20 parts of methyl methacrylate
10 parts of styrene
15 parts of Isooctyl acrylate monomer
5 parts of hydroxyethyl methacrylate
1 part of acrylic acid
1 part of initiator
1 part of solvent
1 part of industrial naptha
The initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene
The composition of one or more of potassium acid esters.
The solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, one in dipropylene
Kind or several compositions.
The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is that 1:1 is added in reaction kettle according to volume ratio by solvent and industrial naptha, is warming up to 100 ~ 140 DEG C；
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
It is uniformly mixed according to volume ratio for 20:10:15:5:1:1, then it is gradually added drop-wise in reaction kettle, time for adding is 3 ~ 5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl mistake
Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters
Object.
Embodiment 2: the aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number
Point:
39 parts of methyl methacrylate
20 parts of styrene
25 parts of Isooctyl acrylate monomer
25 parts of hydroxyethyl methacrylate
5 parts of acrylic acid
8 parts of initiator
15 parts of solvent
20 parts of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy
Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is that 15:20 is added in reaction kettle according to volume ratio by solvent and industrial naptha, is warming up to 100 ~ 140 DEG C；
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
It being uniformly mixed according to volume ratio for 39:20:25:25:5:8, then it is gradually added drop-wise in reaction kettle, time for adding is 3 ~
5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl mistake
Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters
Object.
Embodiment 3: the aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number
Point:
29.5 parts of methyl methacrylate
15 parts of styrene
20 parts of Isooctyl acrylate monomer
15 parts of hydroxyethyl methacrylate
3 parts of acrylic acid
4.5 parts of initiator
8 parts of solvent
10.5 parts of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy
Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is that 10.5:10.5 is added in reaction kettle according to volume ratio by solvent and industrial naptha, is warming up to 100 ~ 140 DEG C；
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
It being uniformly mixed according to volume ratio for 29.5:15:20:15:3:4.5, then it is gradually added drop-wise in reaction kettle, time for adding is 3 ~
5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
One or more of composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl mistake
Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters
Object.
The present invention is not limited to the above embodiment the specific technical solution, and in addition to the implementation, the present invention may be used also
To there is other embodiments.For those skilled in the art, all within the spirits and principles of the present invention, made
The technical solution of the formation such as what modification, equivalent replacement, improvement, should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of aqueous double-component metallic paint resin dispersion liquid, which is characterized in that each component including following volumes number:
20 ~ 39 parts of methyl methacrylate；
10 ~ 20 parts of styrene；
15 ~ 25 parts of Isooctyl acrylate monomer；
5 ~ 25 parts of hydroxyethyl methacrylate；
1 ~ 5 part of acrylic acid；
1 ~ 8 part of initiator；
1 ~ 15 part of solvent；
1 ~ 20 part of industrial naptha.
2. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the initiator
For one of special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters or
Several compositions.
3. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the solvent is
The composition of one or more of Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene.
4. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the industrial naptha
Boiling range be 120 DEG C ~ 200 DEG C.
5. the preparation method of aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that including
Following steps:
(1) be (1 ~ 15) according to volume ratio by solvent and industrial naptha: (1 ~ 20) is added in reaction kettle, is warming up to 100 ~ 140
℃；
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed
Be (20 ~ 39): (10 ~ 20): (15 ~ 25): (5 ~ 25): (1 ~ 5) according to volume ratio: (1 ~ 8) is uniformly mixed, then it is gradually added drop-wise to
In reaction kettle, time for adding is 3 ~ 5h；
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C；
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
6. the preparation method of aqueous double-component metallic paint resin dispersion liquid according to claim 5, which is characterized in that institute
The solvent stated is one or more of Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene
Composition；The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C；The initiator is special hexyl peroxidating trimethylace tonitric
The composition of one or more of ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2018107228040 | 2018-07-04 | ||
| CN201810722804.0A CN108795207A (en) | 2018-07-04 | 2018-07-04 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109337488A true CN109337488A (en) | 2019-02-15 |
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| CN201810722804.0A Pending CN108795207A (en) | 2018-07-04 | 2018-07-04 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
| CN201811564837.3A Pending CN109337488A (en) | 2018-07-04 | 2018-12-20 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
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| CN201810722804.0A Pending CN108795207A (en) | 2018-07-04 | 2018-07-04 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970618A (en) * | 2006-11-28 | 2007-05-30 | 中国化工建设总公司常州涂料化工研究院 | Acrylic acid series non-aqueous dispersoid |
| CN105713133A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid |
| CN105713132A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | High-hardness water-borne wood paint and preparation method thereof |
| CN106832109A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
| CN106893041A (en) * | 2015-10-19 | 2017-06-27 | 南亚塑胶工业股份有限公司 | Method for preparing solvent-free aqueous polyurethane dispersion |
-
2018
- 2018-07-04 CN CN201810722804.0A patent/CN108795207A/en active Pending
- 2018-12-20 CN CN201811564837.3A patent/CN109337488A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970618A (en) * | 2006-11-28 | 2007-05-30 | 中国化工建设总公司常州涂料化工研究院 | Acrylic acid series non-aqueous dispersoid |
| CN106893041A (en) * | 2015-10-19 | 2017-06-27 | 南亚塑胶工业股份有限公司 | Method for preparing solvent-free aqueous polyurethane dispersion |
| CN105713133A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid |
| CN105713132A (en) * | 2016-02-29 | 2016-06-29 | 苏州凯康化工科技有限公司 | High-hardness water-borne wood paint and preparation method thereof |
| CN106832109A (en) * | 2017-02-15 | 2017-06-13 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
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|---|---|
| CN108795207A (en) | 2018-11-13 |
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Application publication date: 20190215 |