CN108795207A - A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof - Google Patents

A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof Download PDF

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Publication number
CN108795207A
CN108795207A CN201810722804.0A CN201810722804A CN108795207A CN 108795207 A CN108795207 A CN 108795207A CN 201810722804 A CN201810722804 A CN 201810722804A CN 108795207 A CN108795207 A CN 108795207A
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CN
China
Prior art keywords
resin dispersion
metallic paint
dispersion liquid
parts
propylene glycol
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Pending
Application number
CN201810722804.0A
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Chinese (zh)
Inventor
费元明
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SUZHOU KAIKANG CHEMICAL TECHNOLOGY Co Ltd
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SUZHOU KAIKANG CHEMICAL TECHNOLOGY Co Ltd
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Priority to CN201810722804.0A priority Critical patent/CN108795207A/en
Publication of CN108795207A publication Critical patent/CN108795207A/en
Priority to CN201811564837.3A priority patent/CN109337488A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • C09D133/066Copolymers with monomers not covered by C09D133/06 containing -OH groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of aqueous double-component metallic paint resin dispersion liquids, include each component of following volumes number:20 ~ 39 parts of methyl methacrylate;10 ~ 20 parts of styrene;15 ~ 25 parts of Isooctyl acrylate monomer;5 ~ 25 parts of hydroxyethyl methacrylate;1 ~ 5 part of acrylic acid;1 ~ 8 part of initiator;1 ~ 15 part of solvent;1 ~ 20 part of industrial naptha.And the aqueous double-component metallic paint resin dispersion liquid and preparation method thereof is provided, there is the advantageous effect that finished product stability is good, production cost is low.

Description

A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof
Technical field
The invention belongs to water paint technical fields, and in particular to a kind of aqueous dual-component metallic paint resin dispersion liquid and its Preparation method.
Background technology
Metallic paint is called metal flash paint, added with fine metal powder in its paint base(Such as aluminium powder, copper powder), After light is mapped on metal powder, and it is reflected through air film.Therefore, it appears that as metal is glittering. This metal flash paint gives a kind of pleasant, brisk, novel feeling of people, changes the shapes and sizes of metal powder, so that it may with Control the shining of metallic coating film;In the outside of metallic paint, usually also protected added with one layer of varnish.Metallic paint is general There is aqueous and two kinds of solvent type, with the pressure of environmental protection policy, the continuous promotion of consumer's environmental consciousness is especially in all parts of the country to save City has put into effect VOC emission limit standard, encourages furniture enterprise to use non-solvent coating, to the development of the environmental protection coating materials such as water paint Bring opportunity.
The most important application field of metallic paint is automobile industry.The outer surface of automobile of metallic paint is coated, can not only be allowed Metal plate part surface after application seems more glittering moving, and under a different angle, due to the refraction of light, can allow vehicle Color, even profile can be all varied from.Allow vehicle appearance and modeling to seem more rich, more interesting, this be why " metallic paint " More and more universal one of the reason of meeting.
Although the water paint feature of environmental protection is preferable, metal powder is unstable in water and air, and chemical reaction often occurs and becomes Matter, therefore its surface needs to carry out specially treated, cause it is expensive for the metal powder in water paint, using being restricted, Current metallic paint is mainly based on solvent type.
Therefore, there is an urgent need for new technologies to improve the deficiencies in the prior art.
Invention content
Goal of the invention:The purpose of the present invention is:It is good, raw to provide a kind of finished product stability for the shortcomings that overcoming above-mentioned technology Produce aqueous double-component metallic paint resin dispersion liquid and preparation method thereof at low cost.
Technical solution:A kind of aqueous double-component metallic paint resin dispersion liquid, includes each component of following volumes number:
20 ~ 39 parts of methyl methacrylate
10 ~ 20 parts of styrene
15 ~ 25 parts of Isooctyl acrylate monomer
5 ~ 25 parts of hydroxyethyl methacrylate
1 ~ 5 part of acrylic acid
1 ~ 8 part of initiator
1 ~ 15 part of solvent
1 ~ 20 part of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is according to volume ratio by solvent and industrial naptha(1~15):(1~20)It is added in reaction kettle, is warming up to 100 ~ 140 ℃;(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is according to volume ratio(20~39):(10~20):(15~25):(5~25):(1~5):(1~8)It is uniformly mixed, then it is gradually added drop-wise to In reaction kettle, time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl mistake Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters Object.
The advantageous effect that the present invention is brought is:A kind of aqueous double-component metallic paint resin dispersion liquid provided by the invention, Include each component of following volumes number:20 ~ 39 parts of methyl methacrylate;10 ~ 20 parts of styrene;Isooctyl acrylate monomer 15 ~ 25 parts;5 ~ 25 parts of hydroxyethyl methacrylate;1 ~ 5 part of acrylic acid;1 ~ 8 part of initiator;1 ~ 15 part of solvent;Industrial naptha 1 ~ 20 Part.And the aqueous double-component metallic paint resin dispersion liquid and preparation method thereof is provided, have that finished product stability is good, production cost is low Advantageous effect.
Specific implementation mode
Technical scheme of the present invention is described further below.
A kind of aqueous double-component metallic paint resin dispersion liquid, includes each component of following volumes number:
20 ~ 39 parts of methyl methacrylate
10 ~ 20 parts of styrene
15 ~ 25 parts of Isooctyl acrylate monomer
5 ~ 25 parts of hydroxyethyl methacrylate
1 ~ 5 part of acrylic acid
1 ~ 8 part of initiator
1 ~ 15 part of solvent
1 ~ 20 part of industrial naptha
The initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene The composition of one or more of potassium acid esters.
The solvent is one in Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene Kind or several compositions.
The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is according to volume ratio by solvent and industrial naptha(1~15):(1~20)It is added in reaction kettle, is warming up to 100 ~ 140 ℃;(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is according to volume ratio(20~39):(10~20):(15~25):(5~25):(1~5):(1~8)It is uniformly mixed, then it is gradually added drop-wise to In reaction kettle, time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl mistake Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters Object.
Embodiment 1:The aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number Point:
20 parts of methyl methacrylate
10 parts of styrene
15 parts of Isooctyl acrylate monomer
5 parts of hydroxyethyl methacrylate
1 part of acrylic acid
1 part of initiator
1 part of solvent
1 part of industrial naptha
The initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene The composition of one or more of potassium acid esters.
The solvent is one in Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene Kind or several compositions.
The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is 1 according to volume ratio by solvent and industrial naptha:1 is added in reaction kettle, is warming up to 100 ~ 140 DEG C;
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is 20 according to volume ratio:10:15:5:1:1 is uniformly mixed, then it is gradually added drop-wise in reaction kettle, and time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl mistake Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters Object.
Embodiment 2:The aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number Point:
39 parts of methyl methacrylate
20 parts of styrene
25 parts of Isooctyl acrylate monomer
25 parts of hydroxyethyl methacrylate
5 parts of acrylic acid
8 parts of initiator
15 parts of solvent
20 parts of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is 15 according to volume ratio by solvent and industrial naptha:20 are added in reaction kettle, are warming up to 100 ~ 140 DEG C;
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is 39 according to volume ratio: 20: 25: 25: 5:8 are uniformly mixed, then it are gradually added drop-wise in reaction kettle, and time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl mistake Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters Object.
Embodiment 3:The aqueous double-component metallic paint resin dispersion liquid of the present embodiment includes each group of following volumes number Point:
29.5 parts of methyl methacrylate
15 parts of styrene
20 parts of Isooctyl acrylate monomer
15 parts of hydroxyethyl methacrylate
3 parts of acrylic acid
4.5 parts of initiator
8 parts of solvent
10.5 parts of industrial naptha
Wherein, the initiator is special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy Change the composition of one or more of benzene potassium acid esters.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition.
Wherein, the boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component metallic paint resin dispersion liquid, includes the following steps:
(1) it is 10.5 according to volume ratio by solvent and industrial naptha:10.5 are added in reaction kettle, are warming up to 100 ~ 140 DEG C;
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is 29.5 according to volume ratio:15:20:15:3:4.5 are uniformly mixed, then it are gradually added drop-wise in reaction kettle, and time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
Wherein, the solvent is Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene One or more of composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl mistake Aoxidize the combination of one or more of trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters Object.
The present invention is not limited to the above embodiment the specific technical solution, and in addition to the implementation, the present invention may be used also To there is other embodiment.For those skilled in the art, all within the spirits and principles of the present invention, appoint made by The technical solution of the formation such as what modification, equivalent replacement, improvement, should all be included in the protection scope of the present invention.

Claims (6)

1. a kind of aqueous double-component metallic paint resin dispersion liquid, which is characterized in that include each component of following volumes number:
20 ~ 39 parts of methyl methacrylate;
10 ~ 20 parts of styrene;
15 ~ 25 parts of Isooctyl acrylate monomer;
5 ~ 25 parts of hydroxyethyl methacrylate;
1 ~ 5 part of acrylic acid;
1 ~ 8 part of initiator;
1 ~ 15 part of solvent;
1 ~ 20 part of industrial naptha.
2. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the initiator For in special hexyl peroxidating trimethylace tonitric ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters one kind or Several compositions.
3. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the solvent is The composition of one or more of Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene.
4. aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that the industrial naptha Boiling range be 120 DEG C ~ 200 DEG C.
5. the preparation method of aqueous double-component metallic paint resin dispersion liquid according to claim 1, which is characterized in that including Following steps:
(1) it is according to volume ratio by solvent and industrial naptha(1~15):(1~20)It is added in reaction kettle, is warming up to 100 ~ 140 ℃;
(2) methyl methacrylate, styrene, Isooctyl acrylate monomer, hydroxyethyl methacrylate, acrylic acid, initiator are pressed It is according to volume ratio(20~39):(10~20):(15~25):(5~25):(1~5):(1~8)It is uniformly mixed, then it is gradually added drop-wise to In reaction kettle, time for adding is 3 ~ 5h;
(3) 1 ~ 2h is kept the temperature after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reaction kettle is down to 100 ~ 120 DEG C;
(4) dimethylethanolamine is added, stirring neutralizes, and adds after water makes reactant scatter, cools, make reaction kettle The temperature of middle material is down to 30 ~ 40 DEG C;
(5) it filters to get to aqueous double-component metallic paint resin dispersion liquid.
6. the preparation method of aqueous double-component metallic paint resin dispersion liquid according to claim 5, which is characterized in that institute The solvent stated is one or more of Propylene glycol n-propyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, dipropylene Composition;The boiling range of the industrial naptha is 120 DEG C ~ 200 DEG C;The initiator is special hexyl peroxidating trimethylace tonitric The composition of one or more of ester, tert-butylperoxy caprylate, tert-butylperoxy benzene potassium acid esters.
CN201810722804.0A 2018-07-04 2018-07-04 A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof Pending CN108795207A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201810722804.0A CN108795207A (en) 2018-07-04 2018-07-04 A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof
CN201811564837.3A CN109337488A (en) 2018-07-04 2018-12-20 A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810722804.0A CN108795207A (en) 2018-07-04 2018-07-04 A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof

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CN201811564837.3A Pending CN109337488A (en) 2018-07-04 2018-12-20 A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN100429271C (en) * 2006-11-28 2008-10-29 中国化工建设总公司常州涂料化工研究院 Acrylic acid series non-aqueous dispersoid
TWI577707B (en) * 2015-10-19 2017-04-11 Nanya Plastics Corp A method for producing solventless aqueous polyurethane dispersions
CN105713132A (en) * 2016-02-29 2016-06-29 苏州凯康化工科技有限公司 High-hardness water-borne wood paint and preparation method thereof
CN105713133A (en) * 2016-02-29 2016-06-29 苏州凯康化工科技有限公司 Resin dispersing liquid for water-borne wood paint and preparation method of resin dispersing liquid
CN106832109A (en) * 2017-02-15 2017-06-13 苏州凯康化工科技有限公司 A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof

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Application publication date: 20181113