CN106832109A - A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof - Google Patents
A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof Download PDFInfo
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- CN106832109A CN106832109A CN201710081006.XA CN201710081006A CN106832109A CN 106832109 A CN106832109 A CN 106832109A CN 201710081006 A CN201710081006 A CN 201710081006A CN 106832109 A CN106832109 A CN 106832109A
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- dispersion liquid
- resin dispersion
- plastic paint
- component plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous double-component plastic paint resin dispersion liquid, it is prepared by the component including following volume parts：5 ~ 25 parts of methyl methacrylate, 10 ~ 20 parts of butyl acrylate, 3 ~ 15 parts of hydroxyethyl methacrylate, 2 ~ 6 parts of acrylic acid, 2 ~ 5 parts of initiator, 1 ~ 10 part of solvent, 1 ~ 10 part of industrial naptha, described initiator are one or two peroxide initiator compositions in special peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester.The invention also discloses the preparation method and application of above-mentioned property double-component plastic paint resin dispersion liquid, the plastic paint prepared using the resin dispersion liquid has the advantages that environmental protection, hardness is high, be difficult decortication.
Description
Technical field
The invention belongs to furniture lacquer technical field, and in particular to a kind of aqueous double-component plastic paint resin dispersion liquid and its
Preparation method.
Background technology
Plastic paint application widely, including motorcycle, electric motor car, the helmet, TV, computer, air-conditioning, refrigerator, water dispenser
Deng working of plastics etc..Plastics paint kind mainly has polyurethane paint, acrylic paint, vinylite alkene and epoxy resin coating, by
It is the toxic organic solvents such as banana oil, toluene, dimethylbenzene in these solvents for painting, toxic organic solvents understand the body of harmful to human
, while it is inflammable and explosive, there is hidden fire-fighting danger in body health.And water paint is started with itself from material, solve paint it is inflammable and explosive,
Healthy, contaminated air environment the shortcoming of injury, therefore aqueous plastic paint substitution traditional solvent-borne paint, have been irreversible
Trend.
With the development of modern industry, plastics have substituted traditional material such as timber, steel as new material extensively
Iron is used for all trades and professions, such as automobile, household electrical appliances, building and other commercial uses.In order to attractive in appearance and durable, often need to be entered with coating
Row application.The coating that early stage is used for plastics coating is solvent reducible coatings i.e. containing a large amount of organic solvents, for plastics, particularly pole
The coating of property plastic basis material such as carbonic ester, polyamide, ABS, HIPS etc..It is well known that the shortcoming that solvent reducible coatings brings is wave
The Heavy environmental pollution that the expense energy, a large amount of organic solvents of resource and volatilization bring, meanwhile, solvent reducible coatings also exist transport,
The shortcomings of storing and use dangerous.
With the pressure of environmental protection policy, the continuous lifting of consumer's environmental consciousness, provinces and cities especially in all parts of the country have put into effect VOC
Discharge limit standard, encourages furniture enterprise to use non-solvent coating, and the development to environmental protection coating materials such as water paints brings opportunity.
It is the side for painting class future development although still in occupation of the larger market share, water paint is pollution-free industry to traditional coating
To the water paint leading enterprise in domestic native country emerges.The development of water paint and the shared market share are increasing year by year
It has been undisputable fact, and has had the trend of speed-raising.Some enterprises have appreciated that the wide market potential of water paint, one after another
Research and develop, march, expanding water paint market.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of aqueous double-component plastic paint resin dispersion liquid.
The technical problem also to be solved of the invention is to provide the preparation of above-mentioned aqueous double-component plastic paint resin dispersion liquid
Method.
The technical problem finally to be solved of the invention is to provide aqueous double-component plastic paint resin dispersion liquid and is preparing water
Application in property plastic paint.
A kind of aqueous double-component plastic paint resin dispersion liquid, it is prepared by the component including following volume parts
's：
5 ~ 25 parts of methyl methacrylate
10 ~ 20 parts of butyl acrylate
3 ~ 15 parts of hydroxyethyl methacrylate
2 ~ 6 parts of acrylic acid
2 ~ 5 parts of initiator
1 ~ 10 part of solvent
1 ~ 10 part of industrial naptha
Described initiator is one or two peroxides in special peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester
Compound initiator composition.
Wherein, described solvent mixing for one or more in propandiol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether
Compound.
The boiling range of wherein described industrial naptha is 110 DEG C ~ 180 DEG C.
The preparation method of above-mentioned aqueous double-component plastic paint resin dispersion liquid, comprises the following steps：
(1) it is according to volume ratio by solvent and industrial naptha（1~10）：（1~10）Add in reactor, be warming up to 100 ~ 140
℃；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, initiator according to volume ratio
For（5~25）：（10~20）：（3~15）：（2~6）：（2~5）It is well mixed, then it is progressively added drop-wise in reactor, time for adding
It is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Wherein, described solvent is propane diols ether solvent in propandiol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether
The mixture of one or more；The boiling range of the industrial naptha is 110 DEG C ~ 180 DEG C；Described initiator is special benzoyl peroxide
One or two mixture in t-butyl formate, peroxidating trimethylacetic acid tertiary butyl ester.
The aqueous double-component plastic paint that the preparation method of above-mentioned aqueous double-component plastic paint resin dispersion liquid is prepared
Use resin dispersion liquid.
Application of the above-mentioned aqueous double-component plastic paint resin dispersion liquid in aqueous double-component plastic paint is prepared.
Beneficial effect：
The invention discloses the preparation method of aqueous double-component plastic paint resin dispersion liquid, prepared using the resin dispersion liquid
Plastic paint has the advantages that environmental protection, hardness is high, be difficult decortication.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
Apply the content described by example and be merely to illustrate the present invention, without should also without limitation on sheet described in detail in claims
Invention.
Embodiment 1：
The preparation method of aqueous double-component plastic paint resin dispersion liquid, comprises the following steps：
(1) by methyl methacrylate and industrial naptha（Boiling range is 120 DEG C ~ 160 DEG C）It is 1 according to volume ratio：1 adds reaction
In kettle, 100 ~ 140 DEG C are warming up to；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, special perbenzoic acid uncle
Butyl ester is 5 according to volume ratio：10：5：2：3 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Embodiment 2：
The preparation method of aqueous double-component plastic paint resin dispersion liquid, comprises the following steps：
(1) by propylene glycol monomethyl ether and industrial naptha（Boiling range is 120 DEG C ~ 180 DEG C）It is 5 according to volume ratio：In 3 addition reactors,
It is warming up to 100 ~ 140 DEG C；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, the tertiary fourth of peroxidating trimethylacetic acid
Base ester is 10 according to volume ratio：15：5：3：5 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Wherein, described solvent is propane diols ether solvent in propandiol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether
The mixture of one or more；The boiling range of the industrial naptha is 110 DEG C ~ 180 DEG C；Described initiator is special benzoyl peroxide
One or two mixture in t-butyl formate, peroxidating trimethylacetic acid tertiary butyl ester.
Embodiment 3：
The preparation method of aqueous double-component plastic paint resin dispersion liquid, comprises the following steps：
(1) by dipropylene glycol methyl ether and industrial naptha（Boiling range is 110 DEG C ~ 180 DEG C）It is 10 according to volume ratio：10 add reaction
In kettle, 100 ~ 140 DEG C are warming up to；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, the tertiary fourth of peroxidating trimethylacetic acid
Base ester is 25 according to volume ratio：20：8：5：3 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Embodiment 4：
The preparation method of aqueous double-component plastic paint resin dispersion liquid, comprises the following steps：
(1) by propylene glycol monomethyl ether and industrial naptha（Boiling range is 160 DEG C ~ 180 DEG C）It is 6 according to volume ratio：In 4 addition reactors,
It is warming up to 100 ~ 140 DEG C；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, special perbenzoic acid uncle
Butyl ester is 20 according to volume ratio：12：5：4：3 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Claims (7)
1. a kind of aqueous double-component plastic paint resin dispersion liquid, it is characterised in that it is by the group including following volume parts
What part prepared：
5 ~ 25 parts of methyl methacrylate
10 ~ 20 parts of butyl acrylate
3 ~ 15 parts of hydroxyethyl methacrylate
2 ~ 6 parts of acrylic acid
2 ~ 5 parts of initiator
1 ~ 10 part of solvent
1 ~ 10 part of industrial naptha；
Described initiator is one or two peroxides in special peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester
Compound initiator composition.
2. aqueous double-component plastic paint resin dispersion liquid according to claim 1, it is characterised in that described solvent is
The mixture of one or more in propandiol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether.
3. aqueous double-component plastic paint resin dispersion liquid according to claim 1, it is characterised in that the industrial naptha
Boiling range be 110 DEG C ~ 180 DEG C.
4. the preparation method of aqueous double-component plastic paint resin dispersion liquid described in claim 1 ~ 3, it is characterised in that including such as
Lower step：
(1) it is according to volume ratio by solvent and industrial naptha（1~10）：（1~10）Add in reactor, be warming up to 100 ~ 140
℃；
(2) by methyl methacrylate, butyl acrylate, hydroxyethyl methacrylate, acrylic acid, initiator according to volume ratio
For（5~25）：（10~20）：（3~15）：（2~6）：（2~5）It is well mixed, then it is progressively added drop-wise in reactor, time for adding
It is 3 ~ 5h；
(3) 1 ~ 2h is incubated after completion of dropwise addition at 120 ~ 130 DEG C, the temperature in reactor is down to 80 ~ 100 DEG C；
(4) triethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make thing in reactor
The temperature of material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
5. the preparation method of aqueous double-component plastic paint resin dispersion liquid according to claim 4, it is characterised in that institute
The solvent stated is that propane diols ether solvent is one or more in propandiol butyl ether, propylene glycol monomethyl ether, dipropylene glycol methyl ether
Mixture；The boiling range of the industrial naptha is 110 DEG C ~ 180 DEG C；Described initiator is special peroxidized t-butyl perbenzoate, mistake
One or two mixture in oxidation trimethylacetic acid tertiary butyl ester.
6. what the preparation method of the aqueous double-component plastic paint resin dispersion liquid described in claim 4,5 was prepared is aqueous double
Component plastic paint resin dispersion liquid.
7. the aqueous double-component plastic paint resin dispersion liquid described in claim 6 in aqueous double-component plastic paint is prepared should
With.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710081006.XA CN106832109A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710081006.XA CN106832109A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
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| CN106832109A true CN106832109A (en) | 2017-06-13 |
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| CN201710081006.XA Pending CN106832109A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component plastic paint resin dispersion liquid and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337488A (en) * | 2018-07-04 | 2019-02-15 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
| CN110229292A (en) * | 2019-06-28 | 2019-09-13 | 苏州凯康化工科技有限公司 | The preparation method of high rigidity aqueous woodware paint resin dispersion liquid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6476108B1 (en) * | 1999-04-22 | 2002-11-05 | Jsr Corporation | Aqueous coating composition |
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN106010020A (en) * | 2016-08-03 | 2016-10-12 | 苏州匠品材料科技有限公司 | Two-component aqueous acrylate-epoxy resin hybrid coating |
-
2017
- 2017-02-15 CN CN201710081006.XA patent/CN106832109A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6476108B1 (en) * | 1999-04-22 | 2002-11-05 | Jsr Corporation | Aqueous coating composition |
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN106010020A (en) * | 2016-08-03 | 2016-10-12 | 苏州匠品材料科技有限公司 | Two-component aqueous acrylate-epoxy resin hybrid coating |
Non-Patent Citations (1)
| Title |
|---|
| 李远才 等: "《铸造造型材料实用手册》", 30 June 2015, 机械工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337488A (en) * | 2018-07-04 | 2019-02-15 | 苏州凯康化工科技有限公司 | A kind of aqueous double-component metallic paint resin dispersion liquid and preparation method thereof |
| CN110229292A (en) * | 2019-06-28 | 2019-09-13 | 苏州凯康化工科技有限公司 | The preparation method of high rigidity aqueous woodware paint resin dispersion liquid |
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Application publication date: 20170613 |
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