CN107298739A - A kind of anticorrosive paint water-base resin and preparation method thereof - Google Patents
A kind of anticorrosive paint water-base resin and preparation method thereof Download PDFInfo
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- CN107298739A CN107298739A CN201710403895.7A CN201710403895A CN107298739A CN 107298739 A CN107298739 A CN 107298739A CN 201710403895 A CN201710403895 A CN 201710403895A CN 107298739 A CN107298739 A CN 107298739A
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- base resin
- anticorrosive paint
- acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
Abstract
The invention provides a kind of anticorrosive paint water-base resin, calculate, be made up of 50 80 parts of chlorinated polyether resin, 50 80 parts of active phosphate compound, 50 80 parts of acrylate monomer, 100 200 parts of solvents, 5 30 parts of modified crosslinking monomer, 0.05 0.1 parts of polymerization inhibitor, 100 300 parts of deionized waters by weight.Present invention also offers the preparation method of above-mentioned water-base resin, active phosphate compound, chlorinated polyether resin, polymerization inhibitor and solvent are added in a reaction vessel, heat and stir, heat up when being completely dissolved, acrylate monomer, modified crosslinking monomer mixture solution are added, after addition is finished, temperature reaction, cooling, regulation pH value are 7 ~ 8 after reaction terminates, and add deionized water and quickly stir, produce anticorrosive paint water-base resin.The features such as present invention has good anti-corrosive properties, good weatherability；It can be widely applied to the anti-corrosion protection of the technical fields such as chemical industry, extra large construction equipment, naval vessel.
Description
Technical field
The invention belongs to polymeric material field, it is related to a kind of coating, specifically a kind of anticorrosive paint is with aqueous tree
Fat and preparation method thereof.
Background technology
In recent years, as Chinese national economy is fast-developing, the fields such as automobile, petrochemical industry, ship, pipeline, aviation have been driven
Fast development.It is badly in need of the protection that High Performance Corrosion Protective Coatings are corroded to it.Conventional solvent-borne type anticorrosive paint, such as chlorination rubber
The material that glue, epoxy coating, acrylate paint, polyurethane coating etc. can be very good to use above field carries out anticorrosion
Protection.But with attention both at home and abroad in environmental protection, the development of anticorrosive coating with it is pollution-free, nuisanceless, save the energy,
Economical and efficient is principle, develops new environmentally friendly anticorrosive paint system extremely urgent.It is aqueous to apply compared with solvent based coating
Material has many advantages, such as that such as low VOC contents, few smell is nonflammable, using safety, can wash by water.At present
With water-base resin it is mainly water-and acrylate, aqueous epoxy resins, waterborne polyurethane resin, aqueous fluorine in water-based anticorrosive paint
The principal items such as carbon resin, these resins have that antiseptic effect is not good, water resistance is not good, adhesive force not, single tree
Fat is difficult to the need for meeting long-acting weather-proof anticorrosive paint.
Based on background above, it is necessary to develop a kind of environmental protection, performance close to solvent type anticorrosive paint water-base resin and its
Preparation method.
The content of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of anticorrosive paint water-base resin and its system
Preparation Method, described this anticorrosive paint water-base resin and preparation method thereof will solve water-based anticorrosive paint of the prior art
With the technical problem that water-base resin antiseptic effect is not good, water resistance is not good, adhesive force is not good.
The invention provides a kind of anticorrosive paint water-base resin, calculate by weight, its raw material composition and content are such as
Under：
50-80 parts of chlorinated polyether resin；
50-80 parts of active phosphate compound；
50-80 parts of acrylate monomer；
100-200 parts of solvent；
5-30 parts of modified crosslinking monomer；
0.05-0.1 parts of polymerization inhibitor；
100-300 parts of deionized water；
Wherein：Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, acrylic acid
Isobutyl ester, tert-butyl acrylate, acrylic acid-2-ethyl caproite, n-octyl, decyl acrylate, acrylic acid -2- hydroxyl second
In ester, 2-hydroxypropyl acrylate, acrylic acid -2- ethoxy ethyl esters, cyclohexyl acrylate or isobornyl acrylate monomer
Any one or two or more combinations；
Described modified crosslinking monomer is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three（2- ethoxys）Isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris third
Olefin(e) acid ester, third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate,
Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane tris acrylic acid
Ester, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester
Any one or two kinds in mono acrylic ester, epoxy silicone monomer, silicone acrylate or vinyl ethers monomer with
On combination；
Described solvent be ethylene glycol diethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, propylene glycol monomethyl ether, ethanol, butanol,
In butyl ether, isopropyl ether or methyl tertiary butyl ether(MTBE), dioxane or ethyleneglycol monophenylether any one or it is two or more
Combination；
Described polymerization inhibitor is hydroquinones, 2- TBHQs, 2,5- di-tert-butyl hydroquinones, 1,4-benzoquinone, methyl
Any one in quinhydrones or MEHQ or two or more combinations.
Further, described chlorinated polyether resin is domestic MP45 resins.
Further, described active phosphate compound is one in Sipomer PAM-100, SipomerPAM-200
Kind or two kinds of combination.
Further, described solvent is one kind or two in propylene glycol monomethyl ether, butyl glycol ether, acetone, butanone, ethanol
Plant the combination of the above.
Present invention also offers a kind of preparation method of above-mentioned anticorrosive paint water-base resin, comprise the following steps：Press
Each reaction raw materials are weighed according to parts by weight, active phosphate compound, chlorinated polyether resin, polymerization inhibitor and solvent are added to one instead
Answer in container, heat and stir, be warming up to 100-110 DEG C and when active phosphate compound is completely dissolved, add acrylate
Monomer, modified crosslinking monomer mixture solution, after addition is finished, are warming up to 115-121 DEG C of reaction, the lower h of constant temperature 3 ~ 5 of stirring stops
Only heat, treat that temperature drops to 40 ~ 50 DEG C, regulation pH value is 7 ~ 8, adds deionized water and quickly stirs, the h of constant temperature 0.5 ~ 2, i.e.,
Obtain anticorrosive paint water-base resin.
The anticorrosive paint water-base resin of the present invention, outward appearance is the white emulsion of blueing, and environmental protection, storage at room temperature stability is big
In half a year.The NDJ-1 rotation viscometers provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai, by GB/T2794-2013,
《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, detected under conditions of 25 DEG C of room temperature, its viscosity is 500-
3000mPa.s。
The anticorrosive paint water-base resin of the present invention, by acrylate, the chlorine of active phosphate compound graft modification
Ether resin simultaneously turns into water-base resin through Water-borne modification effect, the water-base resin is had good film forming and Corrosion Protection,
Water-base resin is completed a certain degree of crosslinking using crosslinking agent, further improve intensity, decay resistance, while by
The features such as prepared aqueous macromolecular has non-volatile, nontoxic, therefore obtained water-base resin is nontoxic to environment.
The present invention is compared with prior art, and its technological progress is significant.The anticorrosive paint of the present invention has with water-base resin
The features such as having good anti-corrosive properties, good weatherability；The features such as anticorrosive paint prepared therefrom has good higher anti-corrosive properties, weatherability,
It can be widely applied to the anti-corrosion protection of the technical fields such as chemical industry, extra large construction equipment, naval vessel.And reaction condition is simple, reaction side
Method is ripe, and preparation technology is simple, suitable for large-scale production.
Brief description of the drawings
Fig. 1 is that the anticorrosive paint of the gained of embodiment 1 carries out infrared spectrum analysis institute with water-base resin by infrared chromatograph
The infrared spectrogram obtained.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of anticorrosive paint water-base resin, is calculated by weight, and its raw material composition and content are as follows：
50 parts of chlorinated polyether resin；
50 parts of active phosphate compound；
50 parts of acrylate monomer；
100 parts of solvent；
5 parts of modified crosslinking monomer；
0.05 part of polymerization inhibitor；
100 parts of deionized water；
Wherein：Described chlorinated polyether resin is domestic MP45 resins；
Described acrylate monomer is acrylic acid, methyl acrylate, n-butyl acrylate, 2-Hydroxy ethyl acrylate by matter
Amount is than being 1:10:10:The mix monomer of 3 compositions；
Described active phosphate compound is Sipomer PAM-100；
Described modified crosslinking monomer is selected from diethylene glycol diacrylate, ethoxylated bisphenol A dimethylacrylates and presses quality
Than 1:The mixture of 1 composition；
Described solvent is ethylene glycol diethyl ether, butyl glycol ether, butanol in mass ratio 10:10:The mixture of 3 compositions；
Described polymerization inhibitor is hydroquinones；
In the present embodiment, a kind of preparation method of anticorrosive paint water-base resin specifically includes following steps：
According to formula, 50 parts of chlorinated polyether resins, 50 parts of active phosphate compounds, 0.05 part of polymerization inhibitor and 100 parts of solvents are added
In 500ml flask with four necks,round bottom, heat and stir, 100 DEG C or so are warming up to when chlorinated polyether resin is completely dissolved, with certain speed
After the mixed solution that 50 parts of crylic acid ester mixture monomers of dropwise addition, 5 parts of modified crosslinking monomers are constituted, completion of dropping, 115 DEG C are warming up to
Left and right is reacted, the lower h of constant temperature 3 of stirring, stops heating, treats that temperature drops to 40 DEG C, regulation pH value is 7, adds 100 parts of deionized waters
And quickly stir, the h of constant temperature 0.5, vacuum distillation removes solvent, produces anticorrosive paint water-base resin.
The anticorrosive paint water-base resin of above-mentioned gained passes through infrared chromatograph（The type of Nicolet companies of the U.S. 380）Enter
Row infrared spectrum analysis, the infrared spectrogram of gained is as shown in figure 1, from figure 1 it appears that 3392.33cm-1It is O-H keys
Stretching vibration absworption peak；
2954.84 cm-1It is for chlorinated polyether resin-CH2The stretching vibration absworption peak of middle c h bond；
In 1726.74 cm-1It is significantly C=O characteristic peaks, this is due to the acrylic acid for the generation being grafted on chlorine ether strand
Ester and phosphate joint contribution；
1068.07cm-1Locate the stretching vibration absworption peak of the ether-oxygen bond C-O for chlorinated polyether resin；
1144.67cm-1Locate the stretching vibration absworption peak of the C-O for acrylate, this explanation acrylic monomer oneself through successfully connecing
Branch is on chlorinated polyether resin；
Indicated above, the anticorrosive paint obtained by the present invention is successfully prepared with water-base resin；
Anticorrosive paint water-base resin obtained by above-described embodiment, the NDJ- provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai
1 rotation viscometer, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of room temperature
Under conditions of detected, its viscosity be 500mPa.s.
Further, a kind of anticorrosive paint water-base resin of the present embodiment, through being solidified into water-based isocyanate curing agent
Film, acid resistance and alkali resistance test, acid resistance have been carried out to the film（96h）Detected, applied according to GB/T 1763-1989
Film outward appearance is unchanged；Alkali resistance（96h）Detected that appearance of film is unchanged according to GB/T 1763-1989.And to coating
Ageing properties are evaluated, and are carried out by GB/ T9277, coating is after 400 h artificial accelerated aging tests, and light-protection rate is more than
83 %, coating is non-foaming, do not peel off, flawless.
With explanation higher after water-base resin film, it is that a kind of long-acting effect is weather-proof to the anticorrosive paint of the gained of above example 2
Type anticorrosive paint resin, antiseptic effect is good.
Embodiment 2
A kind of anticorrosive paint water-base resin, is calculated by weight, and its raw material composition and content are as follows：
80 parts of chlorinated polyether resin；
80 parts of active phosphate compound；
80 parts of acrylate monomer；
200 parts of solvent；
30 parts of modified crosslinking monomer；
0.1 part of polymerization inhibitor；
300 parts of deionized water；
Wherein：Described chlorinated polyether resin is domestic MP45 resins；
Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, acrylic acid -2- hydroxyls
Base propyl ester in mass ratio 1:8：10：5：The mix monomer of 5 compositions；
Described modified crosslinking monomer is selected from diethylene glycol diacrylate, tetramethylol methane tetraacrylate, isobomyl acrylate
Ester in mass ratio 1:2:The mixture of 1 composition；
Described active phosphate compound is Sipomer PAM-200；
Described solvent is diethylene glycol dimethyl ether, propylene glycol monomethyl ether, butanol in mass ratio 5:5:The mixture of 2 compositions；
Described polymerization inhibitor is MEHQ.
In the present embodiment, a kind of preparation method of anticorrosive paint water-base resin specifically includes following steps：
According to formula, 80 parts of chlorinated polyether resins, 80 parts of active phosphate compounds, 0.1 part of polymerization inhibitor and 200 parts of solvents are added
In 500ml flask with four necks,round bottom, heat and stir, 110 DEG C or so are warming up to when chlorinated polyether resin is completely dissolved, with certain speed
After the mixed solution that 80 parts of crylic acid ester mixture monomers of dropwise addition, 30 parts of modified crosslinking monomers are constituted, completion of dropping, 121 are warming up to
DEG C or so reaction, the lower constant temperature 5h of stirring stops heating, treats that temperature drops to 50 DEG C, regulation pH value is 8, adds 300 parts of deionized waters
And quickly stir, the h of constant temperature 3, vacuum distillation removes solvent, produces anticorrosive paint water-base resin.
Anticorrosive paint water-base resin obtained by above-described embodiment, the NDJ- provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai
1 rotation viscometer, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, in 25 DEG C of room temperature
Under conditions of detected, its viscosity be 3000mPa.s.
Further, a kind of anticorrosive paint water-base resin of the present embodiment, it is right through solidifying with water-based isocyanate curing agent
Film carries out acid resistance and alkali resistance test, acid resistance（96h）Detected that appearance of film is without change according to GB/T 1763-1989
Change；Alkali resistance（96h）Detected that appearance of film is unchanged according to GB/T 1763-1989.GB/ is pressed in the aging evaluation of coating
T9277 is carried out, and coating is after 400 h artificial accelerated aging tests, and light-protection rate is more than 75 %, and coating is non-foaming, do not peel off, nothing
Crackle.
With explanation higher after water-base resin film, it is that a kind of long-acting effect is weather-proof to the anticorrosive paint of the gained of above example 2
Type anticorrosive paint resin, antiseptic effect is good.
In summary, anticorrosive paint of the invention is used with water-base resin by containing fluorine structure, acrylic ester grafted
Modified chlorinated polyether resin reacts what is prepared through Water-borne modification, and water-base resin is completed a certain degree of friendship by using crosslinking agent
Connection, with preferable Long-effect corrosion-resistant performance, simultaneously because the features such as prepared aqueous macromolecular has non-volatile, nontoxic,
Therefore obtained water-base resin is nontoxic to environment, and the water-base resin is a kind of long-acting weather resistant anticorrosion water-soluble resin.
Above said content is only the basic explanation under present inventive concept, and according to appointing that technical scheme is made
What equivalent transformation, all should belong to protection scope of the present invention.
Claims (6)
1. a kind of anticorrosive paint water-base resin, it is characterised in that calculate by weight, its raw material composition and content are as follows：
50-80 parts of chlorinated polyether resin；
50-80 parts of active phosphate compound；
50-80 parts of acrylate monomer；
100-200 parts of solvent；
5-30 parts of modified crosslinking monomer；
0.05-0.1 parts of polymerization inhibitor；
100-300 parts of deionized water；
Wherein：Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, acrylic acid
Isobutyl ester, tert-butyl acrylate, acrylic acid-2-ethyl caproite, n-octyl, decyl acrylate, acrylic acid -2- hydroxyl second
In ester, 2-hydroxypropyl acrylate, acrylic acid -2- ethoxy ethyl esters, cyclohexyl acrylate or isobornyl acrylate monomer
Any one or two or more combinations；
Described modified crosslinking monomer is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third
Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid
Ester, three（2- ethoxys）Isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris third
Olefin(e) acid ester, third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate,
Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane tris acrylic acid
Ester, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester
Any one or two kinds in mono acrylic ester, epoxy silicone monomer, silicone acrylate or vinyl ethers monomer with
On combination；
Described solvent be ethylene glycol diethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, propylene glycol monomethyl ether, ethanol, butanol,
In butyl ether, isopropyl ether or methyl tertiary butyl ether(MTBE), dioxane or ethyleneglycol monophenylether any one or it is two or more
Combination；
Described polymerization inhibitor is hydroquinones, 2- TBHQs, 2,5- di-tert-butyl hydroquinones, 1,4-benzoquinone, methyl
Any one in quinhydrones or MEHQ or two or more combinations.
2. a kind of anticorrosive paint water-base resin according to claim 1, it is characterised in that described chlorinated polyether resin is state
Produce MP45 resins.
3. a kind of anticorrosive paint water-base resin according to claim 1, it is characterised in that described active phosphate
Compound is one or both of Sipomer PAM-100, SipomerPAM-200 combination.
4. a kind of anticorrosive paint water-base resin according to claim 1, it is characterised in that the viscosity at its 25 DEG C is
500-3000mPa.s, outward appearance is the white emulsion of blueing, and storage at room temperature stability is more than half a year.
5. a kind of anticorrosive paint water-base resin according to claim 1, it is characterised in that described solvent is propane diols
Combination more than one or both of methyl ether, butyl glycol ether, acetone, butanone, ethanol.
6. the preparation method of a kind of anticorrosive paint water-base resin described in claim 1, it is characterised in that comprise the following steps：
Each reaction raw materials are weighed according to parts by weight, active phosphate compound, chlorinated polyether resin, polymerization inhibitor and solvent are added to one
In reaction vessel, heat and stir, be warming up to 100-110 DEG C and when active phosphate compound is completely dissolved, add acrylic acid
Ester monomer, modified crosslinking monomer mixture solution, after addition is finished, are warming up to 115-121 DEG C of reaction, the h of constant temperature 3 ~ 5 under stirring,
Stop heating, treat that temperature drops to 40 ~ 50 DEG C, regulation pH value is 7 ~ 8, adds 100-300 parts of deionized waters and quickly stirs, constant temperature
0.5 ~ 2 h, produces anticorrosive paint water-base resin.
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| CN201710403895.7A CN107298739A (en) | 2017-06-01 | 2017-06-01 | A kind of anticorrosive paint water-base resin and preparation method thereof |
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| CN112662260A (en) * | 2020-12-29 | 2021-04-16 | 山西中涂交通科技股份有限公司 | Flame-retardant anti-skid road surface coating for tunnel |
| CN116716006A (en) * | 2023-06-19 | 2023-09-08 | 浙江理工大学 | Water-based hybrid acrylic acid flame-retardant resin composition and preparation method thereof |
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| CN101250365A (en) * | 2008-03-28 | 2008-08-27 | 江苏荣昌化工有限公司 | Method for manufacturing acrylic ester emulsion containing phosphate group for antiseptic paint |
| CN106519920A (en) * | 2016-10-26 | 2017-03-22 | 中国人民解放军空军勤务学院 | Metal water-soluble anticorrosive coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112662260A (en) * | 2020-12-29 | 2021-04-16 | 山西中涂交通科技股份有限公司 | Flame-retardant anti-skid road surface coating for tunnel |
| CN116716006A (en) * | 2023-06-19 | 2023-09-08 | 浙江理工大学 | Water-based hybrid acrylic acid flame-retardant resin composition and preparation method thereof |
| CN116716006B (en) * | 2023-06-19 | 2024-04-19 | 浙江理工大学 | Water-based hybrid acrylic acid flame-retardant resin composition and preparation method thereof |
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