CN107267034A - A kind of long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof - Google Patents

A kind of long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof Download PDF

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Publication number
CN107267034A
CN107267034A CN201710456801.2A CN201710456801A CN107267034A CN 107267034 A CN107267034 A CN 107267034A CN 201710456801 A CN201710456801 A CN 201710456801A CN 107267034 A CN107267034 A CN 107267034A
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parts
ester
resin
monomer
acrylate
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张英强
单昌礼
闫雅贤
王晨蕾
李烨
李静怡
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Shanghai Institute of Technology
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Shanghai Institute of Technology
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1433Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14Polycondensates modified by chemical after-treatment
    • C08G59/1433Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461Unsaturated monoacids
    • C08G59/1466Acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C08G65/3322Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/337Polymers modified by chemical after-treatment with organic compounds containing other elements
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D171/00Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D171/02Polyalkylene oxides
    • C09D171/03Polyepihalohydrins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
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Abstract

The invention discloses a kind of long-acting weather-resistant type anticorrosive paint water-base resin, calculate, be made up of 50 80 parts of epoxy resin, 50 80 parts of chlorinated polyether resin, 50 80 parts of functional fluoropolymer monomer, 50 80 parts of acrylate monomer, 100 200 parts of solvents, 5 30 parts of modified crosslinking monomer, 0.05 0.1 parts of polymerization inhibitor and 100 200 parts of deionized water by weight.Present invention also offers the preparation method of above-mentioned long-acting weather-resistant type anticorrosive paint water-base resin.The features such as long-acting weather-resistant type anticorrosive paint water-base resin of the present invention has good anti-corrosive properties, good weatherability;The features such as anticorrosive paint prepared therefrom has preferable anti-corrosive properties, weatherability, can be widely applied to the anti-corrosion protection of the technical fields such as chemical industry, extra large construction equipment, naval vessel.

Description

A kind of long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof
Technical field
The invention belongs to technical field of polymer materials, it is related to a kind of resin, specifically a kind of long-acting weather resistant is prevented Rotten aqueous coating resin and preparation method thereof.
Background technology
In recent years, as Chinese national economy is fast-developing, the fields such as automobile, petrochemical industry, ship, pipeline, aviation have been driven Fast development.It is badly in need of the protection that High Performance Corrosion Protective Coatings are corroded to it.Conventional solvent-borne type anticorrosive paint, such as chlorination rubber The material that glue, epoxy coating, acrylate paint, polyurethane coating etc. can be very good to use above field carries out anticorrosion Protection.But with attention both at home and abroad in environmental protection, the development of anticorrosive coating with it is pollution-free, nuisanceless, save the energy, Economical and efficient is principle, develops new environmentally friendly anticorrosive paint system extremely urgent.It is aqueous to apply compared with solvent based coating Material has many advantages, such as that such as low VOC contents, few smell is nonflammable, using safety, can wash by water.At present With water-base resin be mainly water-and acrylate in aqueous long-acting weather-resistant type anticorrosive paint, it is aqueous fluorine-containing function monomer, aqueous poly- The principal items such as urethane resin, water-based fluorocarbon resin, these resins have that antiseptic effect is not good, water resistance is not good, adhesive force not Good the problems such as, single resin is difficult to the need for meeting long-acting weather-proof anticorrosive paint.
Based on background above, it is necessary to develop a kind of environmentally friendly, performance close to solvent type long-acting weather-resistant type anticorrosive paint water Property resin and preparation method thereof.
The content of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of long-acting weather-resistant type anticorrosive paint with aqueous Resin and preparation method thereof, described this long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof will solve existing There is the technical problem that antiseptic effect is not good, water resistance is not good, adhesive force is not good in the resin in technology.
The invention provides a kind of long-acting weather-resistant type anticorrosive paint water-base resin, calculate by weight, its raw material group Into and content it is as follows:
50-80 parts of epoxy resin;
50-80 parts of chlorinated polyether resin;
50-80 parts of functional fluoropolymer monomer;
50-80 parts of acrylate monomer;
100-200 parts of solvent;
5-30 parts of modified crosslinking monomer;
0.05-0.1 parts of polymerization inhibitor;
100-200 parts of deionized water;
Wherein:Described epoxy resin be E-12 glycidyl ether type epoxies resin, E20 glycidyl ether type epoxies resin, E44 glycidyl ether type epoxies resin, E51 glycidyl ether type epoxies resin, glycidyl ester epoxy resin, shrink Any one in glycerine amine epoxy resin, linear aliphatic epoxy resin or alicyclic based epoxy resin or two kinds Combination above;
Described chlorinated polyether resin is domestic MP45 resins;
Described functional fluoropolymer monomer is acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, the fluorine propyl ester of acrylic acid five, methyl The fluorine propyl ester of acrylic acid five, methacrylic acid octafluoro pentyl ester, the fluorine nonyl ester of methacrylic acid 17 or the fluorine last of the ten Heavenly stems of methacrylic acid 19 Any one in ester or two or more combinations;
Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, i-butyl Ester, tert-butyl acrylate, acrylic acid-2-ethyl caproite, n-octyl, decyl acrylate, 2-Hydroxy ethyl acrylate, In 2-hydroxypropyl acrylate, acrylic acid -2- ethoxy ethyl esters, cyclohexyl acrylate or isobornyl acrylate monomer Any one or two or more combinations;
Described modified crosslinking monomer is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid Ester, three(2- ethoxys)Isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris third Olefin(e) acid ester, third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane tris acrylic acid Ester, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester Any one or two kinds in mono acrylic ester, epoxy silicone monomer, silicone acrylate or vinyl ethers monomer with On combination;
Described solvent be ethylene glycol diethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, propylene glycol monomethyl ether, ethanol, butanol, One or more mixtures in butyl ether, isopropyl ether or methyl tertiary butyl ether(MTBE), dioxane or ethyleneglycol monophenylether;
Described polymerization inhibitor is hydroquinones, 2- TBHQs, 2,5- di-tert-butyl hydroquinones, 1,4-benzoquinone, methyl Any one in quinhydrones or MEHQ or two or more combinations;
Further, above-mentioned long-acting weather-resistant type anticorrosive paint is 500-3000mPa.s with the viscosity at its 25 DEG C of water-base resin, Outward appearance is the white emulsion of blueing, and storage at room temperature stability is more than half a year.
Further, described solvent is any in propylene glycol monomethyl ether, butyl glycol ether, acetone, butanone or ethanol One or more kinds of combinations.
Present invention also offers the preparation method of above-mentioned long-acting weather-resistant type anticorrosive paint water-base resin, including following step Suddenly:Functional fluoropolymer monomer, chlorinated polyether resin, epoxy resin, polymerization inhibitor and solvent are added in a reaction vessel, heats and stirs Mix, be warming up to 100-110 DEG C and when functional fluoropolymer monomer is completely dissolved, add acrylate monomer, the mixing of modified crosslinking monomer After solution, completion of dropping, 115-120 DEG C or so reaction is warming up to, the lower h of constant temperature 3 ~ 5 of stirring stops heating, treats that temperature is dropped to 40 ~ 50 DEG C, regulation pH value is 7 ~ 8, adds deionized water and quickly stirs, the h of constant temperature 0.5 ~ 2 produces long-acting weather resistant anti-corrosion Aqueous coating resin.
The long-acting weather-resistant type anticorrosive paint water-base resin of the present invention, the functional fluoropolymer list by acrylic ester grafted modification Body, chlorinated polyether resin are simultaneously acted on through Water-borne modification, the water-base resin is had good film forming and Corrosion Protection, using crosslinking Agent makes water-base resin complete a certain degree of crosslinking, further improves intensity, decay resistance, simultaneously because prepared Aqueous macromolecular the features such as have non-volatile, nontoxic, therefore obtained water-base resin is nontoxic to environment.
The long-acting weather-resistant type anticorrosive paint water-base resin of the present invention, outward appearance is the white emulsion of blueing, and environmental protection, room temperature is deposited Store up stability and be more than half a year.The NDJ-1 rotation viscometers provided using the sharp bearing device Manufacturing Co., Ltd in Shanghai, pass through GB/ T2794-2013,《The measure list cylinder rotary viscosimeter method of adhesive viscosity》, detected under conditions of 25 DEG C of room temperature, Its viscosity is 500-3000mPa.s.A kind of preparation method of long-acting weather-resistant type anticorrosive paint water-base resin of the present invention, due to Reaction condition is simple, and reaction method is ripe, therefore preparation technology is simple, suitable for large-scale production.
The present invention is compared with prior art, and its technological progress is significant.Approached the invention provides a kind of environmental protection, performance Solvent type long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof.The long-acting weather-resistant type anticorrosive paint of the present invention is used Water-base resin water resistance is excellent, anticorrosion ability is good.Anticorrosive paint prepared therefrom has good, good weatherability of antiseptic property etc. Feature, can be widely applied to the anti-corrosion protection of the technical fields such as chemical industry, extra large construction equipment, naval vessel.
Brief description of the drawings
Fig. 1 is that the long-acting weather-resistant type anticorrosive paint water-base resin of embodiment 1 passes through infrared chromatograph(U.S. Nicolet The type of company 380)Carry out the infrared spectrogram obtained by infrared spectrum analysis.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available, Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows:
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of long-acting weather-resistant type anticorrosive paint water-base resin, is calculated by weight, and its raw material composition and content are as follows:
50 parts of epoxy resin
50 parts of chlorinated polyether resin
50 parts of functional fluoropolymer monomer
50 parts of acrylate monomer
100 parts of solvent
5 parts of modified crosslinking monomer
0.05 part of polymerization inhibitor
100 parts of deionized water;
Wherein:Described epoxy resin is E51;
Described chlorinated polyether resin is domestic MP45 resins;
Described functional fluoropolymer monomer is acrylic acid trifluoro ethyl ester, methacrylic acid octafluoro pentyl ester in mass ratio 1:3 compositions it is mixed Compound;
Described acrylate monomer is acrylic acid, methyl acrylate, n-butyl acrylate, 2-Hydroxy ethyl acrylate by matter Amount is than being 1:10:10:The mix monomer of 3 compositions;
Described modified crosslinking monomer is selected from diethylene glycol diacrylate, ethoxylated bisphenol A dimethylacrylates and presses quality Than 1:The mixture of 1 composition;
Described solvent is propylene glycol monomethyl ether, butanol, dioxane in mass ratio 1:0.3:The mixture of 0.2 composition;
Described polymerization inhibitor is hydroquinones;
In the present embodiment, a kind of preparation method of long-acting weather-resistant type anticorrosive paint water-base resin specifically includes following steps:
According to formula, by 50 parts of chlorinated polyether resins, 50 parts of functional fluoropolymer monomers, 50 parts of epoxy resin, 0.05 part of polymerization inhibitor and 100 parts Solvent is added in 500ml flask with four necks,round bottom, is heated and is stirred, is warming up to 100 DEG C or so and treats that functional fluoropolymer monomer is completely dissolved When, the mixed solution that 50 parts of crylic acid ester mixture monomers, 5 parts of modified crosslinking monomers are constituted, completion of dropping are added dropwise with certain speed Afterwards, 115 DEG C or so reactions are warming up to, the lower h of constant temperature 3 of stirring stops heating, treats that temperature drops to 40 DEG C, regulation pH value is 7, is added 100 parts of deionized waters are simultaneously quickly stirred, the h of constant temperature 0.5, and vacuum distillation removes solvent, produces long-acting weather-resistant type anticorrosive paint water Property resin.
The long-acting weather-resistant type anticorrosive paint water-base resin of above-mentioned gained passes through infrared chromatograph(Nicolet companies of the U.S. 380 types)Infrared spectrum analysis is carried out, the infrared spectrogram of gained is as shown in figure 1, from figure 1 it appears that 3450.53cm-1 It is the stretching vibration absworption peak of O-H keys;
2922.94 cm-1It is for chlorinated polyether resin-CH2The stretching vibration absworption peak of middle c h bond;
1259.74cm-1Locate the stretching vibration absworption peak for C-F;
1084.35cm-1Locate the stretching vibration absworption peak of the ether-oxygen bond C-O for chlorinated polyether resin;
1188.18cm-1Locate the stretching vibration absworption peak of the C-O for acrylate, this explanation acrylic monomer oneself through successfully connecing Branch is on chlorinated polyether resin;
Indicated above, the anticorrosive paint obtained by the present invention is successfully prepared with water-base resin;
Long-acting weather-resistant type anticorrosive paint water-base resin obtained by above-described embodiment, using the sharp bearing device Manufacturing Co., Ltd in Shanghai The NDJ-1 rotation viscometers of offer, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter of adhesive viscosity Method》, detected under conditions of 25 DEG C of room temperature, its viscosity is 500mPa.s.
Further, a kind of long-acting weather-resistant type anticorrosive paint water-base resin of the present embodiment, through solid with water-based isocyanate Agent film-forming, acid resistance and alkali resistance test, acid resistance have been carried out to the film(96h)Enter according to GB/T 1763-1989 Row detection, appearance of film is unchanged;Alkali resistance(96h)Detected that appearance of film is unchanged according to GB/T 1763-1989.And The ageing properties of coating are evaluated, carried out by GB/ T9277, coating is protected after 600 h artificial accelerated aging tests Light rate is more than 83 %, and coating is non-foaming, do not peel off, flawless.
With explanation higher after water-base resin film, it is a kind of to the long-acting weather-resistant type anticorrosive paint of the gained of above example 2 Long-acting effect weather-resistant type anticorrosive paint resin, antiseptic effect is good.
Embodiment 2
A kind of long-acting weather-resistant type anticorrosive paint water-base resin, is calculated by weight, and its raw material composition and content are as follows:
80 parts of epoxy resin
80 parts of chlorinated polyether resin
80 parts of functional fluoropolymer monomer
80 parts of acrylate monomer
200 parts of solvent
30 parts of modified crosslinking monomer
0.1 part of polymerization inhibitor
200 parts of deionized water;
Wherein:Described epoxy resin is E-44;
Described chlorinated polyether resin is domestic MP45 resins;
Described functional fluoropolymer monomer is the fluorine propyl ester of methacrylic acid five, methacrylic acid octafluoro pentyl ester in mass ratio 1:1 composition Mixture;
Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, acrylic acid -2- hydroxyls Base propyl ester in mass ratio 1:8:10:5:The mix monomer of 5 compositions;
Described modified crosslinking monomer is selected from diethylene glycol diacrylate, tetramethylol methane tetraacrylate, isobomyl acrylate Ester in mass ratio 1:2:The mixture of 1 composition;
Described solvent is butyl glycol ether, diethylene glycol dimethyl ether, butanol in mass ratio 1:1:The mixture of 0.3 composition;
Described polymerization inhibitor is MEHQ.
In the present embodiment, a kind of preparation method of long-acting weather-resistant type anticorrosive paint water-base resin specifically includes following step Suddenly:
According to formula, by 80 parts of chlorinated polyether resins, 80 parts of functional fluoropolymer monomers, 80 parts of epoxy resin, 0.1 part of polymerization inhibitor and 200 parts Solvent is added in 500ml flask with four necks,round bottom, is heated and is stirred, is warming up to 110 DEG C or so and treats that functional fluoropolymer monomer is completely dissolved When, the mixed solution that 80 parts of crylic acid ester mixture monomers, 30 parts of modified crosslinking monomers are constituted, completion of dropping are added dropwise with certain speed Afterwards, 120 DEG C or so reactions are warming up to, the lower constant temperature 5h of stirring stops heating, treats that temperature drops to 50 DEG C, regulation pH value is 8, is added 200 parts of deionized waters are simultaneously quickly stirred, the h of constant temperature 3, and vacuum distillation removes solvent, produce long-acting weather-resistant type anticorrosive paint with aqueous Resin.
Long-acting weather-resistant type anticorrosive paint water-base resin obtained by above-described embodiment, using the sharp bearing device Manufacturing Co., Ltd in Shanghai The NDJ-1 rotation viscometers of offer, by GB/T2794-2013,《The measure list cylinder rotary viscosimeter of adhesive viscosity Method》, detected under conditions of 25 DEG C of room temperature, its viscosity is 3000mPa.s.
Further, a kind of long-acting weather-resistant type anticorrosive paint water-base resin of the present embodiment, through solid with water-based isocyanate Agent solidifies, and acid resistance is carried out to film and alkali resistance is tested, acid resistance(96h)Detected according to GB/T 1763-1989, Appearance of film is unchanged;Alkali resistance(96h)Detected that appearance of film is unchanged according to GB/T 1763-1989.Coating it is old Change to evaluate and carried out by GB/ T9277, coating is after 600 h artificial accelerated aging tests, and light-protection rate is more than 78 %, and coating does not rise Steep, do not peel off, flawless.
With explanation higher after water-base resin film, it is a kind of to the long-acting weather-resistant type anticorrosive paint of the gained of above example 2 Long-acting effect weather-resistant type anticorrosive paint resin, antiseptic effect is good.
In summary, long-acting weather-resistant type anticorrosive paint of the invention is used with water-base resin by containing fluorine structure, third Olefin(e) acid ester graft modification chlorinated polyether resin reacts what is prepared through Water-borne modification, and water-base resin is completed necessarily by using crosslinking agent The crosslinking of degree, with preferable Long-effect corrosion-resistant performance, simultaneously because prepared aqueous macromolecular have it is non-volatile, nontoxic The features such as, therefore obtained water-base resin is nontoxic to environment, the water-base resin is a kind of long-acting weather resistant anticorrosion water-soluble Resin.
Above said content is only the basic explanation under present inventive concept, and according to appointing that technical scheme is made What equivalent transformation, all should belong to protection scope of the present invention.

Claims (4)

1. a kind of long-acting weather-resistant type anticorrosive paint water-base resin, it is characterised in that calculate by weight, its raw material composition and Content is as follows:
50-80 parts of epoxy resin;
50-80 parts of chlorinated polyether resin;
50-80 parts of functional fluoropolymer monomer;
50-80 parts of acrylate monomer;
100-200 parts of solvent;
5-30 parts of modified crosslinking monomer;
0.05-0.1 parts of polymerization inhibitor;
100-200 parts of deionized water;
Wherein:Described epoxy resin be E-12 glycidyl ether type epoxies resin, E20 glycidyl ether type epoxies resin, E44 glycidyl ether type epoxies resin, E51 glycidyl ether type epoxies resin, glycidyl ester epoxy resin, shrink Any one in glycerine amine epoxy resin, linear aliphatic epoxy resin or alicyclic based epoxy resin or two kinds Combination above;
Described chlorinated polyether resin is domestic MP45 resins;
Described functional fluoropolymer monomer is acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, the fluorine propyl ester of acrylic acid five, methyl The fluorine propyl ester of acrylic acid five, methacrylic acid octafluoro pentyl ester, the fluorine nonyl ester of methacrylic acid 17 or the fluorine last of the ten Heavenly stems of methacrylic acid 19 Any one in ester or two or more combinations;
Described acrylate monomer is acrylic acid, methyl acrylate, ethyl acrylate, n-butyl acrylate, i-butyl Ester, tert-butyl acrylate, acrylic acid-2-ethyl caproite, n-octyl, decyl acrylate, 2-Hydroxy ethyl acrylate, In 2-hydroxypropyl acrylate, acrylic acid -2- ethoxy ethyl esters, cyclohexyl acrylate or isobornyl acrylate monomer Any one or two or more combinations;
Described modified crosslinking monomer is selected from double pentaerythritol methacrylate, diethylene glycol diacrylate, tetrahydrofuran third Olefin(e) acid ester, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylates, two-trimethylolpropane tetra acid Ester, three(2- ethoxys)Isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane tris third Olefin(e) acid ester, third oxidation trimethylolpropane trimethacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane tris acrylic acid Ester, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester Any one or two kinds in mono acrylic ester, epoxy silicone monomer, silicone acrylate or vinyl ethers monomer with On combination;
Described solvent be ethylene glycol diethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, propylene glycol monomethyl ether, ethanol, butanol, One or more mixtures in butyl ether, isopropyl ether or methyl tertiary butyl ether(MTBE), dioxane or ethyleneglycol monophenylether;
Described polymerization inhibitor is hydroquinones, 2- TBHQs, 2,5- di-tert-butyl hydroquinones, 1,4-benzoquinone, methyl Any one in quinhydrones or MEHQ or two or more combinations.
2. long-acting weather-resistant type anticorrosive paint water-base resin according to claim 1, it is characterised in that viscous at its 25 DEG C Spend for 500-3000mPa.s, outward appearance is the white emulsion of blueing, storage at room temperature stability is more than half a year.
3. long-acting weather-resistant type anticorrosive paint water-base resin according to claim 1, it is characterised in that described solvent is Any one in propylene glycol monomethyl ether, butyl glycol ether, acetone, butanone or ethanol or two or more combinations.
4. the preparation method of the long-acting weather-resistant type anticorrosive paint water-base resin described in claim 1, it is characterised in that including such as Lower step:Functional fluoropolymer monomer, chlorinated polyether resin, epoxy resin, polymerization inhibitor and solvent are added in a reaction vessel, heated And stir, it is warming up to 100-110 DEG C and when functional fluoropolymer monomer is completely dissolved, adds acrylate monomer, modified crosslinking monomer After mixed solution, completion of dropping, 115-120 DEG C or so reaction is warming up to, the lower h of constant temperature 3 ~ 5 of stirring stops heating, treats temperature 40 ~ 50 DEG C are dropped to, regulation pH value is 7 ~ 8, add deionized water and quickly stir, the h of constant temperature 0.5 ~ 2 produces long-acting weather resistant Anticorrosive paint water-base resin.
CN201710456801.2A 2017-06-16 2017-06-16 A kind of long-acting weather-resistant type anticorrosive paint water-base resin and preparation method thereof Pending CN107267034A (en)

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CN108129966A (en) * 2017-12-19 2018-06-08 海洋化工研究院有限公司 A kind of chlorinated polyether emulsion water-based anticorrosive paint
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CN113683719A (en) * 2021-08-17 2021-11-23 上海应用技术大学 Multifunctional water-based emulsion
CN113583546A (en) * 2021-09-14 2021-11-02 安徽新大陆特种涂料有限责任公司 Production process of epichlorohydrin blended rubber-plastic emulsion anticorrosive paint

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Application publication date: 20171020